In a general Markov decision progress system, only one agent’s learning evolution is considered. However, considering the learning evolution of a single agent in many problems has some limitations, more and more applications involve multi-agent. There are two types of cooperation, game environment among multi-agent. Therefore, this paper introduces a Cooperation Markov Decision Process system with two agents, which is suitable for the learning evolution of cooperative decision between two agents. It is further found that the value function in the system also converges in the end, and the convergence value is independent of the choice of the value of the initial value function. This paper presents an algorithm for finding the optimal strategy pair in the system, whose fundamental task is to find an optimal strategy pair and form an evolutionary system . Finally, an example is given to support the theoretical results.