Peeling Off Research Articles

Evaluation and Antibacterial Activity Test of Peel-off Mask Preparation from Combination of Pegagan Leaves (Centella asiatica (L) Urb.) and Charcoal Powder

Pegagan leaf (Centella asiatica (L) Urb.) is a plant that contains flavonoids, tannins, triterpenoids, and saponins that function as antibacterials. Pegagan leaf is combined with activated charcoal powder, which has the job of absorbing facial oil, so that it is formulated in the form of a peel off mask to produce a synergistic effect. This study aims to formulate, evaluate, and test the antibacterial effectiveness of the peel-off mask preparation of pegagan leaf extract at concentrations of 1.5%, 2%, and 2.5%. This study uses an experimental method by testing the parameters of the physical evaluation requirements and testing antibacterial activity with the disc method on the peel off mask preparation. The results were evaluated for 28 days, and the results of the organoleptic test were stable, homogeneity stable, pH (5.6–6.2), dry time (16–25 minutes), dispersion (6.1-6.4 cm), and irritation (2 respondents). The effectiveness test against the bacteria Propionibacterium acnes has inhibitory power of 12.3 mm in the strong category. So, it can be concluded that the peel off mask produced has stable physical characteristics and can be used as an antibacterial mask.

Peeling off behavior of centimeter-level molten pool subjected to subsonic tangential airflow during laser ablation process

In this paper, a computational fluid dynamics model considering the interaction between subsonic tangential airflow and centimeter-level molten pool was established to investigate the melt peeling off behavior during laser ablation process. The results showed that the airflow resulted in violent fluctuations on the surface of molten pool and then flowed upward at a velocity of 2–10.5 m/s, accelerating the surface melt to move upward. A liquid column was formed and elongated slender along the metal surface pushed by the subsonic tangential airflow. An upward-bending tail appeared at the end of the liquid column, which was accelerated up to 6 m/s and then cut off by the airflow, making the melt peel away from the molten pool. Compared with the partial melt peeling off at 0.3 Ma, almost all of the melt was pushed out of the molten pool to peel off when the airflow velocity was increased to 0.5 Ma. When the airflow velocity was further increased to 0.8 Ma, the metal on the surface was accelerated in short time, leading to the peel-off occurring in advance. In addition, the melt temperature decreased due to the forced convection cooling effect of airflow. When the melt solidified, the solid-liquid interfacial tension generated in the liquid column provided tangential force conducive to cutting off the liquid column and peeling off. The decrease rate of the melt temperature with time accelerated significantly and then expedited the melt solidifying and peeling off when the airflow velocity was increased to 0.5 Ma. The decrease rate further accelerated and the temperature decrease occurred earlier at 0.8 Ma, reaching a stable state in a shorter time.

Atomic Sn Encapsulation with Visualizing Mitigated Active Zinc Loss toward Anode‐Lean Zinc Metal Battery

Atomic Sn Encapsulation with Visualizing Mitigated Active Zinc Loss toward Anode‐Lean Zinc Metal Battery

Experimental study and characterisation of 316L stainless steel parts fabricated with metal fused filament fabrication

The 3D printing process of Fused Deposition Modelling (FDM) can be used for fabricating metal parts without the need of mold. Metal Material Extrusion uses metal-polymer composite filament in the 3D printer to extrude the green part, then a de-binding process for removing the polymer binder, and eventually, the sintering process under high temperatures for making a metallic part. A comprehensive research is conducted in which sintering parameters including heating rate, dwell time, and sintering atmospheres are varied for metal parts mechanical characteristics including tensile strength, ductility, and density. Moreover, sintering atmospheres including vacuum and argon are taken into consideration in this research study. The metal part is known as silver part which has exhibited a high mechanical strength of 540 MPa, a considerable density of 7.57 g/cm3, and a high hardness of 220 HV under a vacuum sintering atmosphere. Whereas the metal parts produced under argon atmosphere have shown comparatively low mechanical strength 424 MPa, density 7.1 g/cm3 and 177 HV. The results are compared with an industrial benchmark process where catalytic de-binding and sintering are used to achieve 500 MPa tensile strength, density 7.83 g/cm3, and 175 HV. Scanning Electron Microscopy reveals that grains are coarsened in a vacuum, and grains appear peeled off along with small pores in the boundaries. The industrial benchmark part has uniform and finer grains.

Impact damage testing based on high-speed continuous water jet aircraft coatings

When an aircraft passes through a rainy area at high speed, the coating on the front edge of the fuselage will be continuously eroded by raindrops, causing the coating to wear, crack or even peel off. This paper uses carbon fiber T300 material as the base material, and at the different impact speeds and impact numbers, water cutting equipment was used to simulate the erosion of the coating caused by the continuous impact of water droplets. The damage morphology of samples at different damage stages was observed by digital microscope and Scanning Electron Microscope (SEM), and the damage evolution curve was established to analyze and reveal the damage behavior and damage mechanism of rain erosion. The results show that the degree of damage experienced an increasing trend with the increase of impact numbers and speed, until circular peel damage was formed; no damage occurred during the incubation period, and the curvature of the damage evolution curve increased significantly after the expansion period and eventually showed a stable expansion trend. The mechanical properties of the coating material were the main influencing factors of its rain corrosion resistance. Moreover, the axially symmetric unsteady contact problem of droplets impacting the surface of a solid deformable body was studied. And the contact area was determined based on the iterative algorithm boundary positioning method. A mathematical model and closed mathematical formula describing the unsteady interaction between a droplet and a solid deformable obstacle were proposed.

Peningkatan Ikatan Adhesi terhadap Pengurangan Retak Lapisan PVA pada Ti-6Al-4V ELI untuk Aplikasi Biomedis

The lack of adhesion bonding of the hydroxyapatite (HA) coating layer on the surface of implant material can cause the coating layer to peel off during implantation and will increase the risk of metallic ion release to human body and may also to increase inflammatory effect and slow down the osseointegration process. In order to increase the adhesion of HA coated Ti-6Al-4V ELI by adding Zirconium Oxide (ZrO2) into the coating layer.The coating process of the HA suspension with addition ZrO2 into Ti-6Al-4V ELI sample surfaces was conducted by using dip-coating method. The samples were then heated at 800, 900, and 950 °C. The improvement of adhesion coating was correlated by calculating the removed area. The low value of removed coating area indicated the adhesion coating is good. The test specimen with the addition of ZrO2, has a removed area fewer than the test specimen without the addition of PVA- ZrO2 has. This shows that the test specimen with the addition of ZrO2 has good coating adhesion.The addition of PVA- ZrO2 to the HA suspension increases adhesion bonding of the coating layer, as indicated by the low removed area as compared to that of without PVA- ZrO2 coating.

The oil lubricated fretting wear behavior under different sliding displacements and frequencies of Ti6Al4V titanium alloy as affected by micro-shot peening

The fretting wear behavior under oil lubricants is of great practical significance since oil is usually used to regulate fretting regime for minimizing wear. In this study, micro-shot peening (MSP) was performed on Ti6Al4V titanium alloy, in which 0.6 MPa injection air pressure, 60 s shot time and high-speed steel particles with an average diameter of 50 μm were used. Surface topography, microstructure, hardness and compression residual stress of test samples were examined. Oil lubricated fretting wear tests were then conducted between titanium alloy sample and GCr15 counterbody under different sliding displacements and frequencies. The test results show that the surface structure of MSP treated samples experienced severe plastic deformation, the surface hardness was increased from 310.8 HV to 433.5 HV, and a compression residual stress of −303.5 MPa was introduced within surface layer. Moreover, MSP treatment reduced the coefficients of friction through producing a micro-dimpled surface. Thereby, the fretting wear resistance of MSP treated sample under oil lubricated condition was improved. By comparison, at higher sliding displacement and frequency, the ability of MSP treatment to resist fretting wear was improved more significantly since more better lubricating effect can be obtained. Fretting damage of untreated sample under oil lubrication was mainly attributed to fatigue wear, delamination wear, abrasive wear and oxidation wear, while that of MSP treated sample was mainly regional peeling off and abrasive wear.

Cavitation erosion of the AA7050 aluminum alloy in 3.5 wt% NaCl solution—Part 1: mitigating effect by corrosion

The corrosion in 3.5 wt% NaCl solution caused a mitigated weight loss of the aluminum alloy 7050 (AA7050) under cavitation erosion condition. The mechanism was observed using high-resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), electro back-scattered diffraction (EBSD), and potentiodynamic polarization. Both in deionized water and in 3.5 wt% NaCl solution, the cavitation erosion degradation of the AA7050 was mainly attributed to fatigue fracture like peeling off of surface layer materials. The corrosion significantly mitigated the weight loss of AA7050 under cavitation erosion condition because the loose surface oxide film (generated by corrosion) dissipated the cavitation impact energy and therefore alleviated the stress concentration on the alloy surface.

Self‐healing characteristics of superabsorbent polymers in epoxy coating for corrosion inhibition of carbon steels

AbstractThis study evaluated the self‐healing characteristics of superabsorbent polymers (SAP) in epoxy polyamide paint systems applied using brush application. The SAP underwent preliminary characterization to determine its primary properties and was then incorporated into the epoxy primer at different percentages. The epoxy‐SAP coating systems then underwent various tests to evaluate their self‐healing capability. Excellent adhesion is obtained with the coating system composed of initial epoxy primer, epoxy‐SAP layer, final epoxy primer, and an epoxy enamel topcoat. Electrochemical impedance spectroscopy (EIS) reveals that the addition of SAP increased the charge transfer resistance and pore resistance and decreased the double layer capacitance of the coating system in a span of 5 h, confirming the self‐healing of the coating. Maximum corrosion protection for 5 h is obtained between 15 to 20 wt% SAP. Lastly, it is determined through long‐term immersion tests that the addition of SAP in the coating significantly decreases the rust formation; however, the coating starts to peel off due to the swelling of SAP after 2–3 days.

Combined Terahertz Pulsed Imaging and Optical Coherence Tomography Detection Method for Multiple Defects in Thermal Barrier Coatings

While thermal barrier coatings (TBCs) are being sprayed onto aero-engine turbine blades, or while the engine blade is working, high temperatures and strong impact forces will damage TBCs under thermal cycles, resulting in the coating peeling off from the blades. The current method of using ECT, IRT, or another method alone cannot achieve the real-time detection of coating defects with both high precision and high penetration power. Two detection methods, namely, terahertz pulsed imaging (TPI) and optical coherence tomography (OCT), were combined to evaluate typical defects observed in TBCs (including internal debonding cracks, surface high-temperature cracks, and surface etched cracks). The results showed that the OCT system successfully obtained the micron-level axial resolution, but the detection depth of the OCT system was limited. The TPI system achieved a higher penetration depth than OCT—hence, it can be used for the nondestructive detection and evaluation of the internal debonding defects in the sample—but its resolution needs to be improved. Following this conclusion, a method is proposed using TPI and OCT concurrently for the nondestructive testing and quantitative evaluation of TBCs on etched cracks, thus achieving progress both in terms of depth and resolution. In our experiment, defects with a depth of 519 μm and a width of 100 μm were measured. The proposed method is suitable for situations where multiple defects in TBC samples of blades need to be detected simultaneously during the working process. When there are defects deep inside the sample, more small cracks on the surface can be evaluated to achieve a combination of depth and accuracy.

Hierarchical microporous Ni-based electrodes enable “Two Birds with One Stone” in highly efficient and robust anion exchange membrane water electrolysis (AEMWE)

Anion exchange membrane water electrolysis (AEMWE) is currently the most promising technology to produce green hydrogen. However, the lack of cost-effective and scalable methods for fabricating robust and highly active non-noble metal electrodes primarily inhibits its large-scale industrialization. This study unveils an effective strategy for tackling this challenge by creating a novel hierarchical conical-microporous nickel-based electrode, through a synergistic implementation of both rapid and scalable atmospheric plasma spraying (APS) and laser texturing (LT) processes. The resultant NA-LT-CA electrodes exhibits remarkable catalytic performances for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Notably, the AEMWE cell with NA-LT-CA electrodes yields a remarkable enhancement of cell efficiency, toward a reduction in cell voltage of 244 mV at 0.8 A cm−2, compared to the NA-CA electrode (without LT) cell. The notable achievements stem from the improved bubble dynamic contributed by the introduced hierarchical micropores into NA-LT-CA electrodes by the LT process. Moreover, the cell equipped with the NA-LT-CA electrodes demonstrates an outstanding durability, maintaining its performance for 1000 h without visible degradation under 0.8 A cm−2, which can be ascribed to the distinctive “pinning effect” produced by the transition layer during the LT process, adeptly preventing the catalytic layer peeling off even under industrial-scale current densities. Notably, introducing the LT process delivers a dual benefit, akin to achieving “Two Birds with One Stone.”. This work supports the effectiveness of combining APS and LT processes as a potent strategy for fabricating high-efficiency and enduring electrodes, thus advancing AEMWE for practical industrial applications.

Enhancing Long-Term Durability of Electrochemical Reactors Producing Formate from CO2 and Water Designed for Integration with Solar Cells.

Artificial photosynthetic cells producing organic matter from CO2 and water have been extensively studied for carbon neutrality, and the research trend is currently transitioning from proof of concept using small-sized cells to large-scale demonstrations for practical applications. We previously demonstrated a 1 m2 size cell in which an electrochemical (EC) reactor featuring a ruthenium (Ru)-complex polymer (RuCP) cathode catalyst was integrated with photovoltaic cells. In this study, we tackled the remaining issue to improve the long-term durability of cathode electrodes used in the EC reactors, demonstrating high Faradaic efficiencies exceeding 80% and around 60% electricity-to-chemical energy-conversion efficiencies of a 75 cm2 sized EC reactor after continuous operation for 3000 h under practical conditions. Introduction of a pyrrole derivative containing an amino group in the RuCP coupled with UV-ozone treatment to create carboxyl groups on the carbon supports effectively reduced the detachment of the RuCP catalyst by forming a strong amide linkage. A newly developed chemically resistant graphite adhesive prevented the carbon supports from peeling off of the conductive substrates. In addition, highly durable anodes composed of IrOx-TaOy/Pt-metal oxide/Ti were adopted. Even though the EC reactor was installed at an inclined angle of 30°, which is approximately the optimal angle for receiving more solar energy, the crossover reactions were sufficiently suppressed because the porous separator film impeded the transfer of oxygen gas bubbles from the anode to the cathode. The intermittent operation improved the energy-conversion efficiency because the accumulated bubbles were removed at night.

Effect of martensitic reversal and grain size on the corrosion and wear behaviour of Cr-Mn steel

In this study, the effect of corrosion and wear behaviour of Cr-Mn steel on fine grains were investigated. The sample were solution annealed (SA) for 1 h at 1050 °C and then cold rolled (CW) to 30%. Further the cold rolled sample were thermally aged (CW + TA) 900 °C for four hours. The findings showed that under the 10 N applied load, wear resistance increased with an increase in hardness and martensite fraction of the cold worked (CW) samples. However, the Cr-Mn steel had the superior wear resistance after thermal ageing (TA). In microstructural examination deformation bands can also be visible in cold work samples. The analysis implies that the γ-phase is apparent across all peaks within the spectra of SA samples. In instances involving 30% cold work, prominent α′ martensite peaks were observed, accompanied by minimal ε-martensite peaks. Electrochemical impedance spectroscopy (EIS) analysis discloses a reduction in impedance and a concurrent increase in the defect density of the passive film. The CW+TA structure with good inclusive performances created an early constant hardened layer, which didn’t delaminate and peel off prematurely, thereby effectively increasing the wear resistance, according to analysis of the wear mechanism. The results also concluded that the corrosion resistance of CW sample decreases due to SIM formation, however CW+TA sample provide better corrosion resistance due to smaller and refined grain size.

Rod-like BiVO4 with two-phase structure to boost photoelectrocatalytic degradation activity for tetracycline via the p-n junction

Bismuth vanadate (BiVO4) as a potential photoanode is widely applied in photoelectrocatalytic (PEC) degradation flied. However, it is inhibited due to easy recombination of the photogenerated carries. Herein, rod-like morphology BiVO4 with monoclinic and tetragonal phase structure (R-BVO) are prepared using hydrothermal approach. Density functional theory (DFT) calculation confirms that the build-in electron field is constituted at contact interface of two-phase structure. Benefiting from the one-dimensional conduction of rod like morphology and the p-n junction formed by two-phase structure, R-BVO indicates outstanding photocurrent, the applied bias photo-to-current efficiency (ABPE) and the incident photoelectron conversion efficiency (IPCE). Compared with the single phase structure particle BiVO4 (P-BVO), the PEC degradation rate for TC of R-BVO is 96.4 %, which is 1.4 times of P-BVO. Equally importantly, the Ni foam is used as conducting substrate owing to its low cost and practicability, moreover, it is not only easy to determine catalyst dosage, but also ensures the tight contact between active substance and substrate, preventing the catalyst from peeling off in reaction. This study puts forward an adventurous strategy for designing effective photoanode materials.

Is monochloramine pre-oxidation a viable strategy for enhancing the treatment efficiency of algae-laden water with conventional drinking water treatment process?

Algal blooms worldwide pose many challenges to drinking water production. Pre-oxidation with NaClO, KMnO4, or ozone is commonly used to enhance algal removal in conventional drinking water treatment processes. However, these currently utilized oxidation methods often result in significant algal cell lysis or impede the operation of the subsequent units. Higher algal removal with pre-chlorination in algal solutions prepared with natural water, compared to those prepared with ultrapure water, has been observed. In the present studies, preliminary findings indicate that ammonium in natural water alters chlorine species to NH2Cl, leading to improved treatment efficiency. NH2Cl with 1.5–3.0 mg∙L−1 as Cl2 with an oxidation time of 3–7 h significantly enhancing algal removal by coagulation. The selective oxidation of surface-absorbed organic matter (S-AOM) by NH2Cl, followed by the subsequent peeling off of this material from the algal surface, leading to an increase in zeta potential from −20.2 mV to −3.8 mV, constitutes the primary mechanism of enhanced algal removal through coagulation. These peeled S-AOM retained their large molecular weight and acted as polymer aids. Compared with NaClO and KMnO4, NH2Cl displays the best performance in improving algal removal, avoiding cell lysis, and decreasing the potential for nitrogenous disinfection byproducts formation under the reaction conditions used in this study. Notably, in major Chinese cities, water purification plants commonly rely on suburban lakes or reservoirs as water sources, necessitating the transportation of raw water over long distances for times up to several hours. These conditions favor the implementation of NH2Cl pre-oxidation. The collective results indicate the potential of NH2Cl oxidation as a viable pretreatment strategy for algal contamination during water treatment processes.

First report of Diplodia bulgarica causing black canker on apple in California.

California is the sixth largest apple-producing state in the United States with a production that reached 4,654 ha in 2021. During the late winter of 2023, black canker symptoms were observed on branches of 'Gravenstein' apple (Malus domestica) in two commercial orchards in Sonoma County, California. The prevalence of symptomatic trees ranged from 10 to 30%. External symptoms included charcoal looking-cankers with the bark peeling off from the primary and secondary branches. Internally, cankers were dark brown in color with a hard consistency. Pycnidia were observed on the surface of older cankers. Fungal isolations were performed from disinfected (70% ethanol, 30 s) symptomatic branch samples (n = 15). Small wood pieces (5 mm length) were taken from the margin of diseased and healthy tissues, and placed on potato dextrose agar acidified with 92% lactic acid at 0.5 mL per liter (APDA). Plates were incubated at room temperature (20-22 °C) for 7 days. Colonies of Botryosphaeriaceae species (Phillips et al. 2013) (n = 12) were consistently recovered and pure cultures were obtained by transferring a single hyphal tip onto fresh APDA. Colonies were light gray with irregular margins. To induce pycnidia formation, two isolates (UCD11350 and UCD11351) were grown on pistachio leaf agar for 21 days. Conidia (n = 50) were thick-walled and ovoid in shape, initially hyaline, then turned pale brown and dark brown at maturity, and some of them became 1-septate, ranging from 18.9 to 24.0 (21.9) × 11.5 to 14.7 (13.4) µm. Isolates were identified by sequencing a partial region of the beta-tubulin (tub2) gene using the primers Bt2a/Bt2b (Glass and Donaldson 1995). BLAST searches on NCBI GenBank revealed 99.5 % identity with the Diplodia bulgarica ex-type (CBS 1245254). To confirm the identity, the rRNA internal transcribed spacer (ITS) and the translation elongation factor 1-alpha (tef1) were also sequenced using ITS5/ITS4 (White et al. 1990), and EF1-688F/EF1-1251R (Alves et al. 2008), respectively. A maximum parsimony multi-locus phylogenetic analysis clustered Californian isolates with reference strains of D. bulgarica. Sequences were deposited in GenBank (nos. OR631209 to OR631210, OR637361 to OR637362, OR637363 to OR637364 for ITS, tub2, and tef1, respectively). Pathogenicity tests were conducted on 2 to 3-year-old branches (n = 5) of over 20-year-old trees by inserting a 5-mm segment of a toothpick, completely colonized with each of the two isolates mentioned above, into a 1-mm-diameter hole made with a sterile drill bit. The same number of branches where mock inoculated with a non-colonized toothpick as negative control. The experiment was performed twice. After ten weeks, inoculations resulted in dark brown necrotic lesions that ranged from 54.0 to 59.8 mm in length. Negative controls remained asymptomatic. Koch's postulates were fulfilled by successfully recovering the isolates from the lesion margins, which were confirmed by morphology. Diplodia bulgarica was first described affecting M. sylvestris in Bulgaria (Phillips et al. 2012), and then detected on M. domestica causing cankers in Iran (Abdollahzadeh 2015), India (Nabi et al. 2020), Germany (Hinrichs-Berger al. 2021) and Türkiye (Eken 2021). The pathogen was also identified causing postharvest fruit rot (Eken 2022). To our knowledge, this is the first report of D. bulgarica causing branch canker on apple in California, which provides important information for developing detection and control strategies.

Preparation and corrosion resistance of polyaniline and waterborne polyurethane composite coating film

AbstractPolyaniline (PANI) particles were synthesized using aniline (AN), dodecyl benzene sulfonic acid (DBSA), and ammonium persulfate (APS). The particles were analyzed using scanning electron microscope (SEM), X‐ray diffraction (XRD), and fourier transform infrared spectroscopy (FTIR). A PANI/waterborne polyurethane composite material (PANI‐WPU) was obtained by combining it with polyethylene glycol (PEG600), diphenylmethane diisocyanate (MDI), dimethylol propionic acid (DMPA), N‐methyl pyrrolidone (NMP), and dibutyltin lauric acid (DBTDL). The structure was characterized by the FTIR spectrum. The mechanical characteristics of the coating film were evaluated with respect to the PANI content, as well as its water absorption, glossiness, electrochemical corrosion resistance, and acid and alkali resistance. The PANI/waterborne polyurethane film has a maximum tensile strength of 23 MPa, an elongation of 1012%, a pencil hardness of 5H, a flexibility of 2 mm, an impact resistance of 50 cm, the water absorption of 14.66%, and the glossiness of 99.9 at 60°. When the PANI content is 0.7%, the mechanical characteristics, glossiness, and anti‐corrosion performance of the composite film improve. The corrosion inhibition efficiency of the aqueous polyurethane coating film with PANI can reach 99.74%, as shown by the examination of electrochemical polarization curves and impedance spectra. The tinplate is coated with a 0.7% PANI‐WPU composite material and edge sealing. This coating provides excellent protection against acid and alkali resistance, as demonstrated by its ability to withstand immersion in 10% H2SO4 and 10% NaOH solution for 90 days without any paint peeling off.

FORMULASI MASKER GEL PEEL OFF EKSTRAK BUNGA TELANG (Clitoria ternatea L.) SEBAGAI ANTIOKSIDAN ALAMI

Natural ingredients containing antioxidant compounds can be made in the form of a peel-off gel mask which can help care for facial skin. Butterfly pea flowers (Clitoria ternatea L.) contain flavonoid anthocyanin compounds which can break the chain reaction of free radicals. The aim of this research is to determine the antioxidant activity of butterfly pea flower extract and the preparation of butterfly pea peel off gel mask. The peel off gel mask formulation uses butterfly pea flower extract with a concentration of 5%. Testing for antioxidant activity uses the DPPH method. Physical characteristics assessment includes organoleptic tests, homogeneity observations, spreadability tests, viscosity tests, drying time tests, and preparation pH tests. Based on the research results, the IC50 value of telang flower extract is 43.68 ppm in the very strong category and the IC50 value of the peel-off gel mask preparation is 307.71 ppm in the inactive category. This research shows that the ethanol extract of butterfly pea flowers has potential as a natural antioxidant.

Hybrid Binder Chemistry with Hydrogen-Bond Helix for High-Voltage Cathode of Sodium-Ion Batteries.

Since sodium-ion batteries (SIBs) have become increasingly commercialized in recent years, Na3V2(PO4)2O2F (NVPOF) offers promising economic potential as a cathode for SIBs because of its high operating voltage and energy density. According to reports, NVPOF performs poorly in normal commercial poly(vinylidene fluoride) (PVDF) binder systems and performs best in combination with aqueous binder. Although in line with the concept of green and sustainable development for future electrode preparation, aqueous binders are challenging to achieve high active material loadings at the electrode level, and their relatively high surface tension tends to cause the active material on the electrode sheet to crack or even peel off from the collector. Herein, a cross-linkable and easily commercial hybrid binder constructed by intermolecular hydrogen bonding (named HPP) has been developed and utilized in an NVPOF system, which enables the generation of a stable cathode electrolyte interphase on the surface of active materials. According to theoretical simulations, the HPP binder enhances electronic/ionic conductivity, which greatly lowers the energy barrier for Na+ migration. Additionally, the strong hydrogen-bond interactions between the HPP binder and NVPOF effectively prevent electrolyte corrosion and transition-metal dissolution, lessen the lattice volume effect, and ensure structural stability during cycling. The HPP-based NVPOF offers considerably improved rate capability and cycling performance, benefiting from these benefits. This comprehensive binder can be extended to the development of next-generation energy storage technologies with superior performance.

Evaluation of Three Common Green Building Materials Using ELECTRE Method

This research paper examines various options for replacing halogenated flame retardants with non-halogenated green construction material choices. Cellulosic construction materials like bamboo do not form compounds with conventional flame retardants. Due to a number of circumstances, including the minimal effectiveness of the flame-retardant activity, they may thus be an unnecessary component of the substrate and simply peel off. Utilizing an additive that comes into direct contact with at least one component of the "green building material" will provide long-lasting flame retardancy since the flame retardant will become a structurally integral element of the substrate. The response mechanisms of various treatment approaches are also discussed in this research to ensure that non-halogenated flame retardants effectively protect sustainable building materials like wood and bamboo. This paper demonstrates how various ELECTRE approaches may be used to choose effective tactics that take into account both technical and human behavioral barriers using a typical case study inside an organization. The impact of impedance from each system subsystem is investigated to assure the dependability of the selected method. When employee participation is a deciding element in the multidimensional strategic planning problem, a comparison of a range of compensated and non-compensatory models reveals that the models may produce less. Resistance strategies; However, ELECTRE shows very reasonable sensitivity. The alternatives are Gladstone, Port Augusta, Collie and Tarong. the evaluation parameters are Construction cost, Procurement cost, Waste reduction, GHG emissions, Cement replacement and Self-consolidating. The Final Result of Net superior value and rank the Gladstone is in fourth rank, The Port Augusta is in second rank, The Collie is in third rank, The Tarong is in first rank of the Net Inferior Value and Rank the Tarong is in fourth rank, The Gladstone is in first rank, The Port Augusta is in Second rank, The Collie is in third rank.