The use of traditional fossil fuels has contributed to rapid economic expansion while simultaneously having negative implications, such as increasing global warming and the devastation of the biosphere. Niching Penalized Chimp Optimization (NPChOA) is presented in this research in order to address the Environmental Economic Dispatch (EED) problem. In terms of global search capability, robustness, convergence rate, and durability, the proposed NPChOA outperforms the current ChOA. Following that, a novel constrained handling operator addresses the multi-objective optimization difficulty. The performance of NPChOA is evaluated using an IEEE 30 bus with six generators and a ten-unit system. The result of NPChOA is compared with Grey Wolf Optimizer (GWO), Space Reduction Strategy Particle Swarm Optimization (SRSPSO), Chaotic Biogeography-Based Optimizer (CBBO), Dynamic Population Artificial Bee Colony (DPABC), Modified Bacterial Foraging Algorithm (MBFA), Covariance Matrix Adaptation Evolution Strategy (CMA-ES), Differential Evolution-Crossover Quantum Particle Swarm Optimization (DE-CQPSO), standard ChOA, Dynamic Levy Flight ChOA (DLF-ChOA), and Weighted ChOA (WChOA) as the most recent modified version of ChOA to confirm its efficiency. NPChOA's evaluation score and convergence rate are outstanding compared to other benchmarks for single and multi-objective optimizations. The NPChOA's efficacy and robustness in dealing with environmental economic dispatch challenges have been demonstrated by discovering a good compromise value.