In order to increase the power of isobaric identification in accelerator mass spectrometry (AMS) measurements, we built a new gas-filled time-of-flight (GF-TOF) detector system (Jiang et al.). The principle, construction and results of first on line tests with a Cu sample are described. Based on the GF-TOF detector system, we also propose a new particle identification method called energy-loss and time-of-flight ( ΔE– T) parabola. The principle of the method and the first test for the method with the 36 Cl AMS measurement are described.