Freezing of supercooled water drops has been studied by a constant-temperature method to determine the dependence of heterogeneous nucleation on temperature and on the duration of supercooling. A polished metal surface, coated with a water repelling film of liquid paraffin, is used to support the rain-sized water drops being frozen. Complex and rather unexpected behavior was observed during initial freezing after sudden chilling. However, the latter part of the freezing process agrees with the equation developed from the probability considerations by Bigg and shows time dependence. The complex parts of the curves obtained during initial freezing can be explained by the recently discovered dependence of freezing temperature of supercooled drops on rate of cooling.