Performance Of Oxidation Process Research Articles

Enhancing ferrate(VI) oxidation process to remove blue 203 from wastewater utilizing MgO nanoparticles

The aim of this study is to investigate the beneficial effect of utilizing MgO nanoparticles on the performance of ferrate(VI) oxidation process to remove blue-203 dye from wastewater. It was also made an attempt to assess the effects of pH, temperature, and MgO nanoparticle dosage on this oxidation process performance. Several sets of batch experiment were conducted to find out the effects of temperature ranging from 25 to 65 °C, pH ranging from 1.5 to 13, ferrate(VI) concentration ranging from 0.5 to 5.9 mg/L and MgO nanoparticles dosage ranging from 0.01 to 0.05 g in 150 mL solution on the removal efficiency. The results showed that adding MgO nanoparticles can improve the performance of ferrate(VI) oxidation removal method significantly, spec. at basic conditions. This synergistic effect can be attributed to the simultaneous adsorption of ferrate(VI) and dye molecules on the surface of nanoparticles. The results also revealed that the reaction between blue-203 dye and ferrate(VI) takes place rapidly at high mixing rate. It means that the required time to complete the removal process is controlled by mixing rate. It was finally concluded that adding MgO nanoparticles was an efficient means to enhance the performance of ferrate(VI) to oxidize blue-203 dye, esp. under basic conditions.

UV/H2O2 process performance improvement by ultrafiltration and physicochemical clarification systems for industrial effluent pretreatment

The present study evaluated the removal of TOC from an effluent with high organic load resulted from the treatment of oil-water emulsion by thermal process. Hollow Fiber Ultrafiltration membrane (HF-UF) and physicochemical clarification process were used as pretreatment options to assess the influence of feed effluent quality on the UV/H2O2 oxidation process. Results for TOC removals showed HF-UF and physicochemical clarification processes can significantly improve the efficiency of UV/H2O2 oxidation process, when compared with the direct effluent oxidation. Reaction time for obtaining a TOC removal higher than 90% was reduced to approximately half of the time needed when no pretreatment was applied. Considering both pretreatment processes it was not possible to notice any significant difference on the UV/H2O2 oxidation process performance. However, the complexity of physicochemical process due to the use of three different chemicals and sludge production made the HF-UF process the best pretreatment alternative, without increasing the Total Dissolved Solids of the effluent, a very important issue when water reuse is considered.