Release Of Pb Research Articles

Isotopic Signatures and Outputs of Lead from Coal Fly Ash Disposal in China, India, and the United States.

Despite extensive research and technology to reduce the atmospheric emission of Pb from burning coal for power generation, minimal attention has been paid to Pb associated with coal ash disposal in the environment. This study investigates the isotopic signatures and output rates of Pb in fly ash disposal in China, India, and the United States. Pairwise comparison between feed coal and fly ash samples collected from coal-fired power plants from each country shows that the Pb isotope composition of fly ash largely resembles that of feed coal, and its isotopic distinction allows for tracing the release of Pb from coal fly ash into the environment. Between 2000 and 2020, approx. 236, 56, and 46 Gg Pb from fly ash have been disposed in China, India, and the U.S., respectively, posing a significant environmental burden. A Bayesian Pb isotope mixing model shows that during the past 40 to 70 years, coal fly ash has contributed significantly higher Pb (∼26%) than leaded gasoline (∼7%) to Pb accumulation in the sediments of five freshwater lakes in North Carolina, U.S.A. This implies that the release of disposed coal fly ash Pb at local and regional scales can outweigh that of other anthropogenic Pb sources.

Development of a physiologically based toxicokinetic model for lead in pregnant women: The role of bone tissue in the maternal and fetal internal exposure

Epidemiological studies have shown associations between prenatal exposure to lead (Pb) and neurodevelopmental effects in young children. Prenatal exposure is generally characterized by measuring the concentration in the umbilical cord at delivery or in the maternal blood during pregnancy. To assess internal Pb exposure during prenatal life, we developed a pregnancy physiologically based pharmacokinetic (p-PBPK) model that to simulates Pb levels in blood and target tissues in the fetus, especially during critical periods for brain development. An existing Pb PBPK model was adapted to pregnant women and fetuses. Using data from literature, both the additional maternal bone remodeling, that causes Pb release into the blood, and the Pb placental transfers were estimated by Bayesian inference. Additional maternal bone remodeling was estimated to start at 21.6 weeks. Placental transfers were estimated between 4.6 and 283 L.day−1 at delivery with high interindividual variability. Once calibrated, the p-PBPK model was used to simulate fetal exposure to Pb. Internal fetal exposure greatly varies over the pregnancy with two peaks of Pb levels in blood and brain at the end of the 1st and 3rd trimesters. Sensitivity analysis shows that the fetal blood lead levels are affected by the maternal burden of bone Pb via maternal bone remodeling and by fetal bone formation at different pregnancy stages. Coupling the p-PBPK model with an effect model such as an adverse outcome pathway could help to predict the effects on children's neurodevelopment.

The release of Cd, Cu, Fe, Mn, Ni, Pb, and Zn from clay loam and sandy loam soils under the influence of various organic amendments and low-molecular-weight organic acids

Low-molecular-weight organic acids (LMWOAs) interact with potentially toxic elements (PTEs) and affect their mobility; however, the effect of different amendments on PTEs release from soils when added along with LMWOAs is still unclear. In this study, two soils (a clay loam and a sandy loam) amended with sugar beet bagasse ash (SBBA), poultry manure (PM), sewage sludge (SS) from Kermanshah city (SSK), and SS from Toyserkan city (SST) at a rate of 5 %. In these treatments we studied release of Cd, Cu, Fe, Mn, Ni, Pb, and Zn with citric, oxalic, and malic acids added at 10 different rates each, i.e., 0.1, 1, 2.5, 5, 10, 30, 40, 50, 70, and 100 mmol L−1. We found that the percentage of PTEs release was higher for citric, followed by oxalic and malic acids. The highest amount of PTEs released in both soils decreased in the following order: SST > SBBA > SSK > PM. The percentage of PTEs complexed with LMWOAs and the log activity of PTEs species mostly increased with decreasing pH. It could be concluded that the application of PM is more environmentally friendly than that of the other amendments. Since Cd had the highest percentage of release in all treated soils and LMWOAs, more consideration should be given to Cd to prevent environmental pollution.

Analysis on the Distribution Characteristics and Influence Mechanism of Migration and Transformation of Heavy Metals in Mining Wasteland

In order to explore the distribution characteristics and the influence mechanism of migration and transformation of heavy metals in mining wasteland, soil and tailings samples were collected from the mining wasteland in the Dabaoshan Mining area, Guangdong Province, and the morphological characteristics of heavy metals were analyzed. At the same time, the pollution sources of the mining area were analyzed using Pb stable isotope analysis, and the characteristics and influencing factors of heavy metal migration and transformation in the mining area were expounded by combining X-ray diffraction analysis, transmission electron microscope-energy spectrum analysis (TEM-EDS), and Raman analysis of typical minerals in the mining area, as well as laboratory-simulated leaching experiments. Morphological analysis showed that the forms of Cd, Pb, and As in the soil and tailings samples in the mining area were mainly the residual phase, accounting for 85%-95% of the total, followed by the iron and manganese oxide-bound form (1%-15%). The main mineral types in the soil and tailings in the Dabaoshan Mining area were pyrite (FeS2), chalcopyrite (CuFeS2), and metal oxides, as well as a small amount of sphalerite (ZnS) and galena (PbS). Acidic conditions (pH=3.0) were beneficial to the release and migration of Cd and Pb from soil, tailings, and minerals (pyrite, chalcopyrite) and from the residual phase to the non-residual phase. Lead isotope analysis showed that the lead in the soil and tailings mainly came from the release of metal minerals in the mining area, and the contribution of diesel in the mining area was less than 30%. Multivariate statistical analysis showed that Pyrite, Chalcopyrite, Sphalerite, and Metal oxide were the main sources of heavy metals in the soil and tailings in the mining area, in which Cd, As, and Pb were mainly contributed by sphalerite and metal oxide. The form change in heavy metals in the mining wasteland was easily affected by environmental factors. The form characteristics and migration and transformation factors of heavy metals should be considered in the source control of heavy metal pollution in mining wasteland.

Microwave-Assisted Digestion of Polyurethane Foam as an Alternative to Elution: Solid Phase Extraction of Cd(II) and Pb(II) for Their Determination in Swimming Pool Waters.

In this work, a separation/preconcentration method is proposed for the determination of Cd(II) and Pb(II) in swimming pool waters, using ammonium pyrrolidine dithiocarbamate (APDC) as a complexing agent and unloaded polyurethane foam (PUF) as a sorbent. The proposed method was optimized, and the defined optimal conditions were a pH of 7, 30 min of shaking time, 400 mg of PUF, and 0.5% (m/v) of the APDC solution. The release of Cd(II) and Pb(II) from the solid phase was achieved through the total digestion of PUF using a microwave-assisted acid approach with a 10.5 mol·L-1 HNO3 solution. The methodology was applied to four samples of swimming pool water for the determination of Cd(II) and Pb(II) using graphite furnace atomic absorption spectrometry (GF AAS). The limits of detection and quantification obtained were 0.02 and 0.06 μg·L-1 for Cd(II) and 0.5 e 1.8 μg·L-1 for Pb(II), respectively. We analyzed four samples of swimming pool waters, finding Cd concentrations between 0.22 and 1.37 μg·L-1. On the other hand, only one sample presented Pb concentration above the limit of quantification (11.4 μg·L-1). Recovery tests were performed by spiking the samples with known concentrations of the analytes, and recovery percentages between 82% and 105% were obtained.

Geochemical fractionation and potential release behaviour of heavy metals in lead‒zinc smelting soils

The lack of understanding of heavy metal speciation and solubility control mechanisms in smelting soils limits the effective pollution control. In this study smelting soils were investigated by an advanced mineralogical analysis (AMICS), leaching tests and thermodynamic modelling. The aims were to identify the partitioning and release behaviour of Pb, Zn, Cd and As. The integration of multiple techniques was necessary and displayed coherent results. In addition to the residual fraction, Pb and Zn were predominantly associated with reducible fractions, and As primarily existed as the crystalline iron oxide-bound fractions. AMICS quantitative analysis further confirmed that Fe oxyhydroxides were the common dominant phase for As, Cd, Pb and Zn. In addition, a metal arsenate (paulmooreite) was an important mineral host for Pb and As. The pH-stat leaching indicted that the release of Pb, Zn and Cd increased towards low pH values while release of As increased towards high pH values. The separate leaching schemes were associated with the geochemical behaviour under the control of minerals and were confirmed by thermodynamic modelling. PHREEQC calculations suggested that the formation of arsenate minerals (schultenite, mimetite and koritnigite) and the binding to Fe oxyhydroxides synchronously controlled the release of Pb, Zn, Cd and As. Our results emphasized the governing role of Fe oxyhydroxides and secondary insoluble minerals in natural attenuation of heavy metals, which provides a novelty strategy for the stabilization of multi-metals in smelting sites.

Effect and mechanism of biochar as a support on immobilization of different heavy metals by iron oxides in a multi-contaminated soil

The effect and mechanism of biochar as a support on immobilization of different heavy metals (HMs) by iron oxides (FexOy) were still poorly understood. Herein, biochar-supported zero-valent iron (ZVI/BC) was fabricated via the simple one-step thermal reduction approach and applied to a soil multi-contaminated with cadmium (Cd), zinc (Zn), and lead (Pb) for 60-d. Results showed that individual pyrogenic FexOy effectively immobilized Cd but facilitated the release of Pb and Zn in soils. Biochar as a support compromised the immobilization of Cd by FexOy, possibly ascribing to cationic competition effect. ZVI/BC can synergistically immobilize Zn and Pb with the immobilization effectiveness of 33.7 % and 11.9 %, respectively owing to the dispersion effect of BC on ZVI. ZVI/BC addition increased soil pH, but soil pH increase can be not the key factor for the immobilization of HMs in soils. Moreover, biochar increased the diversity of soil bacteria community, but pyrogenic FexOy significantly lowered it. Further, ZVI/BC supplementation significantly stimulated the relative abundances of Fe(Ⅲ)-reducing bacteria (e.g., Geobacter and Acinetobacter) and sulfate-reducing bacteria (e.g., Desulfosporosinus and Desulfurispora) in soils, boosting the microbial reduction of Fe(Ⅲ) minerals and increasing the HCl-extractable Fe(Ⅱ) concentration. The adsorption/co-precipitation of secondary Fe minerals and formation of metal sulfide precipitates could play an important role in immobilization of HMs in soils. Overall, the present study highlighted the coupling of biotic and abiotic processes for stabilization remediation of HMs multi-contaminated soils by ZVI/BC.

Immobilization of Pb and Zn leached from mining residue materials in Kabwe, Zambia: Performance of calcined dolomite in column experiments

Legacy Pb-Zn mine in Kabwe, Zambia, has left massive stockpiles of mining residue materials (MRM) that contain potentially toxic elements, such as lead (Pb) and zinc (Zn), which pollute the environment. In situ remediation of the contaminated area is an attractive technique for immobilizing hazardous metals. In this study, the efficacy of modified dolomite, i.e., calcined dolomite (CD), was evaluated by mixing with the MRM at 1, 5, and 10 % ratios (CD1, CD5, and CD10, respectively). The leaching of hazardous metals, Pb and Zn, from the MRM was assessed by four-column experiments. Measurements of mineralogical and chemical constituents of the MRM, sequential extraction, and thermodynamic modeling of the leachates were carried out to determine the attenuation mechanisms. Sequential extraction results indicated that the leachable Pb and Zn in the MRM were mainly from the exchangeable and carbonate fractions. Furthermore, the results showed that the effluents from the column with MRM (CD0) exceeded the Zambian effluent regulatory values throughout 30 weeks of the experimental period. The introduction of the CD into the MRM increased effluent pH and decreased the leaching concentrations of Pb and Zn. The CD5 was enough to decrease the leaching concentrations of both hazardous metals below the Zambian effluent standard by prohibiting the release of Pb and Zn via the dissolution of carbonate minerals and retaining them in the carbonate fraction. The saturation indices of Pb and Zn suggest that the retention mechanisms by the CD accredit to precipitation, co-precipitation, and adsorption reactions. These results present an effective and inexpensive immobilization technology for hazardous wastes in abandoned mines.

The accumulation and release characteristics of heavy metals on the cultivation environment in Gracilaria litters during decay process

Gracilaria bioremediates heavy metals (Cd, Cr, Pb, Ni, Cu, Zn, Fe, and Mn) and improves water quality in mariculture zones. However, Gracilaria litter produced during the growth and harvest process has become a critical bottleneck problem that limits the sustainable development of the Gracilaria cultivation industry. Experiments of decaying dried (dead) and frozen fresh (falling and dying) G. lemaneiformis and G. lichenosdies were carried out using the litterbag technique under laboratory-controlled and in situ conditions. The results showed that decay rates (k), decomposed time in 50 % (t50) and in 95 % (t95) varied between dried and frozen fresh Gracilaria and were different between G. lemaneiformis and G. lichenosdies. All Gracilaria samples showed an 80 %–90 % weight loss in 15–45 d. The variation in MAIs (accumulation index of metals) between the dried and frozen fresh Gracilaria litters differed significantly and provided evidence that metals could be imported or exported from litter to the environment. Based on our estimates from the 15–45 d experiment, the decay of Gracilaria can release and adsorb heavy metals. The enrichment of Fe, Pb, and Mn was more significant than the release, but the release of Cr, Zn, Cd, Pb, Cu, and Ni was more significant than the enrichment. Heavy metals in Gracilaria litters were accumulated and released simultaneously during decay. The present study simulated and underscores that Gracilaria cultivation intensely influences heavy metals recycled in marine environments It provides a theoretical basis for seaweed management for the sustainable development of the seaweed industry in the mariculture zone.

P/Pb transport at the interface of water and Al-substituted ferrihydrite: Effect of P/Pb loading sequence

Sediment mineral such as Al-substituted ferrihydrite plays a critical role for contaminant transport in the river systems. Heavy metals and nutrient pollutants often coexisted in the natural aquatic environment, and they may enter the river at different time frames, altering the fate and transport of each other subsequently discharged into the river. However, most studies focused on the simultaneous adsorption of co-existing pollutants instead of their loading sequence. In this study, the transport of P and Pb at the interface of Al-substituted ferrihydrite and water was investigated under different P and Pb loading sequences. The results showed that preloaded P provided additional adsorption sites for the following adsorption of Pb, with enhanced Pb adsorption amount and accelerated adsorption process. Moreover, Pb preferred to be bounded with the preloaded P to form P–O–Pb ternary complexes rather than directly reacted with Fe–OH. The formation of the ternary complexes effectively prevented the release of Pb once adsorbed. However, the adsorption of P was slightly affected by the preloaded Pb, and most of the P were adsorbed onto Al-substituted ferrihydrite directly with the formation of Fe/Al–O–P. Moreover, the release process of the preloaded Pb was significantly inhibited by the following adsorbed P due to the formation of Pb–O–P. Meanwhile, the release of P was not detected from all P and Pb loaded samples of different adding sequence due to the high affinity between P and the mineral. Thus, the transport of Pb at the interface of Al-substituted ferrihydrite was seriously influenced by the adding sequence of Pb and P, while the transport of P was not sensitive to the adding sequence. The results provided important information for the transport of heavy metal and nutrients in river system with different discharging sequence, and offered new insights to further understand the secondary pollution in multi-contaminated river.

Insights into Health Risks of Face Paint Application to Opera Performers: The Release of Heavy Metals and Stage-Light-Induced Production of Reactive Oxygen Species.

Face paints used by opera performers have been shown to contain high levels of heavy metals. However, whether frequent exposure, via dermal contact and inadvertent oral ingestion, results in occupational diseases is unknown, as is the potential exacerbation of toxicity by high-intensity irradiation from stage lights. In this study, we examined the release of Cr, Cu, Pb, and Zn from 40 face paints and the consequent health risks posed by different practical scenarios involving their use. The results showed that the in vitro bioaccessibility (IVBA) of Cr, Cu, Pb, and Zn in the tested products was, on average, 7.0, 5.5, 19.9, and 7.9% through oral ingestion and 1.1, 2.2, 1.6, and 1.2% through dermal contact, respectively. Stage light irradiation significantly increased the IVBA associated with dermal contact, to the average of 4.8, 34.9, 5.7, and 1.9% for Cr, Cu, Pb, and Zn, respectively. The increase was mainly due to the light-induced generation of reactive oxygen species, particularly hydroxyl free radicals. The vitality and transcriptional response of 3D skin models as well as a quantitative risk assessment of skin sensitization indicated that dermal contact with face paints may induce predictable skin damage and potentially other skin diseases. Long-term exposure to face paints on stage may also pose a non-carcinogenic health risk. The demonstrated health risks to opera performers of face paint exposure should lead to strict regulations regarding the content of theatrical face paints.

Hydrodynamic release of Pb, Zn, and Cd from impermeable tailings as deduced from physical parameters evolution and multivariate statistical analysis: case study of Jbel Ressas mine waste (North Tunisia)

Tailings are one of the largest pollutant sources in the world. The wind and water leaching were often considered the main distribution tool of their pollutants. However, the carbonate crust precipitation has negated the trace toxic element (TTE) release. To identify the release mode of Pb, Zn, and Cd from mine wastes, the hydrodynamic evolution of waste piles was considered. The macroscopic and microscopic observation, the grain sizes, cohesion particles, density, hydraulic conductivity, and Pb, Zn, and Cd concentrations performed from eight drill cores of the two waste dumps and the principal component and the hierarchical cluster analysis showed that the physical properties of waste piles closely controlled the TTE mobility and migration from the tailings. The obtained data also showed that the upper carbonate layers were first eroded by wind and rainfall. Then, the formation of an impermeable carbonate crust limited the Pb, Zn, and Cd releases. However, the hydrodynamic evolution of the underneath layers was different. As the high pile waste sediments' weight meaning the lithostatic pressure (Pl), the geostatic ratios (λ = Pf/Pl) were in DII and DIII dumps superior to 0.29 and 0.26, respectively. Therefore, the overpressured fluids increased the mineral dissolution, including the sulfides and carbonates of metals, and hydraulic fracturing that raised the percentages of the mobile TTE and migration indexes. By the secondary pore and fracture volumes, the polluted fluids were progressively channeled towards the underpressured marge (dumps edge) by repetitive (polyphase) fluid pulsations.

Development of a rapid and efficient analytical method for trace lead determination: Manganese dioxide nanoflower based dispersive solid-phase extraction

Lead (Pb) is a heavy metal that is highly toxic and a major environmental pollutant. Anthropogenic activities are the main sources of Pb release into the air, water and food, from which humans and other organisms become exposed. In this study, a suitable, rapid, and environmental friendly dispersive solid phase extraction procedure based on manganese dioxide nanoflower (MnO 2 NF-DSPE) was developed for the effective enrichment of Pb coupled with flame atomic absorption spectrometry (FAAS). Under the optimal experimental conditions, limit of detection (LOD), quantification (LOQ) values and enhancement in detection power (EDP) obtained for the MnO 2 NFs-DSPE-FAAS system were calculated as 6.1 µg/L, 20.3 µg/L and 44, respectively. Three different ginger tea samples were used in recovery studies to investigate the applicability/accuracy of the proposed method. Matrix matching calibration strategy was performed in recovery studies and percentage recoveries were calculated between 106 and 122% with low standard deviation values. • Trace level lead was preconcentrated by DSPE prior to FAAS measurement. • MnO 2 nanoflowers were used as adsorbent in the extraction procedure. • LOD and LOQ for ginger tea matrix were 6.09 µg/L and 20.29 µg/L, respectively. • The detection limit for conventional FAAS system was improved by about 43.7 folds. • Recovery results for the prepared ginger tea were found in the range of 106.1–121.5%.

Elevated CO2 may increase the health risks of consuming leafy vegetables cultivated in flooded soils contaminated with Cd and Pb.

Elevated CO2 levels threat the crop quality by altering the environmental behavior of heavy metals (HMs) in soils. In reality, multiple HMs often co-exist in field, while details regarding coexisting HMs migration in flooded soil at elevated CO2 levels remain unclear. A pot experiment in open-top chambers (CO2 at 400 and 600μmolmol-1) was conducted to explore the uptake and transfer of cadmium (Cd) and lead (Pb) in water dropwort (Oenanthe javanica DC.) grown in flooded soils contaminated with Cd and Pb. Results showed that elevated CO2 significantly reduced soil pH, promoting the release of Cd and Pb (by 63.64-106.90% and 10.66-30.99%, respectively) into soil porewater. In the harvested O. javanica, elevated CO2 decreased the root uptake of Cd but promoted that of Pb. Further mechanism analysis showed that elevated CO2 promoted the formation of iron plaque on root surface by 44.60-139.57%, with lower adsorption capacity to HMs (0-34.93% and 63.61-67.69% for Cd and Pb, respectively). Meanwhile, Pb showed lower adsorbability in iron plaque but higher transfer capacity when compared with Cd. Ultimately, elevated CO2 increased the target hazard quotient values of Pb in O. javanica. These findings provide new insights on the effects of elevated CO2 on the transfer of coexisting HMs in soil-plant system, and the risk of HMs pollution under climate changes needs to be more fully assessed.

A Sustainable Approach towards the Restoration of Lead-Contaminated Soils through Nutrient-Doped Olive Waste-Derived Biochar Application

The current study was conducted to investigate the efficiency of olive mill waste-derived biochar and its silica-embedded and nutrient-loaded derivatives in immobilizing lead (Pb) and improving nutrients availability in contaminated sandy loam soils. Biochar was produced at 500 °C and latterly modified with silica and enriched with nutrients (P and N). An incubation experiment was conducted for a period of 45 days to observe the dynamics in heavy metals and nutrient release. The produced biochar and its modified versions were characterized for physiochemical and structural properties prior to soil application. The results of incubation trials demonstrated that pseudo second-order kinetic model was fitted best to Pb, P, NO3− and NH4+ release characteristics. Silica embedded and nutrient loaded biochars performed outclass and showed up to 85% decline in Pb release against control treatment. Similarly, 38%, 69% and 59% increase in P, NO3− and NH4+ availability, respectively, was observed with modified biochars, as compared to 22%, 59% and 32% increase with pristine biochar application, respectively. Overall, silica and nutrient doping of biochar resulted in significantly higher immobilization of Pb in contaminated soil and increased the nutrient availability, which could be helpful in restoring heavy metal contaminated soil and improving soil fertility.

Enhanced immobility of Pb(II) during ferrihydrite-Pb(II) coprecipitates aging impacted by malic acid or phosphate.

Metastable ferrihydrite is omnipresent in environments and can influence the fate of Pb(II) during ferrihydrite transformation. Ferrihydrite is rarely pure and often coexists with impurities, which may influence the mineralogical changes of ferrihydrite and Pb(II) behavior. In this work, we investigated the effect of malic acid or phosphate on Pb(II)-ferrihydrite coprecipitates (Fh-Pb) transformation and the subsequent fate of Pb(II) during the 10-day aging of Fh-Pb. Results showed that both malic acid and phosphate retarded Fh-Pb transformation and prevented the release of Pb(II) from Fh-Pb back into solutions. Pb(II) was beneficial to goethite formation by inhibiting hematite formation while both malic acid and phosphate inhibited goethite formation since they could act as templates of nucleation. Besides, malic acid and phosphate improved the proportion of non-extracted Pb(II) during Fh-Pb transformation, indicating that Pb(II) was incorporated into secondary minerals. Pb(II) could not replace Fe(III) within the crystal lattice due to its large radius but was occluded into pores and defect structures within the secondary mineral lattices. This work can advance our understanding of the influences of malic acid and phosphate on Pb(II) immobility during Fh-Pb aging.

Process analysis of Pb transformation in the coal devolatilization stage

The transformation of Pb during coal devolatilization affects its emission characteristics. Herein, devolatilization experiments were conducted at 1100–1300 °C in a fixed-bed experimental system using four types of coal samples. The occurrences of Pb in coal and devolatilization products were characterized. The release ratio of Pb first increased and then stabilized with time. The Pb release ratio and rate were higher at higher temperatures. Pb in some coal samples was completely released at 1100 °C. Pb in coal was mainly in carbonate- and oxide-bound, sulfide-bound, and residual forms. During devolatilization, carbonate-, oxide-, and sulfide-bound Pb gradually disappeared. Organic-bound and residual Pb first increased and then decreased owing to the conversion of gaseous Pb into Char-Pb by char, according to further form analysis of residual Pb and the experiments of char retaining PbCl2 and PbO. The effects of different volatile components on residual Pb were compared, and H2S was found to significantly promote the release of residual Pb in coal. The transformation paths of Pb during coal devolatilization were proposed, including the release of original Pb in coal and the reversible conversion between gaseous Pb and Char-Pb. The results help understanding Pb emission and developing control techniques for coal-fired plants.

Investigation of health and ecological risk attributed to the soil heavy metals in Iran: Systematic review and meta-analysis.

The presence of heavy metals (HMs) in the soil can pose risks to human health via ingestion and dermal absorption. This systematic review and meta-analysis study focused on both of health and ecological risks attributed to the six HMs (As, Cd, Cr, Cu, Pb, Zn) in the soil of different Provinces of Iran. Articles were selected in the Web of Science and Scopus from 2000 to August 2021. The study was carried out according to Preferred Reporting Items for Systematic reviews and Meta-Analyses (PRISMA) guideline. Based on the inclusion and exclusion criteria, finally 32 studies were reviewed which the ranking of mean concentrations of the studied metals followed as: As > Zn > Cr > Pb > Cu > Cd. Mean concentration of Cd and As calculated via meta-analysis in the studied Provinces was found to be more than Iran's environment protection agency (EPA) guideline values. Other HMs met guideline values. A significant non-carcinogenic risk attributed to the As found in Kurdistan Province (hazard index, HI > 1). Furthermore, a significant carcinogenic health risk was found in Kurdistan and West Azerbaijan associated to As and in Fars, Khozestan and Khorasan-e-Razavi Provinces associated to Cd (ELCR >10-4). Concerning the impact on the ecosystem, Cd, As and Pb caused ecological risks in some areas of Iran (ecological risk, ER > 40 and potential ecological risk, PER >150). Hence, we can conclude that Cd and As are important heavy metals from the health aspect. Moreover, Cd, As and Pb must be considered from an ecological point of view. Therefore, control of the Cd, As and Pb release in the environment and remediation of polluted sites through novel approaches is recommended.

Distribution, chemical fractionation, and potential environmental risks of Hg, Cr, Cd, Pb, and As in wastes from ultra-low emission coal-fired industrial boilers in China

This study conducted a comprehensive investigation of the distribution, chemical fractionation, and potential environmental risks of Hg, Cd, Cr, Pb, and As in waste based on new data from five ultra-low emission (ULE) coal-fired industrial boilers (CFIBs). The results showed that fly ash was enriched with Cd, Pb, As, and Hg, while its Cr contents were not invariably higher than those of slag. Fly ash was the predominant output flow for Hg, Cd, Cr, Pb, and As in the tested ULE boilers, with higher proportions of HTEs in the fly ash and lower proportions of HTEs in the flue gas than in the non-ULE boilers. The average proportions of residual Hg, Cd, Cr, Pb, and As in wastes revealed the following order: slag > fly ash > flue gas desulfurization (FGD) by-products. The potential environmental risks of Hg, Cd, Cr, Pb, and As in the fly ash, slag, and FGD by-products of CFIBs at the county level in the Beijing-Tianjin-Hebei Air Pollution Transmission Channel Cities (“2 +26 cities”) region showed spatial heterogeneity. It is predicted that the potential release of Pb, Cr, and Cd in the fly ash would increase and that of the FGD by-products would decrease after the implementation of the ULE retrofitting of all CFIBs.

Sensitive and Environmentally Friendly Field Analysis of Waterborne Arsenic by Electrochemical Hydride Generation Microplasma Optical Emission Spectrometry.

To avoid polluting the environment, it is desirable to develop methods consuming as few chemicals as possible for field elemental analysis. In this work, a lithium-ion battery supplied, compact handheld optical emission spectrometer (OES) (0.3 kg, length 18 cm × width 5 cm × height 10 cm) was fabricated for the sensitive field analysis of waterborne arsenic by utilizing electrochemical hydride generation (ECHG) and miniaturized ballpoint discharge (μPD) as sample introduction means and excitation source, respectively. The high ECHG efficiency of arsenic was obtained using a superior cathode of Fe@PbO/Pb and the generated arsine was separated from an aqueous phase and further swept to the μPD microplasma for detection. It is worth noting that the Fe@PbO/Pb cathode not only retains advantages of large specific surface area, robust stability, and excellent reproducibility for the ECHG of arsenic but also accomplishes the preconcentration of As(III), thus improving the kinetics of the surface chemistry at the cathode, alleviating the corrosion of the electrode, and minimizing the release of Pb. A limit of detection of 1.0 μg L-1 was obtained with a relative standard deviation of 4.2% for 20 μg L-1 As(III). Owing to the advantages of ECHG and μPD-OES, the system retains a promising potential for the sensitive, cost-effective, and environmentally friendly field analysis of waterborne arsenic.