Capture Performance Research Articles

Design and synthesis of Mg-HKUST-1/solid ionic liquid composites for CO2 capture with improved water stability

The water sensitivity HKUST-1, is a critical concern for realizing practical CO2 capture. Water stability and high CO2 adsorption are difficult to achieve simultaneously. Mg and piperazinium-based solid ionic liquids (SoILs) were incorporated into HKUST-1 to enhance its water stability and selective CO2 capture performance, respectively. The eco-friendly route was utilized for the synthesis of bimetallic Mg(x)-HKUST-1, employing water as the sole solvent with stirring and microwave treatment. The SoILs were incorporated into the pore structure of Mg(15)-HKUST-1 by wet impregnation. Among the different ratios of Mg used for the synthesis, 15 % Mg exhibited the highest improvement in CO2 capacity (5.32 mmol/g) and CO2/N2 selectivity (27) compared to the parent HKUST-1 (CO2 capacity, 4.2 mmol/g; CO2/N2 selectivity, 17). Once Mg(15)-HKUST-1 was impregnated with 10 % SoIL, the CO2 capture performance was further improved. In the stability study, 10 % SoIL/Mg(15)-HKUST-1 and Mg(15)-HKUST-1 preserved respectively 92.4 % and 85.3 % CO2 adsorption capacity after 20 days of exposure to a humid environment (60 % RH) at 298±5 K, an improvement compared to the HKUST-1 (26 %). The CO2 and N2 adsorption capacities of HKUST-1, Mg-HKUST-1, and SoIL/Mg-HKUST-1 composite were measured using a volumetric method and characterized using Brunauer-Emmett-Teller (BET) analysis, scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, powder X-ray diffraction (PXRD), and thermogravimetric analysis (TGA).

Enhanced hydrogen storage and CO2 capture capacities on carbon aerogels from Ni-N co-doping

Carbon aerogels (CAs) has been a promising candidate for gas adsorption due to their unique attributes, but the poor surface properties and temperature reliance limit the application range. Investigations have proven that surface modification can enhance the adsorption performance. Thus, nickel and nitrogen co-doped cellulose-based carbon aerogels were synthesized by introducing nanoparticles. The outcomes demonstrate the excellent adsorption capacity and reversible adsorption/desorption features. Nickel particles improved the dissociation of hydrogen by “hydrogen spillover” effect, and interacted electrostatically with CO2 enhanced the capture performance. Nitrogen particles enhanced the unsaturation of Ni active sites and the surface basicity, resulting a stronger interaction force with adsorbed gases. Ultimately, despite a slightly decrease in specific surface area and micropore volume, the sample exhibit the hydrogen storage capacity of 0.79 wt.% (298 K) and 7.4 wt.% (77 K), and the CO2 capture of 17.1 mmol/g (298 K). Unique design strategy of co-doping reduced the reliance on surface area and temperature changes, and is expected to be a regular means of industrial modification of carbon materials.

Experimental and DFT study of Na4SiO4 doped with oxysalts for high-temperature CO2 capture

Eutectic doping has been considered as one of the most efficient ways to modify the Na4SiO4-based CO2 sorbent. Nevertheless, the effects of different acid radical ions and alkali metal cations of the oxysalts on the CO2 capture performances of Na4SiO4 have never been explored. In this study, Na4SiO4-based CO2 sorbents were prepared using four kinds of oxysalts as the dopants. The effects of acid radical ions/alkali metal cations, doping ratios and sorption/desorption temperatures on the CO2 capture performances of sorbents were investigated. The results showed that the promotion effects of CO32− and Li+/K+ ions were stronger than others, the maximum CO2 sorption capacity of Na4SiO4-30Li2CO3 and Na4SiO4-30K2CO3 at 700 °C reached 20.6 wt% and 19.5 wt%, respectively. The cyclic sorption capacity of Na4SiO4-30Li2CO3 was 8.5 wt%, which was 40.0% higher than that of Na4SiO4. Further, the oxysalt dopants could enhance the CO2 adsorption energy on the Na4SiO4 surfaces and reduce the energy level of the systems using density functional theory calculation, which were consistent with the experimental values. Finally, the effects of water vapor on the sorption of Na4SiO4 and Na4SiO4-K2CO3 were simulated, which could enhance the activity of O atoms on sorbent surfaces and promote rapid carbonization during the sorption progress. Thus, Na4SiO4 doped with oxysalts exhibit promising potential for high-temperature CO2 capture application.

A combined experimental and simulations assessment of CO2 capture and CO2/H2 separation performance of aminosilane-grafted MCM-41 and pore-expanded MCM-41

Amine-functionalized mesoporous silica materials have attracted considerable attention as robust adsorbents for large-scale CO2 capture and direct air capture (DAC). Amine grafting increases selective affinity at low pressures, yet also often reduces the adsorbent's pore volume and surface area, affecting the kinetics and capacity upon CO2 adsorption. MCM-41 and pore-expanded MCM-41 (PE-MCM-41) were developed here, functionalized using 3-aminopropyl triethoxy silane (APTES), and comparably evaluated for their carbon capture performance at different conditions by a combinational experimental, equilibrium and kinetic modelling, and molecular simulations approach. In specific, CO2 adsorption capacity, CO2/N2 selectivity, CO2 adsorption at humid conditions, heat of adsorption, and regeneration/cyclability were assessed, coupled to molecular simulation insights on the physisorption and chemisorption contribution to the overall adsorption uptake. Indicatively, a capacity value of 3.07 and 2.44 mmol/g was obtained for APTES-PE-MCM-41, and 2.27 and 1.89 mmol/g for APTES-MCM-41, under wet and dry conditions, respectively. The CO2 selective adsorption from H2 rich gas streams was also examined over APTES-MCM-41 in order to assess the potential application in H2 stream purification process. The latter is of high significance in order to use hydrogen as fuel e.g. in anion exchange membrane fuel cells for power production since the presence of CO2 in the feed composition is considered a major drawback in their commercialization.

Carbon Dioxide Capture Performance of Mesostructured Adsorbent Impregnated with Polyethylenimine

Carbon Dioxide Capture Performance of Mesostructured Adsorbent Impregnated with Polyethylenimine

Direct air capture with amino acid solvent: Operational optimization using a crossflow air‐liquid contactor

AbstractDirect air capture (DAC) is a negative emission technology for removing CO2 from the atmosphere to maintain the CO2 level within a reasonable range so as to address greenhouse effects. In this study, the operational optimization of lab‐scale DAC has been investigated using a crossflow air‐liquid contactor loaded with a three dimensionally printed Gyroid packing structure and a potassium sarcosinate solvent. The effects of various parameters, including feed air flow rate, liquid solvent flow rate, contactor geometry, and ambient temperature, are examined. The results demonstrate that the Gyroid packing design achieves comparable CO2 capture performance to conventional packed beds but with a significantly lower pressure drop of up to 77.8%, suggesting its potential as an efficient and cost‐effective solution for gas–liquid contactors in DAC. Additionally, the study explores the climate impact on CO2 capture performance and finds that as the air temperature increases from 35 to 95°F at a fixed relative humidity of 80%, the CO2 capture rate increased from 23.2% to 46.8% with better stability. The research highlights the importance of optimizing contactor design and operational conditions to improve the CO2 capture rate and feasibility of DAC systems as a negative emission technology for addressing greenhouse effects.

CO2 capture and H2 production performance of calcium-based sorbent doped with iron and cerium during calcium looping cycle

As the interest in environmentally-friendly energy processes increases, many studies have been focused on producing hydrogen as an alternative energy carrier via catalytic reaction processes. Sorption enhanced water gas shift (SEWGS) that combines WGS and in situ CO2 removal is a promising technology for high-purity H2 production and CO2 capture. In this study, Fe/Ce-modified CaO-Ca12Al14O33 bi-functional porous nanotubes were synthesized in one step by template method and applied for H2 production from SEWGS process. The unique porous nanotube structure fully exposes the catalytic active sites and facilitates the gas-solid transport, resulting in the excellent H2 production and CO2 capture performance in SEWGS/regeneration cycles. The introduction of Ce enhances the basicity of the nanotube material, thereby increasing the affinity for CO2. The interaction of Fe-Ce improves the redox capability of Fe2+ and Fe3+, which is beneficial to the conversion of CO. In addition, the formed Ca2Fe2O5 and Ca2CeO4 both increase the concentration of oxygen vacancies, further enhancing the SEWGS reactivity of the material. The optimal molar ratio of Fe/Ce/Al/Ca is 10/3/10/100, and the CO conversion, H2 concentration, CO2 capture capacity of the Fe/Ce-modified bi-functional material were 76.9 %, 70.1 % and 83.2 % after 20 cycles. The effect of Fe/Ce doping on CaO-based materials was investigated at the molecular level using density functional theory (DFT). The results demonstrate that the addition of Ce can effectively maintain the stable structure of Fe-CaO-based materials. The modification of Fe/Ce is expected to promote efficient H2 generation from CaO-based materials through the SEWGS process.

In-situ constructing an innovative and versatile nanotraps for incorporation of zero–valent iron nanoparticles into zeolite imidazole framework–8 towards high efficient detoxification and imprisonment of U(VI) and Se(IV) from water via a combination study of capture performance and underlying mechanism aspects

This work reported an in-situ constructing of innovative and versatile nanotraps (NZVI/ZIF–8) namely incorporation of zero–valent iron nanoparticles (NZVI) into zeolite imidazole framework–8 (ZIF–8), and the application of the as-constructed NZVI/ZIF–8 in high efficient detoxification and imprisonment of U(VI) and Se(IV) from wastewater. The results demonstrated that controllable incorporation of NZVI with ZIF–8 used advantages of each component to generate an emphatic boosted interaction in U(VI)/Se(IV) imprisoning. The kinetic adsorption for U(VI)/Se(IV) imprisoned onto NZVI/ZIF–8 was described by pseudo-second-order model well, and the adsorption isotherms followed the Langmuir model better. Thermodynamic analysis (ΔG < 0, ΔS > 0, ΔH > 0) demonstrated that U(VI)/Se(IV) imprisoned onto NZVI/ZIF–8 was endothermic and spontaneous. XPS measurements unveiled that NZVI/ZIF–8 imprisoned U(VI)/Se(IV) by synergistic mechanism of adsorption and reduction. The N–containing functional groups on ZIF–8 was primarily responsible for adsorption, while Fe(0) and surface enriched Fe(II) from NZVI predominantly contributed to reductive conversion of U(VI)/Se(IV) into U(IV)/Se(0). In a word, ZIF-8 played an important role in imprisonment of U(VI)/Se(IV) onto the as-constructed NZVI/ZIF–8 nanotraps with intensified reactivity in comparison with naked NZVI. The findings revealed that the NZVI/ZIF–8 nanotraps would be superb scavengers towards U(VI)/Se(IV), and implied a bright future in potential application in nuclear waste management.

Quaternized Graphene for High-Performance Moisture Swing Direct Air Capture of CO2.

Nowadays, moisture-swing adsorption technology still relies on quaternary ammonium resins with limited CO2 capacity under ambient air conditions. In this work, a groundbreaking moisture-driven sorbent is developed starting from commercial graphene flakes and using glycidyltrimethylammonium chloride for incorporation of CO2-sensitive quaternary ammonium functional groups. Boasting an outstanding CO2 capture performance under ultra-diluted conditions (namely, 3.24mmolg-1 at CO2 400ppm and 20% RH), the functionalized sorbent (fGO) features clear competitive advantages over current technologies for direct air capture. Notably, fGO demonstrated unprecedented moisture-swing capacity, ease of regenerability, versatility, selectivity, and longevity. These distinctive features position the fGO as an advanced and promising solution, showcasing its potential to outperform existing methods for moisture-swing direct air capture of CO2.

Digital light processing 3D printing of polymerizable ionic liquids towards carbon capture applications

This study presents new 3D printable materials based on ad-hoc synthesized photocurable imidazolium ionic liquids (ILs) with bis(trifluoromethanesulfonyl)imide (NTf2)− as counterion and two different alkyl chain's structures at the cation, with enhanced CO2 capture properties. The molecular structure of the synthesized ILs was confirmed through NMR technique and a polymerization study was carried out, by means of photorheological tests and FT-IR analyses, on formulations containing a crosslinking monomer (PEGDA). The study confirmed the good reactivity of the formulations that makes them suitable for digital light processing (DLP) 3D printing technique. Simple membranes were then tested through high pressure CO2 uptake analysis to estimate their capture efficiency, comparing the results with the standard room temperature ionic liquid (RTIL) counterpart, and evidencing an increase of CO2 absorption regardless the pressure applied. At last, complex gyroid-like structures incorporating the synthesized ILs were successfully 3D printed, showing the remarkable ability of these materials to be processed with 3D printing technology while maintaining the great CO2 capture performances of ionic liquids. This preliminary work paves the way for the implementation of “ad-hoc” designs to create filters or devices to enhance the CO2 capture.

Biomass waste-assisted micro(nano)plastics capture, utilization, and storage for sustainable water remediation

Micro(nano)plastics (MNPs) have become a significant environmental concern due to their widespread presence in the biosphere and potential harm to ecosystems and human health. Here, we propose for the first time a MNPs capture, utilization, and storage (PCUS) concept to achieve MNPs remediation from water while meeting economically productive upcycling and environmentally sustainable plastic waste management. A highly efficient capturing material derived from surface-modified woody biomass waste (M-Basswood) is developed to remove a broad spectrum of multidimensional and compositional MNPs from water. The M-Basswood delivered a high and stable capture efficiency of >99.1% at different pH or salinity levels. This exceptional capture performance is driven by multiscale interactions between M-Basswood and MNPs, involving physical trapping, strong electrostatic attractions, and triggered MNPs cluster-like aggregation sedimentation. Additionally, the invivo biodistribution of MNPs shows low ingestion and accumulation of MNPs in the mice organs. After MNPs remediation from water, the M-Basswood, together with captured MNPs, is further processed into a high-performance composite board product where MNPs serve as the glue for utilization and storage. Furthermore, the life cycle assessment (LCA) and techno-economic analysis (TEA) results demonstrate the environmental friendliness and economic viability of our proposed full-chain PCUS strategy, promising to drive positive change in plastic pollution and foster a circular economy.

Efficient capture performance and mechanism of thiadiazole-functionalized covalent organic framework for Pb(II) ion

Covalent organic frameworks (COFs) are very promising adsorbent developed during recent years. Here, a COFs adsorbent (COF@HPLC) for efficient adsorption of lead is designed by post-modification. The adsorption properties were studied by batch adsorption. It is shown that pH 4 is the optimum value for the adsorption of Pb(II) by COF@HPLC. When the temperature is 25 °C, the maximum adsorption capacity of COF@HPLC reaches 251.37 mg/g. The fitting results of adsorption isotherm indicate that the process is a non-uniform adsorption in a single molecular layer. The activation energy fitted by the Dubinin-Radushkevich model are 16.22 kJ/mol, 21.32 kJ/mol, 18.87 kJ/mol and 16.67 kJ/mol, showing that Pb(II) adsorption by COF@HPLC is a chemical reaction. Kinetic studies show also that Pb(II) adsorption is a chemically controlled process. Thermodynamic shows that the adsorption is a spontaneously exothermic process. Finally, COF@HPLC has good adsorption selectivity and reusability. The adsorption mechanism of Pb(II) by COF@HPLC was the electrostatic and chelating interaction between functional groups containing sulphide and nitrogen and Pb(II) based on the zeta potential, XPS and DFT analyses. This work offers guidance toward the design and preparation of functional adsorbents for the treatment and removal of Pb(II).

Studies on the CO2 Adsorption of Li‐Containing Porous Carbon Materials with Supported CuO

AbstractIn this study, Li‐containing porous carbon materials were prepared from terephthalic acid and lithium hydroxide, and then loaded with different contents of copper oxide. After these materials were fully characterized with X‐ray diffraction, scanning electron microscope, Raman spectrum, nitrogen adsorption and desorption, and CO2‐TPD, their CO2 capture performance was measured. Results showed that the CO2 capture capacity of CuO(0.75)/LiC at 0 °C under 1 bar was as high as 142.8 mg‐CO2 g−1. However, excess CuO significantly reduced CO2 capture performance of the material. For example, the maximum adsorption capacity of CuO(2)/LiC was only 119.7 mg‐CO2 g−1. Meanwhile, with CO2/N2 mixed gas, these materials had significantly and selectively higher CO2 adsorption capacity over N2. Additionally, all of these lithium‐containing carbon‐based porous materials with supported copper oxide, including CuO(0.75)/LiC, could effectively capture CO2 with high selectivity and reproducibility.

Assessment of Potential and Techno-Economic Performance of Solid Sorbent Direct Air Capture with CO2 Storage in Europe.

Direct air capture with CO2 storage (DACCS) is among the carbon dioxide removal (CDR) options, with the largest gap between current deployment and needed upscaling. Here, we present a geospatial analysis of the techno-economic performance of large-scale DACCS deployment in Europe using two performance indicators: CDR costs and potential. Different low-temperature heat DACCS configurations are considered, i.e., coupled to the national power grid, using waste heat and powered by curtailed electricity. Our findings reveal that the CDR potential and costs of DACCS systems are mainly driven by (i) the availability of energy sources, (ii) the location-specific climate conditions, (iii) the price and GHG intensity of electricity, and (iv) the CO2 transport distance to the nearest CO2 storage location. The results further highlight the following key findings: (i) the limited availability of waste heat, with only Sweden potentially compensating nearly 10% of national emissions through CDR, and (ii) the need for considering transport and storage of CO2 in a comprehensive techno-economic assessment of DACCS. Finally, our geospatial analysis reveals substantial differences between regions due to location-specific conditions, i.e., useful information elements and consistent insights that will contribute to assessment and feasibility studies toward effective DACCS implementation.

Biomass betulin-based porous aromatic frameworks nanomicrospheres as adsorbents for reversible capture of iodine

Betulin with a modifiable hydroxyl group and a rigid backbone is a kind of natural triterpene product that extracted from white barked birch bark with up to 30 % of its dry weight. Herin, we prepared a series of betulin-based porous aromatic frameworks (BEPAFs) nanomicrospheres by [Rh(nbd)Cl]2 polymerization or Sonogashira-Hagihara coupling reaction for iodine vapor capture and adsorption. The resulting BEPAFs nanomicrospheres presented perfect thermal stability and high specific surface areas that up to 324.6 m2 g−1, 506.3 m2 g−1 and 320.5 m2 g−1 for BEPAF-1, BEPAF-2 and BEPAF-3, respectively. Based on the above characteristics, the BEPFAs nanomicrospheres showed an excellent iodine capture performance with the volatile iodine capture ability reached 3.79 g g−1 and iodine adsorption in cyclohexane solution up to 389.9 mg g−1. The iodine capture behavior is consistent with the pseudo-second-order model, indicating that the iodine adsorption process of BEPAFs microspheres belongs to multilayer heterogeneous surface chemical adsorption. Furthermore, the BEPFAs nanomicrospheres could maintained 88.26 % of the absorption capacity after four cycles that endow them a great potential in practical application. This research provides a facile synthesis of biomass porous aromatic framework nanomicrospheres adsorbents based on the natural product.

Impact of thermodynamics and kinetics on the carbon capture performance of the amine-based CO2 capture system

Solvent-based CO2 capture is a commonly employed post-combustion technique in processes involving absorber-stripper columns. This study focused on computer simulations with equilibrium- and rate-based modeling of CO2 capture using the amine solvents 2-amino-2-methyl-1-propanol (AMP), diethanolamine (DEA), and methyl diethanolamine (MDEA) and thermodynamic methods involving electrolyte NRTL models. The objective of this study was to understand the impacts of rate-based modeling, the type of amine, and thermodynamic methods on carbon capture. Within this study, the amine-based CO2 capture process from coal-power plant flue gas was studied using Aspen Plus modeling. Simulations were also conducted to determine the impact of thermodynamics and kinetics on the CO2 capture performance of the system. The results were analyzed on the basis of captured CO2 according to the solvents and models. The equilibrium approach was mostly invalid because of the oversimplified ideal stage assumptions through the column. The lowest carbon capture capacity was obtained with MDEA, while DEA yielded the best results. A sensitivity analysis with rate-based modeling showed the significant impact of the inlet CO2 composition. The amine-based CO2 capture process simulation included solution chemistry, electrolyte thermodynamics, rigorous transport property modeling, reaction kinetics, and rate-based multistage simulation, which could be applicable to different solvent systems.

Optimizing wave energy harvesting through oscillating water columns in semi-submersible energy harvesting platforms: A comprehensive study on enhancing efficiency and competitiveness

In coastal regions with substantial wave energy potential, significant efforts have been dedicated to advancing both the Technology Readiness Level (TRL) and Technology Performance Level (TPL) of Wave Energy Converters (WECs). Despite their promising energy generation capabilities, the widespread adoption of WEC devices faces a notable challenge in the form of their relatively high Levelized Cost of Energy (LCOE). This economic hurdle hampers their competitiveness when compared to conventional fossil fuels and other renewable energy sources. Oscillating Water Columns (OWCs) stand out due to their noteworthy potential, primarily attributed to their low Operations and Maintenance (O&M) costs. To enhance the energy performance of OWC arrays and pave the way for hybrid offshore energy solutions, the integration of a semi-submersible Energy Harvesting Platform (EHP) is proposed. This integration involves configuring the array with specific OWC End-Stop limitations and geometry to establish resonant conditions during the predominant wave, thereby optimizing constructive interactions and desirable OWC motion with the EHP's heave, pitch, and roll. A Genetic Algorithm (GA) is employed for this optimization process. Additionally, a novel parameter, the In Situ Interaction Factor (ISIF) is introduced, to evaluate the EHP's power capture performance. This metric compares the actual energy harvested from the array of WECs on the platform to the cumulative energy harvested by each device in isolation. Notably, ISIF achieved a remarkable value of 1.99, highlighting the highly efficient constructive interaction achieved through the precise positioning of OWCs. This resulted in nearly doubling the power capture compared to 23 OWCs operating in isolation, underscoring the potential of the EHP in harnessing wave energy. Validation of the analytical analysis was conducted using the open-source Boundary Element Method (BEM) tool NEMOH, alongside reference to the experimental studies.

Fine particle capture performance assessment in an electrostatic-fabric integrated precipitator

Electrostatic precipitators, which are more commonly referred to as precipitators, play a crucial role in the process of reducing the quantity of airborne contaminants that are present in both atmospheric and flue gas settings. This is because precipitators are able to lower the concentration of contaminants in the air. The fine particles, ash, and oil that make up these pollutants are included. With a special emphasis on a Cottrell-type electro-filter that makes use of the wire-cylinder arrangement, the goals of this study are to evaluate the practicability of various filtration systems for the purpose of air decontamination. Specifically, the study will focus on the Cottrell-type electro-filter. By conducting a thorough examination of the peculiarities of the electrical and physical parameters that regulate the mechanisms of particle aggregation, our major purpose is to achieve a comprehensive understanding of these parameters. Through the use of experimental design strategies, we will make an effort to construct and perfect the filtration process in the subsequent stage. In addition to that, the purpose of this inquiry is to explore the impact that high voltage levels and the diameter of the conductor wire that is incorporated into the prototype have. Especially notable is the fact that our prototype exhibits an incredible filtration efficiency, with rates reaching up to 98%. This performance is really remarkable. Its exceptional performance reveals that it has the potential to be suitable for a wide variety of contexts, including residential, commercial, healthcare, industrial, and workshop applications. This suggests that it has the potential to be suitable for a wide range of applications.

Nitrate-promoted gas–solid reactions of H2 and CaCO3 for mid-temperature integrated CO2 capture and methanation

Integrated CO2 capture and methanation (ICCM) technology has attracted increasing attention for Carbon Neutrality. However, in the mid-temperature ICCM studies dominated by MgO, which involves the gas–gas catalytic pathway, the problems of high CO2 escape and low CH4 yield are common. Replacing MgO with CaO reduced CO2 escape because the reaction proceeded via the gas–solid pathway. However, the lower CaCO3 conversion rate limits its further applications. Here, we present an ICCM process with efficient CaCO3 conversion using alkali metal nitrates (KNO3, LiNO3, and (Li-K)NO3) to promote Ru/CeO2-CaO. The results showed that the doping of nitrates led to a decrease in the specific surface area of CaO, thus losing part of the CO2 capture performance. On the other hand, forming the molten liquid layer facilitated the gas–solid reaction between CaCO3 and H2, which improved the CaCO3 conversion. Compared with the Ru/CeO2-Neat CaO without nitrate promotion, the CaCO3 conversion of Ru/CeO2-KNO3/CaO was increased by 42% and CH4 yield by 52% after five ICCM cycles. Furthermore, kinetic analysis and in situ DRIFTS experiments demonstrated that molten KNO3 facilitated mass transfer in the diffusion-controlled stage of direct CaCO3 hydrogenation.

Mesoporous polymer supported Metal-Based deep eutectic solvents for enhanced capture of Low-Content Ammonia

The capture the low-content NH3 from industrial streams, and recycle it as the feedstocks for industrial processes is very important. In this work, we reported the use of mesoporous polydivinylbenzene (PDVB) as the support of metal-based deep eutectic solvents (DESs) containing choline chloride (ChCl) and metal chlorides (SnCl2, FeCl3 or ZnCl2) for NH3 capture. The structure of composite materials was characterized in details, and the NH3 capture performance and mechanism of them were also examined in depth. Owing to the coordination interaction of metal ions with NH3, along with the hydrogen-bond interaction of − OH and Cl− with NH3, the DES@PDVB composites exhibit considerably high low-content NH3 capacities. The optimized sample ChCl + 2ZnCl2@PDVB-1.5 can adsorb 7.43 mol/kg of NH3 at 25 ℃ and 0.122 bar, which is advantageous over most other adsorbents fabricated in the literature. The mechanism of NH3 capture by DES@PDVB composites was also illustrated through spectroscopic characterizations.