A method to calculate the excitation spectra of the impurity Anderson model based on the numerical renormalization group technique is reviewed. The single particle and the magnetic excitation spectra are calculated for the cases of various magnitudes of the 1-1 Coulomb interaction to compare them with experimentally observed broad PES-BIS spectra in U-compounds. Excitation spectra in the Kondo limit are also examined in detail. The Kondo effect due to the magnetic ions with complex multiplet structures, such as the Sm- and the Tm·like ions, is studied. The excitation spectra of the two impurity Anderson model are calculated and roles of the parity splitting are discussed. In this paper we review our recent. calculation for the excitation spectra of the impurity Ande:r;son model. The method of calculation is developed based on the numerical renormalization group (NRG) technique which has been originally introduced by Wilson to study the thermodynamic properties of the Kondo problem. 1 >,z> The purposes of the calculation are three folds. The first one is to study the single particle excitation (SPE) spectra of the impurity Anderson model in wide energy range. 3 >' 4 > We study roles of the atomic/-/ Coulomb interaction in the origin of the broad PES-BIS spectra of U-compounds, in which the atomic interactions and the c-/ hybridization are expected to have comparable magnitude. The second one is to study the dynamical excitation spectra of the Kondo problem. Several approximation schemes have been developed to study the dynami cal properties of the problem, but exact excitation spectra at very low temperature have not been obtained before our calculation. We calculate the spectra of SPE, magnetic and charge excitations in the low energy region of the order of the Kondo · temperature, TK., carefully. 5 >
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