Fractional Oxide Research Articles

Probabilistic Risk Assessment of Heavy Metals in Mining Soils Based on Fractions: A Case Study in Southern Shaanxi, China.

With rapid economic development, soil heavy metal (HM) pollution has emerged as a global environmental concern. Because the toxicity of HMs differs dramatically among various fractions, risk assessments based on these fractions are of great significance for environmental management. This study employed a modified Hakanson index approach to evaluate the possible ecological impacts of soil HMs in a gold mine tailings pond in Shaanxi Province, China. A modified Hakanson-Monte Carlo model was built to perform a probabilistic risk assessment. The results showed that: (1) the exceedance rates of chromium (Cr) and zinc (Zn) were 68.75% and 93.75%, respectively. Moreover, the overall concentrations of nickel (Ni), copper (Cu), arsenic (As), and lead (Pb) were higher than the background soil environmental values in China. (2) HMs with the lowest oxidizable fraction were mostly present in the residual fraction. The oxidizable portions of Cr, Cu, and Pb and the reducible and residual fractions of As were notably distinct. (3) The risk degrees of Cr, Ni, Cu, and Zn were low; those of As and Pb were very high and moderate; and the comprehensive ecological hazard index was very high. This study offers a solid scientific foundation for ecological risk notification and environmental management.

Specific Ventilation in Severe Asthma Evaluated with Noncontrast Tidal Breathing 1H MRI.

Purpose To determine if proton (1H) MRI-derived specific ventilation is responsive to bronchodilator (BD) therapy and associated with clinical biomarkers of type 2 airway inflammation and airways dysfunction in severe asthma. Materials and Methods In this prospective study, 27 participants with severe asthma (mean age, 52 years ± 9 [SD]; 17 female, 10 male) and seven healthy controls (mean age, 47 years ± 16; five female, two male), recruited between 2018 and 2021, underwent same-day spirometry, respiratory oscillometry, and tidal breathing 1H MRI. Participants with severe asthma underwent all assessments before and after BD therapy, and type 2 airway inflammatory biomarkers were determined (blood eosinophil count, sputum eosinophil percentage, sputum eosinophil-free granules, and fraction of exhaled nitric oxide) to generate a cumulative type 2 biomarker score. Specific ventilation was derived from tidal breathing 1H MRI and its response to BD therapy, and relationships with biomarkers of type 2 airway inflammation and airway dysfunction were evaluated. Results Mean MRI specific ventilation improved with BD inhalation (from 0.07 ± 0.04 to 0.11 ± 0.04, P < .001). Post-BD MRI specific ventilation (P = .046) and post-BD change in MRI specific ventilation (P = .006) were greater in participants with asthma with type 2 low biomarkers compared with participants with type 2 high biomarkers of airway inflammation. Post-BD change in MRI specific ventilation was correlated with change in forced expiratory volume in 1 second (r = 0.40, P = .04), resistance at 5 Hz (r = -0.50, P = .01), resistance at 19 Hz (r = -0.42, P = .01), reactance area (r = -0.54, P < .01), and reactance at 5 Hz (r = 0.48, P = .01). Conclusion Specific ventilation evaluated with tidal breathing 1H MRI was responsive to BD therapy and was associated with clinical biomarkers of airways disease in participants with severe asthma. Keywords: MRI, Severe Asthma, Ventilation, Type 2 Inflammation Supplemental material is available for this article. © RSNA, 2023 See also the commentary by Moore and Chandarana in this issue.

Uncertainty analysis of molten corium In-Vessel Retention under External Reactor Vessel Cooling

External Reactor Vessel Cooling (ERVC) is a key measure to realize molten corium In-Vessel Retention (IVR). The uncertainty of severe accident in core leads to the uncertainty of molten pool parameters in lower head, which may threat the reliability of successful implementation of IVR. In this study, an uncertainty analysis is employed to ensure the reliability of ERVC technology to IVR with the final two-layer molten pool configuration of AP1000.600 simulations are performed to determine the effect of five key parameters. As long as parameters are within high probability density range, lower head can remain intact, and safety margin is greater than 15 %. For influence level and correlation of parameters, the order on metal layer is: Decay heat > Fe mass > UO2 mass > Zr oxidation fraction > Emissivity of metal layer. The results can provide guidance for subsequent research direction and optimal design of mitigation measures.

Organic amendment application affects the release behaviour, bioavailability, and speciation of heavy metals in zinc smelting slag: Insight into dissolved organic matter

Organic amendments are commonly used in assisted phytostabilization of mine wastes by improving their physicochemical and biological properties. These amendments are susceptible to leaching and degradation, resulting in the generation of dissolved organic matter (DOM), which significantly influences the geochemical behaviour of heavy metals (HMs). However, the geochemical behaviour of HMs in metal smelting slag driven by organic amendment-derived DOM remains unclear. In this study, we investigated the impact of cow manure-derived DOM on the release behaviour, bioavailability, and speciation of HMs (Cu, Pb, Zn, and Cd) in zinc smelting slag using a multidisciplinary approach. The results showed that DOM enhanced the weathering of the slag, with a minimal impact on the slag’s mineral phases, except for causing gypsum dissolution. The DOM addition resulted in a slight increase in HM release from the slag during the initial inoculation period, followed by a reduction in HM release during the later period. Furthermore, the DOM addition increased the diversity and relative abundance of the bacterial community. This, in turn, led to a decrease in the dissolved organic carbon (DOC) content and enhanced the transformation of labile DOM compounds into recalcitrant compounds. The variation in HM release during various inoculation periods can be attributed to the bacterial decomposition and transformation of DOM, which further enhanced the transformation of HM fractions. Specifically, during the later period, DOM promoted the conversion of a portion of the reducible and oxidizable fractions of Cu, Pb, and Zn into the acid-soluble and residual fractions. Moreover, it partially transformed the reducible, oxidizable, and residual fractions of Cd into the acid-soluble fraction. Overall, this study provides new insights into the geochemical behaviour of HMs in slag governed by the coupling effect of DOM and the bacterial community. These findings have implications for the use of organic amendments in assisted phytostabilization of metal smelting slag. Environmental implicationMetal smelting slag is hazardous due to its high levels of HMs, and its improper disposal has serious consequences for the ecosystem. Organic amendments are employed in assisted phytostabilization of the slag site by improving its microecological properties. However, the impact of organic amendment-derived DOM on HM migration and transformation in slag remains unclear. This study indicated that the coupling effects of DOM and microbes governed the geochemical behaviour of HMs in slag. These findings provide new insights into how organic amendments impact the geochemical behaviour of HMs in slag, contributing to the development of phytostabilization technology.

Heat transfer enhancement in engine oil based hybrid nanofluid through combustive engines: An entropy optimization approach

Engine oil based hybrid nanofluid flow past a non-linearly stretching surface is important in solar energy applications, combustive engines, heat exchangers and many other industrial sector machinery. In this study, engine oil based hybrid nanofluid is modeled with multi-walled carbon nanotubes and copper oxide nanoparticles to enhance the heat transfer phenomena, minimize the entropy generation and to obtain a theoretical model more aligned with experimental findings. Engine oil hybrid nanofluid is modeled with non-linear thermal slip case so that a comparative study for no slip, linear slip and non-linear thermal slip is presented in a broader scenario. A variable magnetic field is applied in perpendicular direction with heat source/sink effects. Similarity analysis is conducted to obtain a non-dimensional system of ordinary differential equations. In order to solve the obtained system, a modified homotopy analysis approach is proposed with least square and Galerkin optimizers. Results are validated through mean squared residual errors and comparison with existing experimental data in literature. Analysis on results is presented through 2D plots, bar plots and pie charts. Highest percentage rate of increase in heat transfer of engine oil is obtained to be 23.75% with increase in heat source when volume fraction of both copper oxide and multi-walled carbon nanotubes is 4%. Moreover, entropy in engine oil flow is optimized till zero at 1% volume fraction of copper oxide and 3% volume fraction of multi-walled carbon nanotube in first order thermal slip case. These results are useful in enhancing various physical and engineering properties of engine oil 10W40C by adding multi-walled carbon nanotubes and copper oxide nanoparticles.

Accumulation of livestock manure–derived heavy metals in the Hexi Corridor oasis agricultural alkaline soil and bioavailability to Chinese cabbage (Brassica pekinensis L.) after 4-year continuous application

Hexi Corridor is one of the most important base of vegetable producing areas in China. Livestock manure (LM) applied to agricultural field could lead to soil heavy metal (HM) pollution. Previous studies have focused on HM pollution following LM application in acidic polluted soils; however, fewer studies have been conducted in alkaline unpolluted soils. A 4–year field vegetable production experiment was conducted using pig manure (PM) and chicken manure (CM) at five application rates (0, 15, 30, 45, and 60 t ha−1) to elucidate potential risks of HMs in an alkaline unpolluted soil in the Hexi Corridor oasis agricultural area and HM uptake by Chinese cabbage. The results showed that LM application caused a significant build–up of Cu, Zn, Pb, Cd, and Ni content in topsoil by 30.6–99.7%, 11.4–51.7%, 1.4–31.3%, 5.6–44.9%, 14%–40.8%, respectively. The Cd, Cu, Zn could potentially exceed the soil threshold in next 8–65 years after 15–60 t ha−1 LM application. Under LM treatment, the soil DTPA–extractable Cu, Zn, Fe, the acid–extractable fraction of Cu, Zn, Fe, Cd, Ni, and the Oxidable fraction of Cu, Zn, Fe, Mn, Cd, Ni significantly increased, but the DTPA–extractable Pb, Cd, the acid–extractable fraction of Pb, and the reducible fraction of Cd significantly decreased. Cu and Zn could migrate to the deeper soil and relatively increase in DTPA–extracted Cu, Zn were found in 20–40 cm soil depth after LM application. The pH and SOM could influence the bioavailability of HMs in soil. The bioaccumulation factor and transfer factor (TF) values were <1 except Mn (TF > 1). HMs in leaf did not approach the threshold for HM toxicity due to the “dilution effect”. Recommend the type of manure was the PM and the annual PM application rate was 30 t ha−1 to ensure a 20–year period of clean production in alkaline unpolluted Fluvo–aqiuc vegetable soils.

Emission of nitrogen/sulfur pollutants and migration of heavy metals during combustion of oily sludge from the oil refining process in fluidized bed

Oily sludge is a kind of hazardous waste due to the enrichment of nitrogen, sulfur, and heavy metals. In this work, the combustion of oily sludge from an oil refining factory in a fluidized bed reactor at 850–1050 °C and 0.8–1.2 excess air ratios were studied, with a focus on emission of nitrogen and sulfur pollutants and migration of Cr, Ni, Cu, Zn, Cd, Pb. The emission characteristics of nitrogen and sulfur pollutants were exhibited through monitoring the flue gas. The migration characteristics of heavy metals were clarified by analyzing their retention in bottom and fly ash. Moreover, the BCR (European Community Bureau of Reference) sequential extraction of the heavy metals in bottom ash was also carried out to obtain the migration of heavy metals in different forms. The contents of NOx and SO2 in the flue gas increased with temperature and excess air ratio increasing. High temperature led to less heavy metal retention in the bottom ash. The strong oxidizing atmosphere can weaken the volatilization of heavy metals. The stabilities of the heavy metal in different forms were in the following order: F4 (residual fraction) > F3 (oxidizable fraction) > F2 (reducible fraction) > F1 (exchangeable and acid soluble fraction). F4 was the dominant fraction of heavy metals in the bottom ash. The >60 % content of F3 and F4 led to the high stability of Cu and Ni while the >57 % content of F1 and F2 led to the high volatility of Cd and Pb in bottom ash. The differences in the component map of F1-F4 for the six heavy metals gave rise to their different migration characteristics during combustion.

Spatial and temporal dynamics and fluxes estimation of manganese fractions in sediments from the Pearl River Estuary, southern China

Sequential extraction was used to study the historical dynamics and fluxes of the chemical fractions of manganese (Mn) in sediments collected from the Pearl River Estuary (PRE), southern China. Results revealed that the proportion of Mn associated with different fractions decreased in the order of acid-soluble fraction (F1) > reducible fraction (F2) > residual fraction (F4) > oxidizable fraction (F3). F1 (47%) was the dominant Mn fraction, indicating the strong bioavailability of Mn to aquatic organisms in the PRE. In addition, the Mn fraction F2 was present at an average rate of 27.93 % in surface sediments, indicating that it could be mobilized when environmental conditions become increasingly reducing or oxidizing. The decline in Mn fraction fluxes after 2006 indicated that the region has partially decreased due to the removal of heavily polluting industries and effective control of sewage discharge.

Exhaled nitric oxide is only an asthma-relevant biomarker among children with allergic sensitization.

Fraction of exhaled nitric oxide (FeNO) is used for diagnosing and monitoring asthma in children, but the influence of allergic sensitization is still poorly understood. Here, we investigate how asthma and allergic sensitization influence FeNO levels during childhood. We investigated the associations between asthma, aeroallergen sensitization, and FeNO measured from age 5-18 years in the COPSAC2000 birth cohort of 411 children using repeated measurement mixed models adjusted for gestational age, sex, concurrent airway infection, inhaled corticosteroids, and tobacco exposure. Replication was sought in the similarly designed COPSAC2010 cohort of 700 children. In the COPSAC2000 cohort, 133 had asthma between age 5 and 18 years, and in the COPSAC2010 cohort, 112 had asthma between age 5 and 10 years. In the COPSAC2000 cohort, asthma and aeroallergen sensitization were both associated with higher FeNO from age 5 to 18 years: adjusted geometric mean ratio (aGMR), 1.22 (1.08-1.35), p < .01, and 1.41 (1.21-1.65), p < 0.001, respectively. However, asthma was associated with increased FeNO among children with aeroallergen sensitization: 1.44 (1.23-1.69), p < .0001, whereas asthma was associated with decreased FeNO among nonsensitized children: 0.80 (0.65-0.99), p = .05 (p-interaction<.0001 for asthma x sensitization). Replication in the COPSAC2010 cohort showed similar results (p-interaction <.01). Further, blood eosinophil count, total-IgE, bronchodilator response, and bronchial hyperreactivity were all associated with increased FeNO among children sensitized to aeroallergens, but not among nonsensitized children. Fraction of exhaled nitric oxide is elevated through childhood in children with asthma and is correlated with asthma-associated traits depending on the presence of aeroallergen sensitization. These findings indicate that FeNO is only a valid asthma biomarker in children with concurrent aeroallergen sensitization, which is important for guideline recommendations on the clinical use of FeNO.

Process Analysis of DLP Photocuring 3D Printing with Modified High-strength Resin

The excellent properties of graphene oxide, along with its dispersibility and hydrophilicity, make it suitable for blending with other substrates to obtain reinforcements. In this paper, high-strength photosensitive resin is mixed with graphene oxide to obtain reinforced photosensitive resin. The impact of different mass fractions of graphene oxide on the appearance, dimensional accuracy, bending strength, tensile strength, and fracture morphology of printed samples is investigated using DLP surface molding 3D printing technology. As the mass fraction of graphene oxide increases, the size error of the printed sample decreases, while the bending strength and tensile strength increase, indicating a favorable bonding effect. However, when the mass fraction of graphene oxide exceeds 0.6%, the bonding between the two materials becomes poorer, leading to the opposite outcome. The hierarchical influence of different parameters on the tensile strength of mixed-material DLP printed samples can be summarized as follows: graphene oxide content exhibits the strongest influence, followed by layer thickness, exposure time, and exposure intensity.

Benralizumab in severe eosinophilic asthma in real life: confirmed effectiveness and contrasted effect on sputum eosinophilia versus exhaled nitric oxide fraction - PROMISE.

Randomised controlled trials have shown that benralizumab, an anti-interleukin-5 receptor monoclonal antibody, reduces exacerbations and oral corticosteroid dose and improves asthma control and lung function in severe eosinophilic asthma. The aim of this study was to confirm results of randomised controlled trials in real life in a population of 73 patients with severe eosinophilic asthma treated with benralizumab for at least 12 months. Patients underwent careful monitoring of asthma exacerbations, exhaled nitric oxide fraction, lung function, asthma control and quality of life questionnaire responses and sputum induction, and gave a blood sample at baseline, after 6 months and then every year. We found significant reductions in exacerbations (by 92%, p<0.0001) and oral corticosteroid dose (by 83%, p<0.001) after 6 months that were maintained over time, with 78% of patients able to stop oral corticosteroid therapy. Patients improved their Asthma Control Test (ACT) score (from 11.7±5.1 to 16.9±5.35, p<0.0001), Asthma Control Questionnaire (ACQ) score (from 2.88±1.26 to 1.77±1.32, p<0.0001) and Asthma Quality of Life Questionnaire score (+1.04, p<0.0001) at 6 months and this was maintained during follow-up. Only 35% and 43% of patients reached asthma control according to an ACT score ≥20 and ACQ score <1.5, respectively. We observed stable post-bronchodilation lung function over time and a significant reduction in sputum eosinophil count, with 85% of patients exhibiting sputum eosinophil counts <3% after 6 months (p<0.01) with no effect on exhaled nitric oxide fraction. In our real-life study, we confirm the results published in randomised controlled trials showing a sharp reduction in exacerbations and oral corticosteroid therapy, an improvement in asthma control and quality of life, and a dramatic reduction in sputum eosinophil count.

Influence of mineralized organic carbon in marine sediments on ecological heavy metal risk: Bohai Bay case study

The organic matter in sediments can mineralize over time, which impacts the morphology of the heavy metals therein, which in turn affects the assessment of the risks posed by heavy metals. We used the sediments of Bohai Bay as the study object and analyzed the effects of different organic carbon mineralization levels on the concentrations of heavy metals (Cr, Pb, Cu, Zn, and Cd) using water extraction and potassium permanganate oxidation. The mean concentrations of Cd, Pb, Cu, and Zn in Bohai Bay were within the limits recommended by the World Health Organization. The proportions of the active and inert organic carbon fractions were 61.72% and 32.94%, respectively. Organic carbon mineralization most strongly impacted Cd and Pb levels, with releases accounting for 47.92% and 25.75%, respectively, of the oxidizable fractions. The release of all heavy metals, except for Cr, increased with increases in organic carbon mineralization, and heavy metals were released at a maximum rate of 12.94% when the organic carbon was highly mineralized, whereas Cr was released at a maximum of 0.023% during the first stage of organic carbon mineralization. In terms of spatial distribution, the concentration of mineralizable organic carbon in the sediments of the estuaries was substantially higher than that in other marine areas. Estuary sediments were more easily affected by organic carbon mineralization; therefore, the heavy metals in the oxidizable fraction of the estuarine region were more easily transformed into unstable heavy metal forms, posing high risk levels. Therefore, this study highlights the effects of organic carbon mineralization on heavy metal morphology and stability, when evaluating the ecological risk of heavy metals in marine sediments.

Soil conditioners promote the formation of Fe-bound organic carbon and its stability

The close association of soil organic carbon (SOC) with Fe oxides is an important stabilization mechanism for soil organic matter (SOM) against biodegradation. Soil conditioners are of great importance in improving soil quality and soil health. Yet it remains unclear how different conditioners would affect the fractionation of SOC, particularly the Fe-bound organic carbon (Fe-OC). Field-based experiments were conducted in farmland to explore the fractionation of organic carbon (OC) and Fe oxides under the effects of three different soil conditioners (mineral, organic, and microbial conditioners). The results showed that all soil conditioners increased the total OC and Fe-OC contents, with the contribution of Fe-OC to total OC increasing from 1.57% to 2.99%. The low OC/Fe molar ratio indicated that surface adsorption played a crucial role in soil Fe-OC accumulation. Nuclear magnetic resonance (NMR) results suggested that soil conditioner altered the composition of SOM, accelerating O-alkyl C degradation and increasing recalcitrant alkyl C and aromatic C sequestration. Scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) analysis indicated that all conditioners promoted the association of OC and Fe oxides. Furthermore, comprehensive analysis of 13C isotope and synchrotron radiation-based Fourier transform infrared (SR-FTIR) spectroscopy showed that the mineral conditioner enhanced the association of microbial-derived OC and Fe oxides, whereas the organic conditioner increased the association of plant-derived OC with Fe oxides. These findings provide important insights into the potential mechanisms through which soil conditioners regulate the stability of OC and guide agricultural management.

Assessing hydrological controls on the lithium isotope weathering tracer

To investigate the impact of riverine discharge and weathering intensity on lithium isotopes (δ7Li) in a mono-lithological terrain, this study examines the dissolved load and leached suspended load (exchangeable, oxide, and clay fractions) from Icelandic rivers spanning a wide range of discharge, weathering rates, and weathering intensity. The δ7Lidissolved co-varies inversely with the discharge, confirming that water-rock interaction time is a primary control on the secondary mineral formation that fractionates Li isotopes. The “boomerang” shape observed in global rivers between the weathering intensity (i.e. W/D = weathering rate/denudation rate) and δ7Lidissolved also exists for these basaltic rivers at low to medium W/D. However, these rivers do not extend to such low δ7Lidissolved values as seen in the global compilation at low W/D, indicating that there is a lithological control on this relationship arising from the type of the lithology-specific secondary minerals forming and their precipitation rates. In addition, the Δ7Lix-dissolved between each leached solid phase and the dissolved load also co-varies with discharge. At low discharge (long water-rock interaction times), Δ7Lix-dissolved values agree with experimentally-determined equilibrium values, whereas less fractionated values are observed at higher discharge (shorter water-rock interaction times). As a result, there is a different relationship between W/D and Δ7Liclay-source in this basaltic terrain than previously reported from global multi-lithological river sediment samples, with clay leachates from Iceland more closely mimicking the boomerang shape of the dissolved load. However, the relationship between δ7Li and weathering processes is complicated because the fractionation between the clay fraction and the dissolved load is not constant but varies with both W/D and discharge. Overall, this study confirms the utility of Li isotopes as a tracer of modern and palaeo-weathering processes, and also has important implications for the specific interpretations of detrital δ7Li values, which may be more sensitive to weathering parameters than previously thought.

Evidence for the accumulation of toxic metal(loid)s in agricultural soils impacted from long-term application of phosphate fertilizer

Phosphate fertilizers may contain elevated concentrations of toxic metals and metalloids and therefore, their excessive application can result in the accumulation of both phosphorus (P) and metal(loid)s in agricultural soils. This study aims to investigate the occurrence, distribution, and potential plant-availability of metal(loid)s originating from phosphate fertilizer in a long-term experimental field at the Tidewater Research Station in North Carolina, where topsoil (10–20 cm deep) and subsoil (up to 150 cm deep) samples were collected from five plots with consistent and individually different application rates of P-fertilizer since 1966. We conducted systematic analyses of P and metal(loid)s in bulk soils, in the plant available fraction, and in four sequentially extracted soil fractions (exchangeable, reducible, oxidizable, and residual). The results show that P content in topsoils were directly associated with the rate of P-fertilizer application (ρ = 1, p < 0.05). Furthermore, P concentrations were highly correlated with concentrations of Cd, U, Cr, V, and As in the bulk topsoil (ρ > 0.58, p < 0.05), as well as the potential plant-available fraction (ρ > 0.67, p < 0.01), indicating the accumulation of the fertilizer-derived toxic metal(loid)s in the topsoil. Significant correlations (p < 0.001) of metal(loid)s concentrations between the bulk soil and the potential plant-available fraction raises the possibility that P-fertilizer application could increase the accumulation of toxic metal(loid)s in plants, which could increase human exposure. Results from sequential leaching experiments revealed that large portions of the trace elements, in particular Cd, occur in the soluble (exchangeable and reducing) fractions of topsoil with higher P-fertilizer input, whereas the levels of redox-sensitive elements (As, V, U, Cr) were higher in the reducible and oxidizable fractions of the soils. Overall, the data presented in this study demonstrate the effect of long-term P-fertilizer application on the occurrence and accumulation of a wide range of toxic metal(loid)s in agricultural topsoil.

Simultaneous evaluation of the fractional exhaled nitric oxide and blood eosinophil count of T2-high endotype in patients with non-cystic fibrosis bronchiectasis.

Recently, a type 2 inflammation (T2) high endotype in bronchiectasis was identified. The fraction of exhaled nitric oxide (FeNO) and blood eosinophil count (BEC) are recognized as representative biomarkers of T2 inflammation. Herein, we investigate the clinical characteristics of T2-high endotype in non-cystic fibrosis bronchiectasis patients classified by FeNO and BEC. This retrospective study included 164 bronchiectasis patients treated in the First Affiliated Hospital of Sun Yat-sen University from December 2017 to July 2022. Clinical characteristics were analyzed after classifying patients into four groups according to T2 inflammation biomarkers (FeNO ≥25ppb; BEC ≥200/µL). Among the 164 bronchiectasis patients, 35.3% (58/164) presented with high FeNO, 30.5% (50/164) presented with high BEC, and 10.4% (17/164) had high FeNO and BEC. Patients with high FeNO and low BEC presented with better lung function, fewer affected lobes, and lower dyspnea prevalence compared with the three other groups. Moreover, decreased FeNO, instead of decreased BEC, is revealed to be an independent predictor for disease severity and airflow obstruction in bronchiectasis. Simultaneous evaluation of FeNO and BEC proposed different endotypes of bronchiectasis established that patients with low BEC and high FeNO had better lung function, fewer affected lobes, lower dyspnea prevalence, and less disease severity. This result will contribute to a more comprehensive assessment of the disease severity and lead to more precise treatment of T2 inflammation in bronchiectasis patients.

Rape Straw Biochar Application Enhances Cadmium Immobilization by Promoting Formation of Sulfide and Poorly Crystallized Fe Oxide in Paddy Soils

The mechanisms of rape straw biochar that affect the fixation of cadmium (Cd) in paddy soil by influencing redox of iron and sulfur are unclear. Several anaerobic incubation experiments were carried out using Cd-contaminated paddy soils (LY and ZZ). Rape straw biochar at pyrolysis temperatures of 450 °C (LRSB) and 800 °C (HRSB) was selected as the soil remediation agent. The electron exchange capacity and electrical conductivity were higher in HRSB than those in LRSB. The lower pe + pH in HRSB enhanced Fe oxide reduction, with a maximum increase in Fe2+ of 46.0% in ZZ. Compared to treatment without biochar (CK), the poorly crystallized Fe oxide (Feo) in HRSB increased by 16.8% in ZZ. This induced Cd bound to Fe, and Mn oxides fraction (Fe-Mn Cd) increased by 42.5%. The SO42−-S content in LRSB was 4.6 times that of HRSB. LRSB addition increased acid-volatile sulfide by 46.4% and 48.9% in LY and ZZ soils, respectively, compared to CK. This resulted in an increase in sulfide’s contribution to Cd fixation, with values rising from 24.2% to 37.8% in LY and 19.1% to 29.8% in ZZ. Overall, LRSB reduced Cd mobility by forming more sulfide, while HRSB increased Fe-Mn Cd by increasing Feo.

Analysis of Thermal Performance of Polylactic Acid Nanocomposite by Using T-History Method

In this study, we perceived the thermo-physical boundary and the thermal efficiency of zinc oxide for volume fraction in polylactic acid based on a heat energy storage system was examined by using the T-history method. The use of the T-history method for the assessment of thermo-physical boundary describes the specific heat capacity and thermal conductivity enhanced in solid as well as liquid phases of the mixture until the addition of 0 to 0.025% of volume part of zinc oxide in the polylactic acid nanocomposite. After the addition of the zinc oxide, the heat of fusion falls and polylactic acid has a high rate of fusion related to 0.025% volume part of zinc oxide mixed with polylactic acid. Further zinc oxide-based polylactic acid nanocomposite has 31.30% and 13.5% higher solid as well as liquid thermal conductivity in comparison with polylactic acid. Moreover, raise the particle size and analysis as well as distributions found by dynamic light dispersing method for different volume parts of zinc oxide mixed on polylactic acid. In contrast to the thermal efficiency analysis of 0.025% of volume fraction zinc oxide in polylactic acid nanocomposite has a 30.6% high heat transfer rate related to pure polylactic acid along the stage of 4 minutes. Further, the addition of zinc oxide above 0.025% volume fraction in polylactic acid, rise the particle settlement rate freely. Whatever can become to end that 0.025% volume fraction of zinc oxide in polylactic acid mixed thermal energy storage arrangement outcome of maximum thermo physical property and thermal efficiency.

Distribution and transformation of potentially toxic elements in crack under coal mining disturbance.

In China, coal provides about 56.8% of the energy. Most of China's coal mines are shaft mines, which cause the surface to collapse and crack during the mining process. The soil near the cracks changes its physicochemical properties due to the altered stress conditions. This will affect the distribution of PTEs in the soil. We collected 18 samples from a selected crack in the abandoned land. The pH, Eh, and PTE and their fractions of the samples were determined. With the test results, we understand the distribution characteristics of pH, Eh, PTEs, and their fractions at the cracks. Meanwhile, we explored the key factors that contribute to this distribution. It was determined that crack decreases surface soil pH while increasing Eh. The total amount of 7 PTEs is higher in the bottom soil of the main crack and 2 m away from the main crack. The content of reducible fractions of PTEs increases with the increase of soil Eh. The oxidizable and residual fractions of PTEs adsorbed to the clay particles migrate to and enrich the deeper layers of the main crack. This study emphasizes the effect of crack generation on the distribution of PTEs in soil. It provides insights to describe the distribution of PTE throughout the full life cycle of crack.

Effect of Co vs. Fe content on early stages of oxidation of Co-Cr-Fe-Mn-Ni-Si complex concentrated alloys at 800 °C

The effect of Co vs. Fe content on early stages of oxidation in air was studied in Co-Cr-Fe-Mn-Ni-Si complex concentrated alloys (CCAs). A higher Co content decreased the phase fraction of protective corundum-type oxide as determined quantitatively. This is consistent with presented thermodynamic calculations, predicting a decrease in Cr activity with increasing Co content. The formation of Cr-rich corundum-type oxide is hindered in favor of Fe/Co/Ni-rich spinel-type oxide. Accordingly, beneficial effects of Co on mechanical properties of 3d transition metal CCAs for high temperature applications need to be balanced with detrimental effects on oxidation resistance.