Passage Of Water Research Articles

ADJUSTMENT OF THE ELEMENTS OF THE FLOW PART OF THE HIGH-EFFICIENCY OF PUMP- TURBINE

The problem of the development of pumped storage power plants in Ukraine is considered, especially in the conditions of military operations, which damaged the energy infrastructure and created capacity shortage. The pumped storage power plants will help stabilize the power system by storing energy during periods of low load and efficiently using it during peak needs or accidents. All this has a positive impact on the role of energy autonomy and the integration of renewable energy sources. Efficiency increase of the hydro-turbine equipment of the PSPP requires the improvement of the water passage of the reversible hydraulic machines. This work shows that the creation of high-efficiency reversible hydraulic equipment depends on the correct selection of the geometry of the pater passage elements of the reversible hydraulic machines, consequently ensure the necessary level of energy characteristics of the hydraulic equipment. The equation of the optimal mode was used for the calculated assessment of kinematic and energy characteristics, analysis of their formation and search for rational variants that provide the specified requirements for the runner energy characteristics of the reversible hydraulic machines. Calculations are carried out using dimensionless kinematic parameters, which simplifies the process and eliminates the need for complex calculations. The numerical analysis data on the influence of the hydrodynamic parameters of the water passage on the parameters of the optimal mode can be used both for profiling the blade system of the runner, with the aim of improving energy characteristics (increasing power, efficiency level, etc.), and for modifying the blade system. The numerical study method for finding optimal variants of the runner blade system is given. The proposed approach was used to estimate the kinematic and energy characteristics of water passages of Francis turbines, as well as high-head reversible hydraulic machines ОRО200 and ОRО500 (both for basic and modified variants of the water passage).

Heterogeneous long-term and seasonal brine evolution, and Artemia fecal pellet controls on Urmia Lake (NW Iran) salt-crust formation and mineralogy

ABSTRACT Urmia Lake resides as a substantial hypersaline lake characterized by notable fluctuations in water salinity, brine composition, and water level over long-term, annual, and seasonal intervals. Extremely rapid water elevation fall (> 7 m) in the last three decades has caused the formation of a salt crust on the lake floor. A manmade stone causeway divided the lake into two relatively deeper northern parts with minimal water inputs and a shallower southern part with maximal river inflows. Restricted water flow through the narrow water passage of the causeway leads to complex salinity processes, brine evolution, and salt-crust formation in Urmia Lake. This research analyzes the ionic composition of lake-sediment and salt-crust pore water, the mineralogy of salt crusts, and the ionic composition of both surface and deep lake waters during both the wet and dry seasons of 2019. The findings indicate that the northern and southern parts of the lake undergo stratification during wet seasons due to significant freshwater input, whereas they become homogenized during dry seasons through progressive evaporative concentration and water mixing. The spatial and temporal variations in the lake brine type (primary Na-Mg-Cl) and ionic composition contribute to the formation of a halite salt crust (NaCl > 97%) with heterogeneous mineralogy and thickness. In Urmia Lake, the variable thickness and mineralogy of the exposed marginal salt crust suggest rapid salt-crust reorganization by annual and seasonal deposition and dissolution processes. Conversely, the submerged central salt crust, with continuous thickening and constant mineralogy, remains unaffected by seasonal variations in brine type and dissolution processes. It is noteworthy to mention that Artemia (a brine shrimp) controls the mineralogy of the lake salt crust through the deposition of calcium and carbonate ions in the form of biochemical fecal pellets.

Enhancing urban sustainability: a study on lightweight and pervious concrete incorporating recycled plastic

Increasing of plastic waste threatening ecosystems globally, this experimental work investigates recycled plastics as sustainable aggregate replacements in pervious concrete. Pervious concrete allows water passage but has installation/maintenance difficulty due to high weight. This research addresses the lack of eco-friendly lightweight pervious solutions by assessing physical and mechanical performance of mixes with 100% recycled plastic and traditional aggregate percentages. Density reduced 12% using a 100% plastic aggregate mix, achieving 1358 kg/m3 with compressive strength of 3.92 MPa, adequate for non-structural applications. A 7.8% decrease in water absorption versus conventional pervious concrete signifies retained porosity and permeability despite the plastic aggregates. Though early material limitations increase costs over 199.32%, recycled plastics show viability as effective, sustainable substitutes for natural aggregates in lightweight pervious concrete. With further availability and affordability improvements, these recyclable mixes can enable significantly greener construction practices. Findings provide key insights on balancing structural requirements, eco-friendliness and water infiltration capacity in plastic-based lightweight pervious concrete for broader adoption. The research examines the mechanical and durability characteristics of Light-Weight Pervious Concrete (LWPC) composed entirely of plastic aggregate. It also investigates the economic viability and potential for sustainable urban applications. The cost assessment reveals long-term environmental advantages, even though the initial expenses are higher. Additionally, the study considers an eco-friendly approach that combines plant growth with pervious concrete to promote greater sustainability.

Driving force shapes the biocake characteristics in membrane-based bioreactors

The operation of membrane-based reactors is inevitably challenged by fouling. The driving force in these reactors is not only critical for water passage through membranes but also significantly influences fouling, such as biocake formation. This study investigated the differences between biocakes formed under transmembrane pressure (TMP) and forward osmosis (FO) conditions, specifically focusing on their components, spatial structures, and microbial communities. The findings reveal that the MF-biocake, formed under TMP conditions, contained a greater diversity of foulants, microbes, and metabolic products compared to the FO-biocake. Clustering and correlation analyses indicated that MF-biocake formation was predominantly influenced by dead cells, extracellular polymeric substances, and physicochemical parameters, whereas FO-biocake formation was mainly affected by live cells and adhesion forces. Particle image velocimetry tests further highlighted nonselective foulant adsorption in MF-biocake formation versus selective adhesion in FO-biocake formation. These insights enhance our understanding of the distinct characteristics of biocakes formed under TMP- and FO-driven conditions, aiding in the development of more targeted strategies to control biocake formation based on the driving forces.

Paracellular barriers: Advances in assessing their contribution to renal epithelial function

Regulation of salt and water balance occupies a dominant role in the physiology of many animals and often relies on the function of the renal system. In the mammalian kidney, epithelial ion and water transport requires high degree of coordination between the transcellular and paracellular pathways, the latter being defined by the intercellular tight junctions (TJs). TJs seal the paracellular pathway in a highly specialized manner, either by forming a barrier against the passage of solutes and/or water or by allowing the passage of ions and/or water through them. This functional TJ plasticity is now known to be provided by the members of the claudin family of tetraspan proteins. Unlike mammalian nephron, the renal structures of insects, the Malpighian tubules, lack TJs and instead have smooth septate junctions (sSJs) as paracellular barrier forming junctions. Many questions regarding the molecular and functional properties of sSJs remain open but research on model species have begun to inform our understanding. The goal of this commentary is to highlight key concepts and most recent findings that have emerged from the molecular and functional dissection of paracellular barriers in the mammalian and insect renal epithelia.

Highly sensitive and chemically resistant moisture sensor based on polyether sulfone and polyimide composite membrane for power transformer oil

Abstract Moisture is the primary factor leading to the deterioration of transformer oil. Real-time detection of transformer oil moisture content holds significant importance to help power companies monitor the transformer’s operational status, track the change curve of the oil moisture content, identify water ingress causes, and implement preventive measures. However, transformer oil has the characteristics of low moisture content and complex chemical composition, which pose a substantial challenge for sensor monitoring, and require the prepared sensor to be chemically resistant and highly sensitive to moisture. To address these challenges, in this paper, a parallel plate oil moisture sensor with high sensitivity and high chemical resistance based on PES and PI was developed using the MEMS process. The sensor incorporates PES as the chemical resistance layer and PI as the moisture sensitivity layer. The parallel plate design not only optimizes sensitivity by effectively utilizing electric field lines but also allows the passage of water while isolating oil molecules, further enhancing the chemical resistance of the sensor. Experimental results in air demonstrate that the prototype sensor exhibits high sensitivity (~1.26 pF/% RH) across the full humidity range of 0-100% RH. Moreover, the sensor can withstand exposure to a wide range of chemical corrosive gases, including acetone, ammonia, etc. Tests in transformer oil reveal that the sensor has a resolution better than 200 ppm and can effectively measure moisture in the range of 0-1400 ppm, demonstrating very high sensitivity (4 pF/100 ppm) and rapid response (10/23 s).

Flood sediments as a source of replenishment of alluvial soils with plant nutrition elements

Flood sedimentation in conditions of regular floodplain flooding is a key factor in the formation of alluvial soil. The nature of the passage of hollow waters and their composition affect the quantitative and qualitative characteristics of flood sediments, while having a significant impact on the agroecological state of the floodplain agricultural landscape. The aim of the research was to study the role of flood sediments in enriching the underlying alluvial soil with nutrients. The experiment was conducted on reclaimed arable lands of the Ryazan region in 2023. Determination of the sediment load level and sampling on the surface were carried out using plastic sedimentation samplers fixed on the soil surface, located at a distance of 200 m from each other. The installation was carried out on March 23, the duration of sediment collection was 42 days before the descent of the hollow waters. The average sediment load level of 15.4 t/ha was established, the agrochemical properties of flood sediments and underlying soil were studied, the structure of organic matter, macro– and microelements with flood sediments and their removal from the corn harvest to silage was analyzed. Together with sediments the soil received (kg/ha): total nitrogen – 107.80, total phosphorus – 43.10, total potassium – 104.70, organic matter – 2464,0, mobile phosphorus 15.20, exchangeable potassium 17.80; trace elements (g/ha): boron – 11.86, molybdenum – 1.54, zinc – 122.74, manganese – 1215.06, copper – 200.20, cobalt – 52.05. With a corn harvest for silage of 36.1 kg/ha, the takeaway was: N – 105 kg/ha, P2O5 – 33 kg/ha, K2O – 105 kg/ha. The conducted studies indicate the undoubted agronomic value of flood sediments, they can partially meet the need for fertilizers, therefore, it is necessary to take into account the mass of the substances used to carry out appropriate adjustments to the fertilizer application system. In 2023, the mass of incoming substances with flood sediments completely covered the need for nitrogen; for mobile phosphorus the need decreased to 17.8 kg/ha, for exchangeable potassium the need decreased to 87.2 kg/ha.

Diffusion mechanism of fracture grouting in rock mass with flowing water

Grouting is a widely used geotechnical procedure known for its strong empirical properties. It has been extensively utilized for sealing subterranean water and strengthening soil and rock masses in their original locations in underground mining and underground space development. The diffusion mechanism of grouting in fractured rock is affected by the geological environment and slurry performance, which should be better revealed and characterized. In this paper, we take the surrounding rock of the roadway as the research object, consider the stress condition of the injected rock and time-dependent viscosity of the slurry, and establish fracture grouting diffusion model based on the rock composite fracture criterion. The grout strengthening mechanism is discussed based on a transparent fracture replica grouting test. According to the different transport characteristics of the slurry interacting with flowing water, it is divided into the following four areas grout-water balance area, grout loss area, stagnation area and water passage. The grout plugging mode is divided into two categories according to its final diffusion pattern: cross-section type water plugging mode and water-drop plugging mode. The pressure monitoring data of the test verified the two grout plugging modes. The diffusion distance of cis-reverse water derived in this study was in good agreement with the experimental results in grouting early stage. The research results can provide a theoretical basis for grouting engineering design.

Cement based nanofiltration membrane of porous boron nitride and graphene oxide for effective oil/water separation

The development of effective filters for crude oil/water separation presents a critical environmental challenge in the face of oil spills. Porous membrane separation stands as a vital technique for removing organic solvents, oils, and dyes from water. In this study, we designed and fabricated a nanofiltration membrane composed of graphene oxide (GO) and boron nitride (BN) incorporated into a cement-based matrix to enhance the selectivity and efficiency of unidirectional flux transportation. The integration of GO, with its rich functional groups, and BN, known for its hydrophobic properties, within the cement matrix, resulted in an improved water permeation rate. Moreover, the inclusion of BN flakes in the cement matrix significantly enhances its mechanical strength, reaching up to 15.93 MPa (∼35 % greater than pristine cement), establishing it as a robust nanofiltration membrane for simultaneous flux enhancement and water purification. This innovative filter demonstrated remarkable separation efficiency, achieving up to 99 % oil removal while allowing the passage of water. To gain a deeper understanding of our experimental findings, we conducted ab initio investigations into the adsorption behavior of water and oil components, including ethanethiol, thiophene, and toluene molecules, on h-BN, GO, and their defective structures (Stone-Wales defect). Our results affirm that porous h-BN and GO nanosheets, characterized by their high specific surface areas, exhibit remarkable sorption capabilities. This nanoengineered membrane showcases substantial adsorption capacity alongside physisorption characteristics suitable for recycling, thereby holding significant potential for the development of functional porous structural materials in the realm of high-performance, cost-effective, and environmentally sustainable water treatment solutions.

Numerical research on disastrous mechanism of seepage instability of karst collapse column considering variable mass effect

In order to reveal the disastrous mechanism of seepage instability of karst collapse column considering variable mass effect, a variable mass fluid–solid coupling mechanical model of water inrush is established, by considering the random distribution characteristics of a collapse column. Taking Qianjin coal mine as the research background, based on the Weibull distribution theory, the heterogeneous distribution characteristics of rock mass is described, and COMSOL Multiphysics numerical simulation software is employed to simulate the seepage characteristics and inrush water changes in collapse columns under different conditions of homogeneity, water pressure, and initial porosity. The research results show that the greater the homogeneity is, the more water conduction channels are formed, and the porosity increases accordingly, when considering the influence of different homogeneity on the seepage characteristics of broken rock mass, which eventually leads to water inrush accidents and a sharp increase in water inflow. Besides, when studying the seepage evolution law of different water pressures on a broken rock mass, an elevation of water pressure dramatically increases the porosity and seepage rate of the water. Over time, the broken rock particles gradually migrate and the fine particles are transported and eroded by the water flow, resulting in changes in the seepage characteristics and the formation of potential water diversion channels. Finally, when taking into account the effect of different initial porosity on the fractured rock mass seepage characteristics, the greater the original porosity is, the higher the seepage velocity is, and the particle migration increases the permeability. This leads to a more pronounced conductive water passage formation, which reveals the disastrous mechanism of seepage instability of karst collapse column considering variable mass effect.

Properties and Microstructure of a Cement-Based Capillary Crystalline Waterproofing Grouting Material

Cement grout is traditionally used for treating water leakage distress in tunnels. However, traditional cement grout has the disadvantages of a poor anti-seepage performance, long setting time, and slow strength gain. To this end, a high-performance cement-based capillary crystalline waterproofing (CCCW) grouting material was synthesized using cement, capillary crystalline material, and several admixtures. The influences of the material proportions on the viscosity, bleeding rate, and setting time of the fresh grout, as well as the permeability coefficient of the grouted aggregate and the unconfined compression strength of the hardened grout material, were systematically studied. The mineralogy and microstructure of the CCCW grouting material were examined using X-ray diffraction, industrial computed tomography, and scanning electron microscopy. The results indicated that the capillary crystalline material PNC803 was not suitable for mixing with bentonite, sodium chloride, and triethanolamine in cementitious slurries, but it can produce excellent synergistic effects with sulfate, calcium chloride, and triisopropanolamine. An analysis of the microstructure of the CCCW grouting material showed that the PNC803 and additives can promote the hydration of cement, which yields more hydration products, sealing water passage and filling micro voids and therefore leading to enhanced waterproofing and strengthening effects. These research results could improve the applicability of CCCW material in tunnel engineering.

Osmoregulatory Challenges Faced by Mosquitoes and Techniques for Studying the Transporters Involved in Their Adaptations.

Mosquitoes are the most important disease vector in the world, and gaining knowledge of their physiology to develop novel population control strategies has been a focus of research for some time. Both aquatic larvae and terrestrial adults face harsh environmental factors that severely challenge their salt and water balance, which are regulated by the function of epithelia of various organs. The regulated passage of water and solutes across epithelia occurs, in part, through transporters expressed in epithelial cell membranes. Identifying these transporters and their localization is necessary to understand how mosquitoes regulate salt and water balance. Here, we review environmental challenges faced by mosquitoes and how they cope with them, in addition to introducing techniques used to identify organ epithelial transporters.

Molecular simulation study of MoSe2 nanochannel for seawater desalination

Reverse osmosis (RO) desalination has become an efficient approach to alleviate the freshwater scarcity, and various two-dimensional (2D) nanomaterials are widely exploited as RO membranes. Due to excellent chemical stability and high flow rate, molybdenum diselenide (MoSe2) has shown great potential in water treatment applications. However, the microscopic understanding of desalination mechanism is still lacking. In this study, by using in silico approach, the high-efficiency desalination performance of layer-stacked MoSe2 nanochannels was investigated. The simulation results reveal that the edge chemical properties and spacing of MoSe2 nanochannels have significant effects on the desalination. Increased spacing can increase the permeability of water but reduces ion rejection. In particular, the permeability through the Mo–Se channel with 8 Å spacing achieves a value of about 3.1 × 10−5 kg m m−2·h−1 bar−1 along with 100 % ion rejection rate, which is several orders of magnitude higher than that of traditional commercial membranes. This indicates that the MoSe2 nanochannels are superior for seawater desalination. In addition, the underlying mechanism of water passage through the MoSe2 channel are investigated by analyzing the potential of mean force, the 2D density of water molecules, and the hydrogen bonding inside the nanochannels during transportation. The results suggest that layer-stacked MoSe2 membrane can be used as a desired RO membrane for efficient seawater purification, which facilitates the design of future filtration membranes.

Heterostructure engineered membranes based on two-dimensional bimetallic MOF for enhanced remediation of dye contaminated wastewater

As a heterogeneous Fenton-like catalyst, two-dimensional (2D) bimetallic MOF can be readily engineered into lamellar membranes which integrate precise separation and Fenton-like degradation to enhance the elimination of organic contaminants from wastewater by rational design of interlayer spacing and constituent units. In this work, a 2D FeNi-MOF is assembled with ultrathin graphitic carbon nitride (g-C3N4) spacers into heterostructure membranes for enhanced remediation of dye contaminated wastewater by synergistic promotion of membrane separation and Fenton-like processes. For the establishment of heterostructure, FeNi-MOF and g-C3N4 nanosheets are alternately arranged by the coordination bonds between bimetallic nodes and pyridinic N to create orderly laminar nanochannels. On the one hand, the heterostructure provides abundant water passages and fixes the membrane interlayer distance to 1.0–1.2 nm with the permeation flux of 47.8–110.1 L·m2·h−1·bar−1. On the other hand, the heterostructure can act as the Fenton-like mediator to expedite the cycle efficiency of Fe(III)/Fe(II) and Ni(II)/Ni(III). The synergistic promotion mechanism of membrane separation and Fenton-like processes is elaborated by simulating the molecular transport peculiarity through membrane nanochannels and the electron transfer efficiency between dual active centers. The contaminant molecules are trapped within the membrane by specific or non-specific channel-guest interaction with heterostructure nanochannels while the steadily generated radicals attack and degrade the confined contaminants, reaching the dye removal rate of approximately 99.0%. Anchoring between adjacent layers and bimetallic cycle reaction in confined fluid confer the stability and recyclability to the heterostructure membrane under wide-range pH and pressures, which are promising for the sustainable treatment of dye contaminated wastewater.

Macro- and Microelements and the Impact of Sub-Mediterranean Downy Oak Forest Communities on Their Composition in Rainwater

In this study, we analyzed the content of chemical elements in rainwater and investigated the influence of forest cover on the composition of precipitation. The results obtained showed that the concentration of some elements in the rainwater collected under the forest canopy was higher than that in the open area. As part of the work, we calculated the enrichment factor and examined the sources of chemical elements in rainwater. We found that all macro-elements had increased values of the enrichment factors compared to the supporting elements of the Earth’s crust. Ca had the highest value. The values of the remaining elements (Sr, Pb, Mn, Cr, Ba, V, Fe) indicated their lithogenic and anthropogenic origins. We noted that the enrichment factor under the forest canopy was significantly lower than in the open area, indicating the dilution of these elements during water passage through the canopy. Elements such as Zn, Co, Cu, and Ni also had high enrichment factors, which indicate their anthropogenic origin. In the open area, most elements had an inverse relationship with pH, except for the alkali metals Na, Mg, and Ca, which had a positive relationship with the pH value. The concentration of K was not dependent on pH. In rainwater that had passed through the forest canopy, the concentrations of Na, Mg, and Ca were also not dependent on pH, while the concentration of K had an inverse relationship with pH. As the concentration of heavy metals in rainwater increases, the role of Na, Mg, and Ca in the process of water neutralization decreases.

Intestinal alterations and mild glucose homeostasis impairments in the offspring born to overweight rats

The gut plays a crucial role in metabolism by regulating the passage of nutrients, water and microbial-derived substances to the portal circulation. Additionally, it produces incretins, such as glucose-insulinotropic releasing peptide (GIP) and glucagon-like derived peptide 1 (GLP1, encoded by gcg gene) in response to nutrient uptake. We aimed to investigate whether offspring from overweight rats develop anomalies in the barrier function and incretin transcription. We observed pro-inflammatory related changes along with a reduction in Claudin-3 levels resulting in increased gut-permeability in fetuses and offspring from overweight rats. Importantly, we found decreased gip mRNA levels in both fetuses and offspring from overweight rats. Differently, gcg mRNA levels were upregulated in fetuses, downregulated in female offspring and unchanged in male offspring from overweight rats. When cultured with high glucose, intestinal explants showed an increase in gip and gcg mRNA levels in control offspring. In contrast, offspring from overweight rats did not exhibit any response in gip mRNA levels. Additionally, while females showed no response, male offspring from overweight rats did exhibit an upregulation in gcg mRNA levels. Furthermore, female and male offspring from overweight rats showed sex-dependent anomalies when orally challenged with a glucose overload, returning to baseline glucose levels after 120 min.These results open new research questions about the role of the adverse maternal metabolic condition in the programming of impairments in glucose homeostasis, enteroendocrine function and gut barrier function in the offspring from overweight mothers and highlight the importance of a perinatal maternal healthy metabolism.

Harnessing plastic waste for sustainable membrane filtration with trimodal structure through acid-catalyzed oxidation

Polyolefin waste is among the most generated yet least recycled. Despite its potential as a feedstock of superhydrophobic membranes for organic solvent filtration, it remains a challenge to achieve high selectivity and permeability for viscous oils. In this study, we valorized polyolefin waste into trimodal water filtration membranes through acid-catalyzed oxidation and a void inducer. This approach enabled the creation of membranes with exceptional wettability and strength, characterized by a combination of micropores, macrovoids (30–70 µm), and cavities (150–200 µm). The acid-catalyzed oxidation introduced oxygen moieties into the membrane structure, resulting in a reduced water contact angle, improved hydrophilicity, and increased permeability. The micropores facilitated capillary action, macrovoids enabled efficient water passage, and cavities acted as oil reservoirs, for optimal oil–water separation. Various membranes were synthesized using low-density and high-density polyethylene (PE), polypropylene (PP), and their blend. The obtained results were compared with commercial membranes, revealing a flow rate of 43 ml/min, a retention capacity of 261 mg, and an oil removal efficiency ranging from 84–94 %. Furthermore, the membranes exhibited recyclability, demonstrating stability over at least 10 cycles. This hybrid process transforms plastic waste into trimodal water filtration membranes, achieving a balance between superoleophilicity and hydrophilicity.

Hydrothermally synthetized WO3 coated stainless steel mesh for oil–water separation purposes

To separate oil–water mixtures especially in oil field operations, new energy-efficient methods are urgently required. Conventional separation techniques using demulsifiers for separation of oil–water mixtures or even use of membranes usually suffered from high cost and energy consumption, composition dependency of demulsifiers and fouling or inability of a single membrane to separate all types of oil–water mixtures. This research aimed to synthesize tungsten oxide-coated stainless steel mesh using the hydrothermal method, with a focus on evaluating its effectiveness in oil–water separation. The coating procedure was carried out using hydrothermal techniques, with an emphasis on investigating the impact of precursor concentration, pH levels, reaction temperature and duration, on the separation efficiency of the optimal coating solution. The hydrothermally coated stainless steel mesh was created within a polytetrafluoroethylene reaction vessel, submerged in a 150 ml aqueous solution containing 0.0094 mol of sodium tungstate di-hydrate at pH 3.0, achieved through the addition of hydrochloric acid. Additionally, 1 g of oxalic acid, acting as a chelating agent, was introduced. Subsequently, the mesh underwent a 4 h reaction at 220 °C and was subsequently annealed for 30 min in a 350 °C furnace. Remarkably, the resultant mesh exhibited an exceptional water separation flux of 9870 ± 15 L/hr/m2 when exposed to 1:1 v/v oil–water mixtures. This performance significantly outperformed previous filters designed for similar oil–water separation tasks. The mesh efficiently facilitated the passage of water through the oil–water mixture, achieving an efficiency rate exceeding 98 ± 1%. To gauge its wetting behavior, the hydrophilic/underwater oleophobic filter underwent static contact angle measurements. The filter's wetting mechanism was primarily attributed to its hierarchical surface structure, which enhanced surface hydrophilicity and roughness. Analytical techniques such as XRD, FTIR, and FE-SEM were employed to scrutinize the fabricated filter's composition. These analyses confirmed the successful creation of a nanostructured WO3 coating on both sides of the stainless steel mesh. Moreover, the utilization of commercially available chemicals and straightforward fabrication techniques underscores the promising potential of this approach for large-scale applications.

DESIGN OF HIGHLY EFFICIENT WATER PASSAGE OF PUMP-TURBINE

The problem of the need to develop renewable energy sources as a way to save the energy supply and energy independence of Ukraine by changing the consumption of carbohydrates is considered. It is shown that the development of Ukrainian renewable energy must occur in parallel with the development of energy storage systems and balancing of the energy system. The most effective system for storing energy and balancing the energy system is pumped storage power stations (PSPS). The work shows that the design of a highly effective equipment of a hydroelectric power plant depends on the correct selection of the element geometry of the pump-turbine water passage. Therefore, it is possible to ensure the necessary level of energy characteristics of hydraulic equipment. A method of dimensionless average parameters was established, which allows even at the initial stages of designing new reversible hydraulic machines to determine the optimal geometry of the watter passage elements. This method showed good results during the numerical research of Francis hydraulic turbines at a wide range of heads, as well as reversible hydromachines at heads of 300–500 m. Using expressions that establish the connection of hydrodynamic characteristics with dimensionless complexes, three variants of the flow part of the high-pressure pump-turbines (ORO500) were investigated. Based on the obtained results, a significant influence of the geometry on the hydraulic indicators of the machine was noted. The distribution of energy losses in the inlet, blade system and outlet was analyzed. The greatest energy losses occur in the inlet of the pump-turbines. To increase the energy and kinematic indicators of the ORO500 pump-turbines, the geometry of the feed elements, as well as the spiral casing and stator, was changed. Variants for improving the parameters in the elements of the supply of the water passage of the pump-turbine are proposed.

Alcohol-gating femtosecond laser-induced micro/nano-structured membranes with reversible switching wettability and breathability.

A reversible liquid gating membrane with the ability to regulate gas/liquid transport is critical for many fields, such as biological applications, multiphase separation, and sewerage treatment. Numerous membranes can respond to external stimuli and dynamically control gas/liquid fluid transport; however, simultaneously achieving regulated gas/liquid transport membranes through simple manufacturing remains a challenge. In this work, we investigated an alcohol-regulation gating membrane via femtosecond laser one-step processing, allowing in situ dynamically controllable gas/liquid transfer. More specifically, the porous membrane, processed by laser, exhibits excellent superhydrophobicity (WCA ∼ 153.4°) and breathability (water-vapor evaporation rates ∼118.3 mg (cm2 h)-1), enabling gas to penetrate but not water. In contrast, it allows the passage of water while preventing the permeation of gas subsequent to the introduction of alcohol. Furthermore, the porous membrane still possesses superbly consistent performance after being placed in air for 90 days or over 100 dropping-drying ethanol cycles test, indicating outstanding durability and reversibility. Significantly, the porous membrane has broad potential applications in medical dressings, providing a new strategy to fabricate next-generation bandages.