Models of cross-language speech perception have had limited success in predicting the discriminability or perceptual similarity of non-native contrasts. These failures may be attributed partly to an inability to quantify the phonetic differences between non-native speech sounds. This study attempted to quantify such gross psychophysical differences between speech sounds, specifically by utilizing dynamic time warping (DTW) on human factor cepstral coefficients to compare the spectrum of the entire length of the speech sounds in question. This technique has been successfully applied to account for the discriminability of different non-native consonant contrasts [Harnsberger, J. D., Shrivastav, R., and Skowronski, M.; J. Acous. Soc. Am. 117, 2460, 2005]. This study extends this work to perceptual similarity judgments of vowels. Specifically, twenty native speakers of English were presented with all possible pairings of ten vowels produced by two speakers of English. Subjects were asked to rate their similarity on a seven point scale. The resulting similarity scores were then compared with the output matrix of the DTW psychophysical difference metric for the same stimulus materials. The results showed a significant correlation (r=.60**) between the two measures, demonstrating the efficacy of the metric with a greater range of stimulus types and tasks.