Liquid Penetration Research Articles

Characterization of liquid-thickness distribution in micropores on elastic surface under sliding and pressurizing conditions.

To improve the performance of studless tires on ice surfaces, the mechanism of liquid film removal must be elucidated. In this study, an experimental system is developed to simulate the running conditions of a studless tire, and the microscopic liquid film flow generated between the rubber surface and glass is observed to evaluate the liquid thickness distribution. Liquid film removal by micropores on foamed rubber samples is investigated by visualizing the liquid thickness in the micropores. The proposed system enables variations in the pressure and sliding velocity between the rubber and glass. The liquid thickness in the micropores is measured using laser-induced fluorescence, and the effects of pressure and sliding velocity on the thickness are examined. Water penetrates the micropores on the rubber sample surface, and different liquid thicknesses are obtained for each pore. The amount of liquid penetrating the pores is affected to a greater extent by the sliding velocity than by the pressure. Therefore, liquid penetration is more strongly influenced by the hydrodynamic effect of the increasing inertia of the liquid under high sliding velocities than by the elastic deformation of the pore.

PVDF and PEO Catholytes in Solid‐State Cathodes Made by Conventional Slurry Casting

AbstractAll‐solid‐state Li batteries are desired for better safety and energy density than Li‐ion batteries. However, the lack of a penetrating liquid electrolyte requires a much different approach to the design of cathodes. The solid catholyte must enable good Li+ conduction, form good interfaces with active material particles, and have the strength to bind the cathode together during repeated volume changes. Catholyte formulation is often simply adapted from Li‐ion design principles, adding a Li salt to the PVDF binder. Here we show that such a PVDF binder at 10 wt % loading is a starved catholyte condition that compromises cell performance. By substituting a 70 : 30 blend of PVDF:PEO, performance is improved while maintaining nearly the same areal loading of LFP active material. Increasing the catholyte fraction to 16 % can also improve performance, but in this case the benefit of including PEO is lessened, with PVDF alone being an adequate catholyte. EIS analysis shows that PEO helps to form charge transfer interfaces at 10 % catholyte, but that its inclusion can degrade interfaces when there is ample catholyte at 16 %. It is also shown that catholyte agglomeration can impede bulk Li conduction, indicating that microstructural factors are of critical importance.

Multi-inspired bump-liked medical protective clothing for effectively profuse perspiration management

Janus medical protective clothing (MPC) with asymmetric wetting properties can enhance the comfort of healthcare workers by transporting sweat from the skin to exterior surfaces. However, these textiles fail to promptly remove heavy sweat (e.g., several liters), resulting in soaked fabrics and reduced comfort. Herein, inspired by superabsorbent polymers (SAPs) and lotus leaves, we propose a bump-liked MPC (BPC) for profuse perspiration management. The fabrics can enable unidirectional sweat transport through the inner Janus fabric layer and sustained absorption of large amounts of sweat by the median layer of SAPs. The bump-liked structure can store SAPs and adapt them to swelling. An external polydimethylsiloxane (PDMS)-coated layer can effectively block water, blood, and ethanol from penetrating the skin (synthetic blood contact angle, 118°; anti-blood penetration resistance, 4.8 kPa), thereby ensuring excellent protective properties. More importantly, BPC possesses an unrivalled sweat removal rate of 5.9 ml cm−2 min−1, which is three orders of magnitude higher than the human sweat rate during high-intensity exercise. This work addresses the dual challenge of profuse perspiration management and resistance to liquid penetration, which represents a promising direction for improving the thermal-moisture comfort of medical protective clothing.

Fluorine-free superhydrophobic Ni/Mn-TiO2 composite coatings on carbon steel via one-step electrodeposition for enhanced durability and corrosion resistance

The application of superhydrophobic coatings on carbon steel (CS) surface represents an effective strategy for mitigating corrosion in these materials. This study presents the preparation of superhydrophobic Ni/Mn-TiO2 composite (SNMT) coatings on CS substrates through a facile one-step electrodeposition technique. The formation mechanism of SNMT coatings was meticulously analyzed under varying conditions of nanoparticle types and concentration levels. The inclusion of TiO2 nanoparticles, with an optimal additive concentration of 1 g, facilitated the formation of numerous low surface energy, cauliflower-like microstructures on CS interface. Surprisingly, the results indicate that SNMT coatings maintained commendable superhydrophobicity even post-exposure to superficial damages such as tape peeling, sandpaper wear, and knife-scratch, as evidenced by a static contact angle (CA) exceeding 158° and a sliding angle (SA) below 2°. Furthermore, the corrosion inhibition efficacy of SNMT coatings was quantitatively assessed via dynamic potential polarization curves in a simulated seawater environment. The results demonstrated that SNMT coatings exhibited excellent corrosion inhibition performance in simulated seawater solution, with a protection efficiency (PE) reaching 96.5%. In conclusion, superhydrophobic surfaces can effectively inhibit the penetration of corrosive liquids. The durability and robustness of such superhydrophobic surfaces advocate for their potential widespread application in enhancing the longevity and reliability of CS in corrosive environments.

Ionic Hydrogel-Based Moisture Electric Generators for Underwater Electronics.

Ubiquitous moisture is of particular interest for sustainable power generation and self-powered electronics. However, current moisture electric generators (MEGs) can only harvest moisture energy in the air, which tremendously limits the energy harvesting efficiency and practical application scenarios. Herein, the operationality of MEG from air to underwater environment, through a sandwiched engineered-hydrogel device with an additional waterproof breathable membrane layer allowing water vapor exchange while preventing liquid water penetration, is expanded. Underwater environment, the device can spontaneously deliver a voltage of 0.55V and a current density of 130µAcm-2 due to the efficient ion separation assisted by negative ions confinement in hydrogel networks. The output can be maintained even under harsh underwater environment with 10% salt concentration, 1ms-1 disturbing flow, as well as >40kPa hydraulic pressure. The engineered hydrogel used for MEG also exhibits excellent self-healing ability, flexibility, and biocompatibility. As the first demonstration of practical applications in self-powered underwater electronics, the MEG device is successfully powering a wireless emitter for remote communication in water. This new type of MEG offers an innovative route for harvesting moisture energy underwater and holds promise in the creation of a new range of innovative electronic devices for marine Internet-of-Things.

Adsorption, Adhesion, and Wettability of Commercially Available Cleansers at Dental Polymer (PMMA) Surfaces.

This study aims to evaluate the adsorptive, adhesive, and wetting energetic properties of five commercially available cleansers in contact with model dental polymer (PMMA). It was assumed that the selected parameters allow for determining the optimal concentration and place of key component accumulation for antibacterial activity in the bulk liquid phase and prevention of oral plaque formation at the prosthetic material surface. The adsorptive (Gibbs' excesses ΓLV, critical micellar concentration) and thermal (entropy and enthalpy) surface characteristics originated from surface tension γLV(T) and γLV(C) dependences. The surface wetting properties were quantified upon the contact angle hysteresis formalism on the advancing ΘA, receding ΘR contact angles, and γLV as the input data, which yield a set of wettability parameters: 2D adsorptive film pressure, surface free energy with its dispersive and polar components, work of adhesion, and adhesional tension, considered as interfacial interaction indicators. In particular, molecular partitioning Kp and ΓLV are indicators of the efficiency of particular active substance accumulation in the volume phase, while γSV, a = ΓSL/ΓLV, and WA point to the degree of its accumulation at the immersed polymer surface. Finally, the liquid penetration coefficient PC and the Marangoni temperature gradient-driven liquid flow speed were estimated.

Pancake bouncing of impacting nanodroplets on smooth and nanopillared surfaces

Reducing the contact time of impacting droplets on solid surfaces has become a research focus due to its promising application prospects in self-cleaning, anti-erosion, and anti-icing. In this study, the pancake bouncing of nanodroplets is investigated through molecular dynamics simulations, achieving a remarkable reduction in contact time. Two distinct patterns of pancake bouncing are identified when nanodroplets impact smooth and nanopillared surfaces with different bouncing mechanisms. The first pancake bouncing pattern with holes on smooth surfaces is attributed to internal-flow collision induced by multiple retraction centers. The second pancake bouncing pattern on nanopillared surfaces results from the storage and release of sufficient surface energy due to liquid penetration and requires satisfying both the timescale and energy criterion. Subsequently, theoretical models for two criteria are developed, which promote two parameter groups (−(s2 + 2ws)h(wcosθ0)−1 and We–1/3Re–1/3R02) corresponding to the surface and droplet. Based on these two parameter groups, a phase diagram is established and indicates the triggering conditions for the second pancake bouncing patterns. Finally, it is further revealed that by increasing the pillar height from smooth to nanopillared surfaces, the bouncing regime is transformed from the first pancake bouncing pattern, regular bouncing, to the second pancake bouncing pattern.

The role of fibre bonds in permanent curl of paper and how it is affected by crosslinking

Irreversible deformation of paper is a challenge for both printer operation and product quality, particularly in inkjet printing with water-based inks. Here we are investigating permanent paper curl, which is the residual curl of paper after drying of the ink (i.e., it is not the immediate paper curl due to wetting). The key aim of this work was to test the hypothesis that permanent paper curl is created by partial opening and rearrangement of the fibre–fibre bonds in the wetted paper layer. In order to test this hypothesis, we produced paper with crosslinked fibre–fibre bonds that do not open in the presence of water. Polyamideamine epichlorohydrin (PAE) and 1,2,3,4-butanetetracarboxylic acid were used as crosslinking agents and properties of the treated paper samples were analysed. Both agents led to significantly improved wet strength of the papers, furthermore we indeed found that the permanent curl of crosslinked papers was strongly reduced. Other curl related mechanisms like differences in fibre swelling, paper hydroexpansion and liquid penetration were not able to explain the reduction in curl. The finding that the creation of fibre–fibre bonds unaffected by water prevents permanent curl of paper after wetting and redrying leads to the conclusion that the mechanism for creating permanent paper curl after wetting is related to the partial opening and rearrangement of fibre–fibre bonds in the wetted paper. Possible pathways to apply these findings to paper production are discussed, for example switchable or temporary wet strength agents.

Experimental study on the effects of n-butanol and n-propanol on the spray and combustion characteristics of diesel/biodiesel blends in a constant volume combustion chamber

The depletion of fossil fuel resources and the escalating environmental impact of greenhouse gas emissions have intensified the global exploration of renewable and sustainable energy sources. Biodiesel produced from vegetable oils and animal fats has become a promising alternative to conventional diesel fuel due to its renewability and lower carbon emission. This study investigates the differences in spray, combustion and flame characteristics between soybean-based biodiesel blended with propanol and butanol at various ratios. The results indicate that the liquid spray penetration length of biodiesel mixed with propanol and butanol exceeds that of soybean-based biodiesel. And the increase of spray penetration is accompanied by a longer flame lift-off length, which indicates the improvement of spray characteristics. Regarding combustion, alcohol-fuel blends exhibit a reduction in peak combustion pressure but an increase in peak apparent heat release rate. Additionally, these fuels show a shorter ignition delay and combustion duration. The peak natural flame luminosity is lower for alcohol fuels, suggesting their potential to reduce carbon soot production and support low-carbon combustion. These experimental results contribute to advancing research on cleaner, more efficient and renewable fuels, thereby reducing reliance on conventional fossil fuels.

Bioinspired Hierarchical T Structures for Tunable Wettability and Droplet Manipulation by Facile and Scalable Nanoimprinting.

Developing surfaces that effectively repel low-surface-tension liquids with tunable adhesive properties remains a pivotal challenge. Micronano hierarchical re-entrant structures emerge as a promising solution, offering a robust structural defense against liquid penetration, minimizing area fraction, and creating narrow gaps that generate substantial upward Laplace pressure. However, the absence of an efficient, scalable, and tunable construction method has impeded their widespread applications. Here, drawing inspiration from springtail epidermal structures, octopus suckers, and rose petals, we present a scalable manufacturing strategy for artificial micronano hierarchical T-shaped structures. This strategy employs double-transfer UV-curing nanoimprint lithography to form nanostructures on microstructured surfaces, offering high structural tunability. This approach enables precise control over topography, feature size, and arrangement of nano- and microscale sections, resulting in superamphiphobic surfaces that exhibit high contact angles (>150°) and tunable adhesive forces for low-surface-energy liquids. These surfaces can be applied to droplet-based microreactors, programmable droplet-transfer systems, and self-cleaning surfaces suitable for various liquids, particularly those with low surface tension. Remarkably, we have also succeeded in fabricating the hierarchical structures on flexible and transparent substrates. We demonstrate the advantages of this strategy in the fabrication of hierarchical micronanostructures, opening up a wide range of potential applications.

Study on the spray characteristics of transverse jets with elliptical nozzles in supersonic crossflows using the volume of fluid–discrete phase model

The atomization characteristics of liquid jets injected transversely into a supersonic crossflow significantly affect the performance of scramjet engines. Existing research on this topic has mainly focused on circular nozzles, while the influence of nozzle geometry, particularly elliptical nozzles, has received relatively limited attention. Therefore, this study employs a numerical simulation method coupling the volume of fluid and discrete particle model to investigate the breakup and atomization characteristics of transverse liquid jets from elliptical nozzles with different aspect ratios under supersonic crossflow conditions, as well as the total pressure loss. The simulation model is validated against experimental data obtained from a pulse wind tunnel, including measurements of the liquid jet penetration depth and the Sauter mean diameter (SMD). The results indicate that for elliptical nozzles with an aspect ratio (AR) greater than 1, columnar breakup occurs earlier, and the columnar breakup length is shorter compared to circular nozzles. As the AR increases, the jet penetration depth decreases, while the spray expansion angle increases. Furthermore, the SMD of the atomized spray field from the circular nozzle is larger than that from the elliptical nozzles, and the SMD of the spray field is smallest for an elliptical nozzle with AR of 4. Finally, the elliptical nozzles exhibit a higher total pressure recovery coefficient, indicating reduced total pressure loss in the combustion chamber. This reduction in pressure loss is expected to improve the thrust performance of the scramjet engine.

Controlled Chemical‐Patterning of Textile to Accelerate Anti‐Gravity Water Flow

AbstractBio‐inspired unidirectional flow of tiny aqueous droplets across the fibrous substrate paved the way for the emergence of various advanced materials. In the past, textiles decorated with noncontact‐based wettability‐patterns enabled unidirectional water flow—without flooding the top surface by the transferred water. However, such approaches mostly suffer from a low (≈0.176 µL mm−2 s−1) flow rate and are likely to delay the overall liquid ejection process. Here, a chemically reactive coating capable of tailoring water wettability (121.3° ± 2.4° to 153.3° ± 1.8°) is introduced on commercially available textiles to develop chemically modulated wettability‐pattern for achieving a rapid (2.57 ± 0.28 µL mm−2 s−1) flow rate of water against the gravity with an ability to roll the accumulated liquids on the top surface. The spatially selected and controlled chemical modification with hydrophilic and hydrophobic small molecules through a 1, 4‐conjugate addition reaction yielded a 3D channel with a customized wettability gradient. The pinning and depinning of invaded water through such chemically decorated channels enabled unidirectional and fast penetration of liquid, where the water penetration resistance largely depends on the water penetration direction and dimension of the chemically modulated channels.

Modelling of an Influence of Liquid Velocity Above the Needle on the Bubble Departures Process

Abstract In the present paper, the influence of liquid flow above the needle on a periodic or chaotic nature of the bubble departures process was numerically investigated. During the numerical simulations bubbles departing from the needle was considered. The perturbations of liquid flow were simulated based on the results of experimental investigations described in the paper [1]. The numerical model contains a bubble growth process and a liquid penetration into a needle process. In order to identify the influence of liquid flow above the needle on a periodic or chaotic nature of bubble departures process, the methods data analysis: wavelet decomposition and FFT were used. It can be inferred that the bubble departure process can be regulated by altering the hydrodynamic conditions above the needle, as variations in the liquid velocity in this area affect the gas supply system’s conditions. Moreover, the results of numerical investigations were compared with the results of experimental investigation which are described in the paper [2]. It can be considered that, described in this paper, the numerical model can be used to study the interaction between the bubbles and the needle system for supplying gas during the bubble departures from two needles, because the interaction between the bubbles is related to disturbances in the liquid flow above the needle.

Multifunctional Porous Bilayer Artificial Skin for Enhanced Wound Healing.

Meeting the exacting demands of wound healing encompasses rapid coagulation, superior exudate absorption, high antibacterial efficacy, and imperative support for cell growth. In this study, by emulating the intricate structure of natural skin, we prepare a multifunctional porous bilayer artificial skin to address these critical requirements. The bottom layer, mimicking the dermis, is crafted through freeze-drying a gel network comprising carboxymethyl chitosan (CMCs) and gelatin (GL), while the top layer, emulating the epidermis, is prepared via electrospinning poly(l-lactic acid) (PLLA) nanofibers. With protocatechuic aldehyde and gallium ion complexation (PA@Ga) as cross-linking agents, the bottom PA@Ga-CMCs/GL layer featured an adjustable pore size (78-138 μm), high hemostatic performance (67s), and excellent bacterial inhibition rate (99.9%), complemented by an impressive liquid-absorbing capacity (2000% swelling rate). The top PLLA layer, with dense micronanostructure and hydrophobic properties, worked as a shield to effectively thwarted liquid or bacterial penetration. Furthermore, accelerated wound closure, reduced inflammatory responses, and enhanced formation of hair follicles and blood vessels are achieved by the porous artificial skin covered on the surface of wound. Bilayer artificial skin integrates the advantages of nanofibers and freeze-drying porous materials to effectively replicate the protective properties of the epidermal layer of the skin, as well as the cell migration and tissue regeneration of the dermis. This bioabsorbable artificial skin demonstrates structural and functional comparability to real skin, which would advance the field of wound care through its multifaceted capabilities.

Comparative analysis of the technological properties of natural and agglomerated stones in epoxy matrix

Brazil occupies a prominent position among the countries that produce the most ornamental stones in the world, with emphasis on the state of Espírito Santo. However, despite this success in production, the sector faces a considerable challenge in relation to waste generation. The objective of this study was to produce and evaluate the technological properties of an agglomerated stone using 87 wt% waste from the processing of Branco Fortaleza stone in a matrix with 13 wt% epoxy resin, using the vacuum vibro-thermo-compression process. The waste was characterized by X-ray fluorescence (XRF) and X-ray diffraction (XRD). The stones were subjected to evaluation of density, apparent porosity, water absorption, abrasion resistance test, staining, chemical attack, 3-point flexural strength and microstructural analysis (SEM). The results showed a density of 2.26 ± 0.02 g/cm3, water absorption of 0.24 ± 0.01%, apparent porosity of 0.55 ± 0.03%, abrasion resistance test of 1.38 mm and flexural strength of 30.13 ± 1.74 MPa. The results compared with the literature reveal a material with technical feasibility to be used as a coating in the construction sector, presenting high mechanical resistance, good interfacial adhesion, application on high traffic floors, as well as environments subject to liquid penetration such as sinks, floors and countertops. Using this waste to manufacturing new materials, such as agglomerated stones, can not only help reduce dependence on raw materials, but also play an important role in minimizing the environmental impact associated with the extraction and processing of natural stones.

In Ukrainian

The contact wetting is one of the effective methods of studying the adsorption capacity of sorbents. The purpose of the work was to compare the experimentally obtained data on the adsorption capacity of shungite, obtained by the sessile drop method, and the results of modeling the behavior of liquid droplets on heterogeneous surfaces using the Boltzmann lattice method, and to show the suitability of the simplified version of the LBM method that we applied within the framework of a two-dimensional model for modeling complex cases of contact interaction between liquids and sorbent, when it cannot be carried out by the method of contact wetting. The adsorption properties of shungite with regard to the extraction of various impurities from water-alcohol solutions and the capability of the sorbent to recover were investigated by the method of contact wetting and analyzed by involving the data obtained by the methods of nitrogen adsorption, thermogravimetry and IR spectroscopy. It is shown that the adsorption properties of shungite are due to the presence on its surface of hydroxyl functional groups attached to carbon atoms in phenol or enol form, which give the surface hydrophilic characteristics. These groups play a key role in the adsorption of components from the liquid (aqueous) phase due to the formation of a hydrogen bond during the sorption of components from the liquid phase, and are restored after heating in the temperature range of 80–180 °C with the formation of carbon-containing gases and water. It has been found that silanol groups present in shungite do not participate in sorption. Compared to the original shungite sample, the sample after five cycles of adsorption is characterized by a noticeable effect of mass loss (1.8 %) in the temperature range of 80–180 °С. At the same time, the loss of mass is not significant at temperatures below 100 °С. This suggests that the sorbed substances are in the pores and not on the surface of shungite, and they begin to be removed only after heating above 100 °C. The LBM method was used to study fast-moving processes at the meso-level. A comparative analysis of the experimental data obtained by the method of contact wetting with the results of simulation by the Boltzmann lattice method within the framework of the two-dimensional model was carried out. 2D modeling by the LBM method turned out to be an effective means of studying capillary condensation in mesopores, anticipatory wetting of the solid phase, liquid penetration into a porous medium with different topologies, and the formation of anisotropic droplets and anisotropic bridges. The role of mesopores in the sorption process was analyzed by modeling the behavior of liquid droplets on heterogeneous surfaces and using data on the course of adsorption and capillary processes on the surface of a solid phase with different levels of porosity, roughness, and functional composition.

Numerical investigation of the influence of the heat exchange structure on the gas-liquid dispersion in a large-scale fermenter

A combination of computational fluid dynamics (CFD) and population balance model (PBM) was used to study the gas-liquid mixing conditions in a fermenter. The effects of the heat exchange structure on the flow structure, gas holdup, agitator power, bubble size distribution and interfacial area were investigated by numerical simulations. The simulation results showed that radial gas dispersion and liquid penetration are strongly hindered by the spiral heat exchanger, as there is no gap between the annular tubes at the circumference. An unstable flow structure, gas accumulation around the shaft and gas leakage, as well as large bubbles around the heat exchange tubes are due to the poor gas distribution. By increasing the spacing of heat exchange tube bundles in circumferential, the gas-liquid mixing in the fermenter is gradually improved with the uniform row heat exchanger, the compact row heat exchanger and the bundle type heat exchanger. The bundle heat exchanger acts as a baffle to suppress the large bubbles and effectively reduce the bubbles sizes and promote gas dispersion, which exhibits the maximum interfacial area and interfacial area per unit power. Compared to the fermenter with a spiral heat exchanger, the interfacial area and interfacial area per unit power of the fermenter with a bundle heat exchanger increase by 36.5 % and 9.1 %, respectively.

Combined Gas Tungsten Arc Welding and Shielded Metal Arc Welding Processes for Joining Tube to Tubesheet in Shell and Tube Heat Exchangers

Abstract Flawless tube and tubesheet joints are necessary for shell and tube heat exchanger with high leakproof ability and durability. The consequence of mixing of transfer fluids due to the defective welded or expanded tube-to-tubesheet joint results in complete malfunctioning of the heat exchange process. In this case, there is a high demand for quality assessment of the fabricated tube-to-tubesheet joints (TTS) based on the international standards. Additionally, the literature on assessing the mechanical and metallurgical characteristics of tube-to-tubesheet joints using any one welding technique is available; however, articles dealing with the use of multiple welding techniques are scanty. In the current work, the quality assessment of strength welded and light expanded (3%) tube-to-tubesheet joints followed by light expansion was performed whereas for welding, combined gas tungsten arc welding (GTAW) and shielded metal arc welding (SMAW) as root pass and cap pass were adopted in the fabrication stage. Quality and sound tube-to-tubesheet joints were produced using welding and tube expansion process. Linear and circular indications representing the cracks were absent on the developer in the liquid penetration test. The minimum leak path (MLP) was greater than the two-third of tube wall thickness. The results strongly qualify the use of combined gas tungsten inert gas and shielded metal arc welding process for manufacturing of tube-to-tubesheet joints. The methodology and results in the current article are beneficial for researchers and industrialists working close to shell and tube heat exchangers and boilers.

Experimental investigation on liquid length of direct-injection ammonia spray under engine-like conditions

The utilization of ammonia fuel in internal combustion engines holds significant promise in achieving carbon neutrality objectives. High-pressure direct injection technology offers precise control over fuel quantity and mixture formation. However, it is crucial to control the impingement of the liquid phase to minimize emissions, especially in the case of ammonia. In this study, we employ the diffused back illumination imaging technique to investigate the dynamic evolution characteristics of the liquid phase in evaporating ammonia sprays, via a comparison with diesel fuel. Parameters, including injection pressure, fuel temperature, nozzle diameter, ambient pressure, and ambient temperature are examined and assessed under engine-like conditions. Our findings highlight the distinct dynamic evolution behavior of diesel spray, which is characterized by periodic detachments of large droplet clusters and cyclic variations in liquid penetration. This contrasts with the smoother evolution of ammonia spray. Notably, during the quasi-steady state, the liquid penetration in ammonia spray exhibits a significant increasing trend due to the large latent heat of evaporation. Finally, a predictive 1D model is proposed with consideration of multiple influencing factors. The findings offer valuable insights into comprehending and modeling the evaporating ammonia spray, thereby contributing to enhanced efficiency and cleaner combustion processes within ammonia engines.

An Experimental Study on the Flash Boiling Characteristics of Liquid Ammonia Spray in a Constant Volume Chamber under High Injection Pressure

The spray characteristics of liquid ammonia under various ambient pressures and temperatures were analyzed in a constant volume chamber to cover a wide range of superheat degrees. The injection pressure was set as 70 and 80 MPa with ambient pressure ranging from 0.2 to 4 MPa. The ambient temperature was 500 K. The results showed that the higher the injection pressure, the greater the kinetic energy obtained. The droplet fragmentation was enhanced, and the phenomenon of gradual separation of the gas–liquid region occurred with increasing injection pressure. Under flash boiling spray conditions, the spray developed faster than non-flash boiling and transition flash boiling spray under the same injection pressure. In addition, the flash boiling spray tip penetration of the gas and liquid increased more than that of cold spray, and the fluctuation of the late stage of the injection was relatively large. Therefore, the injection pressure has a greater effect on the spray tip penetration of flash boiling spray. Moreover, ambient pressure greatly influences the flare flash boiling spray. The spray resistance phenomenon was found during the spray development in the flare flash boiling condition. With the increase in ambient pressure, the spray tip penetration of flash boiling spray decreases due to the reduction in the pressure difference inside and outside the spray hole and the restriction of ambient gas. Meanwhile, owing to the low ambient pressure and ambient density, the liquid penetration in the initial phase of the flare flash boiling spray will be abnormally shorter than that of the non-flash boiling spray.