Microwave-absorbing materials with wide bandwidth and high absorptivity are increasingly playing an important role in over-the-air (OTA) testing. In this work, a kind of pyramid absorbing material was prepared using flame-retardant absorbers as the filler. In addition, a coating was used to further improve the flame-retardant properties of the microwave-absorbing material. To obtain excellent microwave absorption performance (MWAP), a high-frequency structure simulator (HFSS) was adopted to design structural materials. Here, the total height, the base height, the decapitation height of the pyramid tip, the distance between the pyramids, and other parameters were analyzed; then, the actual processing and molding were realized. The MWAP of -30 dB was achieved at 2.7-18 GHz, and the MWAP of -10 dB was also met at 2-18 GHz. In particular, the study also investigated the MWAP of large angle, which can meet the MWAP of -10 dB at 2-18 GHz and MWAP of -30 dB at 4-18 GHz. Most importantly, the absorption mechanism of the pyramid structure was explored. The influence of the tip was proved by the distribution of the electromagnetic field in the pyramid. It can be regarded as a multilayer microwave-absorbing material due to the impedance gradient of the pyramid, which can provide an effective research idea and method for future engineering applications.