Hydroxypropyl Research Articles

Demulsification of water-in-crude oil emulsion via novel Fe3O4@ ethylene oxide–propylene oxide copolymer decorated graphene oxide or multiwall carbon nanotubes magnetic nanodemulsifiers

Demulsification of water-in-crude oil emulsion via novel Fe3O4@ ethylene oxide–propylene oxide copolymer decorated graphene oxide or multiwall carbon nanotubes magnetic nanodemulsifiers

A new stratagem to efficiently synthesize monolithic TS-1 via dry gel conversion in the atmosphere of tripropylamine-water and revealing insight into the structure–activity relationship for propylene epoxidation

The epoxidation of propylene catalyzed by TS-1 possesses the advantages of high atomic utilization and mild reaction conditions. To explore the structure–activity relationship of the catalyst, carbon nanotubes grown on the surface of nickel foam were used as the carrier to synthesize monolithic TS-1 by dry gel conversion in the tripropylamine-water gas environment. Compared with the powder TS-1 by hydrothermal crystallization, the crystallization time of monolithic TS-1 was shortened from 72 h to 12 h. Tripropylamine promoted the dissociation of dry gel by increasing the basicity of liquid film on the surface of dry gel. Water provided the necessary pressure for crystallization and was also the medium of mass transfer in the process of crystallization. Stepwise regression analysis showed the increase of Lewis acid content and pore volume improved the conversion and utilization of hydrogen peroxide and the selectivity of propylene to propylene oxide.

Insight into the role of metal support interface through the synergistic effect between Ag and α-Bi2Mo3O12 support for the selective oxidation of propylene to acrolein

Pre-synthesized morphologically tailored size and shape selective silver nanoparticles (AgNPs) decorated on bismuth molybdate support (AgNPs/α–Bi2Mo3O12) using simple wet impregnation method was employed. The prepared AgNPs/α-Bi2Mo3O12 nanocatalysts were tested in the selective partial oxidation of propylene to acrolein reaction. The introduction of well-defined size and shape of AgNPs on α–Bi2Mo3O12 is greatly promoted the strong metal support interactions (SMSI), creation of oxygen vacancies (Ov) and high propylene adsorption binding energy (calculated by DFT). The strong metal support interactions between Ag and α-Bi2Mo3O12 is clearly elucidated by the high quality HRTEM and STEM–HAADF microscopic images. In addition, surface atomic molar ratio measured by XPS analysis determined the key redox properties of AgNPs/α–Bi2Mo3O12 system and their influence on the overall catalytic efficiency in the oxidation of propylene via reduction of Mo6+ to Mo5+ initiated at low temperatures in Ag/α–Bi2Mo3O12 system. The Mo reduction is further confirmed by the activated oxygen removal from the MoO42– moieties after Ag incorporation on α–Bi2Mo3O12. Thus, confirmed the oxidation reaction pathway follows a Mars–van–Krevelen process. Further, DFT calculations supported the propylene adsorption is more favorable over Ag/α–Bi2Mo3O12 than bare α–Bi2Mo3O12 support. The propylene oxidation performance over Ag/α–Bi2Mo3O12 system was 5.5 times higher than bare α–Bi2Mo3O12 support, probably due to an enabled strong metal support interaction and increased oxygen vacancies.

Synthesis of Polyether, Poly(Ether Carbonate) and Poly(Ether Ester) Polyols Using Double Metal Cyanide Catalysts Bearing Organophosphorus Complexing Agents.

We developed a series of Zn(II)-Co(III) double metal cyanide (DMC) catalysts with exceptional activity for the ring-opening polymerization of various cyclic monomers by employing diverse organophosphorus compounds as complexing agents (CAs). The chemical structure and composition of DMC catalysts were investigated by commonly used analysis such as infrared and X-ray photoelectron spectroscopies, and elemental analysis combining with in situ NMR analysis to determine the complexation types of organophosphorus compounds the catalyst framework. The resulting catalysts exhibited very high turnover frequencies (up to 631.4 min-1) in the ring-opening polymerization (ROP) of propylene oxide and good efficiency for the ROP of ε-caprolactone. The resultant polyester polyols are suitable to use as an macroinitiator to produce well-defined poly(ester ether) triblock copolymers of 1800-6600 g mol-1 and dispersity of 1.16-1.37. Additionally, the DMC catalysts bearing organophosphorus compounds CAs exhibited remarkable selectivity for the copolymerization of PO with CO2, yielding poly(ether carbonate) polyols with carbonate contents up to 34.5%. This study contributes to the development of efficient DMC catalytic systems that enable the synthesis of high-quality polyols for various applications.

Co3-xCrxO4 spinel oxides for propane total oxidation: Essential roles of metal cations in octahedral coordination

The essential roles of octahedrally coordinated cations (B-site in AB2O4 formula) in Co3-xCrxO4 spinel oxides in the total oxidation of propane were demonstrated, using a series of Co3-xCrxO4 spinel oxides with different Co/Cr molar ratios derived from layered double hydroxides. The catalytic activity was strongly related to the compositions of B-site cations. The Co2CrO4 catalyst with B-sites equally occupied with Co and Cr cations was more active than the Co3O4 (Co cations only in B-sites) and CoCr2O4 (Cr cations only in B-sites), giving turnover frequencies of 0.86 × 10-3, 0.72 × 10-3 and 0.11 × 10-3 s−1 at 250 °C (under kinetically-controlled reaction), respectively. Kinetics and density functional theory (DFT) calculations on the Co2CrO4 and CoCr2O4 catalysts indicated that the reaction followed a Langmuir-Hinshelwood mechanism, and the adsorption of oxygen on the former was easier. Moreover, the cleavage of the first C–H bond in the propane as the rate-determining step was more favored on the Co2CrO4, which accounted for its higher activity. These findings thus provide valuable insights on the mechanistic roles of B-site cations of spinel oxides in total oxidation of hydrocarbon.

Model-Based Design of Experiments for Temporal Analysis of Products (TAP): A Simulated Case Study in Oxidative Propane Dehydrogenation.

Temporal analysis of products (TAP) reactors enable experiments that probe numerous kinetic processes within a single set of experimental data through variations in pulse intensity, delay, or temperature. Selecting additional TAP experiments often involves an arbitrary selection of reaction conditions or the use of chemical intuition. To make experiment selection in TAP more robust, we explore the efficacy of model-based design of experiments (MBDoE) for precision in TAP reactor kinetic modeling. We successfully applied this approach to a case study of synthetic oxidative propane dehydrogenation (OPDH) that involves pulses of propane and oxygen. We found that experiments identified as optimal through the MBDoE for precision generally reduce parameter uncertainties to a higher degree than alternative experiments. The performance of MBDoE for model divergence was also explored for OPDH, with the relevant active sites (catalyst structure) being unknown. An experiment that maximized the divergence between the three proposed mechanisms was identified and provided evidence that improved the mechanism discrimination. However, reoptimization of kinetic parameters eliminated the ability to discriminate between models. The findings yield insight into the prospects and limitations of MBDoE for TAP and transient kinetic experiments.

Hybrid anionic block copolymerization: From organocatalysis‐streamlined crossover to internally microphase‐separated aggregates

AbstractPolyolefin‐b‐poly(ethylene oxide) (PEO) represents the most widely investigated amphiphilic block copolymers. So far, one‐pot continuous synthesis of such hybrid block copolymers has only been fulfilled by anionic polymerization through sequential addition of vinyl monomers and ethylene oxide (EO). It still remains challenging to achieve altogether high block efficiency, high polymerization efficiency, and high molar mass for PEO. Here, we report a one‐pot hybrid block copolymerization approach to polyisoprene/polystyrene(PI/PS)‐b‐PEO, in which PI/PS are formed by sBuLi‐initiated anionic vinyl‐addition polymerization, then in situ employed as macroinitiators for the anionic ring‐opening polymerization (ROP) of EO aided by an organic Lewis pair. The cooperative (dual‐ion‐complexing) catalytic effect of organobase and triethylborane is proven, for the first time, effective for lithium alkoxide initiator system, allowing to achieve at room temperature high ROP activity (complete EO conversion and PEO of 3–64 kg/mol reached in 1–6 h), narrow molar mass distribution, controlled block lengths and composition. Density functional theory calculation shows that phosphazene bases are particularly effective, compared with N‐heterocyclic bases, for complexing with Li+ and enhancing the nucleophilicity of oxyanion. The rate of ROP is also affected by Li+‐induced aggregation of the chain‐end ion pairs, which though can be offset by adequate catalyst loadings. The versatility of this approach is further demonstrated in the one‐pot synthesis of tri‐/tetrablock ter‐/quaterpolymers constituted by PI, PS, PEO, and poly(propylene oxide). Of great interest, PS‐b‐PI‐b‐PEO triblock terpolymer with a specific composition is found to form internally microphase‐separated micellar aggregates when dispersed in water.

Comparison of Structure and Reactivity of Hydrothermally Prepared Bi−Mo−Co−Fe−O Catalysts in Selective Propylene and Isobutene Oxidation

AbstractThe elucidation of structure‐activity correlations in selective oxidation of propylene and isobutene over mixed metal oxides (MMO) is attractive for knowledge‐based catalyst design and process optimisation. Particularly, 4‐component Bi−Mo−Co−Fe−O catalysts need to be studied since their complex metal oxide phase mixture leads to higher activity and selectivity than 2‐component Bi−Mo−O. Hence, three Bi−Mo−Co−Fe‐oxides with different metal ratios were prepared by hydrothermal synthesis and compared during selective oxidation tests with propylene and isobutene. The active phases after several days on stream were investigated by synchrotron X‐ray diffraction (XRD) and Raman spectroscopy, while the structural evolution under reaction conditions was followed by operando Raman spectroscopy, synchrotron XRD, and multi‐edge X‐ray absorption spectroscopy. Similar structural transformations were observed during selective oxidation of propylene and isobutene, with similar influence on catalytic performance. A phase mixture of β‐CoMoO4/β‐Co0.7Fe0.3MoO4, γ‐Bi2MoO6, Fe3O4 and Bi3FeMo2O12 was observed, whereby high amounts of β‐CoMoO4/β‐Co0.7Fe0.3MoO4 increased selectivity to acrolein/methacrolein. In contrast, high amounts of γ‐Bi2MoO6 and Fe3O4 favoured total oxidation to CO and CO2. The simultaneous presence of β‐CoMoO4/β‐Co0.7Fe0.3MoO4, Bi3FeMo2O12 and Fe2O3 increased selectivity to methacrolein in isobutene oxidation, whereas no comparative increase in acrolein selectivity was observed in propylene oxidation. This suggests different key active phases in both reactions.

Single-step propane transformation on vanadium-supported catalyst revealed by operando DRS UV–vis study

The present study investigated the influence of silica support texture on the catalytic performance of VOx/silica catalysts in the selective oxidation of propane. Two- and three-dimensional mesoporous materials, SBA-15 and MCF, were synthesized using hydrothermal methods to create different pore structures. Vanadium (approximately 5 wt%) was incorporated into the silica matrices (MCF, SBA-15) and SiO2 (used as a reference system) through impregnation. The surface composition, valence state, and reducibility of the VOx species accommodated in VOx/silica catalysts were characterized using X-ray diffraction (XRD), diffuse reflectance ultraviolet–visible spectroscopy (UV–vis DRS), temperature-programmed reduction with hydrogen (H2-TPR), X-ray photoelectron spectroscopy (XPS), and Fourier transform infrared spectroscopy (FT-IR) techniques. The catalytic properties of the catalysts were evaluated in the propane selective oxidation conducted at 470 °C, utilizing a mixture of oxidants (N2O and O2). Propane oxidation resulted in propane conversion of 34 %, propene selectivity of 49 %, and propene oxide selectivity of 20 %, corresponding to space–time yield of propene reaching 37 gC3H6 kgcat−1·h−1and propene oxide equal to 20 gPO kgcat−1h−1. The textural properties of the support materials noticeably influenced the stability of the catalysts. The vanadium catalysts supported on three-dimensional mesocellular silica foams (MCF) demonstrated superior activity, achieving turnover frequency (TOF) values of 9.0 × 10−4 s−1 for propene and 6.67 × 10−4 s−1 for propene oxide (PO). The unique three-dimensional ultra-large pores of the MCF material facilitated the generation of significant amounts of propene oxide, along with propene, while minimizing the formation of CO, CO2, and other oxygen-bearing by-products. Operando UV–vis studies supported by two-dimensional correlation analysis (2D COS) were employed to explain the diversity in the catalytic performance of VOx/silica catalysts. It has been found that the oligomeric vanadium species are the active sites in propane oxidative dehydrogenation, whereas the monomeric forms participate in propene oxide formation. Moreover, the reduction of V5+ to V4+ and even V3+ was identified as a crucial step in the reaction.A reaction scheme has been proposed based on catalytic experiments and spectroscopic insights.

La/Mn molar ratio tuning the activity of La–Mn perovskites for CO and propane oxidation

A series of non-stoichiometric LaxMnO3 with La/Mn molar ratio x in the range of 0.80–1.2 have been prepared by a glycine combustion method and calcinated at 700 °C. The Mn-rich (x < 1) and La-rich (x > 1) catalysts presented higher and lower activity for CO and propane oxidation than the stoichiometric LaMnO3, respectively. The LaxMnO3 presented pure perovskite phase without La- or Mn-related phases detected even calcinated at 1000 °C. Notably, the 50% conversion temperature for CO and propane oxidation on the best La0·84MnO3 were around 70 and 35 °C lower than those on the stoichiometric LaMnO3, whereas which on the worst La1·15MnO3 were around 60 and 50 °C higher. The La0·84MnO3 possessing higher activity for CO and propane oxidation was predominately attributed to more Mn4+ cations, thus achieving abundant surface Mn4+–O bridge site as redox sites and surface Mn4+ sites as Lewis acidic sites, while the La1·15MnO3 owning lower activity for the reactions was primarily ascribed to less Mn4+ cations, and the lower reducibility of Mn4+ cations and surface adsorbed oxygens.

Ionic Strength Effect in the Equilibrium and Rheological Behavior of an Amphiphilic Triblock Copolymer at the Air/Solution Interface

This study investigates the effect of an inert salt (NaCl) on the equilibrium interfacial tension and dilatational modulus of Pluronic F-68 copolymer, a triblock copolymer consisting of two terminal blocks of poly(ethylene oxide) and a less hydrophilic central block of poly(propylene oxide). Interfacial tension measurements were carried out using a surface force balance and a drop shape tensiometer, while rheological measurements were carried out in two different frequency ranges. This involved the use of the oscillatory barrier/droplet method and electrocapillary wave measurements, complemented by an appropriate theoretical framework. This work aimed to elucidate the influence of NaCl on the interfacial behavior of Gibbs monolayers of Pluronic F-68. In addition, this study highlights some of the technical and theoretical limitations associated with obtaining reliable dilatational rheological data at high frequencies (&lt;1 kHz) using electrocapillary wave measurements. The results provide valuable insights into the interplay between salt presence and interfacial properties of Pluronic F-68 and highlight the challenges of obtaining accurate dilatational rheological data under specific measurement conditions.

The application of a novel amine collector, 1-(dodecylamino)-2-propanol, in the reverse flotation separation of apatite and quartz

This study synthesized a novel amine collector, 1-(dodecylamino)-2-propanol (DDAIP), by incorporating a 2-hydroxy propyl group into the molecular structure of dodecylamine (DDA). Flotation experiments showed that utilizing DDAIP collector resulted in a substantial difference of ∼80% in flotation recoveries between apatite and quartz. Employing DDA as the collector yielded a difference of ∼30% in flotation recoveries between the two minerals. DDAIP demonstrated a superior selectivity in the reverse flotation separation of apatite and quartz in comparison to DDA. Zeta potential experiments indicated that, under identical dosages, DDAIP demonstrated increased adsorption capacities on quartz surface in contrast to DDA, whereas the adsorption amounts on apatite surface remained similar for both the collectors. By combining XPS analysis and first-principles calculations, DDAIP demonstrated enhanced chemical interactions with the Si atoms on quartz surface and a greater number of hydrogen bonds with quartz surface compared to DDA. The presence of an isopropyl group between the hydroxyl and secondary amine groups in DDAIP molecular structure leads to steric hindrance, hindering the simultaneous chemical interactions of the O and N atoms in DDAIP with the Ca2+ ions on apatite surface. Thus, the incorporation of the 2-hydroxy propyl group into DDAIP molecular structure does not enhance its adsorption strength on apatite surface when compared to DDA.

Blood compatibility of poly(propylene glycol diester) and its water structure observed by differential scanning calorimetry and 2H-nuclear magnetic resonance spectroscopy

Recently, we applied solution 2H-nuclear magnetic resonance spectroscopy (2H NMR) to analyze the water (deuterium oxide, D2O) structure in several biopolymers at ambient temperature. We established that polymers with good blood compatibility (i.e. poly(2-methoxyethyl acrylate) (PMEA)) have water observed at high magnetic fields (upfield) compared with bulk water. Polymers containing poly(propylene glycol) (PPG) or poly(propylene oxide) (PPO) exhibit good compatibility; however, the reason for this remains unclear. In addition, reports on the blood compatibility of PPO/PPG are limited. Therefore, PPG diester (PPGest) was prepared as a model polymer, and its blood compatibility and water structure were investigated. PPGest exhibited excellent blood compatibility. The water in PPGest was observed upfield by 2H NMR, and it was defined as non-freezing water via differential scanning calorimetry. Based on these observations, the relationship between the blood compatibility and water structure of PPGest is discussed by comparing with those of PMEA, and the reason for the good performance of PPG/PPO-based polymers is discussed.

Simulation Study of Propylene Glycol Formation from Propylene Oxide and Water: Effect of Reactor Type, Reactant Ratio, Temperature, and Reactor Configuration

This study investigates the effect of reactor type, reactor configuration, reactor temperature, and reactant ratio on the formation of propylene glycol from propylene oxide and water using HYSY Simulation Software. The reactor types studied were Continuous Stirred Tank Reactors (CSTR) and Plug Flow Reactors (PFR). The effect of the reactant ratio was investigated by varying the mole ratio of propylene oxide to water. The effect of temperature was studied by varying the reaction temperature from 24 to 40°C. The HYSYS simulation results showed that the PFR resulted in the highest conversion compared to the CSTR. The CSTR configuration in series resulted in the highest conversion compared to the CSTR configuration in parallel. The conversion of propylene oxide to propylene glycol increased with increasing temperature. The reactant ratio of 1:1 (propylene oxide to water) resulted in the highest conversion compared to other reactant ratios. The implication of this study is to provide information on a more efficient and economical propylene glycol process.

Modulating the Electronic States of Pt Nanoparticles on Reducible Metal-Organic Frameworks for Boosting the Oxidation of Volatile Organic Compounds.

The adsorption and activation of pollutant molecules and oxygen play a critical role in the oxidation reaction of volatile organic compounds (VOCs). In this study, superior adsorption and activation ability was achieved by modulating the interaction between Pt nanoparticles (NPs) and UiO-66 (U6) through the spatial position effect. Pt@U6 exhibits excellent activity in toluene, acetone, propane, and aldehyde oxidation reactions. Spectroscopic studies, 16O2/18O2 kinetic isotopic experiments, and density functional theory (DFT) results jointly reveal that the encapsulated Pt NPs of Pt@U6 possess higher electron density and d-band center, which is conducive for the adsorption and dissociation of oxygen. The toluene oxidation reaction and DFT results indicate that Pt@U6 is more favorable to activate the C-H of toluene and the C═C of maleic anhydride, while Pt/U6 with lower electron density and d-band center exhibits a higher oxygen dissociation temperature and higher reactant activation energy barriers. This study provides a deep insight into the architecture-performance relation of Pt-based catalysts for the catalytic oxidation of VOCs.

Reversed dynamics of bottlebrush polymers with stiff backbone and flexible side chains.

The segmental dynamics of bottlebrush polymers with a stiff backbone and flexible side chains has been studied. The segmental relaxation time of side chains attached to a flexible backbone follows the same trend as linear polymers, an increase with the increasing molecular weight, but is slowed down compared to their linear counterparts. Theoretical work predicts a reversal of the molecular weight dependence of the relaxation time for stiff backbones. As a model for a stiff-g-flexible system, bottlebrushes with poly(norbornene) backbone and poly(propylene oxide) side chains, PNB-g-PPO, at a uniform grafting density have been synthesized and characterized with quasi-elastic neutron scattering. Indeed, the anticipated reversed dynamics was found. Increasing the side chain length decreases the segmental relaxation time. This indicates the importance of the characteristics of the grafting site beyond a simplified picture of an attached side chain. The mean square displacement shows a similar trend with longer side chains exhibiting a larger displacement.

The Effect P Additive on the CeZrAl Support Properties and the Activity of the Pd Catalysts in Propane Oxidation.

The properties of a catalyst support are closely related to the catalyst activity, yet the focus is often placed on the active species, with little attention given to the support properties. In this work, we specifically investigated the changes in support properties after the addition of P, as well as their impact on catalyst activity when used for catalyst preparation. We prepared the CeO2-ZrO2-P2O5-Al2O3 (CeZrPAl) composite oxides using the sol-gel, impregnation, and mechanical mixing methods, and characterized the support properties using techniques such as XRD, XPS, SEM-EDS, N2 adsorption-desorption, and Raman spectra. The results showed that the support prepared using the sol-gel method can exhibit a more stable phase structure, larger surface area, higher adsorption capacity for oxygen species, and greater oxygen storage capacity. The addition of an appropriate amount of P is necessary. On the one hand, the crystallization and growth of CePO4 can lead to a decrease in the Ce content in the cubic phase ceria-zirconia solid solution, resulting in a phase separation of the ceria-zirconia solid solution. On the other hand, CePO4 can lock some of the Ce3+/Ce4+ redox pairs, leading to a reduction in the adsorption of oxygen species and a decrease in the oxygen storage capacity of the CeZrPAl composite oxides. The research results indicated that the optimal P addition is 6 wt.% in the support. Therefore, we prepared a Pd/CeZrPAl catalyst using CeZrAl with 6 wt.% P2O5 as the support and conducted the catalytic oxidation of C3H8. Compared with the support without P added, the catalyst activity of the support loaded with P was significantly improved. The fresh and aged (1000 °C/5 h) catalysts decreased by 20 °C and 5 °C in T50 (C3H8 conversion temperature of 50%), and by 81 °C and 15 °C in T90 (C3H8 conversion temperature of 90%), respectively.

Investigation of AFeO3 (A=Ba, Sr) Perovskites for the Oxidative Dehydrogenation of Light Alkanes under Chemical Looping Conditions.

Oxidative dehydrogenation (ODH) of light alkanes to produce C2-C3 olefins is a promising alternative to conventional steam cracking. Perovskite oxides are emerging as efficient catalysts for this process due to their unique properties such as high oxygen storage capacity (OSC), reversible redox behavior, and tunability. Here, we explore AFeO3 (A=Ba, Sr) bulk perovskites for the ODH of ethane and propane under chemical looping conditions (CL-ODH). The higher OSC and oxygen mobility of SrFeO3 perovskite contributed to its higher activity but lower olefin selectivity than its Ba counterpart. However, SrFeO3 perovskite is superior in terms of cyclic stability over multiple redox cycles. Transformations of the perovskite to reduced phases including brownmillerite A2Fe2O5 were identified by X-ray diffraction (XRD) as a cause of performance degradation, which was fully reversible upon air regeneration. A pre-desorption step was utilized to selectively tune the amount of lattice oxygen as a function of temperature and dwell time to enhance olefin selectivity while suppressing CO2 formation from the deep oxidation of propane. Overall, SrFeO3 exhibits promising potential for the CL-ODH of light alkanes, and optimization through surface and structural modifications may further engineer well-regulated lattice oxygen for maximizing olefin yield.

Hydroxypropyl methacrylate stars as versatile carriers of therapeutic agents

AbstractThree star‐like carriers with poly(hydroxy propyl methacrylate) (PHPMA) cores and poly(oligoethylene glycol methacrylate) (POEGMA) arms as nanocarriers were utilized for the encapsulation of rhodamine B, resveratrol, and curcumin. These drugs differ in hydrophobicity and therapeutic effects. The carriers had high encapsulation and loading efficiency (&gt;95% and 10 wt%, respectively) and formed hydrogen bonds with the drugs. They were spherical in phosphate buffer saline and formed aggregates of various sizes (11–116 nm) depending on the star composition and the drug type. The carriers were stable for 2 months, but released different amounts of drugs afterwards, except for curcumin, which stayed entrapped. The curcumin‐loaded carriers also generated reactive oxygen species. These findings demonstrate the versatility of PHPMA/POEGMA stars as nanocarriers for diverse applications in nanomedicine.

Preparation and Properties of Mechanically Robust, Colorless, and Transparent Aramid Films.

In this study, various diamine monomers were used to synthesize aramid polymer films via a low-temperature solution condensation reaction with diacid chloride. For diamines with relatively high basicity, the reaction system became opaque because amine salt formation inhibited polymer synthesis. Meanwhile, low-basicity diamines with strong electron-withdrawing groups, such as CF3 and sulfone, were smoothly polymerized without amine salt formation to provide highly viscous solutions. The acid byproduct HCl generated during polymerization was removed by adding propylene oxide to the reaction vessel and converting the acid into highly volatile inert substances. The resulting solutions were used as varnishes without any additional purification, and polymer films with an excellent appearance were easily obtained through a conventional casting and convection drying process. The films neither tore nor broke when pulled or bent by hand; furthermore, even when heated up to 400 °C, they did not decompose or melt. Moreover, polymers prepared from 2,2-bis(trifluoromethyl)benzidine (TFMB) and bis(4-aminophenyl)sulfone (pAPS) did not exhibit glass transition until decomposition. The prepared polymer films showed a high elastic modulus of more than 4.1 GPa and a high tensile strength of more than 52 MPa. In particular, TFMB-, pAPS-, and 2,2-bis(4-aminophenyl)hexafluoropropane-based polymer films were colorless and transparent, with very high light transmittances of 95%, 96%, and 91%, respectively, at 420 nm and low yellow indexes of 2.4, 1.9, and 4.3, respectively.