This paper demonstrates a novel bistable energy harvester coupled with a nonlinear elastic boundary (NEB-BVEH). The nonlinear elastic boundary changes the dynamic response of the bistable vibration energy harvester and improves its performance by providing additional support for the inclined spring through coupled dynamics. This work considers the performance of bistable vibration energy harvesters using different elastic boundary under different excitation amplitudes, including bistable energy harvester with linear elastic boundary (LEB-BVEH) and NEB-BVEH with different horizontal spring stiffness. The comparative results show that the performance of NEB-BVEH and LEB-BVEH is approximately the same under small excitation amplitude. However, NEB-BVEH with adding horizontal springs can significantly improve performance compared to LEB-BVEH under larger excitation amplitude. Results of the investigated case show that the bandwidth of NEB-BVEH is increased by 89.31%. The output power is increased by more than 25%. A comparative study demonstrates the superiority of NEB-BVEH, which is very beneficial for energy harvesting.