This work investigates the effect of pulse width on the characteristics of electrical discharge, optical emission spectra and ozone production in a water electrode DBD using a modulable nanosecond pulsed power supply. Results show that the increase of pulse width tpw slightly increases the spectral intensity and the rotational temperature Trot, with a typical Trot of 299 ± 5 K at an applied peak voltage Vp of 18.6 kV and a tpw of 400 ns. The electronic excitation temperature Texc increases linearly with Vp and gradually with tpw, while the electron density ne shows a non-linear relationship with tpw. Results also show that an increase in tpw slightly increases the energy density. At low energy densities (SIE < 50 J/L), increasing tpw can improve ozone generation efficiency, reaching a maximum of 99.64 ± 0.87 g/kWh at 33.60 ± 1.53 J/L at a tpw of 900 ns. This investigation provides substantial insight into the nanosecond pulsed ozone production.
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