We have studied the effect of the electrode material on the switching behavior of the Ovonic Threshold Switch (OTS) composed of metal/amorphous Ge60Se40/metal. The switching voltage is found to depend strongly on the electrode material, showing a much lower value (∼1.74 V) for Mo compared to that (∼5.85 V) of TiN. As the origin, the Schottky barrier and the interface trap states are examined, leading to a conclusion that the latter plays a crucial role. These results are interpreted by a picture of carrier transport at a metal/amorphous chalcogenide interface, providing an effective method to modulate the switching characteristics of the OTS device for various applications.