TWO years ago, we reported2 some preliminary measurements on the ionization produced in liquid carbon disulphide by x-rays. Our interest in the problem lies in its possible application to medical dosage in cases in which we wish to measure the total number of ions produced in tissue-equivalent material. While it is impossible to attain saturation conditions in liquids, as is common with gases, we have shown that the saturation current may be deduced by plotting the reciprocal of the current against the reciprocal of the applied voltage, V, and extrapolating linearly to 1/V = 0. For high fields the plot is nearly linear in accord with Jaffé's theory of columnar ionization (1, 2). However, when a steady direct current potential is applied to a liquid ionization chamber, a barrier potential arising from a space charge or surface layer is built up, which quickly reduces the field in the liquid to roughly 45 per cent of the applied value. This barrier potential reaches an appreciable value in a small fraction of a second but does not attain its maximum magnitude for about ten minutes, during which interval the measured ionization current decreases exponentially. Figure 1 shows the measured ionization current, as a function of the lapse of time for a succession of different potentials applied to the plates of the ionization chamber—with and without x-radiation. It is seen that for each increase in voltage, with x-rays on, the ionization current rises to a high value, then falls off, rapidly at first, to an essentially steady value in about ten minutes. As indicated, this is caused by the building up within the cell of a barrier potential. If, on the other hand, the applied potential be decreased, the ionization current drops abruptly to a low value, then gradually rises again to a considerably higher steady value in about the same ten-minute period. This second sequence results from the partial dissipation of the barrier potential set up by the higher applied voltage and consequently increases the field strength within the liquid. Finally, if the applied potential be removed and the circuit closed, the ionization chamber becomes itself a transient source of current. It is interesting to note, also, how the space charge depends upon other factors associated with the use of a liquid ionization chamber. In Figure 2 the barrier potential is plotted against the potential actually applied to the plates of the chamber. Curves A show that, without x-rays, the barrier potential is proportional to—about 45 per cent of—the applied potential. That is, the barrier potential, in the steady state, makes the field strength within the liquid about half that to be expected from the applied voltage. Curves B show that for a definite applied voltage, the barrier potential decreases with increase in the intensity of the x-rays producing the ionization. Contrary, perhaps, to expectations, this decrease in barrier potential is due to the increased conductivity of the liquid which permits a more rapid dissipation of the space charge.
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