Oxygen Lines Research Articles

Theoretical Strong-line Metallicity Diagnostics for the JWST Era

The ratios of strong rest-frame optical emission lines are the dominant indicators of metallicities in high-redshift galaxies. Since typical strong-line-based metallicity indicators are calibrated on auroral lines at z = 0, their applicability for galaxies in the distant Universe is unclear. In this paper, we make use of mock emission-line data from cosmological simulations to investigate the calibration of rest-frame optical emission lines as metallicity indicators at high redshift. Our model, which couples the simba cosmological galaxy formation simulation with cloudy photoionization calculations, includes contributions from H ii regions, post-asymptotic-giant-branch stars, and diffuse ionized gas (DIG). We find mild redshift evolution in the 12 indicators that we study, which implies that the dominant physical properties that evolve in our simulations do have a discernible impact on the metallicity calibrations at high redshifts. When comparing our calibrations with high-redshift auroral line observations from the James Webb Space Telescope, we find a slight offset between our model results and the observations and find that a higher ionization parameter at high redshifts can be one of the possible explanations. We explore the physics that drives the shapes of strong-line metallicity relationships and propose calibrations for hitherto unexplored low-metallicity regimes. Finally, we study the contribution of DIG to total line fluxes. We find that the contribution of DIG increases with metallicity at z ∼ 0 for singly ionized oxygen and sulfur lines and can be as high as 70%, making it crucial to include their contribution when modeling nebular emission.

EROSITA narrowband maps at the energies of soft X-ray emission lines

Hot plasma plays a crucial role in regulating the baryon cycle within the Milky Way, flowing from the energetic sources in the Galactic center and plane, to the corona and the halo. This hot plasma represents an important fraction of the Galactic baryons, plays a key role in galactic outflows and is an important ingredient in galaxy evolution models. Taking advantage of the Spectrum-Roentgen-Gamma (SRG first all-sky survey (eRASS1), in this work our aim is to provide a panoramic view of the hot circumgalactic medium (CGM) of the Milky Way. Compared to the previous all-sky X-ray survey performed by ROSAT, the improved energy resolution of enabled us to map, for the first time, the sky within the narrow energy bands characteristic of soft X-ray emission lines. These lines provide essential information on the physical properties of the hot plasma. Here we present the eRASS1\ half sky maps in narrow energy bands corresponding to the most prominent soft X-ray lines and which allowed us to constrain the distribution of the hot plasma within and surrounding the Milky Way. We corrected the maps by removing the expected contribution associated with the cosmic X-ray background, the time-variable solar wind charge exchange, and the local hot bubble. We applied corrections to mitigate the effect of absorption, therefore highlighting the emission from the CGM of the Milky Way. We used the line ratio of the oxygen lines as a proxy to constrain the temperature of the warm-hot CGM, and we defined a pseudo-temperature $ T $ map. The map highlights how different regions are dominated by different thermal components. Toward the outer halo, the temperature distribution of the CGM on angular scales of 2--20 deg is consistent with being constant $ T T 4<!PCT!>$ with a marginal detection of $ T T = 2.7 <!PCT!> 0.2<!PCT!>$ (statistical) $ 0.6<!PCT!>$ (systematic) in the southern hemisphere. Instead significant variations of $ 12<!PCT!>$ are observed on scales of many tens of degrees when comparing the northern and southern hemispheres. The pseudo-temperature map shows significant variations across the borders of the bubbles, suggesting temperature variations, possibly linked to shocks, between the interior of the Galactic outflow and the unperturbed CGM. In particular, a shell characterized by a lower line ratio appears close to the edge of the bubbles.

Gas conditions of a star-formation selected sample in the first billion years

ABSTRACT We present Atacama Large Millimetre/submillimetre Array (ALMA) observations of the [O iii] 88 $\mu {\rm m}$ emission of a sample of thirteen galaxies at $z = 6$ to 7.6 selected as [C ii]-emitting companion sources of quasars. To disentangle the origins of the luminous Oxygen line in the $z\, \gt\, 6$ Universe, we looked at emission-line galaxies that are selected through an excellent star-formation tracer [C ii] with star-formation rates between 9 and 162 $\rm {\rm M}_{\odot }\,yr^{-1}$. Direct observations reveal [O iii] emission in just a single galaxy ($L_\mathrm{[O\, {\small III}]}/L_\mathrm{[C\, {\small II}]}$$\, = 2.3$), and a stacked image shows no [O iii] detection, providing deep upper limits on the $L_\mathrm{[O\, {\small III}]}/L_\mathrm{[C\, {\small II}]}$ ratios in the $z \gt 6$ Universe ($L_\mathrm{[O\, {\small III}]}/L_\mathrm{[C\, {\small II}]}$$\, \lt 1.2$ at $3 \sigma$). While the fidelity of this sample is high, no obvious optical/near-infrared counterpart is seen in the JWST imaging available for four galaxies. Additionally accounting for low-z CO emitters, line stacking shows that our sample-wide result remains robust: The enhanced $L_\mathrm{[O\, {\small III}]}/L_\mathrm{[C\, {\small II}]}$ reported in the first billion years of the Universe is likely due to the selection towards bright, blue Lyman-break galaxies with high surface star-formation rates or young stellar populations. The deep upper limit on the rest-frame 90 μm continuum emission ($\lt 141 \mu$Jy at $3 \sigma$), implies a low average dust temperature ($T_\mathrm{dust} \lesssim 30\,$ K) and high-dust mass ($M_\mathrm{dust} \sim 10^8\, \mathrm{M}_\odot$). As more normal galaxies are explored in the early Universe, synergy between JWST and ALMA is fundamental to further investigate the ISM properties of the a broad range of samples of high-z galaxies.

Полярные сияния в периоды экстремальных геомагнитных бурь: особенности среднеширотного сияния 11 февраля 1958 г.

This paper discusses peculiarities of the great mid-latitude aurora that occurred during the extreme magnetic storm on February 11, 1958. This mid-latitude aurora had unusual optical and spectral characteristics, among which, first of all, were very high (10⁵–10⁸ R) intensities of atomic oxygen [OI] 630.0 nm emission and an unusually high ratio of the intensities of two forbidden lines of oxygen [OI] 630.0 nm and 557.7 nm (I₆₃₀/I₅₅₇.₇). In some points, this ratio was as high as 10³–10⁴. Analysis of I₆₃₀ dynamics during other extreme geomagnetic storms and associated geophysical conditions and physical processes in Earth’s ionosphere and magnetosphere allows us to assume that great mid-latitude auroras are formed during intense substorms in main phases of magnetic storms. In order to interpret the observed features of the February 11, 1958 mid-latitude aurora, we propose to examine the mechanism of level [OI] ¹D selective filling in which reactions of resonance recharge of oxygen ions O⁺(²D)+O (³P)→O⁺(⁴S)+O(³P, ¹D) and/or reactions of oxygen atom and molecule collisions with excited components of odd nitrogen can be implemented.

Auroras during extreme geomagnetic storms: Some features of mid-latitude aurora on February 11, 1958

This paper discusses peculiarities of the great mid-latitude aurora that occurred during the extreme magnetic storm on February 11, 1958. This mid-latitude aurora had unusual optical and spectral characteristics, among which, first of all, were very high (10⁵–10⁸ R) intensities of atomic oxygen [OI] 630.0 nm emission and an unusually high ratio of the intensities of two forbidden lines of oxygen [OI] 630.0 nm and 557.7 nm (I₆₃₀/I₅₅₇.₇). In some points, this ratio was as high as 10³–10⁴. Analysis of I₆₃₀ dynamics during other extreme geomagnetic storms and associated geophysical conditions and physical processes in Earth’s ionosphere and magnetosphere allows us to assume that great mid-latitude auroras are formed during intense substorms in main phases of magnetic storms. In order to interpret the observed features of the February 11, 1958 mid-latitude aurora, we propose to examine the mechanism of level [OI] ¹D selective filling in which reactions of resonance recharge of oxygen ions O⁺(²D)+O (³P)→O⁺(⁴S)+O(³P, ¹D) and/or reactions of oxygen atom and molecule collisions with excited components of odd nitrogen can be implemented.

EMPRESS. XIV. Strong High-ionization Lines of Young Galaxies at z = 0–8: Ionizing Spectra Consistent with the Intermediate-mass Black Holes with M BH ∼ 103–106 M ⊙

We present ionizing spectra estimated at 13.6–100 eV for 10 dwarf galaxies with strong high-ionization lines of He ii λ4686 and [Ne v] λ3426 ([Ne iv] λ2424) at z = 0 (z = 8) that are identified in our Keck/LRIS spectroscopy and the literature (the JWST Early Release Observations program). With the flux ratios of these high-ionization lines and >10 low-ionization lines of hydrogen, helium, oxygen, neon, and sulfur, we determine ionizing spectra consisting of stellar and nonthermal power-law radiation by photoionization modeling with free parameters of nebular properties, including metallicity and ionization parameter, canceling out abundance ratio differences. We find that all of the observed flux ratios are well reproduced by the photoionization models with the power-law index α EUV of α EUV ∼ (–1) − 0 and the luminosity L EUV of L EUV ∼ 1040–1042 erg s−1 at ∼55–100 eV for six galaxies, while four galaxies include large systematics in α EUV caused by stellar radiation contamination. We then compare α EUV and L EUV of these six galaxies with those predicted by the black hole (BH) accretion disk models and find that α EUV and L EUV are similar to those of the intermediate-mass BHs (IMBHs) in BH accretion disk models, albeit with possibilities of the other scenarios. Confirming these results with a known IMBH having a mass M BH of M BH = 105.75 M ⊙, we find that four local galaxies and one z = 7.665 galaxy have ionizing spectra consistent with those of IMBHs with M BH ∼ 103–105 M ⊙.

Hyperspectral imaging of a microwave argon plasma jet expanding in ambient air.

Non-equilibrium plasmas at atmospheric pressure are often characterized by optical emission spectroscopy. Despite the simplicity of recording optical emission spectra in plasmas, the determination of spatially resolved plasma properties (e.g., electron temperature) in an efficient way is very challenging. In this study, spatially resolved optical images of a microwave argon plasma jet expanding into the ambient air are recorded over a wide range of wavelengths using a hyperspectral imaging system based on a tunable Bragg-grating imager coupled to a scientific complementary metal-oxide-semiconductor camera. The system's working principle is detailed, along with the necessary post-processing steps. Further analysis of the spatial-spectral data, including the Abel transform used to determine 2D radially resolved spatial mappings, is also presented. Overall, the proposed approach provides unprecedented cartographies of key plasma parameters, such as argon and oxygen line emission intensities, Ar metastable number densities, and argon excitation temperatures. Considering that all these plasma parameters are obtained from measurements performed in a reasonable time, Bragg-grating-based hyperspectral imaging constitutes an advantageous plasma diagnostic technique for detailed analysis of microwave plasma jets used in several applications.

Technoeconomic Analysis of Oxygen-Supported Combined Systems for Recovering Waste Heat in an Iron-Steel Facility

In this study, it is proposed to generate electrical energy by recovering the waste heat of an annealing furnace (AF) in an iron and steel plant using combined cycles such as steam Rankine cycle (SRC), organic Rankine cycle (ORC), Kalina cycle (KC) and transcritical CO2 cycle (t-CO2). Instead of releasing the waste heat into the atmosphere, the waste heat recovery system (WHRS) discharges the waste heat into the plant’s low-temperature oxygen line for the first time, achieving a lower temperature and pressure in the condenser than conventional systems. The waste heat of the flue gas (FG) with a temperature of 1093.15 K from the reheat furnace was evaluated using four different cycles. To maximize power generation, the SRC input temperature of the proposed system was studied parametrically. The cycles were analyzed based on thermal efficiency and net output power. The difference in SRC inlet temperature is 221.6 K for maximum power output. The proposed system currently has a thermal efficiency and total power output of 0.19 and 596.6 kW, respectively. As an environmental impact, an emission reduction potential of 23.16 tons/day was achieved. In addition, the minimum power generation cost of the proposed system is $0.1972 per kWh.

Gas in scattering media absorption spectroscopy for time-resolved characterization of gas diffusion processes in porous materials

Signal denoising is a serious problem for in-situ laser diagnostics of gases dispersed in porous materials. An optical sensor system based on absorption spectroscopy of gases in a scattering environment was built using a 3D printed cell with reference samples of polystyrene foam. Selected A-band spectral lines of molecular oxygen were investigated using wavelength modulated spectroscopy with second harmonic detection. Quantitative information on the concentration of analyte dispersed in the porous medium was obtained at extremely low signal-to-noise ratio (SNR < 10). A spectral line shape fitting procedure based on the Gabor transform followed by a filtered inverse fast Fourier transform allowed to achieve a relatively high SNR with good linearity over a range of reduced oxygen concentrations in air. Finally, the applicability of the optical sensor system to monitor the diffusion of carbon dioxide into air dispersed in a Styrofoam sample and vice versa was successfully demonstrated.

A Fast Forward Modelling Method for Simulating Satellite Observations Using Observing Path Tracking

The higher the atmosphere is, the larger the deviations in atmospheric temperature and humidity are between the vertical column atmosphere above the cross-section of a satellite instrument and a ray’s trajectory from the cross-section to the satellite. In general, satellite instruments that observe using cross-orbit scanning result in the difference between the observed radiance and the simulations using this method becoming incrementally larger and larger as the cross-section moves to the edge of the satellite’s orbit. The deviations depend on the distance from the column to the ray trajectory and on the horizontal gradient of variables in the distance. In fact, the horizontal gradient of water vapour is larger than the gradient of temperature in clear scenarios, which could introduce an impact of temperature and water vapour on the simulated radiance of a satellite. In this study, a new method to simulate upgoing and downgoing radiation synchronously was developed, using the observing path tracking method. The conventional vertical initial atmospheric profile (Exp.1) and the profiles along the upgoing and downgoing rays of the satellite’s observation (Exp.2) were established, in order to simulate the observed radiance of MWHS-II of FY-3D using global numerical forecasts with resolutions of 15 km and 25 km. The results showed that, for channels in the oxygen and water vapour absorption line on the microwave spectrum, deviations of the two atmospheric profiles were larger at the scan edge (0.01 K) than those at the nadir (0.001 K), and were larger in the upper atmosphere than in the lower atmosphere. The deviation was usually negative in low-latitude regions and was positive in southern high-latitude regions. Such results were obtained in experiments using both the numerical forecast method with 15 km grids and the forecast method with 25 km grids. Deviations were analysed for representative channels at 118 GHz and 183 GHz. Then, the results indicated that bigger deviations between the two experiments were observed in the water vapour absorption line than in the oxygen absorption line in the microwave spectrum. In conclusion, this indicates that, because of the greater horizontal gradient of water vapour, the stronger localisation of water vapour makes the atmospheric profile along the satellite’s observing ray have more increments in the simulated radiance at the scan edge, compared to the atmospheric column profile.

Optical spectroscopy of comets using Hanle Echelle Spectrograph (HESP)

ABSTRACT Observing the vibrational/rotational lines in a comet’s optical spectrum requires high-resolution spectroscopy, as they are otherwise seen as a blended feature. To achieve this, we have obtained medium and high-resolution (R (λ/Δλ) = 30 000 and 60 000) spectra of several comets, including C/2015 V2 (Johnson), 46P/Wirtanen, 41P/Tuttle–Giacobini–Kresák, and 38P/Stephan–Oterma, using the Hanle Echelle Spectrograph (HESP) mounted on the 2-m Himalayan Chandra Telescope (HCT) in India. The spectra effectively cover the wavelength range 3700–10 000 Å, allowing us to probe the various vibrational bands and band sequences to identify the rotational lines in the cometary molecular emission. We were also able to separate the cometary Oxygen lines from the telluric lines and analyse the green-to-red (G/R) forbidden oxygen [O i] ratios in a few comets. For comets C/2015 V2, 46P, and 41P, the computed G/R ratios, 0.04 ± 0.01, 0.04 ± 0.01, and 0.08 ± 0.02, respectively, point to H2O being a major source of Oxygen emissions. Notably, in the second fibre pointing at a location 1000 km away from the photocentre of comet 46P, the G/R ratio reduced by more than half the value observed in the first fibre, indicating the effects of quenching within the inner coma. We also measured the NH2 ortho-to-para ratio of comet 46P to be about 3.41 ± 0.05 and derived an ammonia ratio of 1.21 ± 0.03 corresponding to a spin temperature of ∼26 K. With these, we present the results of the study of four comets from different cometary reservoirs using medium and high-resolution optical spectroscopy, emphasizing the capabilities of the instrument for future cometary studies.

One hundred optical emission lines of molecular hydrogen from a low-metallicity photodissociation region

ABSTRACT We report the detection of a rich spectrum of more than one hundred optical emission lines of vibrationally hot molecular hydrogen (H2) from the photodissociation region (PDR) around the mini-starburst cluster NGC 346 in the Small Magellanic Cloud. The lines are concentrated in the spectral range $6000 \, {{\mathring{\rm A}}}$ to $9300 \, {{\mathring{\rm A}}}$ and have observed brightnesses ranging from 0.01 per cent to 0.4 per cent times that of the H β λ4861 hydrogen recombination line. Analysis of the spatial distribution of the H2 lines shows that they originate from a range of depths in the PDR, intermediate between the shallow layers probed by fluorescent lines of neutral nitrogen and oxygen, and the more shielded layers probed by neutral carbon recombination lines. Comparison with other PDRs shows that the relative strength of the H2 lines with respect to the [$\mathrm{C\, \scriptstyle I}$] λ8727 line increases rapidly with decreasing metallicity, being at least 40 times larger in NGC 346 than in the prototypical PDR of the Orion Bar. The internal PDR dust extinction is also found to be anomalously low in NGC 346. A separate result is the discovery of a high-ionization bow shock around the O2 star Walborn 3.

Radio-optical synergies at high redshift to constrain primordial non-Gaussianity

We apply the multi-tracer technique to test the possibility of improved constraints on the amplitude of local primordial non-Gaussianity, f_NL, in the cosmic large-scale structure. A precise measurement of f_NL is difficult because the effects of non-Gaussianity mostly arise on the largest scales, which are heavily affected by the low statistical sampling commonly referred to as cosmic variance. The multi-tracer approach suppresses cosmic variance and we implement it by combining the information from next-generation galaxy surveys in the optical/near-infrared band and neutral hydrogen (Hi) intensity mapping surveys in the radio band. High-redshift surveys enhance the precision on f_NL, due to the larger available volume, and Hi intensity mapping surveys can naturally reach high redshifts. In order to extend the redshift coverage of a galaxy survey, we consider different emission-line galaxy populations, focusing on the Hα line at low redshift and on oxygen lines at higher redshift. By doing so, we cover a wide redshift range 1≲ z≲4. To assess the capability of our approach, we implement a synthetic-data analysis by means of Markov chain Monte Carlo sampling of the (cosmological+nuisance) parameter posterior, to evaluate the constraints on f_NL obtained in different survey configurations. We find significant improvements from the multi-tracer technique: the full data set leads to a precision of σ(f_NL)<1.

Study of Iron and Stony Meteorite Ablation Based on Simulation Experiments in an Arc Heater

To observe meteorite ablation, simulation experiments were conducted on the L5 ordinary chondrite and IAB-MG iron meteorites in an arc-heated facility and three flight conditions were reproduced. To mimic the high heating rates and the significant shear stress that meteorites experience during Earth entry, the samples were machined into 9° spherical cones with a 20 mm nose radius. High-quality video, the surface temperature, a time-resolved spectrum, and infrared video were recorded. The atom species were determined via spectroscopy to analyze the ablation products. Due to the electrode erosion and dissociation of air, the atomic lines of copper, nitrogen, and oxygen were detected in all the tests. Although the copper atom is a pollutant to the flow field, the five copper lines were used to determine the flow-field temperature. The ablation rates and effective heat of ablation of both the samples were measured under different conditions. The results indicate that shear stress is the dominant factor influencing meteorite ablation. Furthermore, the diversity between stony and iron meteorites suggests that the mass loss of stony meteorites depends on the fragmentation of the main body and that of iron meteorites depends on the shearing loss of the molten layer. Then, the fusion crusts were analyzed, the microstructures of the samples were obtained, the crust thicknesses were measured, and the elemental distribution of the stony meteorites was determined via energy dispersion spectroscopy. The study results explain the differences in the ablation and recrystallization process between stony and iron meteorites.

Properties and characteristics of the nanosecond discharge developing at the water–air interface: tracking evolution from a diffused streamer to a spark filament

The characteristics of nanosecond discharge propagating along the water–air interface in a unique dielectric-barrier discharge (DBD)-like configuration with coplanar electrodes submerged in deionised (DI)/tap water are studied by combining ultrafast imaging and emission spectra with electrical characteristics. Time-resolved images provide a clear signature of streamer channels excited on the water surface at either side of the blade (insulated plastic separating the anode/cathode) and propagating perpendicularly away from it towards the anode/cathode with different velocities. Later on, the streamer channels convert into a few discrete and bright discharge channels due to ionisation instability (spark phase). There is no distinctive dependence on water conductivity in the streamer phase, as the optical emission spectroscopy and images of discharges only showed an increase of the luminosity and no significant changes in morphology. However, in the spark phase, more numerous, brighter, and thicker filaments form in tap water. The time-resolved emission spectra reveal the dominance of the first and second positive system of N2 molecular bands in the streamer phase, followed by the appearance of atomic lines of hydrogen, nitrogen, and oxygen in the spark phase. The emission spectra are utilised to estimate several important parameters (gas temperature, reduced electric field ( E/N ), and electron density ( ne )). The streamer phase is characterised by a low gas temperature and a peak E/N amplitude between 700 and 850 Td. On the other hand, the subsequent spark phase is characterised by a gas temperature of ∼400/1100 K and a free electron density up to ne∼1017 –1018 cm−3 in DI/tap water.

Line Profiles of Forbidden Emission Lines and What They Can Tell Us About Protoplanetary Disk Winds

Emission in forbidden lines of oxygen, neon, and other species are commonly used to trace winds from protoplanetary disks. Using Cloudy, we calculate such emission for parametrized wind models of the magnetothermal type, following Bai et al. These models share characteristics with both photoevaporative and magnetocentrifugal winds, which can be regarded as end members, and are favored by recent theoretical research. Both broad and narrow low-velocity components of the lines can be produced with plausible wind parameters, something that traditional wind models have difficulty with. Line luminosities, blueshifts, and widths, as well as trends of these with accretion luminosity and disk inclination, are in general accordance with observations.

Dwarfs in nearby voids: results of SALT spectroscopy

ABSTRACT In the framework of the ongoing project, aimed at the systematical studying galaxies in nearby voids, we conducted spectroscopy with the Southern African Large Telescope (SALT) of 62 objects from the Nearby Void Galaxy (NVG) sample. They include 8 remaining objects of the 60 pre-selected candidates to eXtremely Metal-Poor (XMP) dwarfs, two known void XMP dwarfs and 52 void dwarfs residing within the Local Volume. For 47 galaxies residing in the nearby voids, we obtained spectra of the diverse quality. For 42 of them, we detected the Hydrogen and Oxygen lines that allowed us to get estimates of O/H in the observed H ii regions. For 12 of the 42 objects, we detected the faint line [O iii]λ4363, that allowed us to directly derive the electron temperature Te and obtain their gas O/H by the direct method. 14 objects with the undetected [O iii]λ4363 line fall to the lowest metallicities range (12+log(O/H) ≲ 7.5 dex). For them, we use a carefully checked new empirical ‘Strong line’ method of Izotov et al. For 14 other objects with only strong lines detected and with 12+log(O/H) of ∼7.5–8.0 dex, we used the modified version of ‘semi-empirical’ method of Izotov and Thuan. It accounts for effect of the excitation parameter O32 on Te. 16 new galaxies are found with parameter 12+log(O/H) ≲ 7.39 dex. Of them, four have 12+log(O/H) = 7.07–7.20 dex. Of the 60 observed NVG objects, 15 have mistaken radial velocities in HyperLEDA. They do not reside in the nearby voids.

A precursor plateau and pre-maximum [O ii] emission in the superluminous SN2019szu: a pulsational pair-instability candidate

ABSTRACT We present a detailed study on SN2019szu, a Type I superluminous supernova at z = 0.213 that displayed unique photometric and spectroscopic properties. Pan-STARRS and ZTF forced photometry show a pre-explosion plateau lasting ∼40 d. Unlike other SLSNe that show decreasing photospheric temperatures with time, the optical colours show an apparent temperature increase from ∼15 000 to ∼20 000 K over the first 70 d, likely caused by an additional pseudo-continuum in the spectrum. Remarkably, the spectrum displays a forbidden emission line (likely attributed to λλ7320,7330) visible 16 d before maximum light, inconsistent with an apparently compact photosphere. This identification is further strengthened by the appearances of [O iii] λλ4959, 5007, and [O iii] λ4363 seen in the spectrum. Comparing with nebular spectral models, we find that the oxygen line fluxes and ratios can be reproduced with ∼0.25 M⊙ of oxygen-rich material with a density of $\sim 10^{-15}\, \rm {g\, cm}^{-3}$. The low density suggests a circumstellar origin, but the early onset of the emission lines requires that this material was ejected within the final months before the terminal explosion, consistent with the timing of the precursor plateau. Interaction with denser material closer to the explosion likely produced the pseudo-continuum bluewards of ∼5500 Å. We suggest that this event is one of the best candidates to date for a pulsational pair-instability ejection, with early pulses providing the low density material needed for the formation of the forbidden emission line, and collisions between the final shells of ejected material producing the pre-explosion plateau.

A Primordial Origin for the Gas-rich Debris Disks around Intermediate-mass Stars

While most debris disks consist of dust with little or no gas, a fraction have significant amounts of gas detected via emission lines of CO, ionized carbon, and/or atomic oxygen. Almost all such gaseous debris disks known are around A-type stars with ages up to 50 Myr. We show, using semianalytic disk evolution modeling, that this can be understood if the gaseous debris disks are remnant protoplanetary disks that have become depleted of small grains compared to the interstellar medium. Photoelectric heating by the A stars’ far-UV (FUV) radiation is then inefficient, while the stars’ extreme-UV (EUV) and X-ray emissions are weak owing to a lack of surface convective zones capable of driving magnetic activity. In this picture, it is relatively difficult for stars outside the range of spectral types from A through early B to have such long-lived gas disks. Less-massive stars have stronger magnetic activity in the chromosphere, transition region, and corona with resulting EUV and X-ray emission, while more-massive stars have photospheres hot enough to produce strong EUV radiation. In both cases, primordial disk gas is likely to photoevaporate well before 50 Myr. These results come from 0D disk evolution models where we incorporate internal accretion stresses, MHD winds, and photoevaporation by EUV and X-ray photons with luminosities that are functions of the stellar mass and age. A key issue this work leaves open is how some disks become depleted in small dust so that FUV photoevaporation slows. Candidates include the grains’ growth, settling, radial drift, radiation force, and incorporation into planetary systems.

Detectability of carbon with ChemCam LIBS: Distinguishing sample from Mars atmospheric carbon, and application to Gale crater

Onboard NASA's Curiosity rover, the ChemCam LIBS instrument has provided a wealth of information on the chemistry of rocks within Gale crater. Here, we use ChemCam in order to search for carbonates among the >3500 individual targets analyzed by this instrument. Because the carbon-lines are a combination of signal from the CO2-rich atmosphere and possible carbon from the targets, we developed a laboratory-based univariate calibration obtained under Mars-like atmosphere. We measured different type of carbon-bearing samples (sediments, coals, carbonates) and their mixture with a basaltic powder. Based on this work, the preferred approach to qualitatively assess carbon under a CO2-rich atmosphere is to use a ratio to an oxygen line (777 nm) and the estimated limit of detection for carbon in a single LIBS point are found to be of 4.5 wt% and 6.9 wt% for reduced and organic carbon, respectively. Considering carbonate, this LOD correspond to about 50 wt% carbonate in the analyzed volume.Analysis of data obtained on Mars by ChemCam up to sol 3350 reveals the presence of a correlation between the intensity of carbon and oxygen lines, as observed in the laboratory, confirming that most carbon signal is related to ionization of the atmosphere. Some variability in the carbon signal appears related to the physical state of the atmosphere (density, temperature).Based on a combined analysis of carbon lines and major element compositions (Ca, Fe, Mg), there was no detection of carbonate in the ChemCam dataset up to sol 3355. Therefore, we conclude that carbonate was not present as a major constituent (>50%) in the ChemCam LIBS targets, and that soils are not enriched in carbon beyond the limit of detection. The dominant salts present are sulfate, chlorides, and the lack of carbonates in Gale, while observed in Jezero, may at least partly be related to a difference in protolith.