For a domestic 350 MW coal-fired power plant, the effect of heterogeneous agglomeration technology on the migration and emission of three trace elements of arsenic, selenium and lead in tail flue gas was studied. The results show that heterogeneous agglomeration technology can promote the attachment of gaseous harmful trace elements to particulate matter effectively. The reduction rates of gaseous As, Se and Pb concentrations at the ESP outlet were 24.10%, 61.08%, and 70.38%, respectively. Under the synergistic effect of ESP, more As, Se, and Pb are enriched in fly ash, and the concentration of As, Se, and Pb in fine particles below 10 μm at the ESP outlet is reduced by 54.48%, 56.47%, and 75.17%, respectively. In addition, after spraying the agglomerating agent, the final As, Se, and Pb concentrations in the atmosphere were 1.29 μg/m3, 2.01 μg/m3, and 1.12 μg/m3, which were far lower than those of the relevant EPA emission limits.
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