Permissible Limits Research Articles

Characterization of hydrogeochemical elements in determining the ground water quality for irrigation potential and its correlation with climatological parameters of chennai basin aquifer system, southern india.

An attempt has been made to comprehend the ground water quality and climate impacts of the Chennai River basin, which is aimed at its main socio-economic growth of the state of Tamil Nadu. The ground water samples collected from the study area were analyzed for its hydrogeochemical elements. The ground water quality and irrigation suitability were determined using several water quality assessment metrics. Ground water is extensively utilized for irrigation in the entire basin area for the past two decades, especially in the 38 over-exploited Firkas out of the 109 Firkas of the basin. It is inferred that the phreatic aquifer ground water quality is fresh in about 20%, as indicated by the EC value (< 750µs/cm) at 25°C. In about 63% of the ground water indicating the moderately fresh showing the EC varies between 751 and 2250µs/cm at 25°C, 11% of ground water exerted an EC ranging between 2251 and 3000µs/cm at 25°C indicating that the ground water is slightly mineralized, and in about 6% of groundwater, the EC is > 3000µs/cm at 25°C indicating that the ground water is highly mineralized. There were no water samples that exceeded the permissible limit of chloride either in phreatic aquifer or in fracture aquifer. The changes in rainfall frequency and atmospheric temperature affect the ground water movement and storage directly and indirectly. Similarly, the temperature data shows a positive relationship with the concentration of fluoride and nitrate ions in the water.

Evaluating monsoon season heavy metal contamination in groundwater of Uttar Dinajpur District using pollution indices and Principal Component analysis

Heavy metal contamination in groundwater poses significant environmental and public health challenges globally. This study investigates the presence and distribution of heavy metal contamination in groundwater within Uttar Dinajpur District, India, focusing on zinc (Zn), manganese (Mn), copper (Cu), iron (Fe), and lead (Pb). Groundwater samples were collected and analysed for heavy metal concentrations, and statistical analyses, including descriptive statistics, histograms, box plots, Heavy Metal Pollution Index (HPI) analysis, Metal Index (MI) analysis, and Principal Component Analysis (PCA), were conducted to assess contamination levels, spatial distribution, and potential sources. Results indicate varying levels of heavy metal contamination across the district, with manganese, iron, and lead frequently exceeding permissible limits, posing potential health risks. The PCA revealed common sources and relationships among heavy metals, aiding in understanding contamination patterns. The study underscores the importance of continuous monitoring and targeted interventions to manage heavy metal contamination in groundwater, emphasizing the need for further research to develop effective mitigation strategies.

Health and ecological risk assessment for arsenic contaminated groundwater in Shahpur and Koilwar Blocks, Bhojpur district, Bihar

ABSTRACT Arsenic-contaminated groundwater is a threat to the human population, leading to the occurrence of different cancers and skin problems. A health risk assessment study was conducted using arsenic data from groundwater sampled at Shahpur and Koilwar blocks in Bhojpur district, Bihar. The Inductively Coupled Plasma Mass Spectrophotometry (ICP-MS) analysis of 49 tube well samples (24 from Shahpur; 25 from Koilwar) showed that 22.45% of them had arsenic concentrations above the permissible limit (10 µg/l as recommended by the World Health Organization (WHO)) during the pre-monsoon with a maximum of 153 µg/l at Shahpur and 49 µg/l at Koilwar. The United States Environmental Protection Agency (USEPA) guidelines were applied to calculate the cancer and non-cancer risks. The Hazard quotient (HQ) and Incremental Lifetime Cancer Risk (ILCR) indicated an adverse risk (HQ > 1 and ILCR > 10−6), with Shahpur having three times higher amounts of more toxic arsenic(III). The Water Quality Index (WQI) obtained from chemical analysis indicated Shahpur having fewer poor water quality sites, with its percent ratio to Koilwar being 8:10. Ecological risk indices (Ei and RI) and Nemerow pollution index (NPI) implied moderate to extremely high risks (RI > 600 and 2.5 <NPI≤11). This study’s output necessitates future groundwater monitoring in the arsenic hotspots.

Simultaneous removal of heavy metals and Escherichia coli from water using silver-doped hydroxyapatite-coated activated carbon nano composite-alginate beads

The scarcity of clean water due to heavy metal and microbial contamination is a global issue. In many parts of the world, heavy metals such as Pb, Cd, and U, along with bacteria like Escherichia coli, have been found to exceed permissible limits in groundwater and other water sources that the public depends on for daily drinking water. To address this, we have synthesized a novel composite material consisting of Ag-impregnated hydroxyapatite-coated activated carbon nanoparticles embedded in alginate beads, for the simultaneous removal of heavy metals (U, Pb, and Cd) and Escherichia coli from drinking water. The material's efficiency was evaluated through a series of batch and column experiments. Batch studies indicate 90 % sequestration of U within 5 hours and Pb and Cd within 7 hours, while Escherichia coli (107 cfu/mL) was eradicated instantly. The study confirms that sorption follows pseudo-second-order kinetics via chemisorption and ion-exchange mechanisms. Fixed-bed column studies, using a logistic growth model, showed strong agreement between theoretical and experimental parameters for the Bohart-Adams, Thomas, and Yoon-Nelson models. The beads demonstrated a high affinity for heavy metals, achieving complete removal and disinfection within an empty bed contact time of 1.12 minutes. Reusability studies indicate that even after the third regeneration and reuse cycle, removal efficiency remained about 95 % for U and Pb, and 85 % for Cd. Furthermore, the effects of variations in water quality parameters such as pH, dissolved carbonates, humic acid, and ionic strength (except for Cd) on removal efficiency were minimal. In summary, the study revealed that the Ag-impregnated hydroxyapatite-coated activated carbon nanoparticles embedded in alginate beads are an efficient, sustainable, and cost-effective material for the simultaneous removal of Pb, Cd, U, and Escherichia coli from water with diverse physicochemical properties.

The Study of the Balancing Process for Starting Rotors in Heavy-Duty Vehicles: An Industrial Application

In the heavy-duty vehicle industry, unbalance in the armature is one of the most common problems affecting starters’ performance and durability. This research presents a comprehensive study to improve the balancing process for starting rotors in heavy-duty vehicles. The complete manufacturing process of armatures was analyzed to understand the contribution of assembly processes to unbalancing. The analysis revealed that the primary factor leading to high unbalance in these parts is the misalignment of conductors within the armature winding. During assembly, these conductors experience axial movements, resulting in non-uniform mass distribution and causing unbalanced values ranging from 150 to 350 g·mm. These values surpass the permissible limit, making rectification during the balancing process at the end of the assembly impossible. Consequently, a novel alignment tool was designed to address this issue, significantly reducing the effect and achieving the maximum allowable unbalance of 100 g·mm. This allowed the balancing machine used in the process to correct the initial unbalance of the reinforcements in a single work cycle, improving operation efficiency by about 15%.

Accumulation of Heavy Metals in Tissues of Oreochromis Mossambicus from the uMgeni River and Human Health Risk Assessment

Metal enrichment in aquatic ecosystems has compromised the potential of fish to enhance food security. The uMgeni River drains urban and industrialized catchment and flows through economically disadvantaged rural communities that opt for fish to supplement their protein needs. However, there are uncertainties on the safety of consuming fish from the uMgeni River. The present study aims to explore metal distribution between the water, sediment, and tissues of the preferred Oreochromis mossambicus, and evaluate whether concentrations in the muscle are safe for human consumption. The water, sediment, and fish samples were collected from Inanda and Nagle dams, and metal concentrations were analysed using inductively coupled plasma mass spectrometry. Alkaline pH was observed at both dams and metals were below detectable level in the water column. Even though metal concentrations in the water column were below detectable levels, significant concentrations were found in the sediment. No consistent trend in metal concentrations was observed across tissues, but higher levels were generally found in the liver, followed by the gill, and then the muscle. Nickel (Ni) and lead (Pb) exhibited concentrations exceeding the permissible limit for human consumption. Similarly, the target hazard quotient exceeded the threshold of 1 for Pb, chromium (Cr), and antimony (Sb) at both dams with Inanda Dam showing higher indices for Sb and Pb. The carcinogenic risk for the three metals was also found to be higher than 10–6. These findings suggest that consumption of O. mossambicus from the uMgeni River should be limited to no more than 150 g per week.

Accurate Oil Temperature Prediction Model and Oil Refilling Parameters Optimization for Hydraulic Closed-Circuit System

Oil temperature plays a crucial role in hydraulic closed-circuit systems (HCS), and conventional thermal equilibrium models and coupled simulation models face challenges in terms of accuracy, efficiency, and cost when calculating oil temperature. This study introduces an innovative HCS oil temperature precise prediction model and oil refilling parameter optimization method. The initial sample space was determined through a Sobol sensitivity analysis and improved Latin hypercube sampling, leading to the development of a combinatorial agent model (CAM) suitable for oil temperature prediction with superior accuracy and stability compared to other methods. Based on CAM, the optimal oil refilling flow rates under various operational conditions are computed. To validate the efficacy of the theoretical analysis, an HCS experiment platform was established. The data indicates that the temperature prediction error range of the CAM model falls between 0.30 °C and 1.05 °C, and optimizing the oil refilling flow rate can effectively enhance system efficiency while ensuring that the oil temperature remains within permissible limits. The research methodology and findings are applicable in engineering practice and can be extended to optimize the design of other hydraulic systems.

Impact of fertilizer levels and treated sewage water on heavy metal uptake,growth, agrometeorological indices, and quality of wheat

A field experiment was conducted at Vegetable Research Farm, CCS Haryana Agricultural University, Hisar, Haryana, India to study the agro-physiological, agrometeorological, heavy metals, and quality parameters of wheat under different fertilizer levels and treated sewage water application on sandy loam soil. Among varieties, signifi- cantly higher yield attributes viz effective tillers and yield were observed with variety HD 3086 being at par with WH 1105 over HD 2967, WH 1124, and DBW 90. A higher value of agrometeorological indices viz. thermal (2.67 kg/ ha/0 C day), helio-thermal (0.77 kg/ha degree day hr), and photothermal (0.23 kg/ha degree day hr) use efficiencies were found with variety HD 3086 over other varieties. Among fertilizer levels, significantly higher yield attributes and grain yield were found with 125 % RDF over 75 and 100 % RDF. Significantly higher values of thermal, heliothermal, and photothermal use efficiencies were observed with the application of 125 % RDF over 75 and 100 % RDF Neither the varieties nor the fertility levels bring any significant variation in normalized difference vegeta- tion index and canopy temperature. However, varying levels of fertilizer did have a substantial impact on chloro- phyll content. Similarly, quality parameters viz. hectoliter weight and protein content were not affected significantly by varieties and fertilizer levels. However, sedimentation value was significantly affected by varieties and fertilizer levels. Heavy metal concentration was found in wheat grain, but these were within the permissible limit.

تقدير المعادن الثقيلة في بعض أنواع مختلفة الكعك المجمعة من أسواق مدينة البيضاء – ليبيا

Heavy metals are chemical elements with high density and atomic weight. Despite their widespread use in various industries and applications, they pose significant risks to the environment and public health if not handled properly. This study was conducted to estimate the concentration of some different elements in different types of cakes, where cake samples were collected from different shops from Al-Bayda city, the study dealt with six types of cakes. Flame photometer was used to estimate sodium and potassium salts and spectrophotometer to estimate heavy elements. The samples were digested using the digestion method using HNO1 and HCl and heating until the brown oxides evaporate and we get half the amount. The results showed that the concentration of sodium, chromium, iron and copper is below the permissible limits and the concentration of potassium is higher than the permissible limits and the results also showed that the collected cake samples do not contain lead and a discrepancy was observed .The potassium concentration ranged from (541. 50 to 763.25), sodium concentration ranges from (1.34 to 3.52), iron concentration ranges from (1.72 to 7.16), copper concentration ranges from (44.36 to 67.62), and chromium concentration ranges from (0 to 0.25). The study could be expanded to include other types of cakes, such as filled cakes to provide a more comprehensive picture of heavy metal contamination in these products. More heavy metals, such as mercury, arsenic, and cadmium, could be analyzed to more accurately assess health risks. Keywords: Heavy metals, Cakes types, market and Al-Bayda – Libya.

Water quality assessment using national Water Quality Index (WQI): a case study of the Song Be River, Bing Duong Province, Vietnam

Abstract The Song Be River is a vital water source in Binh Duong Province, Vietnam, playing a crucial role in supplying water for domestic use and agriculture, as well as supporting local ecosystems. However, due to the recent rapid economic and industrial growth, the river’s water quality has encountered significant challenges, particularly from the improper discharge of untreated wastewater from various sources and activities. This study conducts a comprehensive analysis of the Song Be River’s water quality by employing the Water Quality Index (WQI) in conjunction with Geographic Information System (GIS) technology. Subsequently, several strategies are also proposed to effectively manage and enhance the water quality of the Song Be River. Over the period from March 2023 to March 2024, 52 samples were collected from four monitoring points (SB1, SB2, SB3, and SB4) along the Song Be River, with a frequency of once per month. All analytical parameters (such as NH4 +_N: 0.01–0.61 mg l−1, NO2 −_N: 0.014–0.03 mg l−1, Fe: 0.01–0.81 mg l−1, Chemical Oxygen Demand (COD): 4–26 mg l−1, Dessolved Oxygen (DO): 3.8–6.6 mg l−1, Suspendid Solids (SS): 5–69 mg l−1, Coliform: 1200–4300 MPN/100 ml, Total phosphorous: 0.01–0.08 mg l−1 and Total nitrogen: 1.16–4.5 mg l−1) fell within the permissible limits according to the Vietnamese National Standards. Furthermore, the WQI ranged from 73 to 100, indicating that the water quality of The Song Be River is good and suitable for domestic use.

The elemental variance between the "rice" and "non-rice" portions of Maifanitum and its health risk assessment

BackgroundMaifanitum, a mineral used in Chinese medicine, was first documented during the Song Dynasty (960-1279). Historical records suggest its multifaceted therapeutic properties, including detoxification and stasis resolution, necrosis removal and tissue regeneration, diuretic and calculi dissolution and prolonging life. The concentration of elements in Maifanitum may vary depending on its origin, different parts, which can affect its effectiveness in different fields of applications. Therefore, the analysis of elements in Maifanitum and the subsequent health risk assessment have been conducted. This provides an important basis for the quality control and application safety of Maifanitum. MethodThe analytical techniques employed in this study are inductively coupled plasma mass spectrometry (ICP-MS) and inductively coupled plasma optical emission spectrometry (ICP-OES), utilized for the quantitative assessment of 60 elements (Refer to Appendix 1) within Maifanitum samples. Based on the test results, chemometric methods are employed to evaluate the characteristics and differences in elemental concentration from different sources and locations. Additionally, a preliminary health risk assessment is conducted for Maifanitum from different origins and various parts. ResultsWe have established a fingerprint of the elements within Maifanitum, demonstrating a commendable level of similarity. The findings from hierarchical cluster analysis（HCA） corroborated with those from principal component analysis (PCA), collectively unveiling a systematic profile of elemental disparities between Maifanitum samples of diverse origins and applications. It also revealed that there are differences in the concentration of Al, Ga, Be, Hf, Na, Sn, Ti, Zr, Gd, Tb, Sr, Pb, Ce, Ba and other elements in different parts of Maifanitum. While Cd, As, and Cu levels in all samples were within the permissible limits as defined by the Chinese Pharmacopeia, Pb concentrations in the majority of samples were found to surpass these standards, albeit slightly in the ''non-rice'' fraction. The assessment of both beneficial and deleterious elements indicates that the ''non-rice'' fraction of Maifanitum possesses superior quality attributes. Moreover, the overall concentration of rare earth elements in Maifanitum is substantially below the established lower threshold for daily human consumption, with no immediate evidence suggesting any adverse health risks. ConclusionThis study provides a basis for the quality control and safety evaluation of Maifanitum in clinical use.

Continuous beta monitoring technology for uncontrolled radiological release in underwater using integrated beta and gamma detection system

A monitoring system capable of in-situ beta detection has been developed to address the potential risks associated with radioactive releases from nuclear sites. Although releases are controlled within permissible limits and follow strict protocols to minimize environmental and public health impacts, incidents of uncontrolled releases due to human or mechanical failures have occurred, resulting in contamination of underground water sources. To improve response capabilities, transitioning from traditional sample-based monitoring to real-time monitoring of underground water is crucial. The system utilized an NaI(Tl) detector for gamma nuclides and two plastic scintillation detectors for beta nuclides. Beta detection was facilitated through a coincidence method involving the two plastic scintillators, with any influence from gamma radiation effectively mitigated using data from the NaI(Tl) detector. This configuration ensured accurate measurement of beta radiation by removing gamma contributions from the coincidence counts. The system, which was evaluated using detection experiments for beta nuclides 3H and 90Sr, achieved a minimum detectable activity that satisfied the criteria for restricting the intake, distribution, or consumption of 90Sr and 3H to 0.1 and 100 Bq/g, respectively, within 20 min.

Enhancing yields of Pleurotus ostreatus and Lentinula edodes mushrooms using water hyacinth (Eichhornia crassipes [Mart.] Solms) supplemented with locally available feedstock as substrate

This study assessed the performance of Pleurotus ostreatus and Lentinula edodes mushrooms on a variety of substrate combinations. Water hyacinth, rice husk, and cow dung were employed as substrates. Mushroom growth performance, yield, proximate composition, and mineral content were among the variables evaluated. The results indicate significant differences (p < 0.05) in spawn run duration, first harvest duration, total yield, and biological efficiency among the substrate combinations for the mushroom species. The substrate combination of 80% water hyacinth and 20% cow dung consistently exceeded the performances of others, demonstrating higher total yield (863.00 and 799.81 g/bag) and biological efficiency (88.51% and 82.03%) for P. ostreatus and L. edodes mushrooms, respectively. Proximate analysis results also demonstrated that this substrate combination produced mushrooms with higher protein (14.72 and 12.04%) and carbohydrate (55.11 and 58.05%) contents for P. ostreatus and L. edodes, respectively. P, K, Mg, Na, Ca, Fe, Zn, and Cd levels in P. ostreatus samples ranged from 1700 to 2700, 28100 to 39500, 1600 to 7800, 291.55 to 400.23, 310.37 to 372.70, 26.42 to 45.47, 61.87 to 70.40, and 1.13–1.25 mg/kg on average, respectively. The levels for P, K, Mg, Na, Ca, Fe, Zn, and Cd ranged from 19700 to 22700, 22500 to 25000, 2100 to 2500, 250.96 to 300.90, 284.66 to 296.19, 24.04 to 29.49, 74.03 to 83.98, and 1.31–1.45 mg/kg for L. edodes samples. The evaluated mushrooms grown on the various substrate combinations contain higher major and minor minerals needed in the human diet than toxic elements. This indicated that the evaluated edible mushrooms had high important mineral levels and could be considered a good source of vital elements. They are also very good at balancing nutrient supply scarcity, which is common in developing countries like Ethiopia. However, according to the World Health Organization's permissible limits for human intake, adequate attention and control of daily dietary intake is necessary for specific elements.

Evaluating Groundwater Quality for Drinking and Irrigation Purposes and Health Risk Assessment in West Midnapore District of West Bengal, India

Groundwater quality in the West Midnapore district of West Bengal, India is affected by anthropogenic activities as well as by water quality of Subarnarekha and Kangsabati rivers. This study aims to assess quality of groundwater and river water for drinking and irrigation usage, and assess the health risks of the people consuming the water across the rivers. The study also explores the groundwater-river water interaction. The river water and groundwater samples were collected three times during monsoon season from 14 sites across the rivers. The samples were analyzed for 11 water quality parameters, i.e., pH, total dissolved solids (TDS), total hardness (TH), major anions and cations, and iron (Fe). The groundwater was found slightly acidic (mean pH ~ 6.71) and correlated with nitrate concentrations. Most of the water quality parameters were found within their permissible limits of drinking water. However, elevated concentrations of potassium (K), ammonium (NH4), magnesium (Mg), phosphate (PO4), sodium (Na), and Fe were detected at some places, which were likely due to use of fertilizers. Water quality index (WQI), sodium absorption ratio (SAR), and percentage Na values were computed to evaluate the groundwater quality. The mean WQI value of 37.07 showed that the majority of groundwater samples met drinking water standards. Groundwater was also found suitable for irrigation (SAR ~ 0.26 to 1.62 meq L-1 and percentage Na ~ 13.10% to 78.12%). Health risk assessments suggested minimal immediate risks, though high Na levels in certain areas raised concerns. Piper plot showed that increased calcium concentrations in groundwater were mainly due to interactions between river water and groundwater. Overall, groundwater quality did not present any harmful health hazards to the community. The findings of this study can be instrumental for groundwater managers in identifying potential areas for treating groundwater quality.

Impact of lead and nickel contamination on metabolic health: Associations with diabetes mellitus in a pakistani cohort

Environmental exposure to heavy metals, particularly lead (Pb) and nickel (Ni), is implicated in chronic metabolic diseases, including diabetes mellitus (DM). This cross-sectional study assessed the Pb and Ni levels in groundwater using ICP-OES and urine samples collected from 2688 participants using ICP-MS. We aimed to establish the associations between Pb and Ni exposure and risk factors for DM and metabolic disorders. Groundwater analysis revealed the elevated levels of total dissolved solids, electrical conductivity, hardness, turbidity, Ni, and Pb, exceeding the WHO guidelines. The mean concentration of Pb in groundwater samples of study area was 0.025 mg/L which was higher than the WHO permissible limit of 0.01 mg/L. Similarly the mean concentration of Ni in groundwater samples of study area was 0.038 mg/L which was also higher than the WHO permissible limit of 0.02 mg/L. In human study, participants, categorized into Pb-detected and Ni-detected groups, exhibited significantly higher Pb and Ni levels and non-exposed non-diabetic groups. Ni-detected diabetics showed elevated Ni levels compared to non-exposed non-diabetics. Similarly, Pb-detected diabetics showed elevated Pb levels compared to non-exposed non-diabetics. These findings suggest a potential contribution of Pb and Ni exposure to DM development. The study also identified associations between heavy metal exposure and disruptions in various biomarkers related to DM, lipid profile, inflammation, oxidative stress, liver function, and kidney function. Pb-detected diabetics demonstrated elevated levels of glycemic index biomarkers, including fasting blood glucose (P < 0.0001) and HbA1c (P < 0.0001). Ni-detected diabetics exhibited increased inflammatory markers, such as CRP (P < 0.0001) and IL-6 (P < 0.0001). Both Pb and Ni exposure were associated with dyslipidemia, as indicated by elevated levels of total cholesterol (P < 0.0001) and LDL (P < 0.0001). Additionally, heavy metal exposure was linked to impaired liver and kidney function, supported by elevated levels of AST (P < 0.0001), ALT (P < 0.0001), creatinine (P < 0.0001), and blood urea nitrogen (P < 0.0001), with Pb exposure also associated with higher levels of MDA (P < 0.0001). Correlation analyses demonstrated significant associations between urinary Pb and Ni concentrations and various biomarkers related to DM and metabolic disorders. In conclusion, this study provides substantial evidence linking Pb and Ni exposure to the development of DM and metabolic disorders in a Pakistani population, emphasizing the need for strict regulations and preventive measures to reduce heavy metal contamination and safeguard public health. Future longitudinal studies and interventions are warranted to elucidate mechanistic links between heavy metal exposure and metabolic diseases.

Heavy metal contamination in Lebanese lettuce: Quantification and health risk assessment

Heavy metals (HM) contamination in food products is a major risk to public health. Lebanon is constantly suffering from unresolved environmental pollution issues, which have led to an increase in atmospheric deposition of contaminants in water and soil. This study aims to investigates the levels of HM in Lettuce products collected from different market regions in Lebanon. We also estimated the potential human exposure to HM through ingestion of lettuce. We used the Atomic Absorption Spectrophotometry to determine HM levels in the collected samples. Furthermore, we calculated the Metal Pollution Index (MPI) and the Hazard Quotient (HQ) to determine the expectance of adverse health effects in comparison to other countries. The results showed that Lead (Pb), Arsenic (As) and Chromium [Cr (III)] levels in the capital city exceeded the maximum allowable values set by FAO/WHO, whereas Palladium (Pd) was above the safety limit in all collected samples. The MPIs fluctuated over all investigated regions but remained below the critical value (of 1). However, the maximum As HQ exceeded the permissible limit by 186 % and the maximum Pb HQ value was higher than that of industrialized countries including China, Brazil, and Egypt. These findings prove that regular testing and monitoring are highly required to investigate the importance of human exposure to HM in Lebanon and any associated health impacts.

Surface water potential zones delineation and spatiotemporal variation characteristics of water pollution and the cause of pollution formation in Brahmani River Basin, Odisha

Waste water reuse is an effective method for reducing the quantity of wastewater that enters the environment. As a result, the appropriateness was assessed in accordance with its composition and the global criteria for drinking water quality. This study aims to evaluate the quality of surface water of Brahmani River, Odisha, by adapting multivariate statistical approaches, namely Cluster Analysis (CA) and multi-criteria decision-making (MCDM) methods such as Simple Additive Weighting (SAW). Again, Geographical Information System (GIS) is employed to assess the drinking water's quality in relation to its application. Around 15 physicochemical parameters, gathered from seven distinct sites, following a period of 2022 till 2024. The results showed high values of EC, SO42−, NO3−, PO43−, F− and Ca2+, in three stations, while other studied parameters are within the permissible limits defined by WHO standards. The CA three distinct classifications of sites namely, low, medium, and high, based on how comparable the various physicochemical traits and pollutant levels were throughout the sampling locations. Sites H-(4–6) were included in cluster 1, site H-(3) and (7) classified under Cluster 2 and finally, H-(1–2) indicated as Cluster 3. Thus, as stated by CA, 42.86 % of tested water samples were fall into the group of good quality and about 57.14 % of examined locations resides in the poor category of water. The findings indicate which characteristics, as determined by the CA technique, were accountable for the alteration in the water quality and raise the potential of runoff from cities, farms, and industries. Subsequently, MCDM techniques has been implemented to facilitate rapid comprehension of surface water behavior and address problems with water resource management. The obtained SAW index ranges from 0.5 to 0.94. Here, H-(1), (2), and (7) grouped as highly polluted zone, and they seemed to be connected to runoff from farms and untreated industrial and municipal trash as well as local pollution sources. From this innovative study, it is found that even though the water is fit for drinking at 3 places, it is medium to highly suitable for human consumption. Therefore, there needs to be treated in some way before being used in addition to being protected against contamination. Most often, the findings indicate that appropriate management actions are important to restore the water quality of this catchment in order to support a robust and promising aquatic ecosystem. Additionally, the significance of this restoration for objective ecological policy and decision-making processes is underscored.

Measurement of natural radiation levels in some soil samples from the ancient city of Borsippa in Babylon Governorate, Iraq

Abstract In the present study, the activity concentration of natural radionuclides was determined for 40K, 232Th, and 238U. Some samples of soil from the ancient city of Borsippa in Babylon Governorate. The detector sodium iodide activated by Thallium NaI (Tl) has been used to perform the radioactivity measurements. 15 samples had their natural radioactivity levels assessed. 40K, 232Th, and 238U had average specific activities of (167.86±1.19, 25.15±1.09, and 11.75±0.457) Bq/kg. The average radium equivalent (61.17±2.10) Bq/kg. Average internal and external risk factors were (0.15±0.00007, and 0.19±0.00027), As for the average value of the index of representative levels (Iᵧ) was (0.44±0.018) The average absorbed dose level in (nGy/h) (28.19±1.18). The results of this study were within the internationally permissible limits, according to the report of the United Nations Scientific Committee on the Effects of Atomic Radiation.

Evaluation of groundwater in the city of Sousse in eastern Libya for some heavy metals and nitrate ions

Evaluation of groundwater potential and its quality assessment for irrigation has recently become a major concern, especially in developing countries due to various constraints. The aim of this study is to evaluate the quality of groundwater and establish whether they are safe for irrigation usage in Sousa city, Libya. The aim of the study to evaluating of groundwater polluted with Lead, Cadmium and Chromium metals and nitrates ions. Five water samples were collected from different wells were and analyzed. For understanding the hydro chemical and polluted characteristic with some heavy metal as (Pb, Cd and Cr ) respectively, and the suitability for irrigation purposes. Nine parameters were considered for calculating the irrigation water quality indices which are pH , electrical conductivity (EC), ions ( cations and anions) such as Calcium, magnesium, potassium sodium, chloride ,bicarbonate, sulphate,, in addition to some calculated parameters for as SAR, Adj. SAR, RSC, TDS and pHc, furthermore some heavy metals and nitrates ions were investigated. The results of polluted with heavy metals and nitrate ion, showed that the most water samples did not exceed the maximum limit according to FAO and Libyan local standard, except W05 exceeding the permissible limit for lead and nitrate ion, and W02 for pb. The results of this study emphasis that routine monitoring of groundwater play a vital role in maintaining its quality and serve as guideline for sustainable management of water quality in region study. Keywords: irrigation water, heavy metals, nitrate, ground water.

Heavy metals in commonly consumed rice grains in Bangladesh and associated probabilistic human health risks

Food contamination by heavy metals is a concerning issue worldwide. The presence of elevated levels of heavy metals in commonly consumed rice has emerged as a critical issue in ensuring food safety. This research encompassed the collection of 44 rice samples, representing seven distinct varieties, through a randomized sampling approach across various retail markets within Dhaka city. The investigation of heavy metal content (including Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Cd, Hg, and Pb) within the rice samples was carried out employing Inductively Coupled Plasma Mass Spectrometry (ICP-MS). The findings disclosed substantial disparities in heavy metal concentrations among the different rice varieties. Notably, the concentrations of Cr (0.99 mg/kg), Fe (8.35 mg/kg), Pb (0.49 mg/kg), and Co (0.02 mg/kg) were observed to exceed the established maximum permissible limits. This contamination of the rice varieties may stem from either natural processes or human activities. Utilizing these metal concentrations, this study employed Monte-Carlo simulation to calculate health risk and probabilistic health risk. The Target Hazard Quotients (THQs) for Cr, Fe, and As exceeded the threshold of 1 in each rice variety, particularly in Amon and Lal Biroi in Mymensingh, Najirshail in Bogra, 28 in Sherpur and Kushtia, Miniket in Bogra and Rajshahi, and lastly, paijam in Rangpur and Tangail. Furthermore, the Hazard Index (HI) exceeded 1 in all rice varieties, implying that the consumption of these selected rice grains may have a substantial impact on overall food quality and its potential health consequences. Both carcinogenic risk and probabilistic risk for As, Ni, Cd, Cr, and Pb were found to surpass the threshold levels and safe limits, respectively. This suggests that individuals who have regularly consumed these rice varieties may face a heightened probability of developing cancer in the future, as predicted. According to sensitivity analysis, metal concentration and food ingestion rate (FIR) are the most relevant components that contribute to the significant impact of carcinogenic health hazards. Finally, the study concluded that heavy metal intake from food poses a risk to human health, necessitating the effective monitoring based on each geographic location and identify the source of this heavy metal to limit its exposure.