Cell Performance Research Articles

Early Diagnosis of Triple-Negative Breast Cancer Based on Dual microRNA Detection Using a Well-Defined DNA Crown-Carbon Dots Structure as an Electrochemiluminescence Sensing Platform.

Triple-negative breast cancer (TNBC) is the most aggressive subtype of breast cancer (BC). Thus, early detection and accurate diagnosis of this cancer are crucial for improving the survival rate of patients. Specific microRNAs (miRNAs) have been implicated in the occurrence, proliferation, and metastasis of TNBC. Addressing this need, our study developed a biosensor platform for early and accurate TNBC diagnosis by integrating electrochemiluminescence (ECL) technology with a DNA sensing strategy. Specifically, synthesized positively charged carbon dots (CDs) were used to neutralize the electrostatic repulsion between DNA strands and facilitate the assembly of DNA triangular prisms (DNA TP-CDs). Hairpins were then incorporated into the DNA TP-CDs to form the final DNA crown structure. The early TNBC biomarker, microRNA-93-3p (miR-93-3p), allowed for the binding between the DNA Crown and the DNA track on the electrode and initiated the ECL signal. Subsequently, microRNA-210 (miR-210) unlocked the DNA tripedal walker, and its movement on the DNA Crown eventually quenched the ECL signal, enabling accurate TNBC diagnosis and tumor stage assessment. Our proposed biosensor had satisfactory sensing efficiency due to the ordered DNA track and rapid-moving DNA walker. The data revealed a good linear relationship between the ECL signals and the logarithm of miRNA concentrations, with miR-93-3p having a detection limit of 31.04 aM and miR-210 having a detection limit of 7.69 aM. The biosensor also showed satisfactory performance in serum samples and cells. Taken together, this study hopes to provide ideas and applications for clinical diagnosis as well as the personalized treatment of TNBC.

Eco-friendly synthesis of Nd³⁺-doped Eu₂O₃ nanoparticles for enhanced dye-sensitized solar cells utilizing oxalis Corniculata leaf extract

An environmentally friendly synthesis of Nd³⁺-doped Eu₂O₃ nanoparticles (NPs) was developed using Oxalis Corniculata leaf (OCL) extract to enhance the performance of dye-sensitized solar cells (DSSCs). The as-synthesized NPs were annealed at 600 °C to improve their crystallinity. X-ray diffraction and field-emission scanning electron microscopy revealed high crystallinity and a sub-100 nm spherical morphology. Annealing reduced the NP size from ∼85 nm to ∼45 nm and decreased the bandgap from 4.97 eV to 4.62 eV, enhancing low-energy photon absorption. Fourier-transform infrared spectroscopy showed changes in the chemical bonding environment, with a higher presence of dangling bonds in the as-prepared NPs compared to the 600 °C-annealed NPs, likely due to the OCL extract. Photoluminescence spectra confirmed strong red emission peaks at 580 nm and 612 nm, with a slight reduction in the full width at half maximum of the electric dipole transition after annealing. Integrating these NPs into TiO₂ matrices in DSSCs improved power conversion efficiency to 8.58%, outperforming both as-prepared NPs (6.88%) and bare TiO₂ cells (5.05%). This green synthesis approach offers a sustainable pathway for slightly enhancing performance of photovoltaic devices, with additional potential for UV-shielding applications when incorporated into PVA films.

Self‐Induced Bi‐interfacial Modification via Fluoropyridinic Acid For High‐Performance Inverted Perovskite Solar Cells

AbstractThe uncontrolled crystallization of perovskite generates a significant number of internal and interfacial defects, posing a major challenge to the performance of perovskite solar cells (PSCs). In this paper, a novel bi‐interfacial modification strategy utilizing 5‐fluoropyridinic acid (FPA) is proposed to modulate crystal growth and provide defect passivation. It is demonstrated that FPA is self‐deposited at both the top and bottom interfaces of perovskite films during thermal annealing. The CO and N functional groups in FPA serve as chelating agents, binding closely to uncoordinated Pb2+/Pb clusters, thereby passivating defects and reducing charge recombination at the interfaces. The strong chemical interactions between FPA and Pb further stabilize the Pb‐I framework, promoting the formation of high‐quality perovskite films, as confirmed by in situ photoluminescence measurements. Consequently, the modified inverted PSCs achieved an exceptional power conversion efficiency (PCE) of 25.37%. Moreover, the devices retained over 93.17% of initial efficiency after 3000 h of continuous illumination under one‐sun equivalent conditions in a nitrogen atmosphere. This paper presents a promising pathway for enhancing the performance and stability of inverted PSCs through a self‐induced bi‐interfacial modification approach.

Ionic Liquid-Assisted Strategy for Morphology Engineering of Inorganic Cesium-Based Perovskite Thin Films Toward High-Performance Solar Cells.

The wide bandgap CsPbI2Br perovskite materials have attracted significant attention due to their high thermal stability and compatibility with narrow bandgap materials in tandem devices. The performance of perovskite solar cells (PSCs) is highly dependent on the quality of the perovskite layer, which is governed by the crystallization process during solution processing. However, the crystallization dynamics of CsPbI2Br thin films remain less explored compared to conventional organic-inorganic perovskites. Achieving high-quality CsPbI2Br films with uniform morphology and large perovskite grains remains challenging with standard solution techniques. This study applies the ionic liquid (IL) [EMIM]+[PF6]- as an additive within the bulk CsPbI2Br absorber layer. Within our experimental regime, [EMIM]+[PF6]- accelerates the crystallization process while promoting the formation of large perovskite grains, a feature not commonly observed in previous studies. Our experimental results suggest that the IL acts as heterogeneous nucleation sites, and varying IL incorporation amount significantly impacts the morphology of CsPbI2Br perovskite films. Consistent UV-vis and photoluminescence (PL) red-shifts are observed in the IL-incorporated CsPbI2Br films, with X-ray diffraction (XRD) data projecting an influence on the perovskite crystal structure. These findings provide new insights into the role of ILs in controlling crystallization and morphology that have been minimally discussed in the literature. The incorporation of an optimized amount of [EMIM]+[PF6]- promotes the formation of highly crystalline perovskite thin films with excellent morphology, reducing defect density, enhancing carrier transport, and yielding large grain sizes. As a result, PSCs fabricated with [EMIM]+[PF6]- achieved a power conversion efficiency (PCE) of 17.11% (stabilized at 15.87%) and an open-circuit voltage (VOC) of 1.39 V, along with improved stability compared to control devices. This work provides a straightforward approach for producing high-quality CsPbI2Br thin films with high reproducibility, contributing valuable advancements to Cs-based PSCs.

Surface Modification of Heterojunction with Intrinsic Thin Layer Solar Cell Electrode with Organosilane

Solar cell (SC) technologies, which are essential in the transition toward sustainable energy, utilize photovoltaic cells to convert solar energy into electricity. Of the available technologies, heterojunction with intrinsic thin-layer (HIT) solar cells offers high efficiency and reliability. The current study explored the enhancement of HIT solar cell performance through the use of 3-aminopropyltrimethoxysilane (APTMS) self-assembled monolayers (SAMs) on the surface of the cells’ indium tin oxide (ITO) layer. Photoluminescence mapping revealed greater brightness and photocurrent in the HIT sample treated with APTMS SAMs, with the results indicating more favorable optical and electrical properties. The application of APTMS SAMs led to higher open-circuit voltage, fill factor, maximum power output, and efficiency by passivating the ITO surface and achieving energy level alignment, thereby enhancing the charge carrier dynamics. These findings demonstrate the potential of APTMS SAMs to improve HIT solar cell efficiency and reliability.

Evaluating the Impact of Laundering on the Electrical Performance of Wearable Photovoltaic Cells: A Comparative Study of Current Consistency and Resistance

Wearable photovoltaic technology has been prominent in recent years because electronic devices need to be powered continuously without reliance on traditional methods. However, the practical adoption of wearable PV cells is hindered by the need for laundering, potentially degrading performance. This research compared PV cells’ maximum current and electrical resistance before and after laundering testing conditions. This study used eight samples of two types of PV panel cells and laundered them up to five cycles. The current and electrical resistance values were recorded before and after each laundering cycle. This study analyzed the data using a paired sample t-test and MANOVA. It was found that laundering cycles significantly affected the current values in both types of samples, with no differential impact between the types; on the other hand, laundering cycles did not significantly affect the electrical resistance values in both types of samples, with no differential impact between the types. These results are crucial for industries developing textile-based PV panels, where maintaining electrical performance after laundering is essential. These findings could pave the way for more sustainable, self-powered wearable PV technologies, ultimately transforming how users interact with electronic devices daily.

Insulator-donor electron wavefunction coupling in pseudo-bilayer organic solar cells achieving a certificated efficiency of 19.18%

Abstract The incorporation of polymeric insulators has led to notable achievements in the field of organic semiconductors. By altering the blending concentration, polymeric insulators exhibit extensive capabilities in regulating molecular configuration, film crystallinity, and mitigation of defect states. However, current research suggests that the improvement in such physical properties is primarily attributed to the enhancement of thin film morphology, an outcome that seems to be an inevitable consequence of incorporating insulators. Herein, we report a general and completely new effect of polymeric insulators in organic semiconductors: the insulator-donor electron wavefunction coupling effect. Such insulators can couple with donor polymers to reduce the energy barrier level and facilitate the intramolecular electron transport. Besides the morphological effects, we observed that this coupling effect is another mechanism that can significantly enhance the electron mobility (up to 100 times) through the incorporation of polymeric insulators in a series of donor systems. With this effect, we proposed a polymeric insulator blending approach to fabricate state-of-the-art pseudo-bilayer organic solar cells, and the PM6/L8-BO device exhibits a high efficiency of 19.50% (certificated 19.18%) with the improved interfacial electron transport property. This work not only offers a novel perspective on the quantum effect of polymeric insulators in organic semiconductors, but also presents a simple yet effective method for enhancing the performance of organic solar cells.

Performance of dye-sensitized solar cells of perovskite sodium bismuth titanate layer and studying the effect of Fe-doped on the photovoltaic properties

Performance of dye-sensitized solar cells of perovskite sodium bismuth titanate layer and studying the effect of Fe-doped on the photovoltaic properties

Innovative Materials for High-Performance Tin-Based Perovskite Solar Cells: A Review.

With the rapid development of lead-based perovskite solar cells, tin-based perovskite solar cells are emerging as a non-toxic alternative. Material engineering has been an effective approach for the fabrication of efficient perovskite solar cells. This paper summarizes the novel materials used in tin-based perovskite solar cells over the past few years and analyzes the roles of various materials in tin-based devices. It is found that self-assembling materials and fullerene derivatives have shown remarkable performance in tin-based perovskite solar cells. Finally, this article discusses design strategies for new materials, providing constructive suggestions for the development of innovative materials in the future.

Design and performance exploration of Pb-free low-cost all-inorganic perovskite-inspired CuAgBi2I8 solar cells: theoretical approach

Abstract Organic–inorganic halide perovskites have demonstrated great potential for photovoltaic applications owing to their unprecedented optoelectronic properties and low manufacturing costs. However, the commercialization of this technology is hindered by its thermal instability and inherent toxicity. In this study, SCAPS-1D simulation software was used to study the performance of solar cell based on CuAgBi2I8, which is a novel inorganic non-toxic lead-free perovskite-inspired material. Different electron transport layers (TiO2, In2S3, ZnO, Zn0.75Mg0.25O,SnO2 and SrTiO3) and hole transport layers (CuI, PEDOT:PSS, CuSCN and Cu2O) were studied, our research indicated that SnO2 and NiO formed the optimal combination. Further analysis revealed that the optimal absorption layer thickness was 900 nm, the absorption layer doping concentration should be less than 1 × 1013 cm−3 and the defect density should be less than 1 × 1014 cm−3. The optimal thickness of SnO2 and NiO was 30 nm, the optimal doping concentration of SnO2 and NiO was 1 × 1020 cm−3, the defect density of absorber layer/SnO2 and absorber layer/NiO interfaces should be less than 1 × 1012 cm−3, C was the optimal back electrode material. Consequently, the optimal device configuration was identified as FTO/SnO2/CuAgBi2I8/NiO/C, the efficiency was improved from original 2.76% to 19.10% after above optimization. These results indicate that solar cell with CuAgBi2I8 as the absorber layer is a potential alternative to organic–inorganic lead halide perovskite solar cells.

Probing Nanoscale Charge Transport Mechanisms in Quasi-2D Halide Perovskites for Photovoltaic Applications.

Quasi-2D layered halide perovskites (quasi-2DLPs) have emerged as promising materials for photovoltaic (PV) applications owing to their advantageous bandgap for absorbing visible light and the improved stability they enable. Their charge transport mechanism is heavily influenced by the grain orientation of their crystals as well as their nanostructures, such as grain boundaries (GBs) and edge states─the formation of which is inevitable in polycrystalline quasi-2DLP thin films. Despite their importance, the impact of these features on charge transport remains unexplored. In this study, we conduct a detailed investigation on polycrystalline quasi-2DLP thin films and devices, carefully analyzing how grain orientation and nanostructures influence charge transport. Employing nondestructive atomic force microscopy (AFM) topography, along with transient absorption spectroscopy (TAS) and grazing-incidence wide-angle X-ray scattering (GIWAXS), we obtained significant insights regarding the phase purity, crystallographic information, and morphologies of these films. Moreover, our systematic investigation using AFM-based techniques, including Kelvin probe force microscopy (KPFM) and conductive AFM (c-AFM), elucidates the roles played by GBs and edge states in shaping charge transport behavior. In particular, the local band structure along the GBs and edge states within both vertical and parallel grains was found to selectively repel electrons and holes, thus facilitating charge carrier separation. These findings provide perspectives for the development of high-performance quasi-2DLP PV devices and highlight potential approaches that can leverage the intrinsic properties of quasi-2DLPs to advance the performance of perovskite solar cells.

Biocatalyst for carbon veil anode in microbial fuel cells: The effect of precursor and catalyst loading on overall performance

Biocatalysts in anodes have been crucial in improving microbial fuel cell (MFC) performance. Biocatalysts derived from biomass such as coconut wood sawdust (SD-B) and pepper processing residue (PS-B), were used to improve the electrocatalytic properties of Carbon Veil (CV) electrodes. The amorphous graphitic carbon biocatalyst with a mesoporous structure was found to have a surface area of 889.31 m2/g for SD-B and 763.56 m2/g for PS-B. Surface functional groups such as -OH which imparts hydrophilicity and -C=O and COOH which promotes bacterial compatibility have been revealed to be present in both catalysts. Catalyst loading played a major role and at an optimal loading of 2 mg/cm2, the electrodes exhibited maximum electrocatalytic activity in the case of both biocatalysts. The voltammetric capacitances of SD-B and PS-B modified electrodes were 191.6 mF/cm2 and 106.6 mF/cm2 demonstrating their pseudocapacitive behaviour too. The performance of MFC with SD-B revealed a maximum power density of 10.1 W/m3 (Open Circuit Voltage (OCV) of 850 mV), followed by PS-B at 6.89 W/m3 (OCV of 825 mV) whereas the plain CV was at 0.168 W/m3 (OCV of 760 mV). Anode polarization studies indicated reduced slopes for biocatalyst-modified anodes, signifying improved electrode kinetics, particularly notable in the SD-B modified MFC where the cathode became the limiting electrode. Coulombic efficiencies of the biocatalyst-modified MFCs increased to 54.50%, (SD-B 2 mg/cm2) and 37.78% (PS-B 2 mg/cm2) respectively from 12.74% as noticed in the case of unmodified MFC. This study emphasizes the potential of biocatalysts as a simple and low-cost means of enhancing the anode properties – porosity, conductivity, hydrophilicity, and biocompatibility.

PVDF and PEO Catholytes in Solid‐State Cathodes Made by Conventional Slurry Casting

AbstractAll‐solid‐state Li batteries are desired for better safety and energy density than Li‐ion batteries. However, the lack of a penetrating liquid electrolyte requires a much different approach to the design of cathodes. The solid catholyte must enable good Li+ conduction, form good interfaces with active material particles, and have the strength to bind the cathode together during repeated volume changes. Catholyte formulation is often simply adapted from Li‐ion design principles, adding a Li salt to the PVDF binder. Here we show that such a PVDF binder at 10 wt % loading is a starved catholyte condition that compromises cell performance. By substituting a 70 : 30 blend of PVDF:PEO, performance is improved while maintaining nearly the same areal loading of LFP active material. Increasing the catholyte fraction to 16 % can also improve performance, but in this case the benefit of including PEO is lessened, with PVDF alone being an adequate catholyte. EIS analysis shows that PEO helps to form charge transfer interfaces at 10 % catholyte, but that its inclusion can degrade interfaces when there is ample catholyte at 16 %. It is also shown that catholyte agglomeration can impede bulk Li conduction, indicating that microstructural factors are of critical importance.

Effects of droplet dynamical behavior in flow channel of proton exchange membrane fuel cell under vibration conditions on cell performance

Proton exchange membrane fuel cells are subjected to severe vibration in aerospace applications. Understanding the droplet transport characteristics in the flow channelunder vibration conditions is essential for improving cell performance. However, the underlying patterns and mechanisms of the vibration effects on cell performance and its internal water transport remain unclear, and there is a lack of improvement methods for drainage under vibration conditions. This study experimentally investigates the effect of vibration on cell performance. Experimental results indicate that vibration predominantly affects cell performance through its modulation of water transport. Therefore, the droplet dynamic behavior in the flow channel is further studied using the volume of fluid method. The results indicate that vibrations can enhance the average performance of the fuel cells, with the largest increase of 8.30 %. This is attributed to vibrations promoting the detachment of droplets from the gas diffusion layer surface and reducing the water coverage ratio on said surface. Under conditions of low gas velocity, high surface hydrophobicity, and large droplet size, droplets exhibited oscillatory and jumping behavior in the flow channel due to vibration, resulting in the largest 53.5 % increase in peak water coverage ratio on the gas diffusion layer surface compared to no-vibration conditions. Furthermore, enhancing the hydrophobicity of the gas diffusion layer and the hydrophilicity of the channel walls promotes droplet detachment and discharge compared to no-vibration, as well as contributing to the improvement of vibration effects on the drainage process.

Applications of Two-dimensional Materials in Perovskite Solar Cells

As a new type of solar cell, perovskite solar cells (PSCs) exhibit significant potential due to the high performance. In recent years, they have garnered substantial attention due to their impressive photovoltaic conversion efficiency, low production costs, malleability, and other advantageous characteristics. However, there remains considerable room for the improvement in the performance of perovskite solar cells. Key factors that critically influence their performance include the charge transport layer, electrode materials, and overall cell structure. Two-dimensional (2D) materials, as emerging substances, facilitate the modifications of PSCs and enhance the electronic conduction. In this paper, a concise overview of perovskite solar cells is provided, followed by a summary of the current progress in enhancing their performance. The applications of 2D materials in the solar cell sector are highlighted. Finally, the existing challenges and issues confronting perovskite solar cells are discussed. This work will help promote the application of 2D materials in PSCs.

Graphene-Based Materials in Energy Storage and Conversion Devices

Global energy demand and environmental concerns have grown increasingly over the years. To solve these problems, advanced energy storage and conversion technologies are essential. This work explores the applications of graphene-based materials to enhance the performance of lithium-ion batteries, supercapacitors, and solar cells. In lithium-ion batteries, graphene significantly improves electrical conductivity, mechanical stability, and energy capacity, thereby improving battery performance. Likewise, in supercapacitors, graphene-based electrodes exhibit excellent specific capacitance and energy density, which are crucial for high-power applications. In solar cells, graphene improves photoelectric conversion efficiency and stability, especially in perovskite and ZnO/Si heterojunction solar cells. However, the high cost and complexity of producing graphene limit its widespread use. Future research should focus on developing cost-effective production methods, optimizing graphene properties through doping, exploring composite materials, and expanding graphene applications in sustainable energy and environmental fields. This work provides an overview of current progress and suggests directions for future research in this area.

Oxygen enriched PAni-based counter electrode network toward efficient dye-sensitized solar cells (DSSCs)

Dye-sensitized solar cells (DSSCs) have great potential as a renewable energy technology assisting combat climate change due to its low cost, adaptability, and sustainability. Oxygen plasma ion doping is a promising strategy to improve the capacity of a low-cost, platinum-free counter-electrodes (CEs) to absorb photons and drive high-performance DSSCs via generating an abundance of active absorption sites. In this instance, novel PAni–ZnO (PZ) composite layers were designed as a CE material and received various in-situ oxygen plasma dosages, including 0, 2, 4, 6, 8, and 10 min, to improve their physiochemical and microstructural feature for the first time, to the best of our knowledge. Physical evaluations of the microstructure, porosity, morphology, contact angle, roughness, electrical, and optical, electrochemical impedance spectroscopy (EIS) features of CEs were conducted in along with an evaluation of J–V variables. Compared to pristine CE substance, the surface nature of the modified hybrids was gradually enhanced as the plasma level rose, reaching an optimum after 8 min (i.e. 0.2 µm for average pore size and average roughness Ra = 7.21 µm). Expanded plasma treatment doses also improved PV cell performance even further: after 4 min at a plasma level, η = 5.41% was obtained, and after 6 min in a oxygen plasma environment, η = 5.81% was obtained. Mixing high energetic plasma ions increased the mobility of charge carriers in PAni composites along with lowered charge carrier recombination through generating an environment that was conducive to charge dissociation. Therefore, longer lifespans and more effective charge transfer inside the photovoltaic cell as a consequence of the increased mobility less resistive losses. In this respect, following 8 min of plasma surface modification of the PZ CE, the optimized efficiency of 6.31% and Jsc of 15.6 mA/cm2 were obtained. The improvement in efficiency equated to a proportion growth of 77% versus a pristine one. This gain was explained by the reality that suffusing a quantity of oxygen plasma free radicals into the PAni system developed continuous channels that enabled the mixture to move electrons more rapidly, hence raising the photovoltaic efficiency. Overall, this study highlights the advantages of regulating heteroatom species and their co-doping, offering a new perspective for the application of heteroatom-doped CE in DSSCs.

Performance Investigation of a Novel Staggered Round Table Channel for Proton Exchange Membrane Fuel Cells

Based on the internal mass transfer of a proton exchange membrane fuel cell (PEMFC), a novel staggered round table channel is proposed, namely, round table stoppers are arranged on both sides of the channel and in the direction of gas flow. The study systematically investigates the effects of various structural parameters on the PEMFC performance, including the arrangement of round tables on both sides of the channel, radius, degree of sparseness, and number. It is found that the staggered arrangement can improve the cell performance more significantly, and the current density can be increased by 5.0% compared with the direct channel. With the proper increase of the radius and number of round tables, the round table stopper forces the reactant to diffuse downward and improves the uniformity of reactant distribution. Compared with other sparsity, the equidistant arrangement of stoppers in the channel is conductive to accelerating the convective mass transfer and drainage characteristics of the cell. As shown by numerical analysis results, the performance and dewatering efficiency of PEMFC are the best when the round tables on both sides are staggered, the radius is 0.65 mm, the number is 10, and the round table in the channel is arranged equidistantly.

Accelerating T1 relaxation time measurements of noble gas using transverse low-frequency square-wave magnetic field modulation.

The longitudinal relaxation time (T1) of noble gas nuclear spins is a critical parameter for evaluating the performance of an atomic comagnetometer, significantly influencing the signal-to-noise ratio of the system. Traditional measurement techniques, such as the free induction decay method combined with the spin growth technique (FIDSG), are time-consuming for gases with extended T1 durations, such as 21Ne, and are prone to substantial environmental variability. Here, we propose the transverse low-frequency square-wave magnetic field modulation (LSMM) method for the rapid measurement of T1. The experiment indicates that the LSMM significantly condenses the measurement time to 19.2% of the original, thereby diminishing the robustness demands of the system. Although a minor discrepancy of up to 3 min (or 1.3%) exists between LSMM and FIDSG results, the LSMM method provides strong support for calibrating the performance of comagnetometer cells and conducting various nuclear spin polarization experiments, thereby improving efficiency and reducing energy loss.

Correction to: Synergistic enhancement of electrochemical performance in reversible solid oxide cells via deficiency-induced oxygen vacancy and nanoparticle generation

Correction to: Synergistic enhancement of electrochemical performance in reversible solid oxide cells via deficiency-induced oxygen vacancy and nanoparticle generation