Peripheral Ring Research Articles

Photophysical characteristics of Phenylimidazo(4,5-f)1,10-phenanthroline Rhenium(I) complexes - A theoretical approach to their potential applications in lighting devices

In the search for new luminescent semiconductors to be applied in energy conversion devices, we report via DFT/TD-DFT calculations the structure, UV–Vis absorption, and phosphorescent properties of Re(I) complexes denoted as [ReCl(CO)3(Ln)] and [ReTMP(CO)3(Ln)]+, where TMP is 2,4,6-trimethylpyridine and Ln is a bidentate ligand that corresponds to phenylimidazo(4,5-f)1,10-phenanthroline. This last ligand was analyzed for their electron-donating and -withdrawing characters with different substituents on the peripheral phenyl ring (Ln = -H, –CH3, o –F). Regarding the absorptions, at lower energy in the [ReCl(CO)3(Ln)], it was possible to identify a mixture of metal-to-ligand and ligand-to-ligand charge-transfer excitations, while the [ReTMP(CO)3(Ln)]+ series showed ligand centered transitions as responsible for absorption maximum. The phosphorescence of [ReCl(CO)3(Ln)] complexes exhibits an emission wavelength of 609–623 nm, whose deactivation path comes from π* orbital located at Ln ligands, towards the metal and ligands orbitals. By contrast, the emission process of the [ReTMP(CO)3(Ln)]+ complexes are mainly due to ligand-centered electron promotion (70%) in line with absorption features, showing emission wavelengths in the range of 521–527 nm. The change of the substituent Cl for TMP significantly influences the absorption and emission energies, unlike substitution on the Ln ligand. However, this last substitution pattern becomes relevant when considering injection/transport of holes-electrons where the reorganization energy (λ) for [ReCl(CO)3(L3)] neutral complexes improves due to the more balance charge transfer ability required for organic light-emitting diodes (OLED), while [ReTMP(CO)3(L2)]+ is the best choice for a light-emitting electrochemical cell (LEEC). Then, rhenium complexes can be considered as promising luminophores for device applications.

Evaluating Parameters of Bearing Capacity of Ring Footings

Because of its durability, structural ring footings have been used under the maritime structure’s shallow foundations for many years. so, the efficacy and application of shallow foundations ring footings typically are little understood. These footings was tested for the bearing capacity of this research in a laboratory. The impact of ring depth and stiffness on the bearing capacities of ring footing models was studied in this respect. Ring footings design was based on the structural and geometry requirements. it was estimated that using structural rings would increase the support capacities of both soil-rings and soil-footing depth by 1.62 times. The behavior of a ring footing resting on (sand, clay, sand over clay, clay over sand) soil exposed to vertical stresses was investigated in laboratory experiments. A small-scale physical model was built and tested to achieve this goal. included an aluminum circular footing with a diameter of 100 mm and a d/D ratio of (0,0.33,0.5,0.67,0.95) to see how the d/D ratio affected bearing capacity along with different embedding depths to observe how they affect depth and footing size affected bearing capacity. Because the number of drilling and filling operations decreases as it varies from conventional foundations in that it has an increasing number of ring footings. By using the peripheral ring, it is possible to avoid excavating in adjacent construction sites subsurface soil, which reduces the amount of disturbance. This structure appears critical for expense and productivity given the potential advantages of using rings as feet. Meanwhile, further research into the adjacent foundations' bearing capacity and settling activities is needed to show their advantages to practical engineers

Transition from Dendritic to Cell-like Crystalline Structures in Drying Droplets of Fetal Bovine Serum under the Influence of Temperature.

The desiccation of biofluid droplets leads to the formation of complex deposits which are morphologically affected by the environmental conditions, such as temperature. In this work, we examine the effect of substrate temperatures between 20 and 40 °C on the desiccation deposits of fetal bovine serum (FBS) droplets. The final dried deposits consist of different zones: a peripheral protein ring, a zone of protein structures, a protein gel, and a central crystalline zone. We focus on the crystalline zone showing that its morphological and topographical characteristics vary with substrate temperature. The area of the crystalline zone is found to shrink with increasing substrate temperature. Additionally, the morphology of the crystalline structures changes from dendritic at 20 °C to cell-like for substrate temperatures between 25 and 40 °C. Calculation of the thermal and solutal Bénard–Marangoni numbers shows that while thermal effects are negligible when drying takes place at 20 °C, for higher substrate temperatures (25–40 °C), both thermal and solutal convective effects manifest within the drying drops. Thermal effects dominate earlier in the evaporation process leading, we believe, to the development of instabilities and, in turn, to the formation of convective cells in the drying drops. Solutal effects, on the other hand, are dominant toward the end of drying, maintaining circulation within the cells and leading to crystallization of salts in the formed cells. The cell-like structures are considered to form because of the interplay between thermal and solutal convection during drying. Dendritic growth is associated with a thicker fluid layer in the crystalline zone compared to cell-like growth with thinner layers. For cell-like structures, we show that the number of cells increases and the area occupied by each cell decreases with temperature. The average distance between cells decreases linearly with substrate temperature.

Treating COVID with Bike Lanes: Design, Spatial, and Network Analysis of ‘Pop-Up’ Bike Lanes in Paris

Paris bypassed standard-construction processes to rapidly expand its bike-lane network amidst COVID-19. This study analyses these new lanes in terms of their design, spatial footprint, and relationship to the pre-COVID network. Municipal data, street imagery, and in-person observations demonstrate that Paris’s new ‘pop-up’ lanes are a higher share bi-directional than the pre-COVID network (49% vs. 39%), a higher share more protected (77% vs. 73%), and average a higher number of interconnections. These 47 kilometers connect the city’s peripheral ring to its inner core, primarily represent new lanes as opposed to upgrades of existing lanes (66% vs. 33%), and replace both traffic lanes and on-street parking.

Peripheral Sterile Corneal Ring Infiltrate after Accelerated Cross-linking.

Peripheral Sterile Corneal Ring Infiltrate after Accelerated Cross-linking.

Decoration Strategy in Para Boron Position: An Effective Way to Achieve Ideal Multi-Resonance Emitters.

Narrowband, full-color, and quenching-resistant emitters are urgently needed for the next generation high-resolution displays. Though the flourishment of narrowband multiple resonance (MR) emitters in blue region, these materials still face thorny challenges such as effective light-color regulation strategies and concentration-induced spectral broadening/emission quenching. Herein, the research status of an effective "decoration strategy for para B position" is highlighted. On one hand, the introduction of an electron donor or acceptor could induce a hypsochromic- or bathochromic-shift emission, respectively, without undesirable FWHM broadening. On the other hand, a more advanced molecular motif is further proposed through adopting a peripheral benzene ring on the para position of the B-substituted phenyl in MR core to construct the high-purity, high-efficiency, quenching-resistant and stable MR emitters. Such concept is expected to provide a possible way for the modification, optimization and expansion of MR emitters to meet more possible applications.

Nanographene with Multiple Embedded Heptagons: Cascade Radical Photocyclization.

Although heptagons are widely found in graphenic materials, the precise synthesis of nanocarbons containing heptagons remains a challenge, especially for the nanocarbons containing multiple-heptagons. Herein, we show that photo-induced radical cyclization (PIRC) can be used to synthesize multi-heptagon-embedded nanocarbons. Notably, a nanographene containing six heptagons (1) was obtained via a six-fold cascade PIRC reaction. The structure of 1 was clearly validated and showed a Monkey-saddle-shaped conformation. Experimental bond analysis and theoretical calculations indicated that the heptagons in 1 were non-aromatic, whereas the peripheral rings were highly aromatic. Compared to planar nanographene with the same number of π electrons, 1 had a similar optical gap due to a compromise between the decreased conjugation in the wrapped structure and enhanced electronic delocalization at the rim. Electrochemical studies showed that 1 had low-lying oxidation potentials, which was attributed to the nitrogen-doping.

Nanographene with Multiple Embedded Heptagons: Cascade Radical Photocyclization

AbstractAlthough heptagons are widely found in graphenic materials, the precise synthesis of nanocarbons containing heptagons remains a challenge, especially for the nanocarbons containing multiple‐heptagons. Herein, we show that photo‐induced radical cyclization (PIRC) can be used to synthesize multi‐heptagon‐embedded nanocarbons. Notably, a nanographene containing six heptagons (1) was obtained via a six‐fold cascade PIRC reaction. The structure of 1 was clearly validated and showed a Monkey‐saddle‐shaped conformation. Experimental bond analysis and theoretical calculations indicated that the heptagons in 1 were non‐aromatic, whereas the peripheral rings were highly aromatic. Compared to planar nanographene with the same number of π electrons, 1 had a similar optical gap due to a compromise between the decreased conjugation in the wrapped structure and enhanced electronic delocalization at the rim. Electrochemical studies showed that 1 had low‐lying oxidation potentials, which was attributed to the nitrogen‐doping.

Analysis of postoperative visual and surgical outcome following surgery for absorbed cataract in pediatric age group and the intraoperative difficulties

Purpose:To analyze the postoperative visual and surgical outcomes following surgery for pediatric-absorbed cataracts and intraoperative difficulties.Methods:This prospective longitudinal study included 43 eyes (30 children) with absorbed cataracts aged between 6 months and 18 years (either sex). All children underwent best-corrected visual acuity (BCVA), anterior and posterior segment evaluation, rubella titer estimation, intraocular lens (IOL) power calculation, superior small incision cataract surgery with or without posterior capsulotomy/anterior vitrectomy/IOL implantation under general anesthesia, visual rehabilitation, and were followed up for 1 year.Results:The mean age was 7.89 ± 4.84 years. Preoperative BCVA distance: 39 eyes had either perception of light (PL) or counting finger close to face (CFCF); near BCVA: all eyes had either PL or N36. Postoperative (12 months) distant BCVA: a majority of the eyes (27) had 6/60–1/60, 11 eyes had 6/18–6/36; near: N18 in 19 eyes, N6 in 7 eyes. Anterior continuous curvilinear capsulorrhexis (ACCC) was possible in eight eyes. Cortical aspiration was difficult in 16 eyes (peripheral calcified ring). A majority (32 eyes) underwent in the sulcus implantation (in-the-bag: eight eyes); two eyes: no IOL, one eye: secondary IOL. Eleven eyes had early postoperative inflammation. At 12 months, one eye underwent membranectomy for visual axis opacification and 38 eyes had well-centered IOLs.Conclusion:Surgery in absorbed cataracts is challenging because of the anatomic disorganization of the absorbed lens. By adopting appropriate surgical methods and good visual rehabilitation, one can achieve satisfactory surgical and visual outcomes, highlighting the need for surgical intervention.

Cyclazines‐Structure and Aromaticity or Antiaromaticity on the Magnetic Criterion

AbstractStructure and spatial magnetic properties, through‐space NMR shieldings (TSNMRSs), of all ten cycl[2.2.2]azine to cycl[4.4.4]azine, hetero‐analogues and the corresponding hydrocarbons have been calculated at the B3LYP/6‐311G(d,p) theory level using the GIAO perturbation method and employing the nucleus independent chemical shift (NICS) concept. The TSNMRS values (actually, the ring current effect as measurable in1H NMR spectroscopy) are visualized as iso‐chemical‐shielding surfaces (ICSS) of various size and direction, and employed to readily qualify and quantify the degree of (anti)aromaticity. Results are confirmed by NMR [δ(1H)/ppm, δ(15N)/ppm] and geometry (planar, twisted, bow‐shaped) data. The cyclazinesN[2.2.2]−up toN[2.4.4]−are planar or at most slightly bowl‐shaped and, due to coherent peripheral ring currents (except inN[2.3.3]−,N[2.3.4],N[3.3.4]+andN[2.4.4]+), develop aromaticity or anti‐aromaticity of the whole molecules dependent on the number of peripheral conjugated π electrons. The cyclazinesN[2.3.3]−,N[2.3.4],N[3.3.4]+andN[2.4.4]+develop two ring currents of different direction within the same molecule, in which the dominating ring current proves to be paratropic (inN[3.3.4]+diatropic) including the nodalNpzlone pair into the conjugation. The residual cyclazinesN[3.4.4],N[4.4.4]−andN[4.4.4]+are heavily twisted and, therefore, are not developing peripheral or diverse ring currents. The TSNMRS information about cyclazines and the parent tricyclic annulene analogues is congruent subject to structure and number of peripheral or internal conjugated π electrons, the corresponding (anti)aromaticity is in unequivocal accordance with Hückel's rule.

Highly Crowded Twisted Thienylene-Phenylene Structures: Evidence for Through-Space Orbital Coupling in a [4]Catenated Topology.

Sterically highly crowded and twisted thienylene‐phenylenes are synthesized and structurally characterized. Single‐crystal X‐ray structure analyses and theoretical studies give evidence of through‐space delocalization of π‐electrons of peripheral (hetero)aromatic rings in toroidal and catenated topology.

Point-wise variability of threshold sensitivity of 24-2 and 10-2 visual fields.

PURPOSE:To evaluate point-wise variability of threshold sensitivity at different test locations on 24-2 and 10-2 visual field (VF).MATERIALS AND METHODS:Electronic medical records of patients seen at a tertiary eye care center were screened to include those with at least 3 reliable VF with glaucomatous defects involving fixation on 24-2 and confirmed on 10-2 test strategy. Ninety eyes of 90 patients were categorized into 3 severity groups based on mean deviation (MD on 24-2) test strategy; MD<-6 dB and >-12 dB, <-12 dB and >-20 dB and <-20 dB and >-30 dB. Variability of threshold sensitivity at all topographical test locations in central (ring 1), mid-peripheral (ring 2), peripheral rings on 24-2 VF test strategy (ring 3), and central (ring 4) and paracentral (ring 5) on 10-2 VF test along with variability of visual field index and central field index were calculated by multilevel mixed effects model.RESULTS:Central ring1 on 24-2 and ring 4 on 10-2 showed higher variability (>10 dB) than peripheral ring 2, 3, and 5. Seventy-three eyes were adjudged as stable and 17 as progressing in this cohort. The average ring and point-wise variability was higher in stable eyes (2-6 dB) across all glaucoma severities. Across severity, variability was seen to decrease with increasing severity with minimal variability in point-wise threshold sensitivity beyond MD <-20 dB.CONCLUSION:Central test points/ring on 24-2 and 10-2 with greater threshold variability suggests that status of the eye, severity and topographical location of test points should be incorporated into conventional progression algorithms to predict true glaucoma progression.

Evaluation of the structure and characteristics of circumtrindene derivatives: a DFT study

The structures and properties of circumtrindene derivatives were studied at M062X/6-31+G(d,p) level of theory. The UV spectra of compounds were simulated by TD DFT methods. The calculated values of λmax (344 nm to 403 nm) were attributed to HOMO to LUMO electronic transitions of compounds. The frontier molecular orbitals have been studied based on NBO calculations and the results were used to estimate the HOMO—LUMO energy gap, ionization potential, electron affinity, electronegativity, electrophilicity index, global hardness, softness, and chemical potential of the compounds. Among the studied derivatives, the structure containing pyridine and furan rings possessed the highest ionization energy (9.007 eV), electron affinity (2.667 eV), electronegativity (5.837 eV), and was the most polar molecule. In addition, compound 7 had the smallest chemical potential (–5.837 eV), polarizability (328.560 a.u.) and the lowest energy levels of HOMO (–8.3672 eV) and LUMO (–3.3062 eV) orbitals. While the derivative having pyrrole rings had the highest softness (0.172 e/V), chemical potential (–4.272 eV), and the greatest λmax (403 nm) in the UV spectrum. In addition, this compound had the lowest hardness (2.912 eV), ionization energy (7.184 eV) and electronegativity (4.272 eV). Also, the aromaticity of individual rings was evaluated by calculating NICS and HOMHED indices. The NICS results showed that the peripheral 6-membered rings represented the best aromatic properties.

Crystal structure, Hirshfeld surface analysis and DFT study of 2,2''-({[(1E,1'E)-(diselanedi-yl)bis-(2,1-phenyl-ene)]bis-(methane-ylyl-idene)}bis-(aza-neylyl-idene))bis-[3',6'-bis-(di-ethyl-amino)-4a',9a'-di-hydro-spiro-[isoindoline-1,9'-xanthen]-3-one

The title compound, C70H70N8O4Se2, is a spiro bicyclic diselenide, made up of two [SeC6H4CH=N-N(CO)C6H4(C)C6H3NEt2(O)C6H3NEt2] units related by a twofold crystallographic symmetry element bis-ecting the diselenide bond. The compound crystallizes in a non-centrosymmetric polar space group (tetra-gonal, P b2) and the structure was refined as an inversion twin. The two diethyl amine groups and their attached phenyl groups of the xanthene ring are disordered over two orientations, with occupancies of 0.664 (19)/0.336 (19) and 0.665 (11)/0.335 (11), respectively. The dihedral angles between the mean planes of the central isoindoline and the phenyl rings are 26.8 (2) and 2.5 (4)°, respectively. The mean plane of the central xanthene ring forms dihedral angles of 2.0 (5), 8.8 (5), 1.7 (5) and 7.9 (6)° with the peripheral phenyl rings. The isoindoline and xanthene rings subtend a dihedral angle of 89.8 (2)°. The mol-ecular conformation is stabilized by an intra-molecular C-H⋯O hydrogen bond generating an S(6) ring motif. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds together with C-H⋯π (ring) inter-actions, forming a three-dimensional network. A Hirshfeld surface analysis of the crystal structure indicates that the most important contributions to the crystal packing are from H⋯H (68.1%), C⋯H/H⋯C (21.2%) and O⋯H/H⋯O (8.7%) contacts. The optimized structure calculated using density functional theory (DFT) at the B3LYP/6 - 31 G(d) level is compared with the experimentally determined mol-ecular structure in the solid state. The HOMO-LUMO behaviour was used to determine the energy gap and the mol-ecular electrostatic potential (MEP) of the compound was investigated.

Design and construction of an offshore diffuser augmented wind turbine with a high efficiency alternator

This paper describes the design and the assembly of a new type of a ducted wind turbine with an electric power generator adopting permanent high coercive magnets embedded in the peripheral ring of the rotor. The nominal power is 20 kW, and the maximum diameter of the external duct is 9 meters. The project has been carried out within the Marine Energy Laboratory (MEL) funded by the Italian Ministry for Education, University and Research (MIUR) and collects the most advanced technologies of naval maritime engineering and combines them with energy and turbomachinery technologies. The presence of a divergent duct enables the interception of a greater air mass flow rate, allowing the reduction of the rotor diameter and the deflections of the blades; hence, at constant tip speed ratio, a higher rotational speed compared to conventional turbines and a better efficiency of the permanent magnet power generator.

Bare and ligand protected planar hexacoordinate silicon in SiSb3M3 + (M = Ca, Sr, Ba) clusters.

The occurrence of planar hexacoordination is very rare in main group elements. We report here a class of clusters containing a planar hexacoordinate silicon (phSi) atom with the formula SiSb3M3+ (M = Ca, Sr, Ba), which have D3h (1A1′) symmetry in their global minimum structure. The unique ability of heavier alkaline-earth atoms to use their vacant d atomic orbitals in bonding effectively stabilizes the peripheral ring and is responsible for covalent interaction with the Si center. Although the interaction between Si and Sb is significantly stronger than the Si–M one, sizable stabilization energies (−27.4 to −35.4 kcal mol−1) also originated from the combined electrostatic and covalent attraction between Si and M centers. The lighter homologues, SiE3M3+ (E = N, P, As; M = Ca, Sr, Ba) clusters, also possess similar D3h symmetric structures as the global minima. However, the repulsive electrostatic interaction between Si and M dominates over covalent attraction making the Si–M contacts repulsive in nature. Most interestingly, the planarity of the phSi core and the attractive nature of all the six contacts of phSi are maintained in N-heterocyclic carbene (NHC) and benzene (Bz) bound SiSb3M3(NHC)6+ and SiSb3M3(Bz)6+ (M = Ca, Sr, Ba) complexes. Therefore, bare and ligand-protected SiSb3M3+ clusters are suitable candidates for gas-phase detection and large-scale synthesis, respectively.

Cationic surfactant-directed structural control of NaCl crystals from evaporating sessile droplets.

We report morphological regulation of NaCl (sodium chloride) crystals through the evaporative crystallisation process of microdroplets containing a cationic surfactant CTAB (cetyltrimethylammonium bromide). Various fascinating evaporative salt morphologies are observed using different combinations of salt (CNaCl) and surfactant (CCTAB) concentrations. Each observed morphology is carefully explained by the interplaying physical phenomena, such as crystallisation, micellisation, evaporative dewetting, and surface adsorption of anionic couneterions. Salt morphologies are investigated for low (CNaCl = 0.1 (M)), intermediate (CNaCl = 0.5 (M)) and high (CNaCl = 2 (M)) concentrations, whereas surfactant concentrations are varied four orders of magnitudes (from 0.0001 (M) to 0.1 (M)). Interestingly, we observe a threshold in CCTAB at 0.001 (M), beyond which the peripheral rings of dried deposits are found to be composed of CTAB for CNaCl = 0.1 (M), while the same is seen to be made up of NaCl for CNaCl = 2 (M). We have explained the morphological evolution by the process of competitive surface adsorption phenomenon between Cl- and Br- counter ions. Such a detailed study of saline droplet crystallisation in the presence of a cationic surfactant underpins the fundamental understanding of the crystallisation process. In addition, it may further impact application sectors where crystallisation of saline solution plays an important role, especially in the presence of additives.

Development of Highly Efficient Radiation-Convective Recuperator for Furnace of Secondary Aluminum Melting

The high efficient design of the radiation-convective recuperator with secondary emitters have been proposed, in which due to the rational arrangement of heating surfaces, as well as due to the installation of secondary emitters in flues, an increase in heat perception is transmitted to the secondary heat carrier – preheating air. High efficiency of air preheating is provided by two-stage heating: 1st stage of heating – the internal air ring channel with bilateral heating which is washed by combustion products from the parties of the central cylindrical and peripheral ring channels of combustion products; 2nd stage of heating – the external air ring channel in which unilateral heating by products of combustion from the peripheral ring channel of products of combustion is organized. Inner and outer annular air ducts (tanks), interconnected by bypass pipes. To increase the efficiency of heat transfer in the considered recuperator in the central channel of combustion products is placed emitter, which consisting of intersecting radial plates, and in the annular channel of combustion products are placed auxiliary emitters, which made in the form of flat radial edges. These emitters provide an increasing in total heat flux to the walls of the channels of the recuperator. On the basis of the conducted theoretical researches, engineering calculations and CFD – modelling the characteristics of operation of the recuperator for its installation on the furnace of secondary smelting of aluminium are defined. The main advantages of the new design of recuperator are high thermo-hydraulic efficiency, compactness and low metal consumption, ease of installation on the furnace and no need for placement in separate chimneys. It is established that the recuperator provides air heating ta,ex ~ 400 °C at an acceptable aerodynamic drag (pressure drop) on the air track (∆pa ~ 1000 Pa). Appropriate design documentation has been developed for the manufacture of the recuperator, which is installed on a pilot furnace of secondary aluminium smelting by California Die Casting (USA).

Multi-slice spiral CT findings of tubulovillous adenoma of the duodenum

ObjectivesTo analyze the appearance of duodenal tubulovillous adenoma on multi-slice spiral CT images to facilitate early diagnosis and treatment to potentially improve prognosis. MethodsWe retrospectively analyzed clinical data and CT imaging findings of 11 cases of duodenal tubulovillous adenomas, all confirmed by pathology. The location, size, shape, CT density, relationship with surrounding structures, accompanying bile duct obstruction, and enhancement pattern of each lesion were documented. ResultsAll 11 lesions occurred in the descending part of the duodenum. Ten cases occurred in the duodenal papilla area. Nine cases had a low-density ring sign or semicircle sign between the lesion and the adjacent normal intestinal wall on axial images. Eight cases had differing degrees of bile duct dilatation, five of which had concomitant pancreatic duct dilatation. Noncontrast images revealed uniform soft tissue density; contrast enhanced images showed moderate, mostly uniform enhancement, with the most enhancement in the venous phase. In the arterial phase, two lesions showed linear enhancing vessels. ConclusionsOn multi-slice spiral CT imaging, duodenal tubulovillous adenomas have certain characteristics that could be used for clinical diagnosis and treatment. PrecisOn multi-slice spiral CT imaging of duodenal tubulovillous adenoma, findings of nodular or cauliflower-like shape, uniform density, uniform moderate enhancement, and a peripheral low-density ring sign could improve diagnostic accuracy.

Osteoarthritis Affects Mammalian Oogenesis: Effects of Collagenase-Induced Osteoarthritis on Oocyte Cytoskeleton in a Mouse Model.

Known as a degenerative joint disorder of advanced age affecting predominantly females, osteoarthritis can develop in younger and actively working people because of activities involving loading and injuries of joints. Collagenase-induced osteoarthritis (CIOA) in a mouse model allowed us to investigate for the first time its effects on key cytoskeletal structures (meiotic spindles and actin distribution) of ovulated mouse oocytes. Their meiotic spindles, actin caps, and chromatin were analyzed by immunofluorescence. A total of 193 oocytes from mice with CIOA and 209 from control animals were obtained, almost all in metaphase I (M I) or metaphase II (MII). The maturation rate was lower in CIOA (26.42% M II) than in controls (55.50% M II). CIOA oocytes had significantly larger spindles (average 37 μm versus 25 μm in controls, p < 0.001), with a proportion of large spindles more than 64% in CIOA versus up to 15% in controls (p < 0.001). Meiotic spindles were wider in 68.35% M I and 54.90% M II of CIOA oocytes (mean 18.04 μm M I and 17.34 μm M II versus controls: 11.64 μm M I and 12.64 μm M II), and their poles were approximately two times broader (mean 6.9 μm) in CIOA than in controls (3.6 μm). CIOA oocytes often contained disoriented microtubules. Actin cap was visible in over 91% of controls and less than 20% of CIOA oocytes. Many CIOA oocytes without an actin cap had a nonpolarized thick peripheral actin ring (61.87% of M I and 52.94% of M II). Chromosome alignment was normal in more than 82% in both groups. In conclusion, CIOA affects the cytoskeleton of ovulated mouse oocytes—meiotic spindles are longer and wider, their poles are broader and with disorganized fibers, and the actin cap is replaced by a broad nonpolarized ring. Nevertheless, meiotic spindles were successfully formed in CIOA oocytes and, even when abnormal, allowed correct alignment of chromosomes.