Carbon Oxygen Research Articles

Structural Snapshots of Reversible Carbon Dioxide Capture and (De)oxygenation at Group 14 Diradicaloids.

Although diradicals should exhibit a rather small reaction barrier as compared to closed-shell species for activating kinetically inert molecules, the activation and functionalization of carbon dioxide with stable main-group diradicals remain virtually unexplored. In this work, we present a thorough study on CO2 activation, reversible capture, and (de)oxygenation mediated by stable Group 14 singlet diradicals (i.e., diradicaloids) [(ADC)E]2 (E = Si, Ge, Sn) based on an anionic dicarbene (ADC) framework (ADC = PhC{N(Dipp)C}2; Dipp = 2,6-iPr2C6H3). [(ADC)E]2 readily undergo [4 + 2]-cycloadditions with CO2 to result in barrelene-type bis-metallylenes [(ADC)E]2(OC═O). The CO2 addition is reversible for E = Ge; thus, CO2 detaches under vacuum or at an elevated temperature and regenerates [(ADC)Ge]2. [(ADC)Sn]2(OC═O) is isolable but deoxygenates additional CO2 to form [(ADC)Sn]2(O2CO) and CO. [(ADC)Si]2(OC═O) is extremely reactive and could not be isolated or detected as it spontaneously reacts further with CO2 to yield elusive monomeric Si(IV) oxides [(ADC)Si(O)]2(COn) or carbonates [(ADC)Si(CO3)]2(COn) (n = 1 or 2) via the (de)oxygenation of CO2. The molecular structures of all isolated compounds have been established by X-ray diffraction, and a mechanistic insight of their formation has been suggested by DFT calculations.

Characterization and Sustainable Applications of Galinsoga parviflora Natural Fibers: A Pathway to Eco-Friendly Material Development

This study investigates the potential of natural fibers extracted from Galinsoga parviflora as sustainable alternatives to synthetic materials, addressing the increasing demand for eco-friendly and biodegradable options in material science. The main objectives were to evaluate the structural, mechanical, and biological properties of these fibers, focusing on their applicability in structural composites. Driven by environmental sustainability, we performed a range of analyses including X-ray Diffraction (XRD) to determine crystallinity and cellulose structure, Fourier-Transform Infrared Spectroscopy (FTIR) to identify functional groups related to biodegradability, and Scanning Electron Microscopy (SEM) to examine surface morphology and fiber dimensions. Key findings include a crystallinity index of 36.3% with cellulose I dominance, a tensile strength of 17.92 MPa, and a modulus of 11.3 GPa, indicating the fibers’ potential for structural applications. Elemental analysis using Energy-Dispersive X-ray Spectroscopy (EDX) revealed a high carbon content (53.0%) and oxygen content (41.3%), along with trace elements that may enhance interaction in polymer matrices. Antibacterial testing demonstrated effective inhibition of Staphylococcus aureus biofilms, with inhibition zones reaching up to 19 mm, comparable to streptomycin. Confocal Laser Scanning Microscopy (CLSM) further confirmed the fibers' biofilm disruption capabilities.Overall, the results highlight that G. parviflora fibers show significant promise as bio-based alternatives for sustainable material development, offering both mechanical strength and biological functionality for future eco-friendly technologies.

Composição química de revestimentos frios e a influência na refletância solar e emitância térmica

Abstract Cool materials have higher values of solar reflectance and lower values of thermal emittance, although still high when compared to conventional coatings, thus, their surfaces are less heated. In this regard, the goal was to identify the chemical elements present on cool surfaces that influence solar reflectance and thermal emittance. To this end, the spectral reflectance and the thermal emittance were measured with methods and equipment standardized by the Cool Roof Rating Council (CRRC) of 23 elastomeric cool coatings commercialized in the Brazilian market, and the chemical composition of the surfaces with EDS (Energy-dispersive X-ray detector) coupled to the field emission scanning electron microscope (FE-SEM) was analyzed. The presence of the metallic chemical element (titanium) in greater quantities on the surfaces was not decisive for lower thermal emittance values. The surfaces of materials with lower carbon and higher oxygen content have higher near infrared and solar reflectance. Therefore, surfaces with a matte finish have higher solar reflectance values because of the higher ratio of pigments in relation to resin than those with a glossy finish, which are mistakenly associated with higher reflectance due to its high surface gloss.

Laser-induced epoxide ring opening on graphene oxide leading to C–O single bonds: An ab initio prediction

The dynamics of the epoxide in graphene oxide under laser irradiation were investigated based on the frameworks of time-dependent density functional theory and molecular dynamics within the Ehrenfest approximation. Two combinations of the laser wavelength (λ) and full width at half-maximum (FWHM) were examined: λ=266 nm with FWHM=100 fs and λ=810 nm with FWHM=35 fs. Upon tuning the laser fluence to just below the threshold for oxygen desorption, epoxide ring opening to form a carbon–oxygen (C–O) single bond was observed. Further simulations revealed that the laser-generated C–O bonds were inert in the presence of water molecules. Conventional static density functional theory calculations and complete-active-space self-consistent field calculations indicated that the C–O bonds were (meta)stable in the electronically excited and negatively charged states. Finally, the feasibility of experimentally observing the C–O bond was considered.

Vegetation Restoration Patterns Influence the Supply and Interrelations of Grassland Ecosystem Services in Karst Desertification Control

An appropriate vegetation restoration pattern is crucial for maintaining and enhancing ecosystem functions and services in karst rocky desertification control areas. However, it is still unclear whether different vegetation restoration patterns will aggravate the trade-off of grassland ecosystem services in this area. This study focuses on grassland ecosystems in the karst desertification control area, comparing artificial restoration measures (Dactylis glomerata single-species sowing grassland, DG; Lolium perenne single-species sowing grassland, LP; Lolium perenne + Trifolium repens mixed-species sowing grassland, LT) with natural restoration measures (NG). Seven ecosystem services (forage yield, soil retention, soil water conservation, carbon fixation and release, soil carbon storage, soil nutrient retention, and biodiversity conservation) as well as total ecosystem services were quantified using field monitoring data. The relationships between these services were evaluated through Spearman correlation analysis. The results showed that different vegetation restoration patterns significantly influenced the provisioning, regulating, and supporting services of the grassland ecosystem (p < 0.001). Three types of relationships were observed (trade-off, synergy, and neutral), but the trade-off relationship was not significant (p > 0.05). The total ecosystem service of LT (0.79) was significantly higher than that of NG (0.21), DG (0.36), and LP (0.41), with a significant synergy observed between soil nutrient conservation, forage yield, and carbon sequestration and oxygen release (p < 0.05). Therefore, LT is considered the best vegetation restoration practice for the karst rocky desertification control area compared with other patterns. This study provides theoretical guidance for vegetation restoration in degraded karst ecosystems.

Evolution of Auriferous Fluids in the Kraaipan-Amalia Greenstone Belts: Evidence from Mineralogical and Isotopic Constraints

The Kraaipan and Amalia greenstone belts in South Africa occur in the western part of the Kaapvaal Craton. The two belts stretch discontinuously in an approximately north–south orientation over a distance of about 250 km from southern Botswana in the north to the Vaal River near Christiana in the south and are separated by a distance of about 90 km. Gold mineralization is hosted in banded iron formation at both the Kalahari Goldridge deposit (Kalgold) in the Kraaipan greenstone belt in the north and the Amalia deposit in the Amalia greenstone belt in the south, with the mineralization associated with quartz–carbonate veins. The footwalls of these deposits are generally composed of mafic volcanic schist and the hanging walls consisting of graywackes, schist and shale units. The Kalgold and Amalia gold deposits show some variation in the redox condition of the mineralizing system and fluid chemistry. The ore mineral assemblage is characterized by magnetite–pyrrhotite–pyrite at Kalgold, which is indicative of reducing conditions, and a magnetite–hematite–pyrite assemblage at Amalia that suggests a relatively oxidizing environment. Average mineralizing temperatures determined from chlorite geothermometry were relatively higher at the Kalahari Goldridge deposit ranging from 350 to 400 °C compared to the slightly cooler range of 330 to 390 °C at Amalia. The composition of the fluids derived from fluid inclusions is indicative of low salinity H2O--CO2±CH4-rich fluids at Kalgold against relatively H2O-CO2-rich fluids at Amalia. Evidence from strontium–carbon–oxygen isotopic ratios from carbonates suggests that differences in redox conditions in the deposits could be attributed to different flow pathways by an evolving fluid from a common source (with minimum 87Sr/86Sr = 0.70354) to the sites of gold deposition, with a significant ore fluid interaction with a thick sequence of carbonaceous meta-pelitic rock units at the Kalahari Goldridge deposit that is absent in the Amalia deposit.

Variable Cerebral Blood Flow Responsiveness to Acute Hypoxic Hypoxia.

Cerebrovascular reactivity (CVR) to changes in blood carbon dioxide and oxygen levels is a robust indicator of vascular health. Although CVR is typically assessed with hypercapnia, the interplay between carbon dioxide and oxygen, and their ultimate roles in dictating vascular tone, can vary with pathology. Methods to characterize vasoreactivity to oxygen changes, particularly hypoxia, would provide important complementary information to established hypercapnia techniques. However, existing methods to study hypoxic CVR, typically with arterial spin labeling (ASL) MRI, demonstrate high variability and paradoxical responses. To understand whether these responses are real or due to methodological confounds of ASL, we used phase-contrast MRI to quantify whole-brain blood flow in 21 participants during baseline, hypoxic, and hypercapnic respiratory states in three scan sessions. Hypoxic CVR reliability was poor-to-moderate (ICC=0.42 for CVR relative to P ET O 2 changes, ICC=0.56 relative to SpO 2 changes) and was less reliable than hypercapnic CVR (ICC=0.67). Without the uncertainty from ASL-related confounds, we still observed paradoxical responses at each timepoint. Concurrent changes in blood carbon dioxide levels did not account for paradoxical responses. Hypoxic CVR and hypercapnic CVR shared approximately 40% of variance across the dataset, indicating that the two effects may indeed reflect distinct, complementary elements of vascular regulation.

Generation of Surface Ga-H Hydride and Reactivity toward CO2.

Hydrogen adsorption on gallium oxide was investigated by in situ infrared (IR) spectroscopy over a temperature range of 30-450 °C. Both hydroxyl groups and Ga-H hydrides with a pair of characteristic bands at 3685 (3532) cm-1 and 2011 (1988) cm-1 were detected on the surface gallium oxide. The formation and stability of surface Ga-H hydrides were found to be highly dependent on the temperature of H2 dissociation. Through a combination of density functional theory (DFT) calculations and isotopic experiments, a mechanism involving both heterolytic and homolytic pathways for hydrogen dissociation was proposed for the generation of Ga-H hydrides. Furthermore, the reactivity of surface Ga-H hydrides was explored by their interactions with various probe molecules such as carbon dioxide, oxygen, and nitrogen. A potential reaction mechanism involving the attraction between nucleophilic hydrogen and positively charged intermediates was suggested during those hydrogenations.

Spatiotemporal Changes and Driving Mechanisms of Ecosystem Service Supply–Demand Contradictions Under Urbanization

Clarifying the driving mechanisms of ecosystem service (ES) supply and demand under urbanization is of significant importance for urban ecological planning and management. However, how the balance of ES supply and demand and its driving mechanisms vary with the degree of urbanization has been little studied. In this study, we analyzed the spatiotemporal changes and the correlations between ES supply and demand and the degree of urbanization in the Zhengzhou Metropolitan Area (ZZMA) from 2000 to 2020 and further explored the driving mechanisms behind these changes. The results showed that, (1) between 2000 and 2020, the ZZMA experienced a deficit in comprehensive ES supply and demand, and regions with rapid urbanization development were more likely to trigger imbalances in ES supply and demand; (2) the spatial mismatch between low–high ES supply and demand was primarily distributed in the built-up areas of various cities, while the high–low spatial mismatch was mostly found in forest and grassland areas; (3) the comprehensive urbanization level of the ZZMA was spatially negatively correlated with the ratio of ES supply and demand. Regions with lower ES balance were more susceptible to disturbances caused by urbanization; (4) population density was the key factor influencing the supply and demand of carbon sequestration, oxygen release, water conservation, and food provision services, while the proportions of forest land and construction areas had the greatest influence on the supply and demand of air purification and leisure services. It is important to ensure the ecological status of the northwestern, southwestern, and central mountainous and forested areas; maintain the agricultural status of the main grain-producing areas in the eastern plains; strengthen ecological restoration and green infrastructure in built-up areas; and formulate differentiated management policies to promote the sustainable supply of ES and safeguard the ecological security of the region.

Stable isotopic evidence for increased terrestrial productivity through geological time

Marine life on Earth is known back to the Archean Eon, when life on land is assumed to have been less pervasive than now. Precambrian life on land can now be tested with stable isotopes because living soil CO2 is isotopically distinct for both carbon and oxygen from both marine and volcanic CO2. Our novel compilation of previously published oxygen and carbon isotopic compositions of pedogenic and paleokarst carbonate can be compared with the coeval marine record. Long-term enrichment (to heavier isotopic composition) of oxygen, but no significant trend in carbon through time, long apparent from marine carbonate, is now demonstrated also for pedogenic and paleokarst carbonate. Oxygen isotopic enrichment is not due to changing global temperature or hypsometry, but to increased evapotranspiration and photosynthesis on larger continents. Differences in isotopic composition between land and sea have increased in an episodic fashion, peaking at times of major evolutionary innovations for life on land, and also at times of ice ages. The δ13C and δ18O divergences between land and sea correspond to terrestrial productivity spikes including evolution of Neoproterozoic (635 Ma) lichens, middle Ordovician (470 Ma) non-vascular land plants, middle Devonian (385 Ma) forests, early Cretaceous (125 Ma) angiosperms, and middle Miocene (20 Ma) sod grasslands.

Occurrence of Gravitational Collapse in the Accreting Neutron Stars of Binary-driven Hypernovae

The binary-driven hypernova (BdHN) model proposes long gamma-ray bursts (GRBs) originate in binaries composed of a carbon–oxygen (CO) star and a neutron star (NS) companion. The CO core collapse generates a newborn NS and a supernova that triggers the GRB by accreting onto the NSs, rapidly transferring mass and angular momentum to them. This article aims to determine the conditions under which a black hole (BH) forms from NS collapse induced by the accretion and the impact on the GRB’s observational properties and taxonomy. We perform three-dimensional, smoothed particle hydrodynamics simulations of BdHNe using up-to-date NS nuclear equations of state, with and without hyperons, and calculate the structure evolution in full general relativity. We assess the binary parameters leading either NS in the binary to the critical mass for gravitational collapse into a BH and its occurrence time, t col. We include a nonzero angular momentum of the NSs and find that t col ranges from a few tens of seconds to hours for decreasing NS initial angular momentum values. BdHNe I are the most compact (about 5 minute orbital period), promptly form a BH, and release ≳1052 erg of energy. They form NS–BH binaries with tens of kiloyears merger timescales by gravitational-wave emission. BdHNe II and III do not form BHs, and release ∼1050–1052 erg and ≲1050 erg of energy, respectively. They form NS–NS binaries with a range of merger timescales larger than for NS–BH binaries. In some compact BdHNe II, either NS can become supramassive, i.e., above the critical mass of a nonrotating NS. Magnetic braking by a 1013 G field can delay BH formation, leading to BH–BH or NS–BH with tens of kiloyears merger timescales.

Mechanisms of Thermal Decomposition in Spent NCM Lithium-Ion Battery Cathode Materials with Carbon Defects and Oxygen Vacancies.

Resource recovery from retired electric vehicle lithium-ion batteries (LIBs) is a key to sustainable supply of technology-critical metals. However, the mainstream pyrometallurgical recycling approach requires high temperature and high energy consumption. Our study proposes a novel mechanochemical processing combined with hydrogen (H2) reduction strategy to accelerate the breakdown of ternary nickel cobalt manganese oxide (NCM) cathode materials at a significantly lower temperature (450 °C). Particle refinement, material amorphization, and internal energy storage are considered critical success factors for the accelerated decomposition of NCM cathode materials. In our proposed approach, NCM cathode materials can develop active sites with carbon defects (Cv) and oxygen vacancies (Ov), which improve the reduction and breakdown of H2. The adsorbed H2 on the surface of NCM decomposes into H* and combines with oxygen to form OH species, which can be facilitated by Ov via the enhanced charge transfer. The introduced Cv can enhance H2 cracking and generate *C-H species to promote the thermal decomposition of NCM. The presence of defects proves to foster the preferential reduction of Mn(IV) by H2, leading to a lower activation energy for the NCM decomposition (from 139 to 110 kJ/mol) with less H2 consumption. Life cycle assessment suggests a reduction of 4.42 kg CO2 eq for the recycling of every 1.0 kg of retired batteries. This study can promote material circularity and minimize the environmental burden of mining technology-critical metals for a low-carbon transition.

Breakdown cost and recycling processes of Bentonite/TiO2 quantum dots of photo and solar degradation of Congo Red dye and industrial dyes wastes

This research presents the preparation, characterization, and application of a novel bentonite- TiO2 quantum dot (Bent/TQ) nanocomposite for the efficient photodegradation of Congo Red dye, a common pollutant in industrial wastewater. The composite was prepared via a co-precipitation method followed by calcination, which facilitated the uniform dispersion of TiO2 quantum dots within the bentonite matrix. The resulting material exhibited a high specific surface area of 205.45 m2/g and an optimized band gap of 3.15 eV, making it suitable for visible light photocatalysis. The photocatalytic efficiency of Bent/TQ was evaluated under both xenon lamp irradiation and natural sunlight. The composite demonstrated a significant degradation rate constant of 23.35 × 10⁻³ s⁻1, which is comparable to that of pure TiO2 quantum dots (28.86 × 10⁻³ s⁻1). Mechanistic studies revealed that the primary active species responsible for the degradation were hydroxyl radicals (•OH), generated through the interaction of photogenerated electron-hole pairs with H2O molecules and molecular oxygen. Total Organic Carbon (TOC) and Chemical Oxygen Demand (COD) analyses were employed to assess the mineralization efficiency of the composite. The Bent/TQ catalyst achieved a COD removal efficiency of 84.5% and a TOC reduction of 76.2% after 240 minutes of irradiation under natural sunlight. Reusability tests indicated that the photocatalyst retained approximately 80% of its original efficiency after seven consecutive cycles, though a slight decline was observed due to particle agglomeration under prolonged light exposure. The economic analysis suggested that the use of Bent/TQ nanocomposites could reduce operational costs by 29.12% compared to conventional TiO2-based systems, making it a cost-effective solution for large-scale wastewater treatment. This work highlights the potential of Bent/TQ nanocomposites as sustainable and efficient photocatalysts for environmental remediation, with future efforts aimed at enhancing their long-term stability and expanding their applicability to a broader range of pollutants.

No Evidence for a Dip in the Binary Black Hole Mass Spectrum

Stellar models indicate that the core compactness of a star, which is a common proxy for its explodability in a supernova, does not increase monotonically with the star’s mass. Rather, the core compactness dips sharply over a range of carbon–oxygen core masses; this range may be somewhat sensitive to the star’s metallicity and evolutionary history. Stars in this compactness dip are expected to experience supernovae leaving behind neutron stars, whereas stars on either side of this range are expected to form black holes. This results in a hypothetical mass range in which black holes should seldom form. Quantitatively, when applied to binary stripped stars, these models predict a dearth of binary black holes with component masses ≈10M ⊙–15M ⊙. The population of gravitational-wave signals indicates potential evidence for a dip in the distribution of chirp masses of merging binary black holes near ≈10M ⊙–12M ⊙. This feature could be linked to the hypothetical component mass gap described above, but this interpretation depends on what assumptions are made of the binaries’ mass ratios. Here, we directly probe the distribution of binary black hole component masses to look for evidence of a gap. We find no evidence for this feature using data from the third gravitational-wave transient catalog. If this gap does exist in nature, we find that it is unlikely to be resolvable by the end of the current (fourth) LIGO–Virgo–KAGRA observing run.

Gas Transfer Across Air‐Water Interfaces in Inland Waters: From Micro‐Eddies to Super‐Statistics

AbstractIn inland water covering lakes, reservoirs, and ponds, the gas exchange of slightly soluble gases such as carbon dioxide, dimethyl sulfide, methane, or oxygen across a clean and nearly flat air‐water interface is routinely described using a water‐side mean gas transfer velocity , where overline indicates time or ensemble averaging. The micro‐eddy surface renewal model predicts , where is the molecular Schmidt number, is the water kinematic viscosity, and is the waterside mean turbulent kinetic energy dissipation rate at or near the interface. While has been reported across a number of data sets, others report large scatter or variability around this value range. It is shown here that this scatter can be partly explained by high temporal variability in instantaneous around , a mechanism that was not previously considered. As the coefficient of variation in increases, must be adjusted by a multiplier that was derived from a log‐normal model for the probability density function of . Reported variations in with a macro‐scale Reynolds number can also be partly attributed to intermittency effects in . Such intermittency is characterized by the long‐range (i.e., power‐law decay) spatial auto‐correlation function of . That varies with a macro‐scale Reynolds number does not necessarily violate the micro‐eddy model. Instead, it points to a coordination between the macro‐ and micro‐scales arising from the transfer of energy across scales in the energy cascade.

Understanding and estimating the role of large-scale seaweed cultivation for carbon sequestration on a global scale over the past two decades

Seaweeds, as marine photosynthetic organisms, are harvested by humans from the wild or through cultivation for various production purposes and to provide a range of marine ecosystem services, including nutrient removal, oxygen production, and carbon sequestration. The potential use of cultivated seaweed in mitigating carbon dioxide (CO2) has been extensively proposed in conjunction with commercial seaweed production worldwide. This study aims to assess the annual potential and benefits of cultivated seaweed in reducing and fixing anthropogenic CO2. Over the past two decades (2000–2019), global seaweed production has seen significant growth. The total output of cultivated seaweed reached 407.4 × 107 tons (t), with coastal mariculture removing 4.26 × 107 t of carbon annually and wild capture removing 2.24 × 106 t. The recalcitrant dissolved organic carbon (RDOC, 549.88–621.60 × 104 t) plays a significant role in the carbon sinks of seaweed cultivation. The substantial benefits of carbon sink resulting from the formation of RDOC from seaweed make up a considerable proportion in the calculation of carbon sequestration and sink enhancement benefits in large-scale seaweed cultivation. The sizable carbon sink base of seaweed cultivation (8631.90–9567.37 × 104 t) results in significant carbon fixation benefits. The total economic value of carbon sequestration and oxygen production was estimated at $70.36 ± 1.52 billion, with an annual average benefit of $3.52 ± 1.70 billion. Increasing the area and yield available for cultivated seaweed has the potential to enhance biomass production, carbon accumulation, and CO2 drawdown. It is crucial to emphasize the need for improved communication regarding the essential criteria for the feasibility of CO2 removal (CDR), with a focus on conducting life cycle assessments (LCA) when utilizing marine processes in the present and future work. The sustainable development of the seaweed cultivation industry not only ensures that Asian-Pacific countries remain leaders in this field but also provides an effective yet overlooked solution to excessive CO2 emissions worldwide.

Magnetic Field Evolution for Crystallization-driven Dynamos in C/O White Dwarfs

We investigate the evolution of magnetic fields generated by the crystallization-driven dynamo in carbon–oxygen white dwarfs (WDs) with masses ≲1.05 M ⊙. We use scalings for the dynamo to demonstrate that the initial magnetic field strength (B 0) has an upper limit that depends on the initial convection zone size (R out,0) and the WD mass. We solve the induction equation to follow the magnetic field evolution after the dynamo phase ends. We show that the predicted surface magnetic field strength (B surf) differs from B 0 by at least a factor of ∼0.3. This reduction depends on R out,0, where values smaller than half of the star radius give B surf ≲ 0.01 B 0. We implement electrical conductivities that account for the solid phase effect on the ohmic diffusion. We observe that the conductivity increases as the solid core grows, freezing in the magnetic field at a certain point of the evolution and slowing its outward transport. We study the effect of turbulent magnetic diffusivity induced by the convection and find that for a small R out,0, B surf is stronger than the nonturbulent diffusion cases because of the more rapid transport, but still orders of magnitude smaller than B 0. Given these limitations, the crystallization-driven dynamo theory could explain only magnetic C/O WDs with field strengths less than a few megagauss for the mass range 0.45–1.05 M ⊙. Our results also suggest that a buried fossil field must be at least 100 times stronger than observed surface fields if crystallization-driven convection is responsible for its transport to the surface.

VENO-VENOUS EXTRACORPOREAL MEMBRANE OXYGENATION IMPROVES OUTCOMES IN TRAUMA PATIENTS SUFFERING RESPIRATORY FAILURE.

Veno-venous extracorporeal membrane oxygenation (VV ECMO) improves hypoxemia and carbon dioxide clearance in patients with severe respiratory derangements. A greater understanding of the potential benefits of VV ECMO in trauma patients could lead to broader adoption. We hypothesize that trauma patients who receive VV ECMO have improved mortality outcomes when compared to those receiving conventional ventilator management given the rapid stabilization VV ECMO promotes. We performed a single center, propensity score matched cohort study. All trauma patients from January 1, 2014, to October 30, 2023, who were placed on VV ECMO or who would have met institutional guidelines for VV ECMO but were managed with conventional ventilator strategies were matched 1:1. The primary outcome analysis was survival at hospital discharge. Significance was defined as p < 0.05. Eighty-one trauma VV ECMO patients and 128 patients who received conventional management met criteria for inclusion. After matching, VV ECMO and conventional treatment cohort characteristics were similar in age and MOI. Matched ISS, SI, lactate levels, and frequency of TBI were also similar. Finally, respiratory parameters including pre-intervention, pH, partial pressure of carbon dioxide (PaCO2), lactate levels, and oxygen saturation were similar between matched groups. VV ECMO patients had higher survival rates at discharge when compared to the matched conventional treatment group (70% v 41%, p < 0.001). Corresponding hazard ratio for VV ECMO use was 0.31 (95%CI 0.18-0.52; p < 0.001). The odds ratio of mortality in matched trauma patients who receive VV ECMO versus conventional treatment was 0.29 (95%CI 0.14-0.58; p < 0.001). VV ECMO may represent a safe, alternative treatment approach for appropriately screened trauma patients with acute respiratory failure, however further studies are warranted.

Hydrodynamic simulations of white dwarf–white dwarf mergers and the origin of R Coronae Borealis stars

ABSTRACT We study the properties of double white dwarf (DWD) mergers by performing hydrodynamic simulations using the new and improved adaptive mesh refinement code octo-tiger. We follow the orbital evolution of DWD systems of mass ratio $q=0.7$ for tens of orbits until and after the merger to investigate them as a possible origin for R Coronae Borealis (RCB) type stars. We reproduce previous results, finding that during the merger, the helium WD donor star is tidally disrupted within 20–80 min since the beginning of the simulation onto the accretor carbon–oxygen WD, creating a high temperature shell around the accretor. We investigate the possible helium burning in this shell and the merged object’s general structure. Specifically, we are interested in the amount of oxygen-16 dredged-up from the accretor to the hot shell and the amount of oxygen-18 produced. This is critical as the discovery of very low oxygen-16 to oxygen-18 ratios in RCB stars pointed out the merger scenario as a favourable explanation for their origin. A small amount of hydrogen in the donor may help keep the oxygen-16 to oxygen-18 ratios within observational bounds, even if moderate dredge-up from the accretor occurs. In addition, we perform a resolution study to reconcile the difference found in the amount of oxygen-16 dredge-up between smoothed-particle hydrodynamics and grid-based simulations.

Tandem mass tag-based quantitative proteomics analysis of modified atmosphere packaging in large yellow croaker (Pseudosciaena crocea) fillets during refrigerated storage

A tandem mass tagging-labeled proteomic approach was employed to explore the relationship between quality parameters and protein changes in large yellow croaker fillets refrigerated under carbon dioxide, oxygen, and nitrogen atmospheres. After 96 h, fillets stored in carbon dioxide and nitrogen showed improved texture, water-holding capacity, and color, compared to those stored in oxygen. Functional analysis respectively identified 117 and 65 differentially expressed proteins in carbon dioxide and nitrogen, including key proteins such as troponin, myosin light chain, actin, and collagen types IV and XIII, that were linked to extracellular adhesion, cytoskeleton integrity, energy metabolism, and membrane functions. Carbon dioxide and nitrogen were detrimental to the growth and reproduction of aerobic microorganisms. High concentrations of carbon dioxide can inhibit microbial activity, while nitrogen preserves freshness by regulating the pressure balance within the packaging. These findings provided a theoretical basis for the optimized gas-conditioned preservation of large yellow croaker fillets.