Performance Of Adsorption Chiller Research Articles

Experimental studies on the impact of adsorbent particle size on the adsorption chiller performance

Adsorption chiller dynamics and its effect on the performance are greatly influenced by the adsorbent particle size because they govern both the micro (intra-particle) and macro (inter-particle) heat and mass transfer resistances within the adsorber bed. The net effect of adsorbent particle size and shape on the overall cooling system performance is addressed here. Initial CFD analysis of columnar adsorber bed with silica gel + water as the working pair, assuming uniform spherical adsorbent, showed increased uptake capacity with smaller sized (0.23 mm radius) particles over bigger sized (0.8 mm radius) ones despite smaller vapor penetration depth of the former. Subsequently, the effect of adsorbent particle size and shape on the overall cooling system performance is investigated experimentally in a single-stage one-bed mode for RD 2060 (0.8 mm radius) and RD 3070 (0.23 mm radius) silica gel specimens. Though the smaller size of RD 3070 is favourable for the adsorption kinetics at the particle level, its non-spherical shape and highly non-uniform size distribution resulted in significantly lower permeability and thermal diffusivity of the packed adsorber bed, thus hindering the cyclic steady state throughput. For the same operating conditions, RD 2060 and RD 3070 yield a cooling capacity (CC) of 107 W and 22 W, respectively. Further, the coefficient of performance (COP) drops by 73% in the case of RD 3070. The present study indicates that the adsorber bed design must consider both the adsorbent size and shape, in addition to other system operational parameters to enhance performance indicators.

The Effect of Nozzle Configuration on Adsorption-Chiller Performance

Broadly defined climate protection is a powerful incentive in the search for environmentally friendly refrigeration technologies. Adsorption chillers are considered to be one such technology; however, their main disadvantages include a low cooling capacity, a low energy efficiency ratio (EER), and cyclic operation. Thus, a great deal of effort is being put into improving adsorption-chiller performance. In this paper, the influence of the spray angle, the number of nozzles, and the water flow rate through the nozzles on adsorption-chiller performance was investigated. Adsorption-chiller performance was investigated mainly in terms of the cooling capacity (CC), the energy efficiency ratio (EER), and the specific cooling power (SCP). The results indicated that the chiller’s cooling capacity increased from about 210 W to 316 W and that the EER increased from 0.110 to 0.167 when the spray angle of the nozzles was increased from 90° to 120°. It was also reported that increasing the flow rate of water through the nozzles did not improve the average cooling capacity or the other performance parameters but resulted in more stable operation of the chiller. Additionally, using six nozzles instead of three improved the average cooling capacity and EER tenfold.

Computer-aided molecular refrigerant design for adsorption chillers based on classical density functional theory and PC-SAFT

Adsorption chillers are a promising technology for sustainable cooling. The performance of adsorption chillers is highly influenced by the selection of the refrigerant. Still, systematic selection of refrigerants is challenging because evaluating adsorption properties requires significant experimental or simulation efforts. Thus, refrigerant design options are often limited.Here, we propose a systematic refrigerant design method for adsorption chillers assessing refrigerants based on their process performance. Our method quantifies adsorption isotherms by 1-dimensional classical density functional theory (DFT) based on the PC-SAFT equation of state. The method is used to screen over 1800 refrigerants based on their coefficient of performance (COP). We identify refrigerants with higher COPs than commonly used refrigerants and highlight the advantage of a process-based objective function over material-based heuristic selection criteria. Finally, we advance from screening to computer-aided molecular design of the refrigerant, leveraging the efficiency of the DFT model to explore the molecular design space systematically.

Performance of an Adsorption Chiller Using Diesel Truck Exhaust: Effect of Operating Parameters

ABSTRACT In India, air conditioning is essential in the truck driver’s cabin during the summer. An air conditioning system powered by the vehicle’s engine adds to the engine’s workload, resulting in higher fuel demand and more emissions. An adsorption chiller that runs on engine exhaust is designed here to lower the interior temperature of a truck cabin to address the above-mentioned issue. Here, an adsorption air conditioner system’s effectiveness is forecast using a lumped analytical technique. During the adsorption process, heat from the adsorber bed is absorbed by cold water and released into the radiator. The desorber bed has been heated using hot water as a heat transfer medium from the engine exhaust heat. The analysis was carried out using the adsorption kinetic equation at adsorption equilibrium. The influence of inlet water flow rate, temperature and switching time (adsorber process to desorber process and vice versa) on adsorption chiller performance has been studied here. According to simulation results, the proposed adsorption chiller can be used to keep the driver cabin cool during summer for operational conditions adopted during the simulation. The adsorption air conditioner’s highest coefficient of performance (COP), as determined by this investigation, was found to be 0.214.

Evaluation and Design of Large-Scale Solar Adsorption Cooling Systems Based on Energetic, Economic and Environmental Performance

In hot and dry regions such as the Gulf Cooperation Council (GCC) countries, the cooling demand is often responsible for more than 70% of electricity consumption, which places a massive strain on the electricity grid and leads to significant emissions. Solar thermal driven Silica-Gel/Water adsorption chillers, used for space cooling, could provide low carbon emission cooling and reduce the reliance on grid electricity. However, a meticulous design is required to make this both economically and environmentally beneficial. This paper aims to evaluate the solar thermal adsorption chiller performance based on large-scale cooling demand through a TRNSYS simulation for 1 year of operation. The proposed system consists of two main parts: first, the solar loop with evacuated tube solar collectors; and second, the adsorption cooling system with a silica-gel/water adsorption chiller. A neighbourhood of 80 typical 197 m2 villas in Riyadh, the capital city of the Kingdom of Saudi Arabia (KSA), was taken as a case study. The solar adsorption cycle’s performance has been compared to the conventional vapour compression cycle in terms of energy, economic and environmental performance. In addition, a parametric study has been performed for the main design parameters. Results reveal that the system can reach a solar fraction of 96% with solar collector area of 5500 m2 and a storage tank volume between 350 and 400 m3. Furthermore, the annual energy cost can be reduced by 74% for the solar adsorption system compared to the conventional vapour compression cycle. Meanwhile, the CO2 saving percentage for the solar adsorption cycle was approximately 75% compared to the conventional vapour compression cycle. Carefully designed solar thermal cooling systems can reduce greenhouse gas emissions while covering a large scale of cooling demands. This can reduce the strain on the electricity grid as well as greenhouse gas emissions.

Effect of heat exchanger materials on the performance of adsorption chiller

The effect of adsorber heat exchanger (adHEX) material on the system performance of a silica gel-water, fin-tube type adsorption chiller was investigated for three typical materials, aluminum (Al), copper (Cu) and stainless steel (SS), following both the first and second laws of thermodynamics. High thermal conductivity was expected to shorten switching time and prolong adsorption/desorption period, and consequently result in a larger amount of water vapor, and lower thermal mass. In other words, since the product of density and heat capacity increases the heat supplied to the system, higher thermal performance was expected for Cu. However, preliminary calculations failed to confirm the expectation. This study examined the causes by artificially changing the Al thermo-physical properties to those of the Cu and SS. Above a threshold thermal conductivity, the main cause was found to be the material’s density, and below the threshold, thermal conductivity was most important. The Al adHEX showed 0.518 of COP, 221 W/kg of SCP and 0.115 of ηe, which were 6.85 % and 6.53 % higher in COP and exergy efficiency than the Cu adHEX.

Relative importance of inter-particle mass transfer resistance in the modeling of adsorption chiller porous bed

In order to investigate the effects of various parameters on the adsorption chiller performance, the adsorbent bed must be modeled with the appropriate governing equations and assumptions. One of the assumptions, which greatly influences the modeling complexity and computational cost is the bed uniform pressure assumption, which relaxes the need for solving the momentum equations governing the motion of the refrigerant vapor through the porous bed. However, in some bed conditions the bed pressure distribution should be calculated and the inter-particle resistance cannot be neglected, which in turn requires the determination of the bed velocity field. It is of great practical importance to know in advance, whether the uniform pressure approach is appropriate for the modeling of the problem in hand. In this study, a dimensionless parameter based on the scale up analysis of the governing equations is introduced, which can be calculated based on the input data of the problem to decide about the appropriate bed pressure assumption prior to start the modeling process.

Dynamic optimization of adsorptive chillers: The “AQSOA™-FAM-Z02 – Water” working pair

Despite significant progress in commercial ACs (adsorption chillers) achieved for the last thirty years, still there is a much room for their further improvement. This paper addresses the optimization of dynamic performance of ACs utilizing loose grains of a novel adsorbent AQSOA™-FAM-Z02. The dynamic data were measured by a Volumetric Large Temperature Jump method under typical conditions of isobaric ad/desorption stages of real AC cycle. For the first time, the effects of number of the adsorbent layers (N = 2, 4, and 8), grain size (0.2–0.9 mm) and cycle boundary conditions were comprehensively studied. The most notable findings revealed for the water ad/desorption dynamics are: 1) the initial part of all kinetic curves is exponential and can be described by a single characteristic time τ; 2) at equal values of the ratio (S/m)=(heat transfer surface)/(adsorbent mass), the dynamic curves are very close regardless the adsorbent grain size R (the “grain size insensitive” regime is observed at 0.44 m2/kg ≤ (S/m) ≤ 1.75 m2/kg); 3) the maximal specific cooling power is a linear function of the (S/m)-ratio. Appropriate recommendations on improving the AC cycle dynamics which concern the optimal conversion degree, grain size and (S/m)-ratio are made.

Optimization of a fin-tube type adsorption chiller by design of experiment

This paper presents a numerical analysis of the performance of a fin-tube type adsorption chiller associated with heat and mass transfer mechanisms. A two-dimensional axisymmetric transient model is developed and 10 parameters are used to investigate their effects on the performance of an adsorption chiller and to obtain the optimized conditions of a fin-tube type adsorption chiller. Ten parameters found in many other studies, such as fin pitch, fin thickness, fin height, diffusion coefficient, particle size, cycle time, cycle ratio, temperature of hot water, fluid velocity and porosity, are used in this study. Based on the design of experiment, an orthogonal array of 10 parameters with three levels, L27(313) is used for the analysis of variance (ANOVA) and through this method, each parameter's level of contribution is carefully examined. The result shows that fin thickness and the temperature of hot water are the dominant parameters for COP and SCP, respectively. The optimum conditions having the highest COP of 0.6782 and SCP of 217.68 W kg−1 are found through the result.

Physical and operating conditions effects on silica gel/water adsorption chiller performance

Adsorption refrigeration systems are commercially developed due to the need of replacing the conventional systems which utilise environmentally harmful refrigerants and consume high grade electrical power. This paper presents the key equations necessary for developing a novel empirical lumped analytical simulation model for commercial 450kW two-bed silica gel/water adsorption chiller incorporating mass and heat recovery schemes. The adsorption chiller governing equations were solved using MATLAB® platform integrated with REFPROP® to determine the working fluids thermo-physical properties. The simulation model predicted the chiller performance within acceptable tolerance and hence it was used as an evaluation and optimisation tool. The simulation model was used for investigating the effect of changing fin spacing on chiller performance where changing fin spacing from its design value to minimum permissible value increased chiller cooling capacity by 3.0% but decreased the COP by 2.3%. Furthermore, the effect of generation temperature lift on chiller performance and the feasibility of using it as a load control tool will be discussed. Genetic Algorithm optimisation tool was used to determine the optimum cycle time corresponding to maximum cooling capacity, where using the new cycle time increased the chiller cooling capacity by 8.3%.

실리카겔-물계 흡착식 냉동기 사이클 시뮬레이션

An adsorption chiller is expected to have high energy-efficiency in utilizing the waste heat exhausted from a process. The objective of this paper is to investigate the performance of silica gel-water adsorption chiller from the cycle simulation and to provide a guideline for design of the adsorption chiller. The effect of cycle time, inlet temperature and water flow rate on the cooling capacity and COP is quantified during the cycle operation. It is found that the performance of adsorption chiller is more sensitive to the change of inlet water temperature rather than the water flow rate. It is concluded that the COP is 0.57 in the standard conditions(hot water 80℃, cooling water 30℃, chilled water inlet temperatures 14℃ and cycle time 420sec).

Experimental investigation of adsorption chiller for Micro-scale BCHP system application

Building cooling, heating and power (BCHP), is an attracting cogeneration system for its economic and environmental friendly qualities. Therefore, it is meaningful to develop Micro-scale BCHP (MBCHP) system based on adsorption chiller and internal combustion gas engine for the use of residential and light commercial buildings. To guide the optimum matching and operation of adsorption chiller in MBCHP system correctly, this paper deals with the performance of adsorption chiller under varying heating conditions. Experimental results show that the value of COP is high in the operation mode of varying hot water inlet temperature with mass recovery in no heating pattern (VTNH). With the hot water inlet temperature of 65 °C, the value of COP is as high as 0.40 in VTNH mode. Under electricity output conditions from 6.0 to 8.3 kW in MBCHP system, VTNH mode is especially preferred when cooling demand is with priority.

Influence of adsorption cycle limitations on the system performance

The economics of heat driven heat pumps are governed by two thermodynamic quantities: the performance on the one hand and the size of the heat exchangers, which is required to obtain this performance, on the other hand. The aim of this paper is to discuss the influence of the main features of adsorption cycles in comparison to absorption cycles on these quantities. In our case, a Zeolite UCC16×40-type 13X has been taken as the adsorbent. The analysis has already been used for absorption heat pumps. In the case of adsorption and other solid sorption chillers, additional limitations appear, e.g. identical design of all adsorbers, incomplete heat recovery between adsorbers, cycling of inert mass, etc., which all contribute to a lowering of the system performance or to an increase of the exchange area required. To show the basic differences between absorption and adsorption cycle optimization, and also to show the impact of physical or technical limitations on the adsorption chiller performance, a detailed analysis has been performed. It is confirmed that it is mainly the lack of a solution heat exchanger which lowers the adsorption system COP and not physical properties of the working pair, so there is still a lot of room for improvement in the solid-sorption of heat pumps.

Multi-bed regenerative adsorption chiller — improving the utilization of waste heat and reducing the chilled water outlet temperature fluctuation

A multi-bed regenerative adsorption chiller design is proposed. The concept aims to extract the most enthalpy from the low-grade waste heat before it is purged into the drain. It is also able to minimise the chilled water temperature fluctuation so that downstream temperature smoothing device may be downsized or even eliminated in applications where tighter temperature control may be required. The design also avoids a master-and-slave configuration so that materials invested are not under-utilised. Because of the nature of low-grade waste heat utilization, the performance of adsorption chillers is measured in terms of the recovery efficiency, η instead of the conventional COP. For the same waste heat source flowrate and inlet temperature, a four-bed chiller generates 70% more cooling capacity than a typical two-bed chiller. A six-bed chiller in turn generates 40% more than that of a four-bed chiller. Since the beds can be triggered into operation sequentially during start-up, the risk of ice formation in the evaporator during start-up is greatly reduced compared with that of a two-bed chiller.