Gel Particles Research Articles

Experimental Evaluation of a Recrosslinkable CO2-Resistant Micro-Sized Preformed Particle Gel for CO2 Sweep Efficiency Improvement in Reservoirs with Super-K Channels

A recrosslinkable CO2-resistant branched preformed particle gel (CO2-BRPPG) was developed for controlling CO2 injection conformance, particularly in reservoirs with super-permeable channels. Previous work focused on a millimeter-sized CO2-BRPPG in open fractures, but its performance in high-permeability channels with pore throat networks remained unexplored. This study used a sandpack model to evaluate a micro-sized CO2-BRPPG under varying conditions of salinity, gel concentration, and pH. At ambient conditions, the equilibrium swelling ratio (ESR) of the gel reached 76 times its original size. This ratio decreased with increasing salinity but remained stable at low pH values, demonstrating the gel’s resilience in acidic environments. Rheological tests revealed shear-thinning behavior, with gel strength improving as salinity increased (the storage modulus rose from 113 Pa in 1% NaCl to 145 Pa in 10% NaCl). Injectivity tests showed that lower gel concentrations reduced the injection pressure, offering flexibility in deep injection treatments. Gels with higher swelling ratios had lower injection pressures due to increased strength and reduced deformability. The gel maintained stable plugging performance during two water-alternating-CO2 cycles, but a decline was observed in the third cycle. It also demonstrated a high CO2 breakthrough pressure of 177 psi in high salinity conditions (10% NaCl). The permeability reduction for water and CO2 was influenced by gel concentration and salinity, with higher salinity increasing the permeability reduction and higher gel concentrations decreasing it. These findings underscore the effectiveness of the CO2-BRPPG in improving CO2 sweep efficiency and managing CO2 sequestration in reservoirs with high permeability.

A Simple Preparation of Crosslinked, Highly Alkaline Diallyldimethylammonium Hydroxide Hydrogel Particles via Inverse Static Anion Exchange.

Highly alkaline hydrogels are gaining increasing attention in building materials research. Specifically, cationic alkaline hydrogels based on diallyldimethylammonium hydroxide (DADMAOH) as the monomer have been effectively used to seal water-bearing cracks or serve as coupling media for electrochemical chloride extraction. However, the residual halogen content and challenges in scaling up monomer production have hindered broader application. Attempts to use a commercially available cation-selective membrane for ion exchange achieved up to 90% chloride-to-hydroxide switch, but the approach proved ineffective due to significant monomer decomposition during the process. By contrast, neutral gels and gel particles can be readily prepared from diallyldimethylammonium chloride (DADMAC) in large quantities and with a wide range of compositions. It is demonstrated here that these neutral gel particles undergo inverse static anion exchange when suspended in NaOH solution, generating DADMAOH particles with residual halide contents of <0.3%, without the need for ion-selective or dialysis membranes. This corresponds to an up to 100-fold reduction in residual chloride content compared to particles produced directly from alkaline monomer solutions, thereby significantly enhancing the efficiency of hydroxide ion release. The swelling behaviour of the particles is primarily influenced by the initial monomer concentration, while conductivity remains largely unaffected, indicating that charge transport occurs mainly along the particle surface. Despite the pronounced increase in swelling with decreasing particle radii, the specific conductivity of 2.8 Ω-1 m-1 is still sufficient for their use as coupling media in concrete applications. In summary, the alkaline particles prepared via inverse static anion exchange meet all necessary requirements for building materials applications, offering a broader range of tuneable properties and greater ease of production compared to gels or particles derived from DADMAOH.

Experimental evaluation of temporary plugging performance and mechanism analysis of degradable preformed particle gel based on NMR technology

Utilizing chemical temporary plugging systems to further increase the stimulated reservoir volume (SRV) and improve oil recovery (IOR) has become a hot topic in the current petroleum industry. Pre-formed gel particles (PPG) possess excellent swelling properties and can form high-strength plugging in high-permeability channels. In addition, degradable pre-formed gel particles (DPPG) further exhibit self-degradation characteristics and excellent temporary plugging and fluid diverting performance. In our previous studies, we examined the temporary plugging mechanisms of DPPG prepared with different molecular weight (MW) of crosslinking agents (PEGDA) through bottle tests and core displacement experiments. However, the microscopic swelling mechanism and temporary plugging mechanism in pore throats of reservoir cores are still unclear. In this paper, comprehensive research was conducted on the microscopic temporary plugging mechanism of DPPG prepared with different MW crosslinking agents using both and method. Results showed that DPPG with different compositions had different micro-swelling performance. NMR-T2 analysis for bottle test showed that DPPG-M1 (with the smallest MW of crosslinking agent) gradually decreased in nuclear signal during the water absorption and swelling process, and had the largest swelling volume and swelling rate. On the other hand, DPPG-M5 (with the largest MW of crosslinking agent) exhibited a slow diffusion process of surface water towards the nucleus, resulting in the smallest swelling volume and swelling rate. However, its complete degradation time was longer. Moreover, the NMR T2 (i.e., spin-spin relaxation time) results of the cores in the dynamic temporary plugging experiment showed that the decrease of the MW of the crosslinking agent enhanced the plugging performance, but with less damage to the formation. The MRI images confirmed that DPPG-M5 had better injection capability in the core and caused greater damage to the core. The research results of this study showed that NMR technology can reveal the temporary plugging mechanism of DPPG from a micro-level perspective.

Impact of pectin and alginate gel particle size and concentration on in vitro gut fermentation

Fermentation by human gut microbiota of dietary fibres (DF) is influenced by the particle size and concentration of these fibres. However, previous studies have faced challenges in investigating these effects in real food systems due to the complex composition and heterogeneous structure of most DF. Here we describe particle size and concentration effects on the fermentation of polysaccharide gel particles, used as examples of defined and homogeneous model DFs. Gel particles of calcium-induced gelling polysaccharides, alginate and pectin, were prepared using dripping (>1 mm) and emulsion-based (<1 mm) methods. These particles were directly introduced into an in vitro fermentation system with a human faecal inoculum to simulate interactions with the gut microbiota. Throughout the fermentation, gas production, short-chain fatty acids, ammonia and unfermented substrate contents were measured. The results showed that pectin fermented faster than alginate in both gel and solution forms, with gelled forms of both polysaccharides fermenting more slowly than their solutions. However, particle size and concentration had minimal effects on fermentation outcomes for particles formed by the dripping method. Notably, small pectin particles (∼0.5 mm) fermented similarly to solutions, suggesting a size threshold below which gel particle fermentation is equivalent to that of solutions. This work highlights the impact of gel particle size on in vitro gut fermentation and provides insights for designing food gels with desired fermentation properties.

Tunable macroscopic self-healing of supramolecular gel through host–guest inclusion

Supramolecular gels (SGs) consisted of noncovalent cross-linking network structures are fascinating due to their efficient energy dissipation and reversible self-healing properties. However, it is unknown how the noncovalent interactions alter the macroscopic self-healing and mechanical properties of SGs. Herein, the peculiar nature of SGs manufactured by combining covalent and noncovalent (host–guest inclusion of β-cyclodextrin and C16 hydrophobic chain) cross-linking structures was studied and compared with covalent cross-linking preformed particle gels. The macroscopic self-healing behaviors, rheology, mechanical tensile properties, as well as the tunable mechanisms of self-healing were explored by visual inspection, rheological, and atomic force microscopy probing methods. The results show that the SGs exhibit excellent self-healing efficiency and mechanical strength after interfacial cutting. Moreover, the SGs exhibited excellent mechanical tensile properties, including loading–unloading, successive loading–unloading, and recovery loading–unloading tensile performances. Notably, the macroscopic self-healing of SGs has good tunability by changing the covalent and noncovalent crosslinker contents and salt contents. This peculiar phenomenon is attributed to certain host–guest inclusion forces (4.7 and 0.3 nN) between different SGs under the distilled and high-salinity water conditions, respectively. This study is beneficial for the development of stimuli–response supramolecular gels in different applications, such as oil recovery in fractured reservoirs.

The Influence of the Design of a Static Multi-Vortex Classifier on the Efficiency Fractionation of Silica Gel Particles

The Influence of the Design of a Static Multi-Vortex Classifier on the Efficiency Fractionation of Silica Gel Particles

Anomalous diffusion of active Brownian particles in responsive elastic gels: Nonergodicity, non-Gaussianity, and distributions of trapping times.

Understanding actual transport mechanisms of self-propelled particles (SPPs) in complex elastic gels-such as in the cell cytoplasm, in in vitro networks of chromatin or of F-actin fibers, or in mucus gels-has far-reaching consequences. Implications beyond biology/biophysics are in engineering and medicine, with a particular focus on microrheology and on targeted drug delivery. Here, we examine via extensive computer simulations the dynamics of SPPs in deformable gellike structures responsive to thermal fluctuations. We treat tracer particles comparable to and larger than the mesh size of the gel. We observe distinct trapping events of active tracers at relatively short times, leading to subdiffusion; it is followed by an escape from meshwork-induced traps due to the flexibility of the network, resulting in superdiffusion. We thus find crossovers between different transport regimes. We also find pronounced nonergodicity in the dynamics of SPPs and non-Gaussianity at intermediate times. The distributions of trapping times of the tracers escaping from "cages" in our quasiperiodic gel often reveal the existence of two distinct timescales in the dynamics. At high activity of the tracers these timescales become comparable. Furthermore, we find that the mean waiting time exhibits a power-law dependence on the activity of SPPs (in terms of their Péclet number). Our results additionally showcase both exponential and nonexponential trapping events at high activities. Extensions of this setup are possible, with the factors such as anisotropy of the particles, different topologies of the gel network, and various interactions between the particles (also of a nonlocal nature) to be considered.

Early properties and reaction mechanism of hybrid alkali-activated cements (HAACs)

Geopolymers have received extensive attention due to their greenhouse effect. However, the application of geopolymers has been restricted by their workability and manufacturing technique. Hybrid alkali-activated cements (HAACs), which are transition materials between cement and geopolymers, have gradually been developed. The chemical reactions of HAACs are complicated, and adjusting their performance is difficult. In this study, the competitive reactivities and phase contents of commonly used HAACs with different raw material compositions and curing conditions are examined. The reaction degrees of the clinker (RoC), C-(A)-S-H+N(C)-A-S-H gel and unreacted amorphous particle (UAP) contents were calculated. The experimental results indicated that the quantity and structure of the gel were optimized when the Si2O/Na2O and Na2O contents of HAAC-G3 were 1.5 and 4 %, respectively, and the cement: mineral admixture ratio was 1:4. Moreover, a large amount of N-A-S-H with a dense structure was produced by alkali reactions rather than cement hydration reactions in HAAC-G3; these reactions improved the macroscopic mechanical properties. Additionally, the effects of steam curing on the properties of the HAACs were slight because of the internal water competition reaction mechanism. This research clarified the influence of different coordination methods on the internal reaction mechanism of HAACs and could be used to promote the engineering application of HAACs. Moreover, HAACs play an important role in mitigating greenhouse effects worldwide.

Machine learning-guided synthesis of nanomaterials for breast cancer therapy

Breast cancer is a common malignant tumor, which mostly occurs in female population and is caused by excessive proliferation of breast epithelial cells. Breast cancer can cause nipple discharge, breast lumps and other symptoms, but these symptoms lack certain specificity and are easily confused with other diseases, thus affecting the early treatment of the disease. Once the tumor progresses to the advanced stage, distant metastasis can occur, leading to dysfunction of the affected organs, and even threatening the patients’ lives. In this study, we synthesized high drug-loading gel particles and applied them to control the release of insoluble drugs. This method is simple to prepare, cost-effective, and validates their potential in breast cancer therapy. We first characterized the morphology and physicochemical properties of gel loaded with newly synthesized compound 1 by scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FT-IR), and thermal gravimetric analysis (TGA). Using newly synthesized insoluble compound 1 as a model drug, its efficacy in treating breast cancer was investigated. The results showed that hydrogel@compound 1 was able to significantly inhibit the proliferation, migration and invasion of breast cancer cells. Additionally, we utilized machine learning to screen three structurally similar compounds, which showed promising therapeutic effects, providing a new approach for the development of novel small-molecule drugs.

Application of Fluorescent Composite Materials as a Sustained Release System in Treatment of Polycystic Ovary Syndrome.

Polycystic ovary syndrome (PCOS) is a multifactorial disease characterized by oxidative stress and follicular dysfunction, leading to menstrual irregularities, hyperandrogenism, and infertility. Traditional drug delivery methods often result in drug loss and side effects on normal tissues. To address these issues, we synthesized two novel Co(II)-containing coordination polymers (CPs), {[Co(L)(H2O)2]·2H2O}n (1) and {[Co(L)(H2O)2]·1.5H2O}n (2), through the reaction of the T-shaped ligand (4 - 3'-pyridyl-,6 - 4'-carboxylphenyl)picolinic acid (H2L) with Co(NO3)2·6H2O via a solvothermal process. Fluorescence spectroscopy revealed that the fluorescence emission of the CPs originates from the ligand, indicating their potential application as blue fluorescence materials. Subsequently, we encapsulated these CPs with hyaluronic acid (HA) and carboxymethyl chitosan (CMCS) hydrogels to create two types of metal gel particles carrying spironolactone (HA/CMCS-CPs@spironolactone). SEM and TEM analyses showed that the material consists of tightly stacked sheet-like structures with an average size of approximately 100nm. Thermogravimetric analysis (TGA) indicated that the material begins to decompose at around 115°C, demonstrating good thermal stability. We assessed the inhibitory effects of these materials on oxidative stress induced by PCOS. The results showed that both types of spironolactone-loaded metal gel particles significantly reduced malondialdehyde (MDA) levels, particularly the particles constructed with CP2. HA/CMCS-CP1@spironolactone reduced MDA levels by approximately 17% and 46% at low and high concentrations, respectively, while HA/CMCS-CP2@spironolactone decreased MDA levels by about 55% and 39% at high and low concentrations, respectively. Therefore, the novel drug delivery system reported in this study has the potential to become a safe and effective option for the localized treatment of PCOS.

A high temperature-resistant, strong, and self-healing double-network hydrogel for profile control in oil recovery

Hydrogels are widely used in profile control to plug high-permeability zones in oil recovery. In this study, a novel double-network (DN) hydrogel is developed for profile control. The two networks of the prepared hydrogel are polyacrylamide (PAAm) crosslinked by N,N’-Methylenebisacrylamide (MBAA) and konjac glucomannan (KGM) crosslinked by borax (B), respectively. The two networks are interconnected by their interpenetrating structures and hydrogen bonds. Based on the results of a series of evaluation experiments, the AAm/KGM DN hydrogels developed in this study exhibit a strong mechanical strength with their fracture stresses exceeding 0.137 MPa. Meanwhile, the AAm/KGM DN hydrogels can remain thermally stable after being heated at 130 °C for 24 h, indicating the good high-temperature resistance of the new sample. Moreover, the prepared AAm/KGM DN hydrogels present excellent self-healing performance due to the abundant hydrogen bonds in their structures, which helps form stable and long-term plugging in porous media. In addition, the pure PAAm hydrogel and the AAm/KGM DN hydrogel are sheared into two dispersed particle gel (DPG) suspensions to investigate their plugging performances. The results demonstrate that the AAm/KGM DN DPG can effectively plug a high-permeability sandpack with a plugging efficiency of 93.2 %, while the pure AAm DPG can only provide a much lower plugging efficiency of 60.5 %. The AAm/KGM DN hydrogel developed in this study, with its high mechanical strength, high-temperature resistance, and self-healing capability, offers a promising new candidate for profile control in oil recovery.

The Formation Mechanism of Residual Oil and Methods of Enhanced Oil Recovery in a Fractured Low-Permeability Metamorphic Rock Reservoir in Bohai Bay

The oil reservoirs of the metamorphic rocks in Bohai Bay have geological characteristics such as low matrix porosity and permeability, developed natural microfractures, which result in the injection water rapidly advancing along fractures, a fast increase in the water content, and difficulties in extracting the remaining oil. In order to reveal water channeling and the residual oil formation mechanisms in fractured low-permeability reservoirs and solve the water channeling problem, we first analyzed the reservoir development status, then studied the formation mechanism of residual oil using a microfluidic chip device, and formed a method of hierarchical control to effectively control the water channeling problem of fractured reservoirs and maximize the displacement of residual oil. The results show that (1) Due to the low permeability of the reservoir matrix, a large amount of injected water flows along the fracture channel, which leads to the long-term high water cut of some oil wells and the retention of a large amount of crude oil in the matrix. (2) The results of microfluidic experiments show that the distribution of residual oil after water flooding mainly includes five types: blind end of the pore throat, columnar, cluster, flake and film, and residual oil. Among them, sheet-like and clustered residual oil are dominant, accounting for 75~85% and 10~13%, respectively. (3) Based on the characteristics of fracture development in buried-hill reservoirs, a hierarchical control technology of “gel particle + liquid crosslinked gel system” is established. The field application effect predicted that the input–output ratio was 1:3. This study provides a reference for the comprehensive treatment of water channeling in the same type of offshore fractured low-permeability metamorphic rock reservoirs.

Investigation on preparation and properties of gel type 188W/188Re generator

As one of the most important integrated nuclides for diagnosis and treatment in recent years, rhenium-188 (188Re) has a broad scope in the clinical application. Due to the specific properties of such radionuclide, it was mainly provided by the chromatographic 188W-188Re generators. There is no doubt that the application of 188Re in the treatment of various diseases depended on the development of 188W-188Re generator. Considering the high standards of such technology on radioactive activity of 188W and impurity content, a 188W-188Re generator filled with the zirconium tungstate gel has been prepared in this work. The effects of molar ratio of chemical agents, pH, reaction temperature, drying methods, rinsing methods and other conditions on the synthesis of gel particles have been studied. Furthermore, a variety of characterization techniques were used to observe the macro-/micro-morphology and chemical structure of gel particles. It can be concluded that vacuum freeze-dried method could significantly increase the specific surface area, pore size and tungsten content of gel particle. In order to decrease the content of 188W in the elute, a handful of acidic alumina was filled in the bottom of our 188W-188Re generator, an elution and purification integrated-generator was formed. During the first five processes, the nuclear purity of 188Re solution was above 99.99%, the radiochemical purity was approximately 99.5%, the pH value was 5.0–7.0 and the average elution efficiency reached up to 82.7%. In addition, the leakage rate of 188W was low as 1.60 × 10−6, and the peak of elute curve was located at 2 mL without the trailing phenomenon. This work lays a solid foundation for the domestic demand of daughter nuclide 188Re, further makes an outstanding contribution to the application of the radiation therapy technology and the protection of people's health.

A study on the microscopic mechanism of oil displacement in an adaptive profile control and plugging composite displacement system

This study employed a self-designed microfluidic chip with visualized oil displacement technology and indoor core flooding experiments to reveal the microscopic plugging and adjustment mechanisms. Additionally, it involved the microscopic oil displacement mechanism of an adaptive plugging and flooding composite system containing PPG (preformed particle gel) particles and two blended surfactants. The results indicated that microfluidic imaging captured the dynamic seepage characteristics of PPG particles after swelling, which involved plugging, deformation, and passage through a 0.3 mm throat in a series of pores, achieving adaptive plugging between the size of PPG particles and the pore size. The plugging mechanism of PPG particles involves blocking larger parallel pores, increasing the displacement velocity in smaller pores, and dynamically adjusting the plugging to achieve simultaneous displacement in the high- and low-permeability layers. The displacement mechanism of PPG particles in the simulated pores includes reducing seepage radius, expanding sweep area, and repeatedly overcoming capillary forces. The pressure variation data along the length of different permeability long cores demonstrated that the pressure drop within the first third of the injection end increases with an increase in permeability. The pressure change curve illustrates the migration characteristics of PPG particles in the pore throats, characterized by “accumulation and plugging–pressure increase–deformation and migration.” After injecting the adaptive plugging and flooding composite system following polymer flooding, the flow fraction in the high-permeability layers decreased to 25.65 %, whereas that in the low-permeability layers increased to 74.56 %. The difference in the water flooding pressure before and after implementing the adaptive plugging and flooding system reached a factor of 29, and the oil recovery rate improved by 5.55 % compared to a weak alkaline ternary composite system. The adaptive plugging and flooding composite system demonstrated a synergistic effect in expanding swept volume, blocking preferential flow channels, and enhancing oil displacement efficiency. It achieved the effects of simultaneous plugging and flooding, dynamic plugging adjustment, and synchronized displacement in the high- and low-permeability layers, thereby significantly improving the mobilization of residual oil after polymer flooding.

Effects of Particle Size and Shape on the Texture Property of a Solid-Liquid Dispersion System With Gel Particles.

Food texture is one of the most important factors for assessing the quality and acceptability of food. However, the study of food texture has been delayed compared with other factors, such as flavor and taste, due to the difficulty of quantitative analysis related to real physiological senses. Furthermore, the numerical and systematic evaluation of the texture property of dispersion systems, in which solid particles are dispersed in a liquid medium, is very difficult, despite most foods being in a solid-liquid dispersion state during mastication in the human mouth. In this study, the texture property of a solid-liquid dispersion system with spherical and cubic gel particles of agar and konjac was examined to evaluate the physical behavior of food during mastication using the back extrusion method. The yield stress of the system strongly depended on the size and shape of the particles, the mixing ratio of particles of different sizes and shapes, and the concentration of components in the particles. The proposed index, reflecting the size, shape, and number of particles and the yield stress of a single particle, expressed well the measured yield stress of the entire dispersion system. However, the adhesiveness and recoverability showed relatively little dependence on particle size. The findings obtained in this study will contribute to elucidating the texture property of various foods and to the development of new and novel food products and cuisines, thereby benefiting food science and industry.

Influence of elastic modulus on enhanced oil recovery ability of branched-preformed particle gel in porous media

A heterogeneous phase combined flooding system composed of polymers, surfactants, and branched-preformed particle gel (B-PPG) has been successfully applied to enhance oil recovery in mature reservoirs. However, the influence of elastic modulus on the enhanced oil recovery of B-PPG is unclear. Thus, based on the sand-pack flooding experiments and visual flooding experiments, the enhanced oil recovery ability of B-PPG with different elastic modulus and similar particle size was investigated under different injection modes. Results show that under the single-slug injection mode, the higher the elastic modulus, the higher the incremental oil recovery, and the better the ability to enhance oil recovery. With the increase in the elastic modulus from 0.7 Pa to 42.2 Pa, the incremental oil recovery increased from 12.7% to 32.6%. Under the multi-slug alternating injection mode, the incremental oil recovery of injecting low elastic modulus B-PPG slug followed by high elastic modulus B-PPG slug was 2.8% higher than that of injecting high elastic modulus B-PPG slug followed by low elastic modulus B-PPG slug. The incremental oil recovery of B-PPG under the multi-slug alternating injection mode was higher than that under the single-slug injection mode. At the microscopic level, the type of remaining oil was mainly clustered after water flooding. With the increase in the elastic modulus, the ratio of the clustered remaining oil decreased and the ratio of the multi-porous, columnar, and droplet remaining oil increased. Compared with the single-slug injection mode, it was easier to recover the clustered remaining oil by B-PPG flooding under the multi-slug alternating injection mode.

Topological Data Analysis for Particulate Gels.

Soft gels, formed via the self-assembly of particulate materials, exhibit intricate multiscale structures that provide them with flexibility and resilience when subjected to external stresses. This work combines particle simulations and topological data analysis (TDA) to characterize the complex multiscale structure of soft gels. Our TDA analysis focuses on the use of the Euler characteristic, which is an interpretable and computationally scalable topological descriptor that is combined with filtration operations to obtain information on the geometric (local) and topological (global) structure of soft gels. We reduce the topological information obtained with TDA using principal component analysis (PCA) and show that this provides an informative low-dimensional representation of the gel structure. We use the proposed computational framework to investigate the influence of gel preparation (e.g., quench rate, volume fraction) on soft gel structure and to explore dynamic deformations that emerge under oscillatory shear in various response regimes (linear, nonlinear, and flow). Our analysis provides evidence of the existence of hierarchical structures in soft gels, which are not easily identifiable otherwise. Moreover, our analysis reveals direct correlations between topological changes of the gel structure under deformation and mechanical phenomena distinctive of gel materials, such as stiffening and yielding. In summary, we show that TDA facilitates the mathematical representation, quantification, and analysis of soft gel structures, extending traditional network analysis methods to capture both local and global organization.

Enhancing geothermal efficiency: Experimental evaluation of a high-temperature preformed particle gel for controlling preferential fluid flow

Enhanced Geothermal System (EGS) reservoirs represent a vital frontier in clean energy production. However, short-circulation flow within these reservoirs can significantly affect their immediate efficiency and long-term viability. Injected cold fluids moving through wide fractures or direct channels between injection and production wells reduce thermal production temperatures, disrupting energy output. Preformed Particle Gels (PPGs) have proven effective in controlling preferential fluid flow in oil and gas reservoirs, effectively regulating fluid movement. This work explores the potential of a novel High-Temperature Preformed Particle Gel (HT-PPG), designed for geothermal applications, to plug fractures in a simulated geothermal reservoir. Core flooding experiments in coated and uncoated sandstone models were conducted under varying HT-PPG sizes, swelling ratios, and fracture widths to determine gel plugging efficiency. Variations in the HT-PPG injection pressure, breakthrough pressure, and residual resistance factor (Frr) were evaluated. Water breakthrough pressures can reach 464.10 psi/ft. While the stable injection pressure of HT-PPG decreased with increasing swelling ratio and fracture width, it was higher in uncoated cores. The HT-PPG significantly sealed the fractures, drastically reducing conductivities to millidarcy levels. This work validates HT-PPG a robust solution to mitigate fluid diversion challenges in sandstone EGS reservoirs, enhancing performance and advancing sustainable geothermal energy production.

Design, synthesis, and characterization of novel copolymer gel particles for water-plugging applications

Abstract Multi-stage plugging represents a promising strategy for enhancing production and injection rates in medium-and low-permeability oilfields. Despite its potential, the efficacy of current plugging agents, particularly hydrophobically bonded water-soluble polyacrylamide-based gel microspheres, is hindered by notable drawbacks such as low stability and inadequate compressive strength. Therefore, a comprehensive understanding of water plugging mechanisms coupled with the optimization of gel microsphere properties is essential for advancing the development of gel-based plugging agents with superior characteristics or intelligent regulatory capabilities. The P(AA-AM-[PrSO3]Vim) ionic liquid copolymerized gel particles were designed and synthesized by using microfluidic technique and titration gel method with AM, acrylic acid (AA), 1-vinylimidazole (Vim) and 1,3-propylsulfonyl lactone (PrSO3) as the raw materials. The morphology and structure of the copolymer gel particles were characterized, and the effects of [PrSO3]Vim and cross-linker content on the water-absorbing properties and strength of the gel particles were investigated. When the amount of [PrSO3]Vim was 12%, the concentration of crosslinker was 1.5%, and the temperature was 40°C, the water absorption capacity reached the maximum value of 163 g·g−1. The strength of the P(AA–AM–[PrSO3]Vim) spherical gel particles was maximized at a [PrSO3]Vim content of 4%. Furthermore, the chemical and physical roles of the P(AA–AM–[PrSO3]Vim) spherical gel particles were studied in a typical water-plugging environment. This study provides experimental data and a theoretical basis for the application of functional spherical gel-plugging particles in current oilfield environments.

CO2-EOR and storage in a low-permeability oil reservoir: Optimization of CO2 balanced displacement from lab experiment to numerical simulation

CO2 flooding can enhance oil recovery associated with CO2 storage, but its performance is often damaged by the gas channeling due to reservoir heterogeneity and the large CO2 mobility. Most current research focuses on chemical agents to prevent CO2 channeling, while there is less attention to reservoir engineering methods. In this study, a concept of balanced displacement was introduced to delay the gas channeling and achieve balanced development in a multi-layer and low-permeability block Y21. A series of lab experiments and numerical simulations were conducted to explore the best CO2 flooding scheme by considering three aspects of optimization. Layer grouping and well pattern and spacing adjustment were applied to seek for balanced utilization of geological reserves; gas channeling plugging and mobility control measures were taken to increase the CO2 swept volume; and the pressure control and injection-production optimization were carried out to improve the oil displacement efficiency. The results show that CO2 can reach miscible with crude oil in block Y21 under the original formation pressure, but gas breakthrough quickly occurs along the hydraulic fractures to the top of the structure. To obtain a balanced displacement, the layers of block Y21 should be divided into two groups for separate development. The current well pattern and spacing are suitable for CO2 flooding, which need not be adjusted. WAG injection with acid-resistant gel particles and foaming agents can be used to inhibit gas channeling. These measures can significantly improve the CO2 displacement profile in block Y21. The oil recovery factor can be increased by 10.01%, and 5.41 × 104 tons of CO2 can be stored. This study can provide valuable guidance for CO2-EOR and storage in low-permeability oil reservoirs.