Characterization Of Particles Research Articles

Quantitative dispersion characterization of cement particles in hardened cement matrix

Optimizing the cement particle distribution in hardened cement matrix is one of the effective means to utilize cement efficiently, and obtaining information about cement distribution is a prerequisite for this. In view of this, this paper investigates the quantitative dispersion of cement particles in hardened cement paste from an experimental perspective. Cement pastes with different water-binder (W/B) ratios were prepared as the objects. BSE images of these samples were acquired for further analysis, including Delaunay triangulation algorithm, nearest neighbor distance function G(r) and fractal theory. Results showed that when the W/B ratio increases from 0.36 to 0.42, the average cement particle spacing rises from 32.7 μm to 34.9 μm and the proportion of particles with spacing between particle centroids <20 μm decreases from 41.96 % to 25.98 %. Similarly, the increasing W/B ratio causes the nearest neighbor distance function G(r) to shift towards larger distances. When the W/B ratio is 0.34, the median distance between particles (R50) exhibits the most significant change. Additionally, the intricate details of cement particle spacing information can be accurately described by fractal theory. Parameters such as R50 and the proportion of particles with spacing between centroids <20 μm demonstrate strong fits with various fractal parameters. Notably, they exhibit optimal fitting with the spectral width of the generalized fractal spectrum, with an R2 value of 0.99.

Contact electrification characteristics of solid oxygen particle-laden flows in liquid hydrogen transportation

The issue of electrostatic safety in liquid hydrogen systems has garnered increasing attention, especially concerning the potential threat of electrostatic explosions due to the collision-electrification phenomenon of solid oxygen particles formed after air leakage in liquid hydrogen pipelines. To delve into the contact electrification characteristics of solid oxygen particle-laden flows in liquid hydrogen transportation, a mathematical model based on the computational fluid dynamics-discrete element method (CFD-DEM) two-phase flow dynamics has been developed. This model integrates the Hertz contact theory for describing particle collision processes and the condenser model for describing particle collision-electrification. The reliability of this model has been validated in existing literature through its ability to capture the flow characteristics of two-phase flow and the electrification characteristics of particle groups. Using density functional theory to compute the solid oxygen work function and considering the low-temperature properties of liquid hydrogen, a series of numerical studies on the flow sedimentation and electrification characteristics of solid oxygen particle-laden flows in liquid hydrogen pipelines have been conducted. The results indicate that particles carry negative charges after colliding with stainless steel pipe walls, with single charge exchange magnitudes of approximately 10−12C for particle-wall continuous collision processes and 10−14C for particle-particle collision processes, resulting in particle charge-to-mass ratios on the order of tens of μC/kg at the outlet interface. The impact of electrostatic forces on particle motion is significant and cannot be overlooked. Furthermore, the effects of velocity, particle diameter, and pipe diameter on particle charge characteristics have been thoroughly analyzed. At low flow velocities, severe particle settlement occurs, leading to increased collision frequency between particles and walls and significant charge accumulation. Increasing flow velocity can mitigate particle settlement and reduce charge levels. Changes in particle and pipe diameters have a minor impact on particle settlement but can increase single charge amounts with larger particle diameters and intensify particle charging with reduced pipe diameters due to shortened radial travel distances, leading to increased collision frequency. Our study meticulously illustrates the charge characteristics of individual particles and particle groups, providing a theoretical basis for assessing the electrostatic safety of liquid hydrogen transportation systems under extreme conditions.

Numerical Modeling of Anisotropic Particle Diffusion through a Cylindrical Channel.

The transport of molecules and particles through single pores is the basis of biological processes, including DNA and protein sequencing. As individual objects pass through a pore, they cause a transient change in the current that can be correlated with the object size, surface charge, and even chemical properties. The majority of experiments and modeling have been performed with spherical objects, while much less is known about the transport characteristics of aspherical particles, which would act as a model system, for example, for proteins and bacteria. The transport kinetics of aspherical objects is an especially important, yet understudied, problem in nanopore analytics. Here, using the Wiener process, we present a simplified model of the diffusion of rod-shaped particles through a cylindrical pore, and apply it to understand the translation and rotation of the particles as they pass through the pore. Specifically, we analyze the influence of the particles' geometrical characteristics on the effective diffusion type, the first passage time distribution, and the particles' orientation in the pore. Our model shows that thicker particles pass through the channel slower than thinner ones, while their lengths do not affect the passage time. We also demonstrate that both spherical and rod-shaped particles undergo normal diffusion, and the first passage time distribution follows an exponential asymptotics. The model provides guidance on how the shape of the particle can be modified to achieve an optimal passage time.

Morphological characterization of concave particle based on convex decomposition

Morphological characterization of concave particle based on convex decomposition

The impact of ammonium hydroxide flow rate on iron oxide nanoparticle hydrodynamic size and colloidal stability

Precise control over the synthesis of iron oxide nanoparticles is essential to achieving optimal particle characteristics such as size, hydrodynamic size, polydispersity index, and zeta potential, all of which significantly influence colloidal stability. The commonly used co-precipitation technique often leads to high polydispersity and variable particle sizes, resulting in poor colloidal stability. This study demonstrates that varying the ammonium hydroxide flow rate during co-precipitation significantly affects particle size, hydrodynamic size, aggregation, and colloidal stability. An optimal flow rate of 4.25 mmol/min produced smaller, more uniform, and colloidally stable nanoparticles. Nanoparticle tracking analysis showed that this flow rate resulted in the smallest and most consistent hydrodynamic size of 123.3 ± 0.7 nm, while both higher and lower flow rates yielded larger and more polydisperse particles, up to 155.8 ± 20 nm. Dynamic light scattering confirmed that the 4.25 mmol/min rate produced the lowest polydispersity index of 0.21 ± 0.04, indicating the highest uniformity. Additionally, UV-Vis measurements demonstrated that nanoparticles synthesized at this optimal flow rate exhibited minimal changes in absorbance over 24 h, indicating superior colloidal stability. This study highlights the importance of optimizing the flow rate during the co-precipitation synthesis of IONPs to control particle hydrodynamic size and polydispersity, which are crucial parameters for numerous biomedical, chemical, and environmental applications.

Quality by Design in Pulmonary Drug Delivery: A Review on Dry Powder Inhaler Development, Nanotherapy Approaches, and Regulatory Considerations.

Dry powder inhalers (DPIs) are state-of-the-art pulmonary drug delivery systems. This article explores the transformative impact of nanotechnology on DPIs, emphasizing the Quality Target Product Profile (QTPP) with a focus on aerodynamic performance and particle characteristics. It navigates global regulatory frameworks, underscoring the need for safety and efficacy standards. Additionally, it highlights the emerging field of nanoparticulate dry powder inhalers, showcasing their potential to enhance targeted drug delivery in respiratory medicine. This concise overview is a valuable resource for researchers, physicians, and pharmaceutical developers, providing insights into the development and commercialization of advanced inhalation systems.

Dynamic characteristics of suspended particles influenced by cavitation bubble in a free field

This study investigates the dynamic characteristics of suspended particles in a free field under the influence of a single cavitation bubble. The phenomenon of suspended particles being influenced by cavitation bubbles of comparable size reflects the dynamic characteristics of particles, a common occurrence in both hydraulic machinery and biopharmaceutical fields. A high-speed camera captures the process of a single cavitation bubble interacting with suspended particles. Combined with three-dimensional numerical simulations, the motion states of suspended particles as the cavitation bubble expands and contracts are analyzed. Observations reveal that at various initial distances between suspended particles and the cavitation bubble, suspended particle motion is consistently influenced by the expansion and contraction of the same cavitation bubble during the initial four processes. The particle motion direction is parallel to the propagation direction of the radiation force produced during the expansion and collapse of the cavitation bubble, consistent with the characteristics of motion under longitudinal wave effects. The initial distance between suspended particles and the cavitation bubble dictates the ultimate displacement direction of suspended particles, with the influence of the cavitation bubble on suspended particle velocity weakening as their distance increases. Under conditions where particle size closely matches that of the bubble, the jet produced by the cavitation bubble does not significantly accelerate particles, and the influence of the jet on suspended particle motion states could be disregarded. The investigation reveals that the suspended particles are primarily influenced by the radiation force, drag force, and virtual mass force exerted by the cavitation bubble.

Numerical simulations of exocomet transits: Insights from β Pic and KIC 3542116

In recent years, the topic of existence and exploration of exocomets has been gaining increasing attention. The asymmetrical decrease in the star’s brightness due to the passage of a comet-like object in front of the star was successfully predicted. It was subsequently confirmed on the basis of the light curves of stars observed by Kepler and TESS orbital telescopes. Since then, there have been successful attempts to fit the asymmetrical dips observed in the stars’ light curves utilizing a simple 1D model of an exponentially decaying optically thin dust tail. In this work, we propose fitting the photometric profiles of some known exocomet transits based on a Monte Carlo approach to build up the distribution of dust particles in a cometary tail. As the exocomet prototypes, we used the physical properties of certain Solar System comets belonging to the different dynamical groups and moving at heliocentric distances of 0.6 au, 1.0 au, 5.0 au, and 5.5 au. We obtained a good agreement between the observed and modeled transit light curves. We also show that the physical characteristics of dust particles, such as the particle size range, the power index of dust size distribution, the particle terminal velocity, and distance to the host star affect the shape of the transit light curve, while the dust productivity of the comet nucleus and the impact parameter influence its depth and duration. The estimated dust production rates of the transiting exocomets are at the level of the most active Solar System comets.

Simulation Study of Motion Characteristics of Fiber Impurity Particles Under Oil Flow and Dielectric Barrier

Simulation Study of Motion Characteristics of Fiber Impurity Particles Under Oil Flow and Dielectric Barrier

CPFD Simulation of Hydrodynamic Characteristics of Multiple Particles Mixing in a Circulating Fluidized Bed

CPFD Simulation of Hydrodynamic Characteristics of Multiple Particles Mixing in a Circulating Fluidized Bed

Enhancing mechanical and corrosion properties of GO and Al2O3 reinforced Cu composite coatings

Despite their significant functions and properties, the performance characteristics of Al2O3 ceramic particles and graphene oxide (GO) within hybrid copper composite coatings have been seldom investigated. This study successfully fabricated a Cu-GO- Al2O3 composite coating featuring fine particulate spherical network-like structures on St37 low carbon steel using an ultrasonic-electroless coating method. The effects of Al2O3-decorated graphene oxide hybrid reinforcement on the texture and nanomechanical properties of the copper matrix were examined. The tribological performance of the Cu-GO- Al2O3 composite coating under dry sliding conditions was evaluated, and the wear mechanism was investigated in detail. Results demonstrate that the Cu-GO- Al2O3 composite coating effectively reduces the wear rate and friction of the GO/ Al2O3 hybrid reinforced composite coating. Potentiodynamic polarization tests indicated that the Cu-GO- Al2O3 composite coating exhibits higher corrosion resistance compared to the copper matrix. The enhanced mechanical, tribological, and corrosion properties of the Cu-GO- Al2O3 composite coating are primarily attributed to: (i) the fine particulate spherical network-like structure; (ii) the synergistic effect of the GO and ceramic particle hybrid with a decorated structure; (iii) the formation of graphene oxide/ Al2O3 nanorolls in tribofilms and the excellent self-lubrication properties of graphene oxide. The Cu-GO- Al2O3 composite coating significantly improves the frictional and electrochemical properties of the copper matrix, offering new perspectives for next-generation electrical contacts and nanoelectromechanical systems.

Characterization of Si particles in additively manufactured AlSi10Mg using synchrotron transmission X-ray nanotomography

Abstract In AlSi10Mg samples manufactured by Laser Powder Bed Fusion, distinguishing the Si eutectic network/Si particles from the Al matrix by X-ray imaging is challenging due to the low absorption contrast between the Al and Si. This work investigates the possibility of overcoming this obstacle in synchrotron transmission X-ray microscopy. Effects of both different defocusing conditions and X-ray beam energies are evaluated and optimal conditions are identified for imaging a sample annealed post-print for 2h at 520°C. It is shown that both large particles (e.g. 4μm) and particles as small as 0.5 μm, can be imaged with reasonable precision in 3D non-destructively.

Characterization of plasma parameters and neutral particles in microwave and radio frequency discharges in the Toroidal Magnetized System.

A characterization of plasma parameters and neutral particle energies and fluxes has been performed for radio frequency and microwave discharges in the Toroidal Magnetized System (TOMAS). A movable triple Langmuir probe was used to study the electron densities and temperatures, and a time-of-flight neutral particle analyzer was used to measure the energy and fluxes of neutral particles, as a function of the total injected power and the antenna frequency used to generate the plasma. The experimental results can provide information on the behavior of neutral particles at low energies in wall conditioning plasmas.

Development of curcumin-loaded lipid nanocapsules for drug delivery across mucus

This study aimed to develop and characterize lipid nanocapsules (LNCs) for mucosal delivery. Curcumin loaded–LNCs (CCM–LNCs) were prepared by phase inversion temperature (PIT) method. Particle characteristics, morphology, entrapment efficiency (EE) and loading capacity were determined. Mucopenetration studies were conducted by Transwell® plate and tube methods. CCM solution served as control.Particle size and zeta-potential of the CCM-loaded LNCs were 67.47 ± 0.15 nm and −32.86 ± 2.51 mV. EE and loading capacity of CCM–LNCs was found to be 98.38 ± 0.45 % and 42.24 ± 2.24 %, respectively. No significant change on stability of CCM–LNCs was found after 30 days storage. CCM–LNCs could penetrate mucus 3 times deeper than CCM solution. Moreover, the delivered amount of CCM across mucus layer was 6 folds higher compared with CCM solution. LNCs with negative charge could be used as a promising particulate delivery system for delivering BCS class IV drug such as CCM across mucus.

Clogging of Noncohesive Suspension Flows

Abstract When flowing through narrow channels or constrictions, many-body systems exhibit various flowing patterns, yet they can also get stuck. In many of these systems, the flowing elements remain as individuals (they do not aggregate or merge), sharing strong analogies among each other. This is the case for systems as contrasting as grains in a silo and pedestrians passing through tight spaces. Interestingly, when these entities flow within a fluid medium, numerous similarities persist. However, the fluid dynamics aspects of such clogging events, such as interstitial flow, liquid pressure, and hydrodynamic interactions, has only recently begun to be explored. In this review, we describe parallels with dry granular clogging and extensively analyze phenomena emerging when particles coexist with fluid in the system. We discuss the influence of diverse flow drive, particle propulsion mechanisms, and particle characteristics, and we conclude with examples from nature.

Real-time dynamic measurement of scattering characteristics of optically-levitated fly ash interacting with water-soluble ammonium sulfate aerosol

This paper proposes a coupled laser levitation and scattering measuring system to realize real-time dynamic measurement of scattering characteristics of individual fly ash particles interacting with water-soluble ammonium sulfate aerosols of different concentrations. The scattering coefficients, absorption coefficients, and phase functions of aerosols were calculated. The disparities in scattering characteristics interacting fly ash with ammonium sulfate, and the impact of typical influencing parameters on the scattering characteristics were discussed in detail. The findings highlighted that the scattering characteristics of aerosols followed with those of Mie particles, with an increase in the particle size leading to an enhancement in the forward scattering intensity. Notably, dynamic measurement demonstrated that the scattering intensity with high ammonium sulfate concentrations (≥1 mol/L) showed an upward trend, exerting a more pronounced impact than low-concentration counterparts. Furthermore, the particle size has a stronger effect on the scattering characteristics than the complex refractive index induced by varying concentrations.

The influence of self-assembled particle layer on particle collision properties

Interactions between particle and particle layers are fundamental in modeling deposition processes. The complex mechanical behaviors of these layers pose significant challenges in precisely predicting the rebound characteristics of incident particle, especially at the micron and nanoscale. Very few related experimental studies have been reported in this area. To better control the structure of particle layers and offer a path to more systematic research, this study introduces the particle self-assembly method, combined with high-speed imaging technology, to investigate the influence of particle monolayer, their diameters, and impact velocity on critical capture velocity (vcr), normal coefficient of restitution (COR), and angle deflection of incident particles. Results indicate that self-assembled particle layers remain stable within an impact velocity range and experimental data within this stable range exhibit good repeatability. These layers significantly enhance kinetic energy dissipation. A semi-logarithmic plot revealed a negative linear relationship between vcr and particle size ratio. The effect of particle layer on COR depends on particle layer diameter and impact velocity. Specifically, the dissipation of particle layer diminishes and approaches zero for smaller layer particles (0.5 μm), but increases and stabilizes for larger particles (2 μm). Moreover, statistical results indicate that angle deflection decreases as particle size ratio increases, aligning with a power-law relationship predicted by Monte Carlo simulations. Overall, this study presents a novel method for understanding micro and nano particle layers' influence on incident particle dynamics.

Multiple Satellite Observations of the High‐Latitude Cusp Aurora During Northward IMF Conditions

AbstractCusp auroras poleward of the typical auroral oval are ascribed to high‐latitude lobe reconnection when the Interplanetary Magnetic Field (IMF) Bz is predominantly northward. In this study, we further investigate the ionospheric characteristics of a unique high‐latitude cusp region employing multiple satellite observations. A cusp aurora event with wide spatial spread was observed in the postnoon polar cap region. It was found to be associated with northward IMF Bz and positive By components. The cusp aurora was located from 68° to 86° in magnetic latitude and within 15–17 hr in magnetic local time. This broad coverage in the polar cap indicates direct precipitating particles from the magnetosheath. Particle energy is different between the equatorward and poleward edges of the cusp aurora. The precipitating ions at the equatorward side maintain magnetosheath particle characteristics as expected, while ions with higher energies occurred in the poleward side. Further, the poleward edge of the cusp aurora was nearly situated in the center of a convection shear and was associated with an upward field‐aligned current. These observations suggest a lobe cell circulation, hence we attribute the formation of the cusp aurora to the high‐latitude lobe reconnection. Simultaneous observations in the southern hemisphere indicate the absence of cusp aurora. The auroral presence only in the northern hemisphere is probably due to the combination of large dipole tilt angle and positive IMF Bz, which facilitates the lobe reconnection.

Modeling the settling and resuspension of microplastics in rivers: Effect of particle properties and flow conditions

Microplastics have numerous different shapes, affecting the fate and transport of these particles in the environment. However, theoretical models generally assume microplastics to be spherical. This study aims to develop a modeling approach that incorporates the shapes of microplastics to investigate the vertical transport of microplastics in rivers and simulate the effect of particle and flow characteristics on settling and resuspension. To achieve these aims, a mechanistic model was developed utilizing the mass-balance and hydrodynamic equations. Scenario analysis was implemented assigning different values to model parameters, such as bed shear stress, shape factor and particle size to simulate the effect of flow patterns and particle properties. The model outcomes revealed that the residence time of microplastics in the water column was longest in medium bed shear stress, whilst it was shortest in low bed shear stress. This suggests that the influence of turbulence is not unidirectional; it can both increase and decrease microplastic concentrations and residence time in the water column. According to the scenario analysis, the settling flux of microplastics was the highest for near-spherical particles and increased with the size of the particles, as well as with increasing bed shear stress. However, the resuspension of particles was primarily influenced by increasing bed shear stress, but the ranking of resuspension flux values for different shaped and sized microplastics exhibited alterations with changing flow patterns. Turbulent conditions predominantly influenced the resuspension of near-spheres and large microplastics. On the contrary, the settling of fibers and small microplastics were significantly influenced by changing flow patterns, whereas near-spheres and largest particles were least affected. The model results were sensitive to changes in shape factor developed for this model, therefore this parameter should be improved in future studies.

A study on the motion characteristics of particle in shear flow of active nematic fluid between two plates

Abstract The motion characteristics of particle in shear flow of active nematic fluid between two plates are investigated numerically. The influence of activity intensity of active nematic fluids on the motion characteristics of particle is focused. The results showed that, when the activity intensity is high, the particle exhibits initially smooth trajectories and ultimately approximate Brownian motion. As the activity intensity increases, both the translational mean square displacement (MSDT) and rotational mean square displacement (MSDR) of the particle increase. The particle exhibits initially super-diffusive behavior and then normal diffusion. The unique vortex lattice mode in the flow plays a role in hindering particle motion, leading to a decrease in MSDT and MSDR. An increase in particle size will lead to a weakening of particle diffusion. In addition, there are topological defects in the active nematic fluid, and the number of topological defects N def in the contractile system is greater than that in the extensible system, while the presence of particle has a smaller impact on N def in the flow.