Paint Additives Research Articles

The Influence of Conditions of Polycondensation in Acid Medium on the Structure of Oligosilsesquioxanes with a Novel Eugenol-Containing Substituent.

Eugenol-containing oligoorganosilsesquioxanes were synthesized by the method of hydrolytic polycondensation in an active medium under various reaction conditions. The obtained products were characterized by 29Si NMR spectroscopy and MALDI-TOF spectrometry. It was shown that factors such as the reaction temperature, polycondensation duration, and molar ratio between the initial alkoxysilane monomer and acetic acid may affect the molecular weight characteristics and molecular structure of the formed oligomer, like the content of stressed cyclic units (T3, DTT, TDT) and unstressed silsesquioxane units TnDm. In particular, an increase in the ratio of the initial reagents led to an increase in the content of silsesquioxane Tn fragments from 28.2%mol to 41.7%mol, while the number of strained cyclic structures decreased by more than two times. An increase in the synthesis time is of no particular practical value since it was found that the composition of the oligomers synthesized for 6 h and 12 h was practically identical, as was that of the oligomers synthesized for 24 h and 48 h. A noticeable transition in the oligomer composition was observed only when the synthesis time was changed from 12 h to 24 h. Finally, it was shown that the choice of synthesis temperature had the strongest effect on the oligomer composition. The oligomer synthesized at 95 °C contained the highest amount of silsesquioxane Tn fragments, >77%mol, while a Tn fragment content of ~42%mol was observed during the synthesis at 117 °C. It was shown that silsesquioxanes are devitrified at room temperature (Tg from -6.4 to -10.6 °C), and their thermal stability in an inert atmosphere is 300 °C. The synthesized oligomers, due to the presence of hydroxyl-containing eugenol units, may be promising binders and additives for functional epoxy-silicone paints and coating materials.

Comprehensive study on mechanical and ignition properties of newly synthesized lanthanide complexes for flame retardant paint additives

Comprehensive study on mechanical and ignition properties of newly synthesized lanthanide complexes for flame retardant paint additives

Antibacterial Size Effect of ZnO Nanoparticles and Their Role as Additives in Emulsion Waterborne Paint.

Nosocomial infections, a prevalent issue in intensive care units due to antibiotic overuse, could potentially be addressed by metal oxide nanoparticles (NPs). However, there is still no comprehensive understanding of the impact of NPs' size on their antibacterial efficacy. Therefore, this study provides a novel investigation into the impact of ZnO NPs' size on bacterial growth kinetics. NPs were synthesized using a sol-gel process with monoethanolamine (MEA) and water. X-ray diffraction (XRD), transmission electron microscopy (TEM), and Raman spectroscopy confirmed their crystallization and size variations. ZnO NPs of 22, 35, and 66 nm were tested against the most common nosocomial bacteria: Escherichia coli, Pseudomonas aeruginosa (Gram-negative), and Staphylococcus aureus (Gram-positive). Evaluation of minimum inhibitory and bactericidal concentrations (MIC and MBC) revealed superior antibacterial activity in small NPs. Bacterial growth kinetics were monitored using optical absorbance, showing a reduced specific growth rate, a prolonged latency period, and an increased inhibition percentage with small NPs, indicating a slowdown in bacterial growth. Pseudomonas aeruginosa showed the lowest sensitivity to ZnO NPs, attributed to its resistance to environmental stress. Moreover, the antibacterial efficacy of paint containing 1 wt% of 22 nm ZnO NPs was evaluated, and showed activity against E. coli and S. aureus.

Synthetic and Natural Vitamin C Modulation of Leaded Paint-Induced Nephrotoxicity of Automobile Painters in Ile-Ife, Nigeria.

Introduction: Lead (Pb) occupational exposure in painters has been documented to be contacted via additives in paints due to its many important properties and vitamin C has been the most widely studied when it comes to Pb- induced oxidative stress.  Aim: This study aimed at the use of freshly squeezed orange-juice due to its accessibility in investigating the modulating role of synthetic and natural vitamin-C on leaded paint-induced nephrotoxicity of automobile painters.  Study Design and Methods: Sixty (60) male automobile painters were consecutively selected and divided equally into 2 groups. Vitamin-C and orange juice were administered daily to painters for 4 weeks at dosage levels of 200 and 184 mg/day respectively. Thirty (30) male non-painters constituted the control group. Orange juice vitamin-C content was assessed by titrimetric method and synthetic vitamin-C served as the standard drug. Renal biomarkers and reduced glutathione (GSH) were done by Colorimetry. Urine aminolevulinic acid (ALA) and Pb were assessed by ELISA technique and atomic absorption spectrophotometry respectively. Phytochemical screenings (quantitative/qualitative) and proximate analysis were done using standard methods. Data were analyzed using Pearson’s correlation coefficient and One-way Analysis of Variance (ANOVA) followed by Tukey’s post-hoc test for pairwise comparison. Statistical significance was p< 0.05.  Results: Baseline results at 0-week of orange juice administered group showed a significantly (P<0.05) higher serum Pb, urea and creatinine compared to non- painters. Also, their urine baseline results at 0-week showed a significantly (P<0.05) higher levels of ALA and GSH compared to non-painters. Orange juice administration at 4 weeks showed significant (P<0.05) reductions in concentrations of lead, urea, and creatinine in serum, decreased concentrations of GSH and ALA in urine but increased urine Pb compared to baseline. However, compared with baseline, after 4 weeks of vitamin-C supplementation, serum Pb, urine GSH, and urine ALA were significantly (P<0.05) reduced and urine Pb significantly (P<0.05) increased. A positive correlation was observed at 2-weeks of taking orange- juice between serum lead and urine ALA (r= 0.703) and GSH (r= 0.913) but 4-week positive correlation between urea and urine GSH (r= 1.000). A negative correlation was observed at 2-week of taking vitamin-C between serum creatinine and urine lead (r= -0.857) while 4-week a negative correlation was observed between urine GSH and urine lead (r= -0.743). Presence of tannin, phenol, saponin, alkaloid, and flavonoid was detected in orange juice.  Conclusion: Orange juice administration conferred significant amelioration to renal and lead toxicity biomarkers by 4 weeks. The presence of phytochemicals suggests why orange juice may be a viable alternative in amelioration of toxic effects of leaded paint among automobile painters.

Enhancing wood coatings with red beetroot-derived pigments: Investigating synergy with UV absorber and composite filler for improved durability and aesthetics

The objective of this study is to assess the synergy among a specific bio-based pigment derived from red beetroot, a composite filler, and a UV absorber as additives for wood paints. The composite filler aims to enhance the mechanical properties of the coating, while the UV absorber is selected to improve the pigment's color stability under solar radiation. The impact of these additives on sample aesthetics is evaluated through color, gloss, and roughness measurements. Mechanical properties are analyzed using Buchholz surface hardness and Taber abrasion resistance tests. The protective role of the UV absorber is further examined through accelerated degradation tests in a UV-B chamber. To ensure that the additives do not compromise the coating's barrier properties, water uptake tests, resistance to liquids, and contact angle measurements are conducted. Overall, the study demonstrates how each additive serves a distinct purpose and their combined application offers benefits such as enhanced color retention and improved mechanical durability of the coating. It highlights the potential of using bio-based pigments to enhance color durability without sacrificing the protective performance of wood coatings.

Marcel Krohnen will guide the global paint additives business of BYK

Marcel Krohnen will guide the global paint additives business of BYK

Evaluating the versatility of stainless steel flakes and magnetite powder as polyvalent additives for wood paints

The objective of this study is to evaluate how various fillers, specifically stainless steel flakes and magnetite powder, affect the visual attributes, durability and versatility of a water-based wood paint. To examine the influence of these two specific pigments on the overall look of the coatings, colorimetric measurements were carried out. The impact of these distinct fillers on the durability of the layers was assessed by subjecting the samples to xenon arc light exposure and cyclic thermal shocks, followed by colorimetric inspections and adhesion tests. Furthermore, the fillers' impact on the coating's ability to act as a barrier was assessed through liquid resistance and water uptake tests. Additionally, the Buchholz hardness indentation test and the Taber test were conducted to quantify how these functional additives affect the mechanical properties of the coatings, such as hardness and resistance to abrasion. Lastly, two specific tests revealed the fillers' role in introducing unique electrical conductivity and magnetic attractive properties to the paint. In conclusion, this study underscores the intriguing influence of stainless steel flakes and magnetite powder, which not only impart vibrant colors and distinct visual characteristics to the paint but also maintain the coating's protective barrier properties, enhance the mechanical properties of the composite layer, and introduce specific multifunctional features to the coating.

Dynamic laser speckle study on the effect of TiO2 and SiO2 nanoparticles in coatings

The coatings of TiO2 and SiO2 nanoparticles mixed with latex paint on the sample are studied. The sample coin is coated primarily with latex paint alone and then with additives such as TiO2 and SiO2 nanoparticles separately with the same percentage of concentration. The sample is illumined by a coherent source of light and produces tiny bright and dark fingerprints by the interference effect of the scattered laser. This cigar-like granular pattern image is known as a speckle pattern which is recorded continuously during the drying process of paint. The modified properties due to the additives in paint on the coin are studied by speckle photography. The surface profile plotting method is adopted for the roughness analysis on the sample. Histogram and gray level co-occurrence matrix perform the intensity analysis in the paint. The brightness examine by means of bright/dark pixel counting method.

Synergistic contribution of bio-based additives in wood paint: The combined effect of pigment deriving from spirulina and multifunctional filler based on carnauba wax

This work aims to reveal the synergistic behavior of two bio-based additives on the durability and protective behavior of a bio-based wood paint. The powder extract form spirulina was introduced as a natural pigment, while carnauba wax was used as a multifunctional filler. The impact of the two additives on the morphology of the coatings was investigated by scanning electron microscopy observations, while their role on the durability of the paint was assessed by exposing the samples to UV-B radiation and continuous thermal shocks. Infrared spectroscopy analysis, colorimetric inspections, adhesion test and scanning electron microscope observations were employed to investigate the impact of the synergic behavior of the bio-based additives. Furthermore, the role of the spirulina and wax powders on the barrier performance of the coatings was evaluated by liquid resistance test ad water uptake test. Finally, Buchholz hardness indentation test and the scrub test were employed to estimate the effect of the additives on the mechanical properties of hardness and abrasion resistance of the coatings. Ultimately, this work demonstrates the interesting synergy of spirulina and wax, able to provide an intense coloring and certain aesthetic features to the paint, to improve the water-repellent properties of the surface and to increase the abrasion resistance of the composite layer.

Status, distribution, source, and risk of polychlorinated biphenyl levels in soils of five cities from the Hexi Corridor, Northwest China

Few studies have been performed on the persistent organic pollutant contamination in soil from the plateau and remote areas, particularly the mid-latitude arid and semi-arid regions of Northwest China. The occurrence, spatial distribution, source, and potential risk of 12 polychlorinated biphenyls (PCBs) were investigated in soil collected from five Hexi Corridor cities in Northwest China. All of the PCBs were detected individually in the soil samples. The concentration of Σ12PCBs in the Hexi Corridor ranged from 2.0 to 148.5ng/g, with an average of 21.3ng/g. The tetra-CBs and hexa-CBs were the dominant PCB components in the soil. Higher PCB levels were found in the industrial city of Jiuquan, and the fewest PCBs were detected at Jinchang. Source analysis by principal component analysis showed that the dominant sources of PCBs were automobile exhaust, paint additives, insulation materials, and other industrial products. The carcinogenic health risk of PCBs in the Hexi Corridor soil was within acceptable levels, but the exposure risk of PCBs in soil for children was higher than that for adults.

Synthesis and Characterization of Polypyrrole/Fe3O4 Nanocomposites: A Promising Material Against Carbon Steel Corrosion

The use of conducting polymers as coating layers for the protection of surfaces against corrosion represents an important topic for investigation, as reported in the literature. In this work, polypyrrole/Fe3O4 nanoparticles (Fe3O4_NPs/PPy) hybrid nanocomposites (HN) were incorporated as anticorrosive additives in an epoxy paint to protect SAE 1010 carbon steel from corrosion. The HN particles were obtained by chemical polymerization of pyrrole in an aqueous solution in the presence of Fe3O4_NPs and were characterized by infrared absorption spectrophotometry, dynamic light scattering (DLS), X-ray diffraction (XRD), transmission electron microscopy (TEM). The electrochemical impedance spectroscopy (EIS) was used in the analysis of the electrochemical response of the coated surface with and without HN. DLS data showed that the Fe3O4_NPs and Fe3O4_NPs/PPy obtained in solution present average diameters of (19.7 ± 9.6) nm and (63.5 ± 27.7) nm, respectively. TEM images showed Fe3O4_NPs with smaller sizes (10 nm - 30 nm), and that the HN had diameters smaller than 100 nm, consisting of Fe3O4 cores coated with polypyrrole. EIS measurements have shown that the addition of HN to the epoxy paint could improve the efficiency of the anticorrosive coating when compared to the original epoxy paint prepared without any corrosion inhibitor.

Experimental Application of Real-Time Optimization with Modifier Adaptation and Quadratic Approximation to a Reactive Extrusion Process

In this contribution, Real-Time Optimization with Modifier Adaptation and Quadratic Approximation (MAWQA) is experimentally applied to a pilot-scale 18 mm reactive extruder for the production of hydrophobically modified ethoxylated urethanes which are used as rheological paint additives. Standard model-based control is in this application not applicable because of the complex coupling of the chemical reaction, complex internal flows within the equipment, and a high sensitivity to external disturbances. The optimization is performed with the goal to minimize the specific energy requirement for the product by changing the overall throughput and the barrel temperature locally while meeting a hard constraint on the product quality. The product quality is determined by the viscosity of the product which is measured online with a capillary viscometer. In contrast to other work, the MAWQA method is applied here purely data-based without using a physical model. Despite the absence of a rigorous model, the method converged to the optimum after 6 initial probing moves and 4 iterations where the product quality constraints were already met.

Fabrication of the superhydrophobic and oleophilic graphene-based sponge for the treatment of oil- and organic solvent-contaminated wastewater

Graphene, a 2D nanomaterial, has been extensively studied and applied in many applications including, but not limited to, energy storage, environmental treatment, additives for paints, rubber, and composite, sensors, and electronic devices. In this work, graphene-based sponge was facilely fabricated by simply immersing melamine sponge into well-dispersed graphene nanoplaletes solution. The prepared graphene sponge revealed superhydrophobic and oleophillic properties in nature. The graphene-based sponge showed remarkable adsorption performance toward oils and organic solvents with the adsorption capacity ranging from 40 to 70 folds of sponge’s weight. The sponge also exhibited high recyclability, which is considered as a promising material for the practical application.

Carboxyl-functionalized aluminum oxide nanofibers for powder coatings

The paper considers the production and use of alumina nanofibrous additives in nanocomposite powder paints. The main component of powder paints are polyester resins with a large number of free carboxyl groups, which are cross-linked with special hardening additives. The introduction of additives into the resin is most effective when their surface is matched in terms of physicochemical properties with the resin material. In order to increase the affinity of the alumina nanofibers with the powder paint matrix, the amphoteric surface of the nanofibers must become acidic. The paper describes a method for the functionalization of alumina nanofibers by successive silanization with aminopropyltriethoxysilane and priming with oxalic acid. The paper described about the compounding of alumina nanofibers leads to increase of the coating strength and an increase in its elasticity. Priming alumina nanofibers by aminopropyltriethoxysilane in toluene leads to its functionalization sufficient to homogenize the nanofibers in the polymer media of the powder paint and improve its product properties. The formation of an amide bond after the final stage of priming of alumina nanofibers in oxalic acid by indirectly method is shown.

Selection of Conditions in PVB Polymer Dissolution Process for Laminated Glass Recycling Applications.

Polyvinyl(butyral) (PVB) post-production waste collected from the windshields of end-of-life vehicles and post-consumer building laminated glass are valuable polymeric materials that can be reused. Every year, large amounts of PVB waste are still being buried in landfills owing to a lack of appropriate recycling techniques. Before reuse, PVB should be thoroughly cleaned of solid contaminants such as glass dust, fused heating wires, and other waste polymers, metals, and ceramics. This can be done by polymer dissolution and filtration. In this study, we propose the purification of PVB from contamination by dissolving the post-consumer polymeric materials into single and binary organic solvents. As part of the experimental work, measurements and optimization of the dissolution time of PVB were performed. PVB dissolves faster when a binary solvent (2-propanol + ethyl acetate) than pure 2-propanol is used. From the point of view of the practical application of PVB solutions, measurements of density and dynamic viscosity as a function of PVB concentration and temperature were performed. The PVB solutions obtained in this work can be widely used as glues for glass, ceramics, metal, impregnating, and insulating materials or as paint additives that are entirely transparent for visible light and to block UV rays.

The anti-corrosion performance of reinforcement behaviour of silica from different sources in bio-based paints

PurposeThe aim of this study is to investigate the usability of horsetail, sunflower stalk, wheat stalk and corn stalk ashes as additives in paints and their performance against corrosion resistance when used.Design/methodology/approachThe ashes of horsetail, sunflower stalk, wheat stalk and corn stalk were investigated in this study in single, binary and ternary combinations with three different percentages as additives in paints. Samples of concrete with any combinations of ashes resisted against the corrosion of steel reinforcements, but horsetail ash proved to be the most effective.FindingsIt can be said that these research results show that the paint containing horsetail ash is an excellent coating material that can be used in paints for the corrosion resistance of steel in reinforced concrete. The corrosion rate decreased with the increase in the amount of reactive SiO2. There was less mass loss with the formation of resistance against corrosion in the horsetail ash added concretes. That is why horsetail ash is one of the most effective options for the aforementioned purpose.Originality/valueBeing cheap and easily obtainable, the materials used for coating in this study are perfect candidates for industrial use.

Possibility of direct rapid determination of inorganic contaminant elements in paints by LA-ICP-MS method

In this work content of inorganic major and trace elements were directly determined in produced in China, Russia, and Germany household use purpose oil, асгуI, and ochre paint samples using laser ablation-inductively coupled plasma-mass spectroscopy (LA_ICP_MS) technique. A sample preparation was simple and rapid: an oil and acryl paint droplets were dried on glass substrate for several hours on a hot plate at 60° C and few mg ochre paint powder samples were solidified with pure paraffin wax on the glass substrate. Dried oil and acryl paint droplets were ablated locally, drilling the hole way, while ochre paint powders were ablated using surface rastering method. Contents of inorganic elements were calculated using the NIST 610 glassy standard sample as the reference. Parallel determination results of lead and chromium in oil paint samples by atomic absorption technique correlates with that of by LA_ICP_MS acceptably (correlation coefficient for lead is 0.85 and for chromium is 0.95). Because of sample organic - reference inorganic matrix difference, the measured by the LA_ICP_MS content of each element must be adjusted being multiplied in some quantity, value of which are different for each element. For lead and chromium value of the quantity found correspondingly as 6.4 and 9.3. The average relative standard deviation (RSD) of measured content of the mostly high content elements Ca, Al, Mn, Pb, Sr, S, Mg, Fe, Sb, Na, Co, Si, Zn, Cu, P, Y, K, CI, Ce, and La is less than 10%, the RSD for elements Ti, Cr, Sn, Ba, Zr, Rb lies between 10 and 20%, and the RSD for trace elements Gd, Nb, Sc, V, U. Pr, Ni, Ga, Eu, As, Th B, Mo, Cd, Li lies in interval from 20 to 50 %. High level of concentration 309 - 24300 ppm for lead, 950- 3134 ppm for chromium are detected by LA-ICP-MS method in samples of red, yellow and green color oil paints produced in China and bestselling in Mongolia certain brand products. Up to 1900 ppm alarming high content of arsenic is tovnd in the Chinese origin yellowish red, brown red color ochre paints. As shows our measurements, the LA-ICP-MS method is possible to use as alternative rapid semi-quantitive detection method with acceptable accuracy and precision for basic inorganic additives in oil, acryl and ochre paints using glassy standard sample.

A review on energy conserving materials for passive cooling in buildings

A growing country needs to satisfy its exponentially growing energy demand consumed by different sectors. Of them, construction sectors consume half of the power supply in any country. In hot and humid regions, the energy requirement for air-conditioning the buildings is more in hot summer days. Hence, it is necessary to construct the energy efficient and green energy buildings to overcome the energy crisis. More researches are going on the modified design in the construction of domestic, agricultural and industrial buildings. Reduction of heat gains into the buildings through the walls, ceilings and roofs plays a vital role among the different passive cooling techniques. The different insulating materials, reflective coating materials, pigments and additives in paints, phase change materials, nanoparticles and thermal energy storing materials are employed to achieve the same. It is not quite easy to envelope certain buildings with energy conserving materials. Hence, a detailed review on the energy conserving materials for the green energy buildings becomes essential. In this paper, the performance parameters, thermal properties, suitability of the material for the specific application is reviewed. This review shows that by using suitable building enveloping materials, the energy demand during peak load conditions can be decreased.

Multifunctionalities of mycosynthesized zinc oxide nanoparticles (ZnONPs) from Cladosporium tenuissimum FCBGr: Antimicrobial additives for paints coating, functionalized fabrics and biomedical properties

The prime focus of this investigation was to synthesize zinc oxide nanoparticles (ZnONPs) and test its potential applications as antimicrobials on textile fabrics, utilize ZnONP-functionalized building paints, evaluate its dye degradation efficiency, and determine its anticancer activity. ZnONPs were synthesized extracellularly in minimal medium at a fixed pH range 7.2 using an endophytic fungus Cladosporium tenuissimum FCBGr isolated from the Aegle marmelos (Vilva tree), a medicinal tree. The molecular identification of endophytic isolate FCBGr was performed using PCR amplification of ITS rDNA. The synthesized particles were characterized using microscopic and spectral analysis viz., SEM, XRD, and FTIR. The mycosynthesized ZnONPs exhibited enhanced antimicrobial and antioxidant properties at minimal concentration. Additionally, ZnONP-coated/functionalized fabrics exhibited a high degree of antimicrobial activity against most clinical pathogens tested. ZnONP-functionalized paints inhibited Aspergillus molds on building walls. Moreover, ZnONPs exhibited anti-angiogenic property by inhibiting blood vessel formation and cytotoxicity against HeLa cell lines even at the lowest concentration. These assessments evinced the promising nature of ZnONPs coatings in bio-medical applications and bioremediation.

Construction and Demolition Waste-Derived Feedstock: Fuel Characterization of a Potential Resource for Sustainable Aviation Fuels Production

Detailed characterization of physical and fuel properties of construction and demolition waste (CDW) can support research and commercial efforts to develop sustainable aviation fuels. The current study reports time-series data for bulk density, mineral composition, reactivity, and fuel properties (proximate analysis, ultimate analysis, heating value and ash fusibility) of the combustible material fraction of samples mined from an active CDW landfill on the island of Oʻahu, Hawaiʻi. The fuel properties are in ranges comparable to other reference solid wastes such as demolition wood, municipal solid wastes, and landfilled materials. Ash fusion temperatures (from initial deformation to fluid deformation) among the samples were found to lie in a narrow range from 1,117 to 1,247°C. Despite higher ash contents, the CDW derived feedstock samples had comparable heating values to reference biomass and construction wood samples, indicating the presence of higher energy content materials (e.g., plastics, roofing material, etc.) in addition to wood. The waste samples show lower reactivity peaks in the devolatilization stage, but higher reactivity peaks (located at lower temperatures) in the gasification and combustion stage, compared with those of reference biomass and construction woods. Mineral elemental analysis revealed that materials from various sources (gypsum, plastic, rust, paint, paint additives, and soils) were present in the samples. Soil recovered from the landfill contained higher Ca, Cu, Fe, K, Mn, Pb, and Zn levels than soil samples from elsewhere on the island. Results from this study can provide insight on variations in the physical and fuel properties of the CDW derived feedstocks, and support the design of conversion systems.