Composite Particles Research Articles

An organic-inorganic dual network built in fast-growing wood veneers to improve the flame retardant and mechanical properties of plywood

Fast-growing wood is widely used in plywood production due to its short growth cycle and low cost. However, its loose fiber structure, inferior material quality, and high flammability significantly limit the application range of plywood products and hinder high-value utilization. This paper reports a simple method for modifying fast-growing wood veneers. We modified phenolic resin with Mg(OH)₂@nano-silica composite particles and impregnated it into the veneers, constructing an organic-inorganic hybrid dual-network structure on both the surface and interior of the veneers. The plywood prepared from the modified veneers exhibited a bending strength of 115.6 MPa, a modulus of elasticity of 9.7 GPa, and a wet shear strength of 2.1 MPa, representing increases of 86.1%, 47.0%, and 90.9%, respectively, compared to plywood made from unmodified veneers. Additionally, the peak heat release rate decreased by 15.3%, and the ignition time was extended to 26 seconds. The uniformly distributed inorganic network effectively mitigated stress concentration and, together with the phenolic resin, formed an efficient thermal insulation layer, enhancing the flame retardancy of the material. This study offers a simple and effective treatment method for reinforcing fast-growing wood veneers, promoting the use of fast-growing wood in high-performance applications.

Composition-optimized NiGa-LDH on MOF-derived and cobalt-nanoparticles-embedded carbon flakes for enhanced potassium-ion storage

Layered double hydroxides (LDHs), renowned for their distinct nanostructures, efficient ion channels, and high specific capacitance, are promising electrode materials for supercapacitors (SCs). However, commercial applications remain limited due to constraints in the rate capabilities and cycling. The synergistic effects of the composites can be leveraged by pairing LDHs with carbon materials to enhance the conductivity for better SC characteristics. Herein, flaky Zeolitic Imidazolate Framework(ZIF)-67 is deposited on carbon cloth and calcined to produce the MOF-derived composite of carbon nanosheet-embedded nano-cobalt particles (CPEC) on the surface of the carbon cloth. Afterward, NiGa-LDH with a controllable Ni to Ga ratio is synthesized on the CPEC to form a flower-like hierarchical nanostructure NiGa-LDH/CPEC@CC. Co nanoparticles act as nucleation sites for cohesive formation within the carbon cloth framework. Ni2Ga1-LDH/CPEC@CC has the best properties, such as a specific capacitance of 729.6F g−1 at 1 mA cm−2 and 97.3 % capacitance retention at 2 mA cm−2. The asymmetric supercapacitor (ASC) consisting of Ni2Ga1-LDH/CPEC@CC//AC has an excellent energy density of 83.96 Wh kg−1 with a power density of 80 W kg−1. Density-functional theory (DFT) calculations of Ni2Ga1-LDH/CPEC@CC affirm a potassium ion adsorption energy of −2.127 eV and density of state (DOS) near the Fermi level. The study imparts theoretical and technical knowledge about the design of complex nanostructures from MOF precursors.

Phages ZC01 and ZC03 require type-IV pilus for Pseudomonas aeruginosa infection and have a potential for therapeutic applications.

There has been a growing interest in bacteriophages as therapeutic agents to treat multidrug-resistant bacterial infections. The present work aimed at expanding the microbiological and molecular characterization of lytic phages ZC01 and ZC03 and investigating their efficacy in the control of Pseudomonas aeruginosa infection in an invertebrate animal model. These two phages were previously isolated from composting using P. aeruginosa strain PA14 as the enrichment host and had their genomes sequenced. ZC01 and ZC03 present, respectively, siphovirus and podovirus morphotypes. ZC01 was recently classified into the genus Abidjanvirus, while ZC03 belongs to Zicotriavirus genus of the Schitoviridae N4-like viruses. Through proteomics analysis, we identified virion structural proteins of ZC01 and ZC03, including a large virion-associated RNA polymerase that is characteristic of N4-like viruses, some hypothetical proteins whose annotation should be changed to virion structural proteins and a putative peptidoglycan hydrolase. Phages ZC01 and ZC03 exhibit a limited yet distinct host range, with moderate to high efficiency of plating (EOP) values observed for a few P. aeruginosa clinical isolates. Phage susceptibility assays in PA14 mutant strains point to the type-IV pilus (T4P) as the primary receptor for phages ZC01 and ZC03, and the major pilin (PilAPA14) is the T4P component recognized by these phages. Moreover, both phages significantly increase survival of Galleria mellonella larvae infected with PA14 strain. Taken together, these results underpin the therapeutic potential of these phages to treat infections by P. aeruginosa and lay the groundwork for a more detailed investigation of phage-bacteria-specific recognition mechanisms.IMPORTANCEPhage therapy is gaining increasing interest in cases of difficult-to-treat bacterial human infections, such as carbapenem-resistant Pseudomonas aeruginosa. In this work, we investigated the molecular mechanism underlying the interaction of the lytic phages ZC01 and ZC03 with the highly virulent P. aeruginosa PA14 strain and their efficacy to treat PA14 infection in Galleria mellonella larvae, a commonly used invertebrate model for phage therapy. We depicted the protein composition of ZC01 and ZC03 viral particles and identified pilin A, the major component of type-4 pilus, as the receptor recognized by these phages. Our findings indicate that phages ZC01 and ZC03 may be further used for developing therapies to treat multidrug-resistant P. aeruginosa infections.

ZIF‐67 Derived Cobalt Catalysts for the Hydroformylation of Liquid Olefins

AbstractIn this work, we described a general monometallic cobalt heterogeneous catalyst for the hydroformylation of olefins, achieving good yields and recyclability up to five times with no loss in catalytic activity. These catalysts were prepared through the pyrolysis of the well‐defined metal–organic framework ZIF‐67. The addition of steam during the pyrolysis did not affect the final phase composition of the cobalt particles; nonetheless, it resulted in an increase of the cobalt particle size and the partial removal of the carbonaceous matrix. The materials were extensively characterized by several techniques, and it was observed that the N‐doped carbon matrix played a crucial role in terms of activity and stability. Different liquid olefins, including internal, terminal, and cyclic were successfully tested in our hydroformylation protocol. Aldehydes yields of 48%–77% for different liquid olefins were achieved with the optimal catalyst. No leaching of the active sites was observed over five catalytic cycles. The high stability of the catalyst is attributed to the presence of stabilizing nitrogen atoms bearing the cobalt sites.

Microstructure of confectionery masses revealed by cryo-planing

Here we present a novel, combined cryo-scanning electron microscopy (cryo-SEM) and confocal laser scanning microscopy (CLSM) method for imaging of chocolate confectionery product microstructures of several millimeters down to about 100 nm. The SEM part of the method is based on cryo-fixation, cryo-polishing, and scanning electron microscopy, at low vacuum and low temperature using the backscattered electron signal. Starting with cryo-fixation of the chocolate sample in a desired state (cooled, ambient, or melted), the sample is cryo-planed in a cryo-ultramicrotome. Once a polished cut is obtained, the sample is analyzed using a cryo-SEM technique, with the unusual combination of low temperature and low vacuum settings, without heavy metal coating. Imaging is done based on material density contrast. Elemental composition of particles is recorded by energy dispersive x-ray spectroscopy (EDS). The combination of imaging contrast and EDS allows identification and measurement of the four main constituents of chocolate (cocoa solids, fat, sugar, and milk solids). Finally, the same cryo-polished sample sections of solid chocolate products are analyzed using a CLSM imaging technique to reveal complementary microstructural details. An obvious application of the method could be the visualization and quantitative analysis of the size, shape, and composition of chocolate confectionery products.

Response tests on the effects of particle size of waste glass sand and glass powder on the mechanical and durability performance of concrete

To investigate the effect of waste glass material particle sizes on the mechanical and durability properties of concrete, a two-phase experimental approach was conducted. First, comprehensive tests were performed to examine the effects of glass sand and glass powder of different particle sizes on concrete performance. Subsequently, based on the experimental results, an orthogonal test was designed to optimize the replacement amounts of composite particle sizes. The results indicated that an appropriate amount of glass sand can enhance the mechanical properties and durability of concrete, while excessive amounts or larger particle sizes may have adverse effects. The pozzolanic effect of glass powder also contributes to performance improvement, but the replacement rate should be limited to 20%. Under composite particle size conditions, the compressive, tensile, and shear strengths of concrete increased by 35.56%, 21.74%, and 13.79%, respectively, while durability significantly improved, with water absorption reduced by 20.73% and chloride ion permeability decreased by 63.10%. At a total replacement rate of 20%, the optimal proportions were determined to be 2.86% for 0.6 mm glass sand, 1.43% for 1.18 mm glass sand, 8.57% for 50–60 μm glass powder, and 7.14% for 60–70 μm glass powder. The incorporation of composite particle sizes improved the microstructure of concrete, thereby enhancing its mechanical and durability properties.

Bio-optical variability of particulate matter in the Southern Ocean

The composition and size distribution of particles in the ocean control their optical (scattering and absorption) properties, as well as a range of biogeochemical and ecological processes. Therefore, they provide important information about the pelagic ocean ecosystem’s structure and functioning, which can be used to assess primary production, particle sinking, and carbon sequestration. Due to its harsh environment and remoteness, the particulate bio-optical properties of the Southern Ocean (SO) remain poorly observed and understood. Here, we combined field measurements from hydrographic casts from two research voyages and from autonomous profiling floats (BGC-Argo) to examine particulate bio-optical properties and relationships among several ecologically and optically important variables, namely the phytoplankton chlorophyll a concentration (Chl), the particulate absorption coefficient (ap), the particulate backscattering coefficient (bbp), and the particulate organic carbon (POC) concentration. In the clearest waters of the SO (Chl < 0.2 mg m−3), we found a significant contribution to absorption by non-algal particles (NAP) at 442 nm, which was up to 10 times greater than the absorption by phytoplankton. This makes the particulate bio-optical properties there remarkably different from typical oceanic case 1 water. A matchup analysis confirms the impact of this larger NAP absorption on the retrieval of Chl from satellite ocean colour observations. For waters with Chl > 0.2 mg m−3, no significant differences are observed between the SO and temperate waters. Our findings also demonstrate consistency in predicting phytoplankton carbon from either Chl or bbp, suggesting that both methods are applicable in the SO.

Photodegradation stability of marine coatings derived from PVC binder loaded with composite metal oxides particles

Photodegradation stability of marine coatings derived from PVC binder loaded with composite metal oxides particles

Solid, structured composite neutron detectors with high dynamic range capability

Neutron detectors are essential across disciplines such as fundamental science, nuclear security, safeguards, and civilian applications. While 3He-filled gas proportional counters have long been revered for their efficacy in detecting thermal neutrons and praised for their efficiency, neutron/gamma discrimination, and stability, the scarcity of 3He has spurred a search for alternatives. Here, we explore a solid structured scintillating particle composite (SPC) consisting of 6Li-containing scintillating glass particles within an acrylic matrix as a neutron detector for high dynamic range applications. We show for the first time that an SPC neutron detector can boast an intrinsic detection efficiency of 0.261% for pure 252Cf fission neutrons and an overall neutron detection efficiency of (0.546 ± 0.003)% at the Neutron Free-in-Air facility while being able to function in an intense gamma-ray environment. We also show that the SPC neutron detector supports fast neutron capture times and enables a dual-readout scheme that extends the detector dynamic range to high incident neutron fluxes. A scalable fabrication process allows for tailoring the SPC detector properties to the requirements of specific applications. Good agreement is found between the experimental results taken with a National Institute of Standards and Technology traceable 252Cf source and the coupled MCNP6 and optical-ray-tracing simulations.

How Porosity Influences the Heterogeneous Ice Nucleation Ability of Secondary Organic Aerosol Particles

AbstractDuring processing in deep convective cloud systems, highly viscous or glassy secondary organic aerosol (SOA) particles can develop a porous structure through a process known as atmospheric freeze‐drying. This structural modification may enhance their heterogeneous ice nucleation ability under cirrus conditions through the pore condensation and freezing mechanism. Pristine, compact SOA particles, on the other hand, are recommended to be treated as ice‐inactive in models. This recommendation also applies to internally mixed particles, where a coating layer of secondary organic matter (SOM) deactivates the intrinsic ice nucleation ability of the core, which may be a mineral dust grain. Ice cloud‐processing may also improve the ice nucleation ability of such a composite particle by inducing structural changes in the coating layer, which can release active sites on the mineral surface. In this work, we investigated the change in the ice nucleation ability of pure SOA particles from the ozonolysis of α‐pinene and two types of internally mixed particles (zeolite and coal fly ash particles coated with SOM) after being subjected to the atmospheric freeze‐drying process simulated in an expansion cloud chamber. For pure α‐pinene SOA, we found only a slight improvement in the ice nucleation ability of the ice cloud‐processed, porous particles compared to their pristine, compact counterparts at 221 and 217 K. In contrast, the zeolite and coal fly ash particles, which were initially deactivated by the organic coating, became significantly more ice‐active after atmospheric freeze‐drying, emphasizing that such composite particles cannot be excluded from model simulations of heterogeneous ice formation.

Cold-Atom Particle Collider

A major objective of the strong ongoing drive to realize quantum simulators of gauge theories is achieving the capability to probe collider-relevant physics on them. In this regard, a highly pertinent and sought-after application is the controlled collisions of elementary and composite particles, as well as the scattering processes in their wake. Here, we propose particle-collision experiments in a cold-atom quantum simulator for a 1+1D (one spatial and one temporal dimension) U(1) lattice gauge theory with a tunable topological θ term, where we demonstrate an experimentally feasible protocol to impart momenta to elementary (anti)particles and their meson composites. We numerically benchmark the collisions of moving wave packets for both elementary and composite particles, uncovering a plethora of rich phenomena, such as oscillatory string dynamics in the wake of elementary (anti)particle collisions due to confinement. We also probe string inversion and entropy production processes across Coleman’s phase transition through far-from-equilibrium quenches. We further demonstrate how collisions of composite particles unveil their internal structure. Our work paves the way towards the experimental investigation of collision dynamics in state-of-the-art quantum simulators of gauge theories, and sets the stage for microscopic understanding of collider-relevant physics in these platforms. Published by the American Physical Society 2024

ExoLyn: A golden mean approach to multispecies cloud modeling in atmospheric retrieval

Clouds are ubiquitous in exoplanets' atmospheres and play an important role in setting the opacity and chemical inventory of the atmosphere. Understanding clouds is a critical step in interpreting exoplanets' spectroscopic data. The aim is to model the multispecies nature of clouds in atmospheric retrieval studies. To this end, we developed -- a 1D cloud model that balances physical consistency with computational efficiency. solves the transport equation of cloud particles and vapor under cloud condensation rates that are self-consistently calculated from thermodynamics. is a standalone, open source package capable of being combined with optool to calculate solid opacities and with petitRADTRANS to generate transmission or emission spectra. With we find that the compositional structure of clouds in hot Jupiter planets' atmospheres is layered with a cloud dominated by magnesiumsilicates on top of an iron cloud. This finding is consistent with more complex cloud formation models but can be obtained with in only a few seconds. The composition of the cloud particles can be constrained from the spectrum, for example MgSiO3 and Mg2SiO4 components give rise to an absorption feature at $8-10\ m $. We investigate the dependence of the cloud structure on the bulk elemental composition of the planet and find that SiO2 -dominated clouds form on metal-rich planets and Fe clouds with a strong extinction effect form on C-rich planets. Designed toward maximum flexibility can also be used in retrieval analysis of sub-Neptunes and self-luminous planets. The efficiency of opens the possibility of joint retrieval of exoplanets' gas and cloud components.

Effective flexoelectric properties of inclusion-based composites based on strain gradient theory and homogenization technique

This study focuses on enhancing flexoelectricity in composites and develops a new micromechanical analytical framework to determine the effective electromechanical properties of inclusion-based flexoelectric composites within the context of SGE. Initially, we specialize in studying isotropic materials and derive the governing Navier equations for the problem. Subsequently, we streamline these differential equations by introducing a Laplacian-type gradient state variable, departing from higher-order gradient-enrichment treatments. The study employs Green’s functions and stress polarization tensors for spherical inhomogeneities, deriving homogenized material properties through volumetric averages of microscopic properties weighted by displacement localization operators. The analytical scheme’s relevance is validated against results from reference models and experimental data. Effective composite properties are evaluated using numerical methods, with an emphasis on assessing the impact of reinforcement on these properties. Our findings lay the foundation for developing a micromechanical method to predict the electromechanical behavior of composites. Specifically, we demonstrate the efficacy of our proposed theory by deriving effective flexoelectric properties of particulate composites.

The emission and physicochemical properties of airborne microplastics and nanoplastics generated during the mechanical recycling of plastic via shredding

This study examined the emission and physicochemical properties of microplastics and nanoplastics (MPs/NPs) generated during shredding, which is regularly used in mechanical recycling. Waste and new polyethylene terephthalate, polypropylene, and high-density polyethylene were investigated herein for a total of six categories. The concentration and size distribution of particles were measured using two spectrometer instruments, and morphology and elemental composition of emitted particles were analyzed with microscopy and spectroscopy. This study found that number concentrations in both submicron and micron sizes of respirable particles were 3–2910× higher during periods of shredding than pre-shredding background concentrations. Maximum concentrations of particles within 10–420 nm, across all six categories, ranged from 22,000- to 1,300,000-particles/cm3 during shredding, compared to average background levels of 700 particles/cm3. Maximum concentrations of particles within 0.3 to 10 μm, across all six categories, ranged from 24- to 2000-particles/cm3 during shredding, compared to average background levels of 2 particles/cm3. Waste plastics consistently generated higher emissions than their new counterparts, which is attributed to the labels, adhesives, and increased additives incorporated into the waste plastic. Morphology varied drastically between particles and an elemental composition analysis found that the samples consisted primarily of C and O, representing the polymer material, as well as Na, Mg, Al, Si, Cu, Cl, K, Ca, Ti, Fe, Rb, and Br representing additives, label, and other contaminates. The shredding of plastic has the potential to expose workers to elevated concentrations of airborne MPs/NPs, especially those between 10 and 100 nm.

Strong spherical V2O5/TiO2–SiO2 composites obtained by template combined with sol-gel method

This study is devoted to the preparation of strong spherical composites V2O5/TiO2–SiO2 by a combined template and sol-gel method. The composition, size and shape of the colloidal particles in butanol ash with tetrabutoxytitanium and tetraethoxysilane, as well as the physicochemical processes leading to the strengthening of the spherical agglomerates obtained using an anion exchanger with a gel structure, have been determined. Electrophoresis, small-angle X-ray scattering, and viscometry were used to demonstrate the presence in the sol of positively charged colloidal particles of lenticular and cylindrical shape, whose size, when the sol is stabilised, reaches 53 Å. The absorption of the sol by the anion exchanger in vanadium form is due to the equalisation of the osmotic pressure in the anion exchanger/sol system. Spherical composites with a diameter of 300 µm were obtained. It was shown by X-ray diffraction that the composites consist of V2O5 with an orthorhombic structure, TiO2 with an anatase structure, and amorphous silicon dioxide. The interaction at the interface between the phases of V2O5 with TiO2 and SiO2, which leads to the strengthening of the sphere of the V2O5/TiO2–SiO2 composite, has been demonstrated by IR and Raman spectroscopy. The results obtained can be used for the synthesis of MxOy/TiO2–SiO2 oxide composites with spherical agglomerates.

Tunnelling of a Composite Particle in Presence of a Magnetic Field

Tunnelling of a Composite Particle in Presence of a Magnetic Field

Spectral and optic-metric methods of monitoring parameters of plasma channels caused by discharge currents between metals granules in working liquids

Introduction. Spark-erosion processing of metals and alloys granules in working liquids is the basis of a several technological processes. Efficiency of energy use in them and parameters of the resulting product largely depend on the accuracy of stabilization and regulation of pulse power in each plasma channel between the granules. To achieve this, until now only the voltage and current of the discharge pulses in the entire layer of granules have been controlled. Problem. The measurement methods, which are used, are not effective enough for monitoring the parameters of individual plasma channels and predicting the size distribution of eroded metals particles at the stage of their formation. The aim of the work is to develop a method for determining the volumes of components of plasma channels in layers of metals granules during their spark-erosion treatment to predict the size distribution of eroded metal particles at the stage of their formation, as well as to simplify the method of spectrometric analysis of the elemental composition of substances surrounding plasma channels for the operational prediction of the chemical composition of resulting products. Methodology. A series of experiments were carried out on spark-erosion processing of Al and Ag granules layers in distilled water. Using a digital camera, images of the plasma channels in them were obtained. Based on the theory of pulsed electrical breakdown of liquid dielectrics, an analysis of the components of plasma channels was carried out. Using the specialized ToupView program, the volumes of equivalent ellipsoids of rotation were determined, approximating the halos of colored radiation likely arising from streamers, as well as the spark cores of plasma channels emitting white light. The shades of the resulting radiation were studied for several metals and working liquids. The obtained data were compared with the known results of spectrometric studies for the same elements excited by similar mechanisms. Results. The theory of discharge-pulse systems for spark-erosion processing of granular conductive media has been developed in the direction of new methods for monitoring the parameters of discharge pulses and predicting the chemical composition and size distribution parameters of eroded metal particles at the stage of their production. An optic-metric method has been developed for determining the volumes of halos and cores of plasma channels. A simplified spectral method for determining the chemical composition of erosion particles based on the shade of the resulting radiation was proposed. Originality. The developed new optic-metric method makes it possible to obtain information about almost every plasma channel, which refines predictions of the size distribution of erosion particles. To implement the method, general-purpose hardware and specialized software that is freely available are used. The developed method of simplified spectral analysis of excited atoms makes it possible to make preliminary predictions of the chemical composition of the obtained erosion particles already at the stage of their formation without the use of expensive specialized equipment. Practical significance. The ratio of the volumes of halos and cores of plasma channels between Al and Ag granules in distilled water was measured. An analysis of the emission spectra of plasma channel halos between Al, Ag and Cu granules in distilled water, Fe in ethyl alcohol, Ni-Mn-Ga and Ti-Zr-Ni alloys in liquid nitrogen, and Ti-Zr-Ni in liquid argon was carried out. Based on spectrometry data, the resulting shades of these radiations were substantiated and their description in the RGB system is given. References 56, table 1, figures 4.

A molecularly imprinted electrochemiluminescence sensor based on mimic enzyme ZIF-90 and MnO2/g-C3N4 magnetic particles for detection of methidathion.

Methidathion (MTDT), a common organophosphorus pesticide with high insecticidal activity, is widely used for pest control. However, the misuse of MTDT leads to widespread residues and endangers human health. Therefore, it is crucial to develop a simple and highly sensitive method for the detection of MTDT residues. Herein, ZIF-90/MnO2/g-C3N4/Fe3O4 composite particles were synthesized: The MnO2 nanosheets could absorb the energy of the excited g-C3N4 to quench the ECL of g-C3N4 while ZIF-90 acted as a mimetic enzyme to catalyze the formation of thiocholine from MTDT. The thiocholine caused the reduction of MnO2 to Mn2+, restoring the ECL signal of g-C3N4. Combined with molecular imprinting technique, an electrochemiluminescence sensor was constructed for the determination of MTDT. The determination range was 1.00 × 10-9 ~ 7.00 × 10-7g/L, and the detection limit was 6.58 × 10-10g/L. Structurally similar organophosphorus pesticides showed no cross-reactivity. The method has high sensitivity and specificity, and has been successfully applied to the determination of MTDT residue in fruits with recoveries in the range 93.75% ~ 102.37%.

The Effects of Montmorillonite–Humic Acid Composite Particles on the Photolysis of Tetracycline in Water

Suspended particulate matter (SPM) is an important component of natural water bodies and can significantly influence the photolytic behavior of water pollutants. A comprehensive understanding of the photochemical behavior of water pollutants in natural waters requires consideration of the presence of SPM. In this study, montmorillonite–humic acid (MMT-HA) composite particles were synthesized to simulate SPM in natural waters and their effects on the photolysis of tetracycline (TC) were investigated. The results demonstrated that the presence of MMT-HA composite particles in water significantly enhanced the photolysis of TC, with the photolytic kinetics following a pseudo-first-order model. Electron spin resonance spectra and free radical quenching experiments indicated that the photoactive components (MMT and humic acids) in the composite particles induced the generation of reactive oxygen species under light exposure, further contributing to the enhanced photolysis of TC. Comparative analysis of the free radical signals and adsorption experiments revealed that the accelerated photolysis of TC was also related to the interfacial interaction between the MMT in the composite particles and the TC molecules. The formation of surface complexes between TC molecules and the negatively charged sites on the MMT surface facilitated light absorption and electron transfer, thereby accelerating the photolysis of TC. Photoproduct analysis indicated that the primary degradation pathways of TC in the composite particle systems included the addition of hydroxyl radicals to the aromatic ring, as well as demethylation, deamination and dehydration in the side chains. This study shows that SPM in water bodies can affect the photochemical behavior of pollutants and should be taken into account when assessing the phototransformation of pollutants in natural waters.

Differences in distribution and characteristics of microplastics in sediments of the south-eastern part of the Gulf of Trieste

IntroductionThe Gulf of Trieste is prone to the accumulation of various pollutants and microplastics due to its geomorphological and hydrological characteristics. However, the distribution and sources of microplastics in this semi-enclosed area are poorly studied. The aim of our study was to determine the distribution and chemical composition of MP particles in the sediments of the Gulf of Trieste.MethodsIn this study, we collected 24 surface sediment samples using a Van Veen grab. Microplastics were extracted by density separation using NaCl. The size, shape, and color of the extracted microplastics were determined using an optical microscope, and the composition of the polymers was determined by Fourier transform infrared spectroscopy.Results and discussionThe highest concentrations of up to 125 microplastic particles per 100 g dry sediment were found in coastal areas. Concentrations in the open sea were much lower, with an average of 3 particles per 100 g of sediment. Most of the microplastic was fibrous, made of polypropylene, 100–300 µm in size, and blue. This is the first study showing that microplastics are present in the sediments of the south-eastern part of the Gulf of Trieste. The findings suggest that microplastics exhibit a tendency to be retained within the sediment, leading to their accumulation primarily in a narrow coastal area rather than dispersing offshore. Our results will contribute to a better knowledge of the distribution and possible sources of plastics and microplastics in the Gulf of Trieste and even beyond in similar semi-enclosed marine areas.