Peanut Shell Research Articles

BIOCHARS FROM SLOW PYROLYSIS OF PEANUT SHELLS, CASHEW NUT SHELLS, AND MILLET STALKS AS VALUE-ADDED PRODUCTS FOR BRIQUETTE PRODUCTION

Biomass is nowadays used for producing biochar briquettes through slow pyrolysis technologies namely for cooking purposes in developing countries. This article investigated some properties of biochar obtained from tropical biomasses like peanut shells, cashew nut shells, and millet stalks, pyrolyzed at 400 °C and 800 °C. Firstly the mass yield and energy yield of the biochar were determined. The main properties investigated were obtained by conducting proximate and ultimate analysis, determination of calorific value, FTIR (Fourier-transform infrared) analysis, and thermogravimetric analysis. The results showed that depending on the biomass and the pyrolysis temperature, the biochar yields varied from 20.26 % to 42.79 % while the energy yields varied from 24.24 % to 60.71 %. The highest yields are obtained with the lowest temperature and are all more important with peanut shells. All the biochars had fixed carbon contents greater than 60%, except biochar obtained at 400°C with millet stalks. The millet stalks biochar obtained at 400 °C was the one with the highest ash content (21.41%) and the lowest fixed carbon content (59.31%). It was observed that the more the pyrolysis temperature increased, the more the carbon content increased. The lower heating value of raw biomasses and biochars varied respectively between 18.36 and 22.51 MJ/kg and between 23.83 and 30.85 MJ/kg. FTIR analysis results showed that the O-H and C-O bonds disappeared in the case of biochars obtained at 800 °C. The reactivity of biochars towards O2 showed that for all biochars, ignition temperatures (Ti) were up to 317 °C and the temperatures at maximum mass loss rate were between 438 °C and 501 °C.

Effects of Combined Peanut Shell and Biochar Application on Soil Nutrient Content, CO2 Emission, and Bacterial Community in Dryland Red Soil of Southern China

Effects of Combined Peanut Shell and Biochar Application on Soil Nutrient Content, CO2 Emission, and Bacterial Community in Dryland Red Soil of Southern China

Waste peanut shells derived activated carbon for dual electrochemical applications

AbstractIn recent scenarios, plenty of research has been conducted on porous activated carbon derived from biowaste precursors. The well‐developed surface area and porous nature of biowaste‐derived activated carbon material make them good candidates for electrochemical devices to use as electrode material. In the present work, we have used waste peanut shells (W.P.) as a precursor material to derive large surface area activated carbon. Chemical activation is used to activate the activated carbon, for which ZnCl2 is used as an activating agent. The waste peanut shell‐derived activated carbon (WPAC) is studied via XRD, FESEM, and BET. Prepared carbon shows a large BET surface area of 1366 m2 g−1 and a well‐developed pore structure; the presence of pores is also confirmed by FESEM images. A solid‐state supercapacitor is also fabricated using waste peanut shell‐based activated carbon and ionic liquid‐based polymer electrolyte. The EDLC is further studied using electrochemical characterizations such as CV, EIS, and GCD. The EIS study found that the WPAC‐based EDLC cell shows a specific capacitance of 25 F/g at 10 mHz. A DSSC is also fabricated using the WPAC on the counter electrode, and it shows an efficiency of 0.96% with a fill factor of 27.79.

Properties and photosynthetic promotion mechanisms of artificial humic acid are feedstock-dependent

AbstractThe artificial humic acids (AHA) approach contributes to achieving the carbon (C) emission peaking and neutrality goal through efficient recycling of waste biomasses and promotion of plant photosynthesis. However, the dependence of their production processes and photosynthetic promotion mechanisms on feedstocks remains unclear. In this study, waste biomasses including camphor leaves (CL), corn stalks (CS), peanut shells (PS), and mixed cyanobacteria (MC) have been respectively converted into artificial humic acids through an environmentally friendly hydrothermal humification approach. The dynamic humification process of different feedstocks and the composition, structural properties, and electron transfer capacity of AHA products were determined. Moreover, the different AHA products were applied to corn to explore their respective photosynthetic promotion mechanisms. High relative contents of lignin and C/N in feedstocks are not conducive to the formation of photodegradable substances and the redox property in AHA. The application of AHA increased the net photosynthetic rate and biomass C of corn by 70–118% and 22–39%, respectively. The AHA produced from higher H/C (0.19) and hemicellulose content (17.09%) in feedstocks (e.g., MC) increased corn photosynthesis by improving light energy capture and conversion efficiency in the PSII process. In contrast, the AHA produced from a higher content of lignin (19.81%) and C/N (7.67) in feedstocks (e.g., CS) increased corn photosynthesis by providing functional enzymes (proteins) and nutrients for leaves. This work provides new insights into the utilization of renewable resources, and the artificial humic acids approach sheds light on environmental sustainability by constructing a closed loop of C in environments. Graphical Abstract

Hydrocarbon-Rich Bio-Oil Production from Ex Situ Catalytic Microwave Co-Pyrolysis of Peanut Shells and Low-Density Polyethylene over Zn-Modified Hierarchical Zeolite

Peanut shells, a major economic and oil crop in China, boast an abundant availability and remarkably high lignin content compared to other agricultural residues. Previous work indicated that the modified hierarchical zeolite (Zn-ZSM-5/MCM41) was effective in promoting the conversion of intermediate macromolecules during the lignin pyrolysis reaction and enhancing the yield and selectivity of liquid products. Thereby, this study aims to improve the quality of liquid products in the ex situ catalytic microwave co-pyrolysis of peanut shells and LDPE by utilizing Zn-ZSM-5/MCM41. Employing a compound center experimental design, we optimized reaction conditions through response surface analysis. The impact of microwave pyrolysis temperature and the catalyst-to-feedstock ratio on yield distribution and liquid product selectivity was explored. Results indicated a marginal increase in liquid product yield with rising pyrolysis temperatures. Moreover, an initial increase followed by a subsequent decrease in liquid product yield was observed with an increase in the catalyst-to-feedstock ratio. Optimal conditions of 450 °C and a catalyst-to-peanut hull ratio of 2.34% yielded the highest bio-oil yield at 34.25%. GC/MS analysis of the bio-oil revealed a peak in hydrocarbon content at 68.36% under conditions of 450 °C and a catalyst-to-feedstock ratio of 13.66%. Additionally, the quadratic model effectively predicted bio-oil yield and the selectivity for major chemical components. This study underscores the potential of Zn-ZSM-5/MCM41 in optimizing liquid product quality during catalytic co-pyrolysis, offering insights into bio-oil production and its chemical composition.

Effective adsorption of cadmium and nickel ions in mono and bicomponent systems using eco-friendly adsorbents prepared from peanut shells

The work investigates the potential of peanut shells, an abundant agro-industrial waste, to serve as an adsorbent precursor for the effective and simple treatment of effluents loaded with cadmium and nickel ions. Among the adsorbents prepared, carbonized peanut shell (CCarb), due to its higher adsorption capacity, proved to be the most effective compared to carbonized and activated peanut shell (CATQ). The carbonization process led to structural changes, which resulted in an increase in surface area (around 6 times more in CATQ) and pore volume (around 3 times more in CATQ). Even so, the amount of H+ acid sites due to acid activation produced unfavorable effects for adsorption. Hydroxyl, carboxyl and carbonyl groups were identified on the adsorbent surface which presented favorable charges for metal adsorption. This improvement propels the carbonized variant to the forefront, demonstrating the highest adsorption capacity and reaching equilibrium in less than 90 and 60 min for cadmium and nickel ions, respectively. In both monocomponent and bicomponent systems concentrations greater than 40 ppm signify an increase in adsorption capacity for Ni2+. The experimental data best fit the Freundlich model, showing maximum adsorption capacities of 17.04 mg g−1 for cadmium and 31.28 mg g−1 for nickel. Despite the antagonistic effect observed in the bicomponent system, this study concludes by underlining the promise of activated carbon from peanut shells to harmonize technical and environmental concerns.

Identification of two major QTLs for pod shell thickness in peanut (Arachis hypogaea L.) using BSA-seq analysis.

Pod shell thickness (PST) is an important agronomic trait of peanut because it affects the ability of shells to resist pest infestations and pathogen attacks, while also influencing the peanut shelling process. However, very few studies have explored the genetic basis of PST. An F2 segregating population derived from a cross between the thick-shelled cultivar Yueyou 18 (YY18) and the thin-shelled cultivar Weihua 8 (WH8) was used to identify the quantitative trait loci (QTLs) for PST. On the basis of a bulked segregant analysis sequencing (BSA-seq), four QTLs were preliminarily mapped to chromosomes 3, 8, 13, and 18. Using the genome resequencing data of YY18 and WH8, 22 kompetitive allele-specific PCR (KASP) markers were designed for the genotyping of the F2 population. Two major QTLs (qPSTA08 and qPSTA18) were identified and finely mapped, with qPSTA08 detected on chromosome 8 (0.69-Mb physical genomic region) and qPSTA18 detected on chromosome 18 (0.15-Mb physical genomic region). Moreover, qPSTA08 and qPSTA18 explained 31.1-32.3% and 16.7-16.8% of the phenotypic variation, respectively. Fifteen genes were detected in the two candidate regions, including three genes with nonsynonymous mutations in the exon region. Two molecular markers (Tif2_A08_31713024 and Tif2_A18_7198124) that were developed for the two major QTL regions effectively distinguished between thick-shelled and thin-shelled materials. Subsequently, the two markers were validated in four F2:3 lines selected. The QTLs identified and molecular markers developed in this study may lay the foundation for breeding cultivars with a shell thickness suitable for mechanized peanut shelling.

Biochar co-pyrolyzed from peanut shells and maize straw improved soil biochemical properties, rice yield, and reduced cadmium mobilization and accumulation by rice: Biogeochemical investigations

Biochar is an eco-friendly amendment for the remediation of soils contaminated with cadmium (Cd). However, little attention has been paid to the influence and underlying mechanisms of the co-pyrolyzed biochar on the bioavailability and uptake of Cd in paddy soils. The current study explored the effects of biochar co-pyrolyzed from peanut shells (P) and maize straw (M) at different mixing ratios (1:0, 1:1, 1:2, 1:3, 0:1, 2:1 and 3:1, w/w), on the bacterial community and Cd fractionation in paddy soil, and its uptake by rice plant. Biochar addition, particularly P1M3 (P/M 1:3), significantly elevated soil pH and cation exchange capacity, transferred the mobile Cd to the residual fraction, and reduced Cd availability in the rhizosphere soil. P1M3 application decreased the concentration of Cd in different rice tissues (root, stem, leaf, and grain) by 30.0%− 49.4%, compared to the control. Also, P1M3 enhanced the microbial diversity indices and relative abundance of iron-oxidizing bacteria in the rhizosphere soil. Moreover, P1M3 was more effective in promoting the formation of iron plaque, increasing the Cd sequestration by iron plaque than other treatments. Consequently, the highest yield and lowest Cd accumulation in rice were observed following P1M3 application. This study revealed the feasibility of applying P1M3 for facilitating paddy soils contaminated with Cd.

Investigation of Mechanical and Thermal Stabilities of Tamarind Seed- and Peanut Shell Powder-Reinforced Vinyl Ester Composite

Efficient exploitation of agricultural waste results in a more sustainable and ecofriendly environment since it lessens the burden of their disposal, which has become increasingly important in recent times. Due to their high mechanical strength and high thermal stability, these biodegradable low-value agrosolid wastes have the potential to successfully replace synthetic fibers and fillers in polymer matrices in the form of reinforcements. This work deals with the addition of low-cost and renewable hybrid natural fillers, tamarind seed filler (TMS), and peanut shell powder (PNS) as particulate reinforcements to the vinyl ester (VE) resin. Traditional compression molding creates TMS/PNS-VE hybrid composites with filler loadings ranging from 5% to 30%. After the composites were fabricated, they were tested for strength properties and heat deflection temperature. A detailed experimental analysis of the mechanical properties was conducted. According to the findings, 20 wt.% hybrid filler loading to the vinyl ester polymer exhibited peak tensile, flexural, and impact strengths of 40.3 MPa, 142 MPa, and 16 kJ/m2, respectively, which is 1.52, 1.69, and 1.29 times the properties of the virgin polymer. However, the peak elongation at break 3.9% was obtained at 30 wt.%. Similarly, the heat deflection temperature (HDT) test of TMS/PNS-VE composites showed a maximum rise of 50.91% at 25 wt.% of filler loading. This is 1.51 times greater than the heat deflection temperature of the pure vinyl ester resin. The findings made it quite clear that adding 20 wt.% biosolid waste hybrid particulate fillers made out of tamarind seed and peanut shell to vinyl ester is the optimum weight, which improves the mechanical and thermal properties of the TMS/PNS-VE composite, making it suitable for making cost-effective materials for lightweight applications. This study also utilizes scanning electron microscopy (SEM) to investigate the microstructural characteristics of the composites, correlating these features with their mechanical performance.

Electron beam pre-irradiation enhances substitution degree, and physicochemical and functional properties of carboxymethyl peanut shell nanocellulose

Nanocellulose (NC) has attracted close attention in research and industry fields because of its excellent properties and plentiful hydroxyl group accessible for surface modification. In this study, the cellulose isolated from peanut shells was used to prepare carboxymethylated nanocellulose (CMNC) under different reaction conditions, and Electron beam irradiation (EBI) pretreatment with different doses (40, 80 and 120 KGy) was previously used before modification to improve the reaction accessibility of nanocellulose. The substitution degree (DS), structural, physicochemical and functional properties of carboxymethyl CMNC with EBI pretreatment were investigated. The results showed that the peanut shell nano cellulose was a typical rod-like structure with a diameter of 5–40 nm and a length of 50–300 nm, the aspect ratio distribution was about 6.37, and EBI pretreatment significantly improved the modification effect of CMNC. The DS of the unirradiated sample was 0.38 and 0.48, and the DS increased to 0.66 and 0.69 at the irradiation dose of 120 kGy, which increased by 74% and 44%, respectively. The carboxymethyl modification changed the morphology of nanocellulose from the original short rod-like to spherical particles, and the effect was more evident with the increase of irradiation dose. FTIR showed that the nanocellulose successfully introduced carboxyl groups, the crystalline structure of nanocellulose was changed by carboxymethyl reaction. The Zeta potential result showed that the dispersion stability of CMNC suspension was improved. These results provide a helpful basis for further investigations on the modification in nanocellulose induced by EBI, verifying the effectiveness and feasibility of using EBI to modify nanofibers. They are expected to guide the transformation of nanocellulose and its most possible applications in the future to improve its performance in different applications.

Biochar relieves the toxic effects of microplastics on the root-rhizosphere soil system by altering root expression profiles and microbial diversity and functions

The accumulation of microplastics in agricultural soil brings unexpected adverse effects on crop growth and soil quality, which is threatening the sustainability of agriculture. Biochar is an emerging soil amendment material of interest as it can remediate soil pollutants. However, the mechanisms underlying biochar alleviated the toxic effects of microplastics in crops and soil were largely unknown. Using a common economic crop, peanut as targeted species, the present study evaluated the plant physiologica and molecular response and rhizosphere microbiome when facing microplastic contamination and biochar amendment. Transcriptome and microbiome analyses were conducted on peanut root and rhizosphere soil treated with CK (no microplastic and no biochar addition), MP (1.5% polystyrene microplastic addition) and MB (1.5% polystyrene microplastic+2% peanut shell biochar addition). The results indicated that microplastics had inhibitory effects on plant root development and rhizosphere bacterial diversity and function. However, biochar application could significantly promote the expressions of key genes associated with antioxidant activities, lignin synthesis, nitrogen transport and energy metabolism to alleviate the reactive oxygen species stress, root structure damage, nutrient transport limitation, and energy metabolism inhibition induced by microplastic contamination on the root. In addition, the peanut rhizosphere microbiome results showed that biochar application could restore the diversity and richness of microbial communities inhibited by microplastic contamination and promote nutrient availability of rhizosphere soil by regulating the abundance of nitrogen cycling-related and organic matter decomposition-related microbial communities. Consequently, the application of biochar could enhance root development by promoting oxidative stress resistance, nitrogen transport and energy metabolism and benefit the rhizosphere microecological environment for root development, thereby improved the plant-soil system health of microplastic-contaminated agroecosystem.

Label-free comparative proteomic analysis of Pleurotus eryngii grown on sawdust, bagasse, and peanut shell substrates

The white rot fungi Pleurotus eryngii are environmental microorganisms that can effectively break down lignocellulosic biomass. However, understanding of the mechanisms by which P. eryngii is effective in degrading lignocellulose is still limited. This work aimed to examine the extracellular secretory proteins implicated in the breakdown of lignocellulose in P. eryngii and identify degradation tactics across various cultivation substrates. Thus, a comparative analysis of the secretory proteins based on Nanoliquid chromatography combined with tandem mass spectrometry was conducted among P. eryngii cultivated on sawdusts, bagasse, peanut shells, and glucose. In total, 647, 616, 604, and 511 proteins were identified from the four samples, respectively. Gene Ontology and Kyoto Encyclopedia of Genes and Genomes pathway analysis of protein expression differences identified pathways (hydrolytic enzymes, catalytic activity, metabolic processes, cellular processes, and response to stimuli) significantly enriched in proteins associated with lignocellulose degradation in P. eryngii. An integrated analysis of proteome data revealed specifically or differentially expressed genes secreted by P. eryngii in different cultivation substrates. The most prevalent carbohydrate-active enzymes involved in lignocellulose degradation in the secretome of the four samples were laccase (Lac), manganese peroxidase (MnP), aryl alcohol oxidase (AaO), and copper radical oxidase (CRO). Among them, Lac 2 mainly involved in the lignin degradation of sawdust peanut shells, and bagasse by P. eryngii, and Mnp 3 was mainly involved in the degradation of peanut shells. AaO and Lac 4 were mainly involved in glucose substrate defense and oxidative stress. It was found that exogenous addition of sawdust and peanut shells significantly increased lignolytic enzyme abundance. These findings provide insight and guidance for improving agricultural waste resource recovery.In this study, the secretomes of P. eryngii grown on four different carbon sources were compared. The findings revealed the extracellular enzymes implicated in the degradation of lignocellulose, offering avenues for further investigation into the biotransformation mechanisms of P. eryngii biomass and the potential utilization of agricultural wastes. SignificanceThe cost of the substrate for mushroom cultivation has increased as the production of edible fungus has risen year after year. Therefore, the use of these locally available lignocellulosic wastes as substrates offers a cost-cutting option.Further, the overuse of wood for the cultivation of edible mushrooms is also detrimental to the conservation of forest resources or the ecological environment.Consequently, the use of other agricultural wastes as an alternative to sawdust or other woody substrates is a viable approach for cultivating P. eryngii.The distribution of extracellular lignocellulosic degrading enzymes, inferred in the present study could help improve the cultivation efficiency of P. eryngii vis-à-vis managing agricultural waste.

Safety of Chinese Cabbage Waste and Rice Straw Mixed Silage and Its Effect on Growth and Health Performance of Hu Sheep

Improper disposal of vegetable waste can cause serious environmental pollution, but because they contain huge water content and organic matter, they are not suitable for disposal by methods such as incineration and landfill. However, vegetable waste contains a large amount of nutrients and have some complementary effects with rice straw in terms of physical structure, nutrients, and moisture. In this experiment, the plant feed (corn husk, peanut shells and sorghum shells) was used as the control group (CON group), and the mixed silage of Chinese cabbage waste and rice straw (mixed silage) was used as the experiment group (TRE group), and its safety performance was evaluated by testing its toxin content, pesticide residues, vitamin contents and feeding experiment of Hu sheep. In the animal experiment, 16 healthy Hu sheep (5.5 months, 39.11 ± 4.16 kg) were randomly divided into two groups of 8 each. The results of the safety performance evaluation showed that the content of mycotoxins, heavy metals, and nitrites as well as pesticide residues in the crude feeds of both groups were within the range of Chinese feed hygiene standards. In addition, the levels of deoxynivalenol (DON) and aflatoxin (AFT) in the CON group were lower, while the content of ochratoxin (OTA) and zearalenone were higher than those in the TRE group (p < 0.05). The levels of plumbum(Pb), chromium (Cr), cadmium (Cd), and nitrite in the CON group were lower than the mixed silage, while the levels of As were higher than the mixed silage (p < 0.05). It is worth noticing that the content of vitamin B2 (VB2) and vitamin C (VC) in the TRE group was higher than the CON group (p < 0.05). The results of the feeding experiment showed that the mixed silage did not affect the growth performance, nutrient digestibility, organ index, and intestinal index of Hu sheep (p > 0.05). In addition, the mixed silage reduced the weight of omasum, the proportion of omasum to live weight before slaughter, the amount of compound stomach, and the proportion of compound stomach to live weight before slaughter, which were higher than those in the TRE group (p < 0.05). The thickness of the basal layer of the rumen abdominal sac, the red blood cell count, the content of IL-10, and TNF-α in the blood, and TNF-α content in the rumen of the Hu sheep in the TRE group were higher than the CON group (p < 0.05). In conclusion, the feed safety index content of the mixed silage did not exceed the Chinese feed hygiene and safety standards and did not cause adverse effects on the growth performance of the Hu sheep, and it improved the immune performance of the body and digestive tract of the sheep to a certain extent and promoted the healthy development of the sheep.

The use of peanut shells as a bio-template to prepare K-doped In2O3 porous sheets for chlorine detection.

Chlorine (Cl2) is highly toxic and pungent, and can cause irreversible harm to humans even at low concentrations. Therefore, it is significant to develop a sensor that is highly sensitive to trace amounts of Cl2 leakage. In this work, inexpensive peanut shells are used as a biological template to prepare K-doped indium oxide (K-In2O3) porous sheets through a simple three-step process. The characterization results reveal the porous sheet microstructure of the prepared K-In2O3 derived from the peanut shell bio-template, and the obtained material possesses rich oxygen vacancies and a high specific surface area. Gas-sensing tests demonstrate that the K-In2O3 porous sheet sensor exhibits excellent sensitivity to low concentrations of Cl2.

Sustainable Solution Economically for The Production of Paper Pulp from Peanut Shell

The increasing demand for sustainable and eco- friendly materials has prompted researchers to explore alternative sources for paper pulp production. This research paper investigates the feasibility of utilizing peanut shells, an abundant agricultural waste, as a potential raw material for paper pulp production. The study focuses on the process of converting peanut shells into high-quality pulp through various methods such as chemical and mechanical pulping. The paper further discusses the potential benefits, challenges, and environmental implications of using peanut shell pulp as a sustainable alternative to conventional wood-based pulps. The findings of this research contribute to the growing body of knowledge on sustainable resource management and promote the utilization of agricultural waste for value- added applications.

Hydrothermal synthesis and electrochemical properties of Sn-based peanut shell biochar electrode materials.

Using activated-carbon-based electrodes derived from waste biomass in super-capacitor energy technologies is an essential future strategy to achieve sustainable energy and environmental protection. Biomass feed-stocks such as bamboo and straw have been used to prepare activated carbon-based electrodes. This experiment used peanut shells (waste biomass) as carbon precursors. Peanut shell-activated biochar materials were prepared using KOH activation and heat treatment, and SnO2@KBC-CNTs, a composite electrode material of biochar loaded with tin oxide. It was produced through hydrothermal synthesis, utilizing SnCl4-5H2O as the tin precursor. The application of KOH activators during pyrolysis markedly enhanced the porosity and specific surface area of the resultant activated biochar, due to effective dispersion and degradation of pyrolytic products. Characterized by a micro-mesoporous structure, the composite's pores boasted a specific surface area of 158.69 m2 g-1. When tested at a density of current of 0.5 A g-1, the specific capacitance of SnO2@KBC-CNTs reached 198.62 F g-1, nearly doubling the performance of the KBC electrode material alone. Moreover, the composite demonstrated a low ion transfer resistance of 0.71 Ω during charge-discharge cycles.

Peanut shell carbon quantum dots modified with citric acid: amplifying visual detection of fluorescence sensitivity for Cu2+

PSCA-CQDs are prepared from peanut shells and CA for the visual detection of Cu2+ ions via fluorescence, which is recovered with EDTA.

Preparation of a biochar-lignosulfonate composite material and its adsorption performance for Cu2.

Biochar was prepared using peanut shells as raw materials, and then composite amino-functionalized lignosulfonate was used to prepare a biochar/lignosulfonate adsorbent (BC-CLS). The morphology and structure of BC-CLS were characterized using FT-IR, SEM, zeta potential, and XPS. The adsorption performance of BC-CLS was evaluated by batch adsorption experiments and dynamic adsorption experiments (adsorption column flow adsorption). The results showed that BC-CLS adsorbent exhibited significant adsorption performance for Cu2+, including a short equilibrium time (50 min), fast adsorption rate (11 mg g-1 min-1), and high static saturation adsorption capacity (354 mg g-1). Dynamic adsorption experiments indicated that the maximum adsorption capacity of BC-CLS adsorbent was approximately 280 mg g-1, with a removal rate of over 99% after five cycles, meeting the wastewater discharge standard (less than 1 mg L-1). The results demonstrated that the adsorption capacity of BC-CLS adsorbent for Cu2+ was controlled by multiple adsorption mechanisms, including electrostatic attraction, precipitation, and metal ion complexation. Additionally, under pH = 5 conditions, using a 40 mg per L Cu2+ solution, the adsorption performance of BC-CLS adsorbent remained above 60% after five adsorption-desorption experiments, indicating good cycling stability of BC-CLS adsorbent.

Activated carbon with composite pore structures made from peanut shell and areca nut fibers as sustainable adsorbent material for the efficient removal of active pharmaceuticals from aqueous media

Activated carbon with composite pore structures made from peanut shell and areca nut fibers as sustainable adsorbent material for the efficient removal of active pharmaceuticals from aqueous media

Removal of Nitrate in Aqueous Solution by Adsorption using Activated Carbon from Peanut (Arachis hypogaea) Shells Impregnated with Zn2+ from ZnCl2 Solution

Removal of Nitrate in Aqueous Solution by Adsorption using Activated Carbon from Peanut (<i>Arachis hypogaea</i>) Shells Impregnated with Zn²⁺ from ZnCl₂ Solution