Parallel Stripes Research Articles

High piezoelectric performance and domain configurations of (K0.45Na0.55)0.98Li0.02Nb0.76Ta0.18Sb0.06O3 lead-free ceramics prepared by two-step sintering

Research for high-performance lead-free piezoelectric materials has become an urgent issue from the environmental concern. Very limited attempts on two-step sintering had been made so far. In this study, (K0.45Na0.55)0.98Li0.02Nb0.76Ta0.18Sb0.06O3 ceramics were prepared by both conventional sintering and two-step sintering. Piezoelectric properties, microstructure and domain structure were found to change significantly with sintering methods and sintering conditions. Two-step sintering was performed in the way that temperature is first quickly raised to 1180 °C, kept for 1 min, then immediately cooled down to 1120 °C and maintained for a desired time length. The effects of dwelling time on piezoelectric performance and microstructure as well as domain structure were investigated. High piezoelectric properties of d33 = 455 pC/N, kp = 0.54 and k33 = 0.67 were obtained in a ceramic prepared under the dwelling time of 20 h. This ceramic also possesses a very good piezoelectric thermal-ageing stability over −50 °C–150 °C. Further investigation reveals that this ceramic has a quite uniform grain-size distribution with the average grain size of about 12 μm in microstructure and shows domain patterns of simple parallel stripes with a hierarchical nanodomain structure appearing inside some of broad stripes. The observed excellent piezoelectric performance is considered to associate closely with the unique domain structure.

Periodic pattern formation in an achiral bent core nematic

We investigated a periodic flexoelectric domain pattern, which appeared as regular parallel stripes in an achiral bent core nematic liquid crystal when dc electric field was applied. We found that such a pattern was first formed at the substrate surface and took place in sandwich cells with a gap larger than 2μm. The field-induced periodic pattern was preserved in the field-off state by a polymer network formed in the cell and was found to exhibit a polar as well as a linear electro-optic response due to in-plane switching of the sample optic axis. A comparison between this response and the one obtained in short cholesteric liquid crystals, aligned in ULH (uniform lying helix) texture, and short pitch ferroelectric liquid crystals, respectively, suggested that a heliconical molecular order is most probably formed in the field-induced periodic stripe pattern, with the helix axis orthogonal to the stripes. To our knowledge, this is the first experimental evidence of field-induced chiral-symmetry breaking in the flexoelectric periodic stripe pattern in achiral bent core nematic, resulting in heliconical molecular order, resembling the one of twist-bend (TB) nematic phase in this kind of nematics.

Shape Evolution of Droplets Growing on Linear Microgrooves.

Anisotropic spreading of liquids and elongated droplet shapes are often encountered on surfaces decorated with a periodic micropattern of linear surface topographies. Numerical calculations and wetting experiments show that the shape evolution of droplets that are slowly growing on a surface with parallel grooves can be grouped into two distinct morphological regimes. In the first regime, the liquid of the growing droplet spreads only into the direction parallel to the grooves. In the second regime, the three-phase contact line advances also perpendicular to the grooves, whereas the growing droplets approach a scale-invariant shape. Here, we demonstrate that shapes of droplets in contact with a large number of linear grooves are identical to the shapes of droplets confined to a plane chemical stripe, where this mapping of shapes is solely based on the knowledge of the cross section of the linear grooves and the material contact angle. The spectrum of interfacial shapes on the chemical stripe can be exploited to predict the particular growth mode and the asymptotic value of the base eccentricity in the limit of droplets covering a large number of grooves. The proposed model shows an excellent agreement with experimentally observed base eccentricities for droplets on grooves of various cross sections. The universality of the model is underlined by the accurate match with available literature data for droplet eccentricities on parallel chemical stripes.

Cycloidal Domains in the Magnetization Reversal Process of Ni80Fe20/Nd16Co84/Gd12Co88 Trilayers

In multilayers with weak perpendicular magnetic anisotropy, nucleation of magnetic vortex-antivortex pairs at the surfaces is set by topological characteristics, yielding a robust means to control vortex motion in extended films. However, exploiting this effect in digital memory devices would require a suitably broad range of fields supporting guided vortex motion. X-ray microscopy reveals cycloidal domains at the top surface with a stability range of tens of mT, in which propagation of magnetic vortices is effectively guided by the pattern of parallel stripes. This finding is an essential step toward the possible application of moving magnetic vortices in unpatterned films.

Self-assembly of polystyrene microspheres into two-level hierarchical structures

Two-level arrays of colloidal particles have been obtained using the method based on an intermittent, ‘‘stick–slip’’ motion of the meniscus during colloidal suspension evaporation. The ethanol suspension of monodisperse polystyrene microspheres of about 1 μm in size was prepared by emulsifier-free emulsion polymerization of styrene with potassium persulphate as an initiator. The resulting structures consist of parallel monolayer stripes of deposited microspheres, repeated with a period of 140–150 μm, and empty spaces between them. The microspheres are packed into a hexagonal structure inside the stripes. Laser diffraction patterns have been demonstrated for both levels of ordering, i.e., for the hexagonal structure at the first level and for the parallel stripes at the second level.

Modeling of X-ray images of Tycho’s supernova remnant

High-resolution Chandra X-ray observations of Tycho’s supernova remnant (SNR 1572) have revealed several series of bright, nearly parallel stripes in some regions of the SNR clearly seen in 4-6 keV band images. The observed radiation of Tycho’s SNR is most likely the synchrotron radiation of electrons with energies well above TeV. In this paper we present the modeling of synchrotron X-ray images of Tycho’s SNR in order to reveal the physical mechanism of the observed coherent structures formation. It is shown that the mirror instability, which evolves in plasma near SNR shock as a result of anisotropic distribution function of accelerated particles, can be the reason of the bright stripes.

Comparison of Cliff-Lorimer-Based Methods of Scanning Transmission Electron Microscopy (STEM) Quantitative X-Ray Microanalysis for Application to Silicon Oxycarbides Thin Films.

In this work, we compare the results of different Cliff-Lorimer (Cliff & Lorimer 1975) based methods in the case of a quantitative energy dispersive spectrometry investigation of light elements in ternary C-O-Si thin films. To determine the Cliff-Lorimer (C-L) k-factors, we fabricated, by focused ion beam, a standard consisting of a wedge lamella with a truncated tip, composed of two parallel SiO2 and 4H-SiC stripes. In 4H-SiC, it was not possible to obtain reliable k-factors from standard extrapolation methods owing to the strong CK-photon absorption. To overcome this problem, an extrapolation method exploiting the shape of the truncated tip of the lamella is proposed herein. The k-factors thus determined, were then used in an application of the C-L quantification procedure to a defect found at the SiO2/4H-SiC interface in the channel region of a metal-oxide field-effect-transistor device. As in this procedure, the sample thickness is required, a method to determine this quantity from the averaged and normalized scanning transmission electron microscopy intensity is also detailed. Monte Carlo simulations were used to investigate the discrepancy between experimental and theoretical k-factors and to bridge the gap between the k-factor and the Watanabe and Williams ζ-factor methods (Watanabe & Williams, 2006).

Crystallization-Induced Morphological Tuning Toward Denim-like Graphene Nanosheets in a KCl-Copolymer Solution.

Although nucleation and crystallization in solution-processed materials synthesis is a natural phenomenon, the morphology design of graphene nanosheets by controlling the dual crystallization has not been established. In this work, we systematically demonstrate how the dual crystallization of ice and potassium chloride induces the morphological variation of the freeze-dried scaffold from fractal structure toward stepped sheet-like structure. A denim-like graphene nanosheet (DGNS) has been fabricated by annealing the F127-coated stepped sheet-like scaffold in nitrogen. DGNS shows parallel and straight stripes with an average stripe spacing of 10 nm. When used as a lithium-ion battery anode, DGNS possesses a superhigh reversible capacity of 1020 mAh g-1 at the current density of 1 A g-1 after 600 cycles. This work reports the control of dual crystallization of ice and salt crystals and provides an efficient way to design the morphology of two-dimensional materials by adjusting the crystallization.

Pattern‐forming fronts in a Swift–Hohenberg equation with directional quenching — parallel and oblique stripes

We study the effect of domain growth on the orientation of striped phases in a Swift-Hohenberg equation. Domain growth is encoded in a step-like parameter dependence that allows stripe formation in a half plane, and suppresses patterns in the complement, while the boundary of the pattern-forming region is propagating with fixed normal velocity. We construct front solutions that leave behind stripes in the pattern-forming region that are parallel to or at a small oblique angle to the boundary. Technically, the construction of stripe formation parallel to the boundary relies on ill-posed, infinite-dimensional spatial dynamics. Stripes forming at a small oblique angle are constructed using a functional-analytic, perturbative approach. Here, the main difficulties are the presence of continuous spectrum and the fact that small oblique angles appear as a singular perturbation in a traveling-wave problem. We resolve the former difficulty using a farfield-core decomposition and Fredholm theory in weighted spaces. The singular perturbation problem is resolved using preconditioners and boot-strapping.

Tuning the order of colloidal monolayers: assembly of heterogeneously charged colloids close to a patterned substrate.

We study the behavior of negatively charged colloids with two positively charged polar caps close to a planar patterned surface. The competition between the different anisotropic components of the particle-particle interaction is able by itself to give rise to a rich assembly scenario: colloids with charged surface patterns already form different crystalline domains when adsorbed to a homogeneously charged substrate. Here we consider substrates composed of alternating (negative/neutral, positive/neutral and positive/negative) parallel stripes and, by means of Monte Carlo simulations, we investigate the ordering of the colloids on changing the number of the stripes. We show that the additional competition between the two different lengths scales characterizing the system (i.e., the particle interaction range and the size of the stripes) gives rise to a plethora of distinct particle arrangements, where some well-defined trends can be observed. By accurately tuning the substrate charged motif it is possible to, e.g., promote specific particle arrangements, disfavor crystalline domains or induce the formation of extended, open clusters.

Numerical Investigation of Tunable Plasmonic Tweezers based on Graphene Stripes

We are proposing tunable plasmonic tweezers, consisting two parallel graphene stripes, which can be utilized to effectively trap and sort nanoparticles. We show that by electrostatically tuning the chemical potential of a graphene stripe by about 100 meV (equivalent to ΔVG ≈ 4.4 V), the plasmonic force can be switched efficiently, without a need to switch the laser intensity. This enables high speed and low power switching with a large number of switching cycles. By applying two independent and appropriate gate bias voltages to the stripes, the direction of the plasmonic force can be reversed, which leads to separation of nanoparticles that satisfy the trapping conditions. Numerical simulations show that the potential depths obtained for polystyrene nanoparticles of refractive index n = 1.5717 and radii r ≥ 50 nm is deeper than −10 kBT , confirming the ability of the proposed system to effectively separate such nanoparticles. This capability holds for smaller nanoparticles with larger refractive indices. Finally, performing thermal simulations, we have demonstrated that the heat induced by the illumination increases the fluid temperature by at most 9 °C, having negligible effect on the trapping mechanism. The proposed system opens up new possibilities in developing tunable on-chip manipulation devices, suitable for biological applications.

Micromagnetic Simulations of Magnetization Spatial Distribution in Ultrathin Cobalt Layers With Gradient Magnetic Anisotropy

Spatial distribution of magnetization in an ultrathin ferromagnetic Co layer with a lateral gradient of magnetic anisotropy, while approaching spin reorientation transition (SRT) (from perpendicular to in-plane magnetization alignment), has been investigated by means of micromagnetic simulations in the 2-D mode, using OOMMF software. The geometry of the out-of-plane-magnetized domains (parallel stripes, labyrinth, and bubbles) has been found to be dependent on both the initial distribution of magnetization and the direction of the applied magnetic field. A fast decrease in the domain size has been observed while moving toward SRT. In the experiment, Pt/Co/Pt layers with initial in-plane magnetization orientation have been irreversibly modified by femtosecond laser pulses. In the irradiated spot, rings with induced perpendicular magnetic anisotropy have been formed, resulting in an appearance of several local SRTs. Magnetic domain structure in the SRT regions has been visualized using magnetic force microscopy. The experimental observations are qualitatively explained by the results of the micromagnetic simulations.

Toward nonlinear magnonics: Intensity-dependent spin-wave switching in insulating side-coupled magnetic stripes

We demonstrate that the nonlinear spin-wave transport in two laterally parallel magnetic stripes exhibit the intensity-dependent power exchange between the adjacent spin-wave channels. By the means of Brillouin light scattering technique, we investigate collective nonlinear spin-wave dynamics in the presence of magnetodipolar coupling. The nonlinear intensity-dependent effect reveals itself in the spin-wave mode transformation and differential nonlinear spin-wave phase shift in each adjacent magnetic stripe. The proposed analytical theory, based on the coupled Ginzburg-Landau equations, predicts the geometry design involving the reduction of power requirement to the all-magnonic switching. A very good agreement between calculation and experiment was found. In addition, a micromagnetic and finite-element approach has been independently used to study the nonlinear behavior of spin waves in adjacent stripes and the nonlinear transformation of spatial profiles of spin-wave modes. Our results show that the proposed spin-wave coupling mechanism provides the basis for nonlinear magnonic circuits and opens the perspectives for all-magnonic computing architecture.

Spatially-resolved optical and structural properties of semi-polar mathrm{(11}bar{2}mathrm{2)} AlxGa1\u2212xN with x up to 0.56

Pushing the emission wavelength of efficient ultraviolet (UV) emitters further into the deep-UV requires material with high crystal quality, while also reducing the detrimental effects of built-in electric fields. Crack-free semi-polar mathrm{(11}bar{2}mathrm{2)} AlxGa1−xN epilayers with AlN contents up to x = 0.56 and high crystal quality were achieved using an overgrowth method employing GaN microrods on m-sapphire. Two dominant emission peaks were identified using cathodoluminescence hyperspectral imaging. The longer wavelength peak originates near and around chevron-shaped features, whose density is greatly increased for higher contents. The emission from the majority of the surface is dominated by the shorter wavelength peak, influenced by the presence of basal-plane stacking faults (BSFs). Due to the overgrowth technique BSFs are bunched up in parallel stripes where the lower wavelength peak is broadened and hence appears slightly redshifted compared with the higher quality regions in-between. Additionally, the density of threading dislocations in these region is one order of magnitude lower compared with areas affected by BSFs as ascertained by electron channelling contrast imaging. Overall, the luminescence properties of semi-polar AlGaN epilayers are strongly influenced by the overgrowth method, which shows that reducing the density of extended defects improves the optical performance of high AlN content AlGaN structures.

Directed droplet motion induced by vibration of the solid support

The unidirectional motion of a droplet settled on an energetically heterogeneous surface undergoing mechanical vibration is studied by means of simulations with a finite element method performed by the Surface Evolver simulation program. The surface energy inhomogeneities are represented by a pattern of a series of parallel stripes of monotonically increasing width and two alternating contact angles. In certain circumstances, the observed shift of the droplet is perpendicular to the stripes and directed toward the increasing width of the stripes. The influence of model parameters on the trajectory of the droplet is discussed. A full profile of the droplet energy along the droplet trajectory was estimated on the basis of density distribution of positions occupied by the droplet along the travel coordinates. The influence of model parameters on the trajectory of the droplet is discussed. On the basis of the asymmetric properties of the energy profile, the ratchet mechanism of unidirectional droplet motion was postulated.

Coupling and braiding Majorana bound states in networks defined in two-dimensional electron gases with proximity-induced superconductivity

Two-dimensional electron gases with strong spin-orbit coupling covered by a superconducting layer offer a flexible and potentially scalable platform for Majorana networks. We predict Majorana bound states (MBSs) to appear for experimentally achievable parameters and realistic gate potentials in two designs: either underneath a narrow stripe of a superconducting layer (S-stripes) or where a narrow stripe has been removed from a uniform layer (N-stripes). The coupling of the MBSs can be tuned for both types in a wide range (< 1 neV to >10 $\mu$eV) using gates placed adjacent to the stripes. For both types, we numerically compute the local density of states for two parallel Majorana-stripe ends as well as Majorana trijunctions formed in a tuning-fork geometry. The MBS coupling between parallel Majorana stripes can be suppressed below 1 neV for potential barriers in the meV range for separations of about 200 nm. We further show that the MBS couplings in a trijunction can be gate-controlled in a range similar to the intra-stripe coupling while maintaining a sizable gap to the excited states (tens of $\mu$eV). Altogether, this suggests that braiding can carried out on a time scale of 10-100 ns.

Apparent slip of shear thinning fluid in a microchannel with a superhydrophobic wall.

The peculiarities of simple shear flow of shear thinning fluids over a superhydrophobic wall consisting of a set of parallel gas-filled grooves and solid stripes (domains with slip and stick boundary conditions) are studied numerically. The Carreau-Yasuda model is used to provide further insight into the problem of the slip behavior of non-Newtonian fluids having a decreasing viscosity with a shear rate increase. This feature is demonstrated to cause a nonlinear velocity profile leading to the apparent slip. The corresponding transverse and longitudinal apparent slip lengths of a striped texture are found to be noticeably larger than the respective effective slip lengths of Newtonian liquids in microchannels of various thicknesses and surface fractions of the slip domains. The viscosity distribution of the shear thinning fluid over the superhydrophobic wall is carefully investigated to describe the mechanism of the apparent slip. Nonmonotonic behavior of the apparent slip length as a function of the applied shear rate is revealed. This important property of shear thinning fluids is considered to be sensitive to the steepness of the viscosity flow curve, thus providing a way to decrease considerably the flow resistance in microchannels.

Compaction of polydimethylsiloxane due to nitrogen ion irradiation and its application for creating microlens arrays

In this work the change in the surface topography of polydimethylsiloxane (PDMS) due to irradiation with 10.5MeV N4+ ion microbeam is investigated. Parallel stripes with different widths and different gaps between the stripes were irradiated. The heavy ion beam induced physical and chemical processes caused shrinkage of the irradiated structures. The degree of compaction, and its relation to the irradiation fluence and pattern was studied by means of atomic force microscopy (AFM). Exploiting the compaction effect, arrays of microlenses with different diameters were designed and fabricated in PDMS. We show that regular microlenses can be produced by the adjustment of their size and irradiation fluence. The focal length of the lenses can be tuned with the diameter of the lens and with the delivered ion fluence.

Contribution of global potential field data to the tectonic reconstruction of the Rio Grande Rise in the South Atlantic

The application of advanced enhancement techniques for geophysical anomalies to global gravity (WGM2012) and magnetic (EMAG2) models sheds light on the complex tectonic evolution of the Rio Grande Rise (RGR) in the southern South Atlantic. Long wavelength Bouguer gravity lows indicate a thicker crust beneath of the ridge, whose nature can be related to a microcontinent or an excess of volcanism within the oceanic realm. Recently dredged continental rocks reinforce the hypothesis of a microcontinent or, at least, slivers of continental crust. However, the reserval magnetic pattern of the processed magnetic anomalies provide no evidence of aborted spreading center similar to the well-studied Jan Mayen microcontinent and the surrounding (inactive) Aegir and (active) Kolbeinsey ridges in the North Atlantic Ocean. The reversal magnetic anomalies show a series N-S trending parallel stripes roughly follow the current South American coastline and segmented by E-W oriented oceanic fracture zones (FZs). The magnetic stripes are bended eastwards at the RGR, showing a more complex magnetic pattern similar to that in the Iceland. The aborted Cruzeiro do Sul Rift (CSR) and the Jean Charcot Chain (JCC) are structures that cross the RGR and contribute to the understanding of the tectonic evolution of the South Atlantic Ocean. NW-SE oriented extensive gravity lows and bathymetric valleys, which mark the CSR, are segmented by E-W trending magnetic lineaments related to FZs. This structural configuration suggests that the extensional event, which formed the rift and the seamounts chain, was replaced by strike-slip movements along the FZs. In addition, we constructed a plate kinematic model for the evolution of the RGR based on bathymetric, free-air and Bouguer gravity and magnetic data. Our model comprises five main stages of the RGR formation and evolution between late Cretaceous and Paleocene (ca. 95 - 60 Ma), separated by published seafloor isochrones. The proposed model suggests that the RGR was built at the mid-Atlantic ridge by increased magmatism probably related to the Tristan da Cunha hotspot.

Spatially periodic deformations in planar and twisted flexoelectric nematic layers.

Electric field induced deformations in twisted and untwisted planar layers of nematic liquid crystals possessing flexoelectric properties were investigated numerically. The spatially periodic deformations, taking the form of parallel stripes, were found to have smaller free energy than the homogeneous deformations. The structures of distorted layers as well as the evolution of deformations during changes of bias voltage were recognized. The role of flexoelectric properties was analyzed. Calculations taking into account the peculiar elastic properties of the bent-core nematics were also performed. In the untwisted planar layers the stripes were parallel to the initial director orientation. In the twisted layers, two different kinds of periodic deformation were distinguished. They had different structures and different directions with respect to the initial director distribution. The results were consistent with existing experimental data.