Permeability Tests Research Articles

Strength and Durability Studies on Concrete using Cashew Nut Shell Ash (CNSA) waste as Supplementary Materials

<p><span style="font-size:12pt"><span style="font-family:"Times New Roman","serif"">As the world population is expected to increase significantly, there is a greater need for housing and, as a result, building materials. Conventional manufacturing methods for materials such as concrete involve substantial energy usage and substantial release of carbon emissions, which contribute to environmental deterioration. This study investigates the incorporation of Cashew Nut Shell Ash (CNSA) as a partial replacement for Ordinary Portland Cement (OPC) as primary cement, while CNSA formed binary blends. The study examined various water-to-binder ratios (0.55, 0.50, and 0.45) and a total binder content of 310 kg/m³, with replacement levels at 0%, 10%, 20%, 30%, and 40%. Compressive strength tests were performed at 2, 7, 28, and 90 days, shows a consistent increase in strength over time. Optimal CNSA content (10-30%) enhanced long-term strength due to its pozzolanic activity. Additionally, the elastic modulus was tested, indicating improved stiffness in mixes containing CNSA in comparison with the conventional concrete systems. Durability tests such as Rapid Chloride Permeability Test and carbonation depth analysis showed that CNSA addition generally decreased chloride conductivity, thereby enhancing durability. However, replacement levels (beyond 40%) exhibited diminishing returns. The results suggest that CNSA is a viable partial replacement for cement, improving concrete's workability, density, and long-term strength while enhancing durability against chloride penetration and carbonation. These findings support CNSA's potential in creating sustainable and resilient concrete systems.</span></span></p>

Microstructural, Fluid Dynamic, and Mechanical Characterization of Zinc Oxide and Magnesium Chloride-Modified Hydrogel Scaffolds.

Scaffolds for the filling and regeneration of osteochondral defects are a current challenge in the biomaterials field, and solutions with greater functionality are still being sought. The novel approach of this work was to obtain scaffolds with biologically active additives possessing microstructural, permeability, and mechanical properties, mimicking the complexity of natural cartilage. Four types of scaffolds with a gelatin/alginate matrix modified with hydroxyapatite were obtained, and the relationship between the modifiers and substrate properties was evaluated. They differed in the type of second modifier used, which was hydrated MgCl2 in two proportions, ZnO, and nanohydroxyapatite. The samples were obtained by freeze-drying by using two-stage freezing. Based on microstructural observations combined with X-ray microanalysis, the microstructure of the samples and the elemental content were assessed. Permeability and mechanical tests were also performed. The scaffolds exhibited a network of interconnected pores and complex microarchitecture, with lower porosity at the surface (15 ± 7 to 29 ± 6%) and higher porosity at the center (67 ± 8 to 75 ± 8%). The additives had varying effects on the pore sizes and permeabilities of the samples. ZnO yielded the most permeable scaffolds (5.92 × 10-11 m2), whereas nanohydroxyapatite yielded the scaffold with the lowest permeability (1.18 × 10-11 m2), values within the range reported for trabecular bone. The magnesium content had no statistically significant effect on the permeability. The best mechanical parameters were obtained for ZnO samples and those containing hydrated MgCl2. The scaffold's properties meet the criteria for filling osteochondral defects. The developed scaffolds follow a biomimetic approach in terms of hierarchical microarchitecture and mechanical parameters as well as chemical composition. The obtained composite materials have the potential as biomimetic scaffolds for the regeneration of osteochondral defects.

Poly(alkylene 2,4-furanoate)s: The potential of structural isomerism for outstanding sustainable food packaging and unexpected evidence of self-healing microstructure

2,5-furandicarboxylic acid is an extremely appealing renewable chemical building block because of its potential to replace the petrochemical and industrially widespread terephthalic acid via the synthesis of poly(alkylene 2,5-furanoate)s (2,5-PAF). The recent interest in its structural isomer, 2,4-furandicarboxylic acid (2,4-FDCA), opened the study of poly(alkylene 2,4-furanoate)s (2,4-PAF). In this work, 2,4-FDCA was polymerized with linear glycols of increasing chain length, via a solvent-free polycondensation reaction, obtaining high molecular weight 2,4-PAF. Namely, poly(trimethylene 2,4-furanoate) (2,4-PTF), poly(pentamethylene 2,4-furanoate) (2,4-PPeF) and poly(hexamethylene 2,4-furanoate) (2,4-PHF). These polyesters were compression molded into films and subjected to NMR, GPC, WAXS, PLOM, TGA and DSC analyses. The functional properties for food packaging applications were evaluated by mechanical and gas permeability tests. 2,4-PAF had tunable mechanical properties, depending on the glycol used, and in some cases, the mechanical behavior of a thermoplastic elastomer and shape recovery after break. In particular, 2,4-PPeF had outstanding gas barrier properties, while DSC analyses on 2,4-PHF showed an endothermic phenomenon attributed to the isotropization of a partially-ordered phase: it was possible to demonstrate that this phase was disrupted during tensile tests and slowly recovered over time, at room temperature. Overall, the results offer new insights into the structure-property relationships of poly(alkylene 2,4-furanoate)s and display their great potential for the production of biobased, monomaterial, easily recyclable and sustainable food packaging.

A facile method to fabricate superhydrophobic cotton fabrics finished using water-proof and antibacterial agent

Superhydrophobic emulsions (SHEs) based on fatty acids (stearic, palmitic, myristic and lauric acids)-melamine (FAMEs) was synthesized without emulsifier and applied on cotton fabric. The superhydrophobic compounds (FAME1, FAME2, FAME3 and FAME4) were successfully prepared on the basis of the reaction between fatty acid anhydrides and melamine. The chemical structures of the prepared FAME compounds were investigated using FTIR,1HNMR spectroscopy and elemental analysis. The cotton fabric samples were treated with the prepared emulsions using different concentrations in the range of 20 – 60 g/L. Hydrostatic pressure, water contact angle (WCA) and water permeability tests were performed on the treated samples. It was shown that super hydrophobicity of the fabric treated with stearic acid-melamine emulsion (60 g/L) recorded the best results due to the combined effect of surface roughness imparted by melamine and the low surface energy of stearic acid. Furthermore, antibacterial agent Biochrol WS1 in concentrations (2 and 8%) was simultaneously applied to the treated samples. The Kirby-Bauer disc diffusion method was used to estimate the biological activity of the treated cotton. Two strains of bacteria: Gram-positive (Bacillus subtilis - Staphylococcus aureus) and Gram-negative (Escherichia coli-Pseudomonas aeruginosa) were used for this purpose. The tensile strength of treated samples was measured as well. The results showed that the antibacterial and water-proof fabrics can be achieved by applying selected material without significant changes on their comfort properties.

Assessing foundation characteristics at the war dam site, lake tana basin, Ethiopia: A geophysical and geotechnical perspective

An integrated geophysical and geotechnical study evaluated the foundation conditions at the War dam site in northwest Ethiopia. This investigation included the classification of rock quality, shallow seismic refraction, and magnetic approaches. The dam's location comprises quaternary soil deposits and rhyolite rock units that have undergone varied weathering and fracturing. The shallow seismic refraction method distinguishes three layers of p-wave velocities that are less than 1.5 km per second with a depth range of 2–6 m, 1.5–2.5 km per second at a depth range of 15–20 m, and 2.5–3.5 km per second ranging from 20 to 40 m, respectively. Magnetic data were used to identify lineaments, and the RQD value acquired from boreholes ranged from extremely poor to excellent. Lineaments were recognized using the tilt angle approach. The results of the permeability tests demonstrated that the rock mass that serves as the dam's foundation had characteristics that are resistant to low permeability. The maximum and minimum lugeon values obtained from the testing were 9Lu and 0.81Lu, respectively. There are weak zones at and below the surface of the dam site, according to the overall findings acquired from seismic refraction, magnetic, and discontinuity surveying. These results were obtained from monitoring the dam site. These significant structures are directed towards a SW-NE, NE-SW, NNW-SSE, and SSW-NNE orientation. The study assessed the geological suitability of a proposed dam site using seismic refraction and magnetic survey methods. Significant geological variations were observed, particularly in the right abutment and valley floor, indicating the need for targeted grouting. The findings suggest that while the site is generally suitable for dam construction, specific areas require further ground improvement to ensure stability.

Study on the protection of gingival epithelial barrier by interleukin-22 through regulating microbiota and E-cadherin expression

Objective: To investigate the regulatory effect and mechanism of interleukin-22 (IL-22) on the gingival epithelial barrier in the context of periodontal inflammation. Methods: IL-22 knockout (IL-22 KO) mice were constructed, and periodontitis mice models were established through oral gavage with polymicrobial inoculation. DNAs were extracted from the oral plaques of IL-22 KO periodontitis mice group (n=7) and their wild-type littermates periodontitis group (n=7) to establish a periodontitis-related oral microbiota database"PD-RiskMicroDB", determining the relationship between changes in oral microbiota and microbial function in two groups using 16S rRNA sequencing results. Gingival epithelial cells (GEC) were cultured by modified trypsinization method, and were stimulated with 100 μg/L IL-22, Porphyromonas gingivalis (Pg) (multiplicity of infection:100), separately or together for 3 and 12 hours. The experimental groups were as follows: control group (no stimulation), IL-22 group, Pg group and Pg+IL-22 group. The expression of barrier protein E-cadherin in each group at 3 h was detected by immunofluorescence, real-time fluorescence quantitative PCR (RT-qPCR) and Western blotting. Fluorescein isothiocyanate-dextran-mediated epithelial cell permeability experiment was conducted to clarify the changes in permeability of GEC in each group at 3 and 12 h. The mRNA expressions of E-cadherin in the gingival epithelium of wild-type littermates periodontitis group and IL-22 KO periodontitis group were detected by RT-qPCR. Fifteen C57BL/6 wild-type mice were randomly divided into control group (n=5), periodontitis group (n=5) and periodontitis+IL-22 treatment group (n=5). RT-qPCR and immunohistochemistry (IHC) staining were used to detect the expression level of E-cadherin in the gingival epithelium of each group. Results: 16S rRNA sequencing results showed that the composition of oral microbiota changed in IL-22 KO periodontitis group, of which the abundance of bacterial genera related to periodontal tissue invasion was significantly increased (linear discriminant analysis score: 2.22, P=0.009), compared with wild-type littermates periodontitis group. In vitro cell experiments showed that after Pg infection for 3 hours, the cell connections of GEC in Pg group were interrupted, and the fluorescence intensity of E-cadherin was reduced in Pg group compared with the control group. Meanwhile, the mRNA and protein expression levels of E-cadherin (mRNA: 0.69±0.12; protein: 0.60±0.12) were downregulated compared with the control group [mRNA: 1.00±0.00 (P=0.043); protein: 1.04±0.08 (P=0.003)], respectively. The fluorescence intensity of E-cadherin in the Pg+IL-22 group was enhanced compared with Pg group, and expression levels of E-cadherin mRNA (1.16±0.10) and protein (0.98±0.07) in Pg+IL-22 group showed a significant increase compared with Pg group [mRNA: 0.69±0.12 (P=0.005); protein: 0.60±0.12 (P=0.007)]. The result of epithelial permeability test showed that there was no statistical difference in epithelial permeability among control group, Pg group, IL-22 group and Pg+IL-22 group with treatment for 3 hours (F=0.20, P=0.893). While when the treatment time turned to be 12 hours, the epithelial barrier permeability showed a significant increase in Pg group (1.39±0.15) compared with control group (1.00±0.00, P=0.027), and a decrease in Pg+IL-22 group (1.02±0.18) compared with Pg group (1.39±0.15, P=0.034). In vivo, the mRNA expression of E-cadherin in the gingival epithelium of IL-22 KO periodontitis group decreased significantly (0.32±0.21) compared with wild-type littermates periodontitis group (1.01±0.01) (t=5.70, P=0.005). Moreover, RT-qPCR and IHC staining results showed that the mRNA expression level of E-cadherin (0.40±0.07) and absorbance value of E-cadherin positive expression (0.02±0.00) in gingival epithelial tissue of periodontitis group were both significantly down-regulated compared with control group [mRNA: 1.00±0.00 (P=0.005); absorbance value of E-cadherin positive expression: 0.04±0.01 (P=0.006)]. Meanwhile, the mRNA expression level of E-cadherin (1.06±0.24) and the absorbance value of E-cadherin positive expression (0.03±0.01) were both observed increase in periodontitis+IL-22 treatment group compared with periodontitis group (P=0.003, P=0.039). Conclusions: IL-22 may exert a protective effect on the gingival epithelial barrier in an inflammatory environment by regulating the invasiveness of oral microbiota and the expression of host barrier protein.

Quantitative Characterization of Pore–Fracture Structures in Coal Reservoirs by Using Mercury Injection–Removal Curves and Permeability Variation under Their Constraints

Pore and fracture structure heterogeneity is the basis for coalbed methane production capacity. In this paper, high-pressure mercury intrusion test curves of 16 coal samples from the Taiyuan Formation in the Linxing area are studied. Based on the fractal dimension values of mercury intrusion and retreat curves, the correlation between the two different fractal parameters is studied. Then, the permeability variation of different types of coal samples is studied using overlying pressure pore permeability tests. The correlation between the permeability variation of coal samples and dimension values is explored, and the results are as follows. (1) Based on porosity and mercury removal efficiency, all coal samples can be divided into three types, that is, types A, B, and C. Among them, Type A samples are characterized by lower total pore volume, with pore volume percentages ranging from 1000 to 10,000 nm not exceeding 15%. (2) During the mercury injection stage, both the M-model and S-model can reflect the heterogeneity of seepage pore distribution. In the mercury removal stage, the M-model cannot characterize the heterogeneity of pore size distribution in each stage, which is slightly different from the mercury injection stage. (3) The permeability of Type A samples is most sensitive to pressure, with a permeability loss rate of up to 96%. The original pore and fracture structure of this type of coal sample is relatively developed, resulting in a high initial permeability. (4) There is no significant relationship between compressibility and fractal dimension of mercury injection and mercury removal, which may be due to the comprehensive influence of pore structure on the compressibility of the sample.

Appraisal of Bhatta Waste as an Admixture for the Stabilization of Fill Soil

Testing of soil and knowing its strength parameter’s is one of the basic components in construction. Testing of soil is carried out to find whether the existing soil can endure the burden of structure withheld upon it or not. In case of a weak soil, one can find difficult to pursue construction or any development project. While talking of solutions, there are many methods to improve its strength and properties: one of them which we decided to work on is ‘Appraisal of Bhatta Waste as an Admixture for the Stabilization of Fill Soil’. It’s a kind of cost effective & economical means of improving soil, as the basic material required for stabilization is Bhatta waste, which is normally easily available material. The main objective of our test is to check the effectiveness of Bhatta waste on mechanical properties of filled material. The testing comprised of performing Atterberg limit, UCS, direct shear test, sieve analysis, Moisture dry density and Permeability test. The Bhatta waste passing no. 40 sieve is mixed with fill soil and testing on different proportions was carried out. Summary was prepared for explanation of engineering properties of different proportions, while further testing on higher proportions is recommended.

Integration of mucus and its impact within in vitro setups for inhaled drugs and formulations: Identifying the limits of simple vs. complex methodologies when studying drug dissolution and permeability

Traditionally, developing inhaled drug formulations relied on trial and error, yet recent technological advancements have deepened the understanding of ‘inhalation biopharmaceutics’ i.e. the processes that occur to influence the rate and extent of drug exposure in the lungs. This knowledge has led to the development of new in vitro models that predict the in vivo behavior of drugs, facilitating the enhancement of existing formulation and the development of novel ones. Our prior research examined how simulated lung fluid (SLF) affects the solubility of inhaled drugs. Building on this, we aimed to explore drug dissolution and permeability in lung mucosa models containing mucus. Thus, the permeation of four active pharmaceutical ingredients (APIs), salbutamol sulphate (SS), tiotropium bromide (TioBr), formoterol fumarate (FF) and budesonide (BUD), was assayed in porcine mucus covered Calu-3 cell layers, cultivated at an air liquid interface (ALI) or submerged in a liquid covered (LC) culture system. Further analysis on BUD and FF involved their transport in a mucus-covered PAMPA system. Finally, their dissolution post-aerosolization from Symbicort® was compared using ‘simple’ Transwell and complex DissolvIt® apparatuses, alone or in presence of porcine mucus or polymer-lipid mucus simulant. The presence of porcine mucus impacted both permeability and dissolution of inhaled drugs. For instance, permeability of SS was reduced by a factor of ten in the Calu-3 ALI model while the permeability of BUD was reduced by factor of two in LC and ALI setups. The comparison of dissolution methodologies indicated that drug dissolution performance was highly dependent on the setup, observing decreased release efficiency and higher variability in Transwell system compared to DissolvIt®. Overall, results demonstrate that relatively simple methodologies can be used to discriminate between formulations in early phase drug product development. However, for more advanced stages complex methods are required. Crucially, it was clear that the impact of mucus and selection of its composition in in vitro testing of dissolution and permeability should not be neglected when developing drugs and formulations intended for inhalation.

Design Constant Head Permeability Meter Digital: A Project-Based Learning Media

The permeability coefficient value is one of the most important parameters in soil mechanics. Quick, simple, and digital direct soil permeability tests in the field are needed to obtain data representing conditions. This research aims to create a portable soil permeability test tool based on microcontroller automation used as a project-based learning for Transportation Cadets peculiarly Palembang Aviation Polytechnic Cadets for new experiences of new learning circumstances. This research method based on the principle of permeability testing using the constant-head method by analyzing the requirements quantitatively. This principle uses water change level parameters, which are used to test the infiltration rate in sample soil. Furthermore, measurements of changes in water level are used by water leveling sensors and processed using Arduino Uno based on fuzzy logic with access to results via the web, tool design, and simulation using SIMULINK software. The results of designing a digital measuring instrument for permeability using the constant head method have been validated for its schematic circuit using SIMULINK and can work without error. In conclusion, a model based on Darcy's Law equation and constant head to find the permeability coefficient can be generated, which can then be a prototype of the tool. It concluded the design of constant head permeability meter digital is useful as project-based leaning media for the Palembang aviation polytechnic. Furthermore, the equipment design will be the first digital measuring tool for permeability coefficient using the constant head method. The design has advantage to measure the soil permeability coefficient at the airport in the fastest way.

Variations in pore structures and permeabilities of ion adsorption rare earth ores during simulated in-situ leaching: Effect of newly formed clay particles and their swelling

In-situ leaching is essential for mining rare earth elements (REEs) from ion-adsorption rare earth (RE) ores. The efficiency of RE mining is dependent on the permeabilities of ion-adsorption RE ores, and the permeabilities are controlled by their pore structures. However, the current understanding of the pore structures and permeabilities of the RE ores during leaching is limited, particularly their dynamic variations, the controlling roles of different pore structure parameters on the permeability, the roles of the influencing factors and the mechanisms causing the variations. To investigate the above-mentioned issues, we conducted an experimental study of simulated in-situ leaching on undisturbed ion-adsorption RE ore samples under different conditions via constant waterhead permeability tests. The leaching conditions included leaching time, concentration and waterhead of the (NH4)2SO4 solution. Three-dimensional (3-D) pore structures of the RE ores before, during, and after leaching were constructed via X-ray computed tomography, and their pore structure parameters were measured using 3-D image computation. It was observed that the dynamic variations in both the pore structure parameters and permeability coefficients of the RE ores occurred in three distinct stages: rapid reduction, less rapid reduction, and little reduction. The experimental results also revealed that the permeability coefficients of the RE ores were primarily dependent on the average coordination number among the seven pore structure parameters examined, and that the pore throats larger than 30 μm in diameter served as the most effective seepage channels within the RE ores. The waterhead of the leaching solution had a stronger influence on the variations in pore structures and permeabilities compared to that of the concentration. Analysis of the particle/aggregate size distribution and mineralogical compositions of the RE ores before and after leaching indicated that the decreases in the pore structure parameters and permeabilities were largely attributed to clogging of the pore throats and pores by migrated and newly formed clays, as well as swelling of the latter. The newly formed clays were the products of the decomposition of K-feldspar and mica resulting from chemical reactions with the leaching solution. The clays from the two sources occurred in disaggregated and aggregated forms. The results of this study provide an important reference for the mining of RE ores via leaching.

Electrospun porous polyacrylonitrile/polyvinylpyrrolidone nanofiber membrane with ultra-hydrophilic and high moisture-permeability for dust personal protection

The serious dust pollution in coal mine working environment can cause occupational lung diseases and other diseases, affecting the life and health of miners. Therefore, the prospect of developing an air filtration membrane with high filtration performance is of remarkable significance. This study prepared a porous Polyacrylonitrile (PAN) /Polyvinylpyrrolidone (PVP) nanofiber membrane based on Electrospinning and post-treatment technology used for downhole personal protection. The prepared porous nanofiber membrane increased the specific surface area by 133.63 % and the porosity by 391.02 % (compared with the pure PAN nanofiber membrane), and was able to achieve a high filtration efficiency of 98.76 % and a low pressure drop of 165 Pa at an air flow rate of 85 L/min. Meanwhile, this study conducted contact angle and moisture permeability tests on the prepared composite fiber membrane. After 1 second of water droplets falling on the fiber membrane, it had a 14° contact angle (strong hydrophilicity), and the moisture permeability reached 4256.677 cm3/m2·d·Pa, which could discharge the water vapor generated by respiration in time. In addition, given the complex and irregular pore distribution of electrospun nanofibers, the fractal correlation dimension of nanofiber membrane pores was studied through fractal theory, and the relationship between the fractal dimension of fiber pores and respiratory resistance was discussed. Based on this, the nanofiber membrane prepared in this study can be widely used in individual protection in mines.

An Innovative Experimental Methodology for Testing Anisotropic Permeabilities of Formation Rocks

Abstract The permeability of reservoir rocks is a typical anisotropic property. Accurate testing and characterization of reservoir in situ anisotropic permeability is crucial for geo-energy applications including geothermal energy extraction, hydrocarbon reservoir development, coalbed methane production, and carbon dioxide geological sequestration. In this work, a novel experimental apparatus was designed to more precisely determine the permeability tensor of reservoir rocks. The device can independently apply stresses in different directions to simulate in situ reservoir stress conditions and reservoir temperatures. The experiment can accurately measure the principal components of the permeability tensor in three directions for rock samples while effectively avoiding experimental errors caused by internal structure damage during disassembly. Using the self-developed apparatus, anisotropic permeability tests were conducted on sandstone, shale, and coal samples. The results show that the three-dimensional permeability of rock samples under in situ reservoir stress conditions is lower than under isotropic stress conditions. However, the variation magnitude of the three-dimensional permeability differs between the three rock types because of lithological differences. This confirms the difference in data between the proposed anisotropic permeability test method and other traditional methods. We also observed that for rocks without distinct oriented internal structures like sandstone, anisotropic permeability is more sensitive to (normal) stress changes. In contrast, for rocks with oriented pore structures such as shale and coal, the degree of anisotropic permeability is less sensitive to (normal) stress changes. The proposed novel anisotropic permeability test method obtains more accurate and realistic data under simulated in situ stress conditions compared with existing methods. It can evaluate rock properties and optimize geothermal or hydrocarbon production well designs to improve production efficiency.

Utilization of Palm Shell Ash as a Filler in Making AC-WC Type Porous Asphalt

The background to the research that will be carried out is that the large amount of standing water on the road pavement in each rainy season results in disturbances to motorists' comfort. This is due to impermeable road pavement and poor drainage along the road. Porous asphalt can increase rainwater absorption, thereby reducing puddles on the road surface. Porous asphalt is a new breakthrough in the world of road pavement to reduce the appearance of puddles of water when it rains. Porous asphalt is also designed to have high porosity so that water can flow through side channels and a waterproof base layer to prevent water from seeping into the subbase layer and road body so as to minimize puddles of water on the road surface which often occur after rain and disrupt the smooth flow of traffic. cross. Advances in road pavement technology have encouraged researchers to conduct research using palm shell ash (fly ash) as a filler in porous asphalt mixtures. The use of palm shell ash is expected to increase the stability value and have large cavities so that water can pass through the road surface, as well as to reduce palm oil waste in Indonesia. The objectives of this research are 1. To find out the optimum asphalt content value in porous asphalt mixtures, 2. To know the results of using palm shell ash at 0%, 1% and 2% as a filler for porous asphalt mixtures in flexible road pavement. The research method is Marshall and Permeability Testing. The tests that will be carried out on a laboratory scale use an AC-WC hot mix asphalt system with guidance, namely the basics of asphalt concrete road construction. The research results showed that by adding palm shell ash as a filler in making AC-WC type porous asphalt, it showed that the stability value was higher, while the permeability value was lower, meaning that the addition of palm shell ash to the porous asphalt mixture did not have a significant effect because it was smaller. air voids in the mixture. The addition of palm shell ash to the porous asphalt mixture increases the stability value which can increase the ability of road construction to accept loads, but the pavement layer is not permeable and water flows over the surface more slowly.

Exploring Urban Sustainability: The Role of Geology and Hydrogeology in Numerical Aquifer Modelling for Open-Loop Geothermal Energy Development, the Case of Torino (Italy)

This research examines the integration of geological and hydrogeological data in numerical aquifer model simulations, with a particular focus on the urban area of Torino, Italy. The role of groundwater resources in urban sustainability is analysed. The objective is to integrate open-loop geothermal plants into the district heating network of IREN S.p.A. Two case studies are examined: the Torino Nord area and the Moncalieri area, both of which host district heating plants. The work entails the collection and analysis of data from a variety of sources, including geognostic surveys and permeability tests, in order to construct a three-dimensional numerical model of the surface aquifer. Models were built using the public MODFLOW 6 (model of groundwater flow) code and calibrated using PESTHP (High Performance of Model Independent Parameter Estimation and Uncertainty Analysis). Results indicate the potential of urban aquifers as renewable energy sources and the necessity of comprehensive geological and hydrogeological assessments for optimal ground water heat pump (GWHP) system installation. This paper emphasises the significance of sustainable water management in the context of climate change and urbanisation challenges.

Study on Mechanical Properties of Sandy Soil Solidified by Enzyme-Induced Calcium Carbonate Precipitation (EICP)

Earth–rock dams are widely distributed in China and play an important role in flood control, water storage, water-level regulation, and water quality improvement. As an emerging seepage control and reinforcement technology in the past few years, enzyme (urease)-induced calcium carbonate precipitation (EICP) has the qualities of durability, environmental friendliness, and great economic efficiency. For EICP-solidified standard sand, this study analyzes the effect of dry density, amount of cementation, standing time, perfusion method, and other factors on the permeability and strength characteristics of solidified sandy soil by conducting a permeability test and an unconfined compression test and then working out the optimal solidification conditions of EICP. Furthermore, a quantitative relationship is established between the permeability coefficient (PC), unconfined compressive strength (UCS), and CaCO3 generation (CG). The test findings indicate that the PC of the solidified sandy soil decreases and the UCS rises as the starting dry density, amount of cementation, and standing time rise. With the increase of CG, the PC of the solidified sandy soil decreases while the UCS increases, indicating a good correlation among PC, UCS, and CG. The optimal condition of solidification by EICP is achieved by the two-stage grouting method with an initial dry density of 1.65 g/cm3, cementation time of 6 d, and standing time of 5 d. Under such conditions, the permeability of the solidified sandy soil is 6.25 × 10−4 cm/s, and the UCS is 1646.94 kPa. The findings of this study are of great theoretical value and scientific significance for guiding the reinforcement of earth–rock dams.

Mechanical performance and permeability of low-carbon printable concrete

Common issues in 3D printed concrete arise due to its high cement content, processing requirements, and the lack of extensive research into its long-term performance. To this end, this study explores using supplementary cementitious materials from local regions to partially replace cement, aiming at reducing the carbon footprint. Various printable mixtures with different substitution rates are formulated, and corresponding mechanical and permeability tests are conducted. It is revealed that the compressive and flexural strengths of 3D printed concrete with low cement content were lower than the strength of cast concrete due to the construction process of printed concrete; the mechanical strength of 3D printed concrete showed prominent anisotropic characteristics. It was found that, compared with the other two sets of ratios, the higher contents of FA and GGBFS could effectively fill the pores of the printed concrete. Both the capillary water absorption and the content of chloride ions of the low-carbon mixture were significantly lower than that of the pure cement-printed specimens.

Permeability and Disintegration Characteristics of Loess Solidified by Guar Gum and Basalt Fiber.

Loess has the characteristics of loose, large pore ratio, and strong water sensitivity. Once it encounters water, its structure is damaged easily and its strength is degraded, causing a degree of subgrade settlement. The water sensitivity of loess can be evaluated by permeability and disintegration tests. This study analyzes the effects of guar gum content, basalt fiber content, and basalt fiber length on the permeability and disintegration characteristics of solidified loess. The microstructure of loess was studied through scanning electron microscopy (SEM) testing, revealing the synergistic solidification mechanism of guar gum and basalt fibers. A permeability model was established through regression analysis with guar gum content, confining pressure, basalt fiber content, and length. The research results indicate that the addition of guar gum reduces the permeability of solidified loess, the addition of fiber improves the overall strength, and the addition of guar gum and basalt fiber improves the disintegration resistance. When the guar gum content is 1.00%, the permeability coefficient and disintegration rate of solidified soil are reduced by 50.50% and 94.10%, respectively. When the guar gum content is 1.00%, the basalt fiber length is 12 mm, and the fiber content is 1.00%, the permeability of the solidified soil decreases by 31.9%, and the disintegration rate is 4.80%. The permeability model has a good fitting effect and is suitable for predicting the permeability of loess reinforced with guar gum and basalt fiber composite. This research is of vital theoretical worth and great scientific significance for guidelines on practicing loess solidification engineering.

Seepage characteristics and mechanism of double damage basalt fiber reinforced concrete under three-dimensional variable stress states

Concrete experiences a three-dimensional variable stress state during its service life. To explore the permeability evolution and mechanism under such conditions, a permeability test was conducted on double damage basalt fiber concrete subjected to loading and unloading of twice confining pressure. Pore structure and microstructure of specimens were analyzed before and after permeability test. The findings reveal that the reduction in permeability after primary cycle of confining pressure loading and unloading is significantly higher than that after secondary cycle, and residual deformation is also more pronounced after primary cycle. Both high temperature and salt freeze-thaw cycles induce initial damage to specimens, consequently altering internal pore structure and subsequently impacting initial permeability. Notably, initial permeability decreases in the case of 10th salt freeze-thaw cycles, while it increases under other conditions. The greater the initial extent of damage to the specimen, the higher the permeability damage coefficient and the permeability damage rate. As the confining pressure decreases, the attenuated permeability increases, with the permeability decay rate reaching a significant 88.53 %. Plastic deformation of pores during loading and unloading process cannot be fully reversed, leading to the development of macropores and mesopores into smaller pore sizes, resulting in a remarkable 87.17 % increase in the proportion of micropores. Microscopic observations reveal smaller pores within the matrix, shorter crack lengths, and narrower crack widths in the specimen. The application of confining pressure reduces permeability channels within specimens, ultimately causing a decline in permeability.

Study on impermeability of reinforced concrete wall with horizontal construction joints

The reinforced concrete (RC) water retaining tank walls with horizontal construction joints are prone to experiencing seepage under high hydrostatic pressure, which can affect the structural integrity and functionality. To evaluate the impermeability of construction joints with different improvement measures, the permeability test of concrete with and without horizontal construction joints was conducted. The test results show that the addition of Polypropylene fibers (PP fiber) and Cementitious Capillary Crystalline Waterproofing materials (CCCW) can improve the self-waterproofing ability of concrete. The impermeability at the construction joint is much lower than that of single-casting concrete. Moreover, applying CCCW to the water-facing surface of the construction joint can significantly enhance its impermeability. Then, two 1:2 scaled RC tank wall specimens were manufactured, with one wall of conventional concrete and the other wall of modified concrete. The impermeability tests of the typical single-casting and double-layer casting parts of the two wall specimens were carried out respectively. The experimental results show the RC tank wall with construction joint is prone to generate initial defects and seepage, making it difficult to achieve the design watertight requirements. The use of modified concrete materials and surface treatment in the relevant part can effectively improve the impermeability performance of the construction joint. Finally, the BP neural network was used to establish a prediction model between the impermeability of concrete and its material parameters and construction technology.