The coal-series kaolin in China possesses abundant resources, and its efficient utilization can be promoted by separation. In this paper, a cascade electrostatic field was designed for the triboelectric separation of coal-series kaolin. The motion behavior of charged particles with different size fraction in cascade electrostatic field was investigated by high-speed dynamic camera system, and the distribution characteristic of charge-to-mass ratio of products was analyzed by the coulometer. The influence of key operating parameters (e.g., feed speed, rotation speed and plate voltage) on product distribution were studied by electric separation test. The results indicated that the charge-to-mass ratio of the product after separation has the characteristics of cascade distribution. In addition, compared with 0.05–0.25 mm and 0.25–0.125 mm, the dispersion performance of 0.125–0.074 mm coal-series kaolin in the cascade electrostatic field was poor. For 0.5–0.25 mm, 0.125–0.25 mm and 0.074–0.125 mm coal-series kaolin, the decarburization efficiency after separation in cascade electric field was 47.09 %, 53.48 % and 44.63 %, respectively. Our study indicates that the setting of cascade electrostatic field achieved efficient purification and enrichment of coal-series kaolin.
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