Outer Corona Research Articles

Whistler instability stimulated by the suprathermal electrons present in space plasmas

In the absence of efficient collisions, deviations from thermal equilibrium of plasma particle distributions are controlled by the self-generated instabilities. The whistler instability is a notorious example, usually responsible for the regulation of electron temperature anisotropy $A = T_{\perp}/T_\parallel>$ (with $\perp, \parallel$ respective to the magnetic field direction) observed in space plasmas, e.g., solar wind and planetary magnetospheres. Suprathermal electrons present in these environments change the plasma dispersion and stability properties, with expected consequences on the kinetic instabilities and the resulting fluctuations, which, in turn, scatter the electrons and reduce their anisotropy. In order to capture these mutual effects we use a quasilinear kinetic approach and PIC simulations, which provide a comprehensive characterization of the whistler instability under the influence of suprathermal electrons. Analysis is performed for a large variety of plasma conditions, ranging from low-beta plasmas encountered in outer corona or planetary magnetospheres to a high-beta solar wind characteristic to large heliospheric distances. Enhanced by the suprathermal electrons, whistler fluctuations stimulate the relaxation of temperature anisotropy, and this influence of suprathermals increases with plasma beta parameter.

On the Nature of the Bright Core of Solar Coronal Mass Ejections

Abstract Coronal mass ejections (CMEs) often exhibit the classic three-part structure in a coronagraph, i.e., the bright front, dark cavity, and bright core, which are traditionally considered as the manifestations of coronal plasma pileup, magnetic flux rope (MFR), and filament, respectively. However, a recent survey based on 42 CMEs all possessing the three-part structure found that a large majority (69%) do not contain an eruptive filament at the Sun. Therefore, a challenging opinion is proposed and claims that the bright core can also correspond to the MFR, which is supported by the CME simulation. Then what is the nature of the CME core? In this paper, we address this issue through a CME associated with the eruption of a filament-hosting MFR on 2013 September 29. This CME exhibits the three-part morphology in multiple white-light coronagraphs from different perspectives. The new finding is that the bright core contains both a sharp and a fuzzy component. Through tracking the filament motion continuously from its source region to the outer corona, we conclude that the sharp component corresponds to the filament. The fuzzy component is suggested to result from the MFR that supports the filament against the gravity in the corona. Our study can shed more light on the nature of CME cores, and explain the core whether or not the filament is involved with a uniform scenario. The nature of the CME cavity is also discussed.

Evidence for Rayleigh-Taylor Plasma Instability at the Front of Solar Coronal Mass Ejections

This work focuses on the interaction of a Coronal Mass Ejection (CME) with the ambient solar corona, by studying the spatial and temporal evolution of the density fluctuations observed by the SOHO/UV Coronagraph Spectrometer (UVCS) during the CME. The investigation is performed by applying a wavelet analysis to the HI Ly α 1216 Å line intensity fluctuations observed with UVCS during the CME occurred on 24 December 2006. Strong and coherent fluctuations, with a significant spatial periodicity of about 84 Mm ≃ 0.12 R ⊙ , are shown to develop in about an hour along the front of the CME. The results seem to indicate the Rayleigh-Taylor (RT) instability, susceptible to the deceleration of the heavier fluid of the CME front into the lighter surrounding coronal plasma, as the likely mechanism underlying the generation of the observed plasma fluctuations. This could be the first inference of the RT instability in the outer solar corona in UV, due to the transit of a CME front in the quiet coronal plasma; this interpretation is also supported by a linear magnetohydrodynamic analysis of the RT instability.

Driving solar coronal MHD simulations on high-performance computers

ABSTRACTThe quality of today's research is often tightly limited to the available computing power and scalability of codes to many processors. For example, tackling the problem of heating the solar corona requires a most realistic description of the plasma dynamics and the magnetic field. Numerically solving such a magneto-hydrodynamical (MHD) description of a small active region (AR) on the Sun requires millions of computation hours on current high-performance computing (HPC) hardware. The aim of this work is to describe methods for an efficient parallelisation of boundary conditions and data input/output (IO) strategies that allow for a better scaling towards thousands of processors (CPUs). The Pencil Code is tested before and after optimisation to compare the performance and scalability of a coronal MHD model above an AR. We present a novel boundary condition for non-vertical magnetic fields in the photosphere, where we approach the realistic pressure increase below the photosphere. With that, magnetic flux bundles become narrower with depth and the flux density increases accordingly. The scalability is improved by more than one order of magnitude through the HPC-friendly boundary conditions and IO strategies. This work describes also the necessary nudging methods to drive the MHD model with observed magnetic fields from the Sun's photosphere. In addition, we present the upper and lower atmospheric boundary conditions (photospheric and towards the outer corona), including swamp layers to diminish perturbations before they reach the boundaries. Altogether, these methods enable more realistic 3D MHD simulations than previous models regarding the coronal heating problem above an AR – simply because of the ability to use a large amount of CPUs efficiently in parallel.

Exploring the outer emission corona spectroscopically by using Visible Emission Line Coronagraph (VELC) on board ADITYA-L1 mission

It is very important to make the spectrographic observations of the outer emission corona in number of emission lines simultaneously in view of the results of the observations made in [Fe x] 6374 Å, [Fe xi] 7892 Å, [Fe xiv] 5303 Å and [Fe xiii] 10,747 Å coronal emission lines with the 25 cm coronagraph at Norikura Observatory in Japan. At ground based observatories, availability of number of hours of clear sky for coronagraphic observations is limited due to aerosols scattering and scattering from the internal coronagraph reflections. A space based coronagraph Visible Emission Line Coronagraph (VELC) on board ADITYA-L1 has been planned to perform spectroscopy in 3 out of the 4 emission lines mentioned above. Here, we discuss the various requirements for the parameters of the payload, given the specifications of the satellite, to observe the outer emission corona reliably with good Signal to Noise Ratio (SNR), realize the projected scientific goals and make the mission a great success.

Effect of the non-uniform solar chromospheric Lyα radiation on determining the coronal H I outflow velocity

We derived maps of the solar wind outflow velocity of coronal neutral hydrogen atoms at solar minimum in the altitude range 1.5–4.0 R⊙. We applied the Doppler dimming technique to coronagraphic observations in the UV H I Lyα line at 121.6 nm. The technique exploits the intensity reduction in the coronal line with increasing velocities of the outflowing plasma to determine the solar wind velocity by iterative modelling. The Lyα line intensity is sensitive to the wind outflow velocity and also depends on the physical properties of coronal particles and underlying chromospheric emission. Measurements of irradiance by the chromospheric Lyα radiation in the corona are required for a rigorous application of the Doppler dimming technique, but they are not provided by past and current instrumentations. A correlation function between the H I 121.6 nm and He II 30.4 nm line intensities was used to construct Carrington rotation maps of the non-uniform solar chromospheric Lyα radiation and thus to compute the Lyα line irradiance throughout the outer corona. Approximations concerning the temperature of the scattering H I atoms and exciting solar disc radiation were also adopted to significantly reduce the computational time and obtain a faster procedure for a quick-look data analysis of future coronagraphic observations. The effect of the chromospheric Lyα brightness distribution on the resulting H I outflow velocities was quantified. In particular, we found that the usual uniform-disc approximation systematically leads to an overestimated velocity in the polar and mid-latitude coronal regions up to a maximum of about 50−60 km s−1 closer to the Sun. This difference decreases at higher altitudes, where an increasingly larger chromospheric portion, including both brighter and darker disc features, contributes to illuminate the solar corona, and the non-uniform radiation condition progressively approaches the uniform-disc approximation.

Synthesis of Thermosensitive Conjugated Triblock Copolymers by Sequential Click Couplings for Drug Delivery and Cell Imaging.

The elegant integration of an excellent light-emitting segment and a biorelevant signal-responsive moiety could generate advanced polymeric delivery systems with simultaneously favorable diagnostic and therapeutic functions with respect to cancer theranostics. Although polymeric delivery systems based on fluorescent polyfluorene (PF) or thermoresponsive poly(N-isopropylacrylamide) (PNIPAAm) have been extensively developed, the preparation of a ternary polymer formulation composed of a PF block, a PNIPAAm sequence, and a hydrophilic moiety remains rarely explored likely because of the difficulty in integrating different synthesis strategies for polymer synthesis. To this end, herein we reported the design and controlled synthesis of a PF- and PNIPAAm-based amphiphilic triblock copolymer, PF11-b-PNIPAAm120-b-poly(oligo(ethylene glycol) monomethyl ether methacrylate)17 (PF11-b-PNIPAAm120-b-POEGMA17), with a well-defined structure by a strategy of sequential click couplings between Suzuki-coupling-generated PF and atom-transfer radical polymerization (ATRP)-produced PNIPAAm and POEGMA. The as-prepared triblock copolymers can self-assemble into micelles with a core-shell-corona (CSC) structure that is composed of an inner hydrophobic core of the PF moiety for fluorescent tracking and drug encapsulation, a thermosensitive middle shell of PNIPAAm block for thermomodulated drug loading and release, and a hydrophilic outer corona of the POEGMA segment for micelle stabilization. Interestingly, the doxorubicin (DOX)-loaded micelles prepared at 25 °C had a greater drug loading capacity than the analogues fabricated at 37 °C due to the better stability of the former formulation, leading to its higher in vitro cytotoxicity in HeLa cells. Together with the integration of a localized hyperthermia-triggered drug release profile and efficiently intracellular trafficking of the nanocarriers by monitoring the fluorescence of the PF moiety, this formulation demonstrates a great potential for cancer theranostics.

Twin CME Launched by a Blowout Jet Originated from the Eruption of a Quiet-Sun Mini-filament

We study a quiet-Sun blowout jet which is observed on 2014 May 16 by the instruments on board Solar Dynamics Observatory (SDO). We find the twin CME as jet-like and bubble-like CME simultaneously as observed by LASCO C2 on board Solar and Heliospheric Observatory (SoHO), Solar Terrestrial Relation Observatory (STEREO A and STEREO B/COR2). They are respectively associated with the eruption of the northern and southern sections of the filament. A circular filament is rooted at the internetwork region at the base of the blowout jet. The collective magnetic cancellation is observed by SDO/HMI line of sight (LOS) magnetograms at the northern end of the filament, which makes this filament unstable and further makes it to erupt in two different stages. In the first stage, northern section of the filament is ejected, and causes an evolution of the northern part of the blowout jet. This part of the blowout jet is further extended as a collimated plasma beam to form a jet-like CME. We also observe the plasma blobs at the northern edge of the blowout jet resulting from Kelvin-Helmholtz (K-H) instability in its twisted magneto-plasma spire. In the second stage, southern section of the filament erupts in form of deformed/twisted magnetic flux rope which forms the southern part of the blowout jet. This eruption is most likely caused by the eruption of the northern section of filament, which removes the confined magnetic field of the southern section of the filament. Alternative scenarios may be a magnetic implosion between these magnetic structures confined in a much larger magnetic domain. This eruption of southern section of the filament further results in the bubble-like CME in the outer corona.

Bacteria-Based Production of Thiol-Clickable, Genetically Encoded Lipid Nanovesicles.

Despite growing research efforts on the preparation of (bio)functional liposomes, synthetic capsules cannot reach the densities of protein loading and the control over peptide display that is achieved by natural vesicles. Herein, a microbial platform for high-yield production of lipidic nanovesicles with clickable thiol moieties in their outer corona is reported. These nanovesicles show low size dispersity, are decorated with a dense, perfectly oriented, and customizable corona of transmembrane polypeptides. Furthermore, this approach enables encapsulation of soluble proteins into the nanovesicles. Due to the mild preparation and loading conditions (absence of organic solvents, pH gradients, or detergents) and their straightforward surface functionalization, which takes advantage of the diversity of commercially available maleimide derivatives, bacteria-based proteoliposomes are an attractive eco-friendly alternative that can outperform currently used liposomes.

Bacteria‐Based Production of Thiol‐Clickable, Genetically Encoded Lipid Nanovesicles

AbstractDespite growing research efforts on the preparation of (bio)functional liposomes, synthetic capsules cannot reach the densities of protein loading and the control over peptide display that is achieved by natural vesicles. Herein, a microbial platform for high‐yield production of lipidic nanovesicles with clickable thiol moieties in their outer corona is reported. These nanovesicles show low size dispersity, are decorated with a dense, perfectly oriented, and customizable corona of transmembrane polypeptides. Furthermore, this approach enables encapsulation of soluble proteins into the nanovesicles. Due to the mild preparation and loading conditions (absence of organic solvents, pH gradients, or detergents) and their straightforward surface functionalization, which takes advantage of the diversity of commercially available maleimide derivatives, bacteria‐based proteoliposomes are an attractive eco‐friendly alternative that can outperform currently used liposomes.

Solar Wind Magnetic Field Turbulence over the Solar Activity Cycle Inferred from Coronal Sounding Experiments with Helios Linear-Polarized Signals

Results of experiments on polarized radio sounding of the outer solar corona using the Helios spacecraft from 1975 to 1984 are presented. The characteristic parameters of the temporal spectra of fluctuations in the Faraday rotation of the plane of polarization for heliocentric distances from 3.5 to 5.5 solar radii are obtained. The absolute level of these fluctuations and, consequently, the level of fluctuations of the magnetic field, is almost independent of the solar activity. It is well known that the global structure of the solar wind varies with the solar cycle such that there is slow solar wind at low latitudes and fast solar wind at high latitudes during solar minima. In contrast, a slow solar wind dominates at all latitudes during solar maxima. One explanation for the invariance of the fluctuations observed by sounding the circumsolar plasma is that the mean magnetohydrodynamic turbulence of the low-latitude, slow solar wind depends weakly on the phase of the solar cycle.

Frequency–Distance Structure of Solar Radio Sources Observed by LOFAR

Abstract Low-frequency radio observations make it possible to study the solar corona at distances up to 2–3 R ☉. Frequency of plasma emission is a proxy for electron density of the emitting plasma and, therefore, observations of solar radio bursts can be used to probe the density structure of the outer corona. In this study, positions of solar radio sources are investigated using the Low-Frequency Array (LOFAR) spectral imaging in the frequency range 30–50 MHz. We show that there are events where apparent positions of the radio sources cannot be explained using the standard coronal density models. Namely, the apparent heliocentric positions of the sources are 0.1–0.7 R ☉ further from the Sun compared with the positions predicted by the Newkirk model, and these shifts are frequency-dependent. We discuss several possible explanations for this effect, including enhanced plasma density in the flaring corona, as well as scattering and refraction of the radio waves.

Hoya of the Philippines, Part II: Hoya pulchra (Apocynaceae), a New Species from Southern Philippines

A new species, Hoya pulchra Aurigue & Cabactulan (Apocynaceae), is described and illustrated. It is compared with the similar H. waymaniae, endemic to Borneo, from which it differs in lamina shape (lanceolate with a flat edge vs. elliptic-ovate with undulate edge) and the absence of bilobed apex in the outer corona lobe apex vs. a short raised bilobed apex.

Modeling and removal of optical ghosts in the PROBA-3/ASPIICS externally occulted solar coronagraph

Context. ASPIICS is a novel externally occulted solar coronagraph, which will be launched onboard the PROBA-3 mission of the European Space Agency. The external occulter will be placed on the first satellite ∼150 m ahead of the second satellite that will carry an optical instrument. For 6 h per orbit, the satellites will fly in a precise formation, constituting a giant externally occulted coronagraph. The large distance between the external occulter and the primary objective will allow observations of the white-light solar corona starting from extremely low heights ∼1.1 R⊙. Aims. We aim to analyze the possible influence of optical ghost images formed inside the telescope and to develop an algorithm for their removal. Methods. We implement the optical layout of ASPIICS in Zemax and study the ghost behavior in sequential and nonsequential regimes. We identify sources of the ghost contributions and analyze their geometrical behavior. Finally we develop a mathematical model and software to calculate ghost images for any given input image. Results. We show that ghost light can be important in the outer part of the field of view, where the coronal signal is weak, since the energy of bright inner corona is redistributed to the outer corona. However, the model allows for the ghost contribution to be removed. Due to the large distance between the external occulter and the primary objective, the primary objective does not produce a significant ghost. The use of the Lyot spot in ASPIICS is not necessary.

Geometry, Kinematics, and Heliospheric Impact of a Large CME-driven Shock in 2017 September

Abstract A powerful coronal mass ejection (CME) occurred on 2017 September 10 near the end of the declining phase of the historically weak solar cycle 24. We obtain new insights concerning the geometry and kinematics of CME-driven shocks in relation to their heliospheric impacts from the optimal, multispacecraft observations of the eruption. The shock, which together with the CME driver can be tracked from the early stage to the outer corona, shows a large oblate structure produced by the vast expansion of the ejecta. The expansion speeds of the shock along the radial and lateral directions are much larger than the translational speed of the shock center, all of which increase during the flare rise phase, peak slightly after the flare maximum and then decrease. The near simultaneous arrival of the CME-driven shock at the Earth and Mars, which are separated by 156.°6 in longitude, is consistent with the dominance of expansion over translation observed near the Sun. The shock decayed and failed to reach STEREO A around the backward direction. Comparison between ENLIL MHD simulations and the multipoint in situ measurements indicates that the shock expansion near the Sun is crucial for determining the arrival or nonarrival and space weather impact at certain heliospheric locations. The large shock geometry and kinematics have to be taken into account and properly treated for accurate predictions of the arrival time and space weather impact of CMEs.

Source Imaging of a Moving Type IV Solar Radio Burst and Its Role in Tracking Coronal Mass Ejection from the Inner to the Outer Corona

Abstract Source imaging of solar radio bursts can be used to track energetic electrons and associated magnetic structures. Here we present a combined analysis of data at different wavelengths for an eruption associated with a moving type IV (t-IVm) radio burst. In the inner corona, the sources are correlated with a hot and twisted eruptive EUV structure, while in the outer corona, the sources are associated with the top front of the bright core of a white-light coronal mass ejection (CME). This reveals the potential of using t-IVm imaging data to continuously track the CME by lighting up the specific component containing radio-emitting electrons. It is found that the t-IVm burst presents a clear spatial dispersion with observing frequencies. The burst manifests broken power law–like spectra in brightness temperature, which is as high as 107–109 K, while the polarization level is generally weak. In addition, the t-IVm burst starts during the declining phase of the flare with a duration as long as 2.5 hr. From the differential emission measure analysis of AIA data, the density of the T-IVm source is found to be at the level of 108 cm−3 at the start of the burst, and the temperature may reach up to several MK. These observations do not favor gyrosynchrotron to be the radiation mechanism but are in line with a coherent plasma emission excited by energetic electrons trapped within the source. Further studies are demanded to elucidate the emission mechanism and explore the full diagnostic potential of t-IVm bursts.

Predicting the COSIE-C Signal from the Outer Corona up to 3 Solar Radii

Abstract We present estimates of the signal to be expected in quiescent solar conditions, as would be obtained with the COronal Spectrographic Imager in the EUV in its coronagraphic mode (COSIE-C). COSIE-C has been proposed to routinely observe the relatively unexplored outer corona, where we know that many fundamental processes affecting both the lower corona and the solar wind are taking place. The COSIE-C spectral band, 186–205 Å, is well-known as it has been observed with Hinode EIS. We present Hinode EIS observations that we obtained in 2007 out to 1.5 R ⊙, to show that this spectral band in quiescent streamers is dominated by Fe xii and Fe xi and that the ionization temperature is nearly constant. To estimate the COSIE-C signal in the 1.5–3.1 R ⊙ region we use a model based on CHIANTI atomic data and SoHO UVCS observations in the Si xii and Mg x coronal lines of two quiescent 1996 streamers. We reproduce the observed EUV radiances with a simple density model, photospheric abundances, and a constant temperature of 1.4 MK. We show that other theoretical or semi-empirical models fail to reproduce the observations. We find that the coronal COSIE-C signal at 3 R ⊙ should be about 5 counts/s per 3.″1 pixel in quiescent streamers. This is unprecedented and opens up a significant discovery space. We also briefly discuss stray light and the visibility of other solar features. In particular, we present UVCS observations of an active region streamer, indicating increased signal compared to the quiet Sun cases.

Cubosomes: The Next Generation of Smart Lipid Nanoparticles?

Cubosomes are highly stable nanoparticles formed from the lipid cubic phase and stabilized by a polymer based outer corona. Bicontinuous lipid cubic phases consist of a single lipid bilayer that forms a continuous periodic membrane lattice structure with pores formed by two interwoven water channels. Cubosome composition can be tuned to engineer pore sizes or include bioactive lipids, the polymer outer corona can be used for targeting and they are highly stable under physiological conditions. Compared to liposomes, the structure provides a significantly higher membrane surface area for loading of membrane proteins and small drug molecules. Owing to recent advances, they can be engineered in vitro in both bulk and nanoparticle formats with applications including drug delivery, membrane bioreactors, artificial cells, and biosensors. This review outlines recent advances in cubosome technology enabling their application and provides guidelines for the rational design of new systems for biomedical applications.

Geology of the Renard 65 kimberlite pipe, Québec, Canada

Renard 65, a diamondiferous pipe in the Neoproterozoic Renard kimberlite cluster (Quebec, Canada), is a steeply-dipping and downward-tapering diatreme comprised of three pipe-filling units: kimb65a, kimb65b, and kimb65d. The pipe is surrounded by a marginal and variably-brecciated country rock aureole and is crosscut by numerous hypabyssal dykes: kimb65c. Extensive petrographic and mineralogical characterization of over 700 m of drill core from four separate drill holes, suggests that Renard 65 is a Group I kimberlite, mineralogically classified as phlogopite kimberlite and serpentine-phlogopite kimberlite. Kimb65a is a massive volcaniclastic kimberlite dominated by lithic clasts, magmaclasts, and discrete olivine macrocrysts, hosted within a fine-grained diopside and serpentine-rich matrix. Kimb65b is massive, macrocrystic, coherent kimberlite with a groundmass assemblage of phlogopite, spinel, perovskite, apatite, calcite, serpentine and rare monticellite. Kimb65c is a massive, macrocrystic, hypabyssal kimberlite with a groundmass assemblage of phlogopite, serpentine, calcite, perovskite, spinel, and apatite. Kimb65d is massive volcaniclastic kimberlite with localized textures that are intermediate between volcaniclastic and coherent, with tightly packed magmaclasts separated by a diopside- and serpentine-rich matrix. Lithic clasts of granite-gneiss in kimb65a are weakly reacted, with partial melting of feldspars and crystallization of richterite and actinolite. Lithic clasts in kimb65b and kimb65d are entirely recrystallized to calcite + serpentine/chlorite + pectolite and display inner coronas of diopside-aegirine and an outer corona of phlogopite. Compositions are reported for all minerals in the groundmass of coherent kimberlites, magmaclasts, interclast matrices, and reacted lithic clasts. The Renard 65 rocks are texturally classified as Kimberley-type pyroclastic kimberlites and display transitional textures. The kimberlite units are interpreted to have formed in three melt batches based on their distinct spinel chemistry: kimb65a, kimb65b and kimb65d. We note a strong correlation between the modal abundances of lithic clasts and the textures of the kimberlites, where increasing modal abundances of granite/gneiss are observed in kimberlites with increasingly fragmental textures.

Packaging pDNA by Polymeric ABC Micelles Simultaneously Achieves Colloidal Stability and Structural Control.

Compaction of DNA by oppositely charged nanoparticles is a fundamental phenomenon in nature and of great interest to developing therapeutics. In addition, the ability to orthogonally control the composition and structure of interpolyelectrolyte complexes is needed to develop materials for diverse applications. Herein, we systematically investigate the complexation of plasmid DNA and polymeric cationic AB and ABC micelles to explore the influence of micelle outer nonionic corona length on the colloidal stability, size, composition, and structure of the resulting "micelleplexes". The micelles were self-assembled from amphiphilic block polymers, poly(ethylene glycol)- block-poly((2-dimethylamino)ethyl methacrylate)- block-poly( n-butyl methacrylate) (PEG- b-PDMAEMA- b-PnBMA), and PDMAEMA- b-PnBMA with the same Mn of PDMAEMA. These spherical micelles have similar hydrodynamic radii and core sizes, but the Mn of the outer PEG block ranged from 0 to 10 kDa. The colloidal stability of micelleplexes as a function of stoichiometric charge ratio was assessed by turbidimetric titration and was found to dramatically improve with the addition of an outer PEG corona, even as short as 2 kDa. With the use of a combination of dynamic and static light scattering, ζ-potential, and cryogenic transmission electron microscopy, it was found that the size, composition, and structure of micelleplexes are closely correlated with the Mn of the PEG block. Indeed, these micelleplexes were found to adopt beads-on-a-string morphologies that resemble the general structure of chromatin, and the number of micelles per micelleplex systematically decreased with increasing PEG length. These findings demonstrate the power of polycationic micelles to condense DNA into biomimetic structures and provide a mechanistic understanding of nucleic acid complexation and of how micelle architecture affects the properties of micelleplexes, while offering an appealing strategy to control the properties of micelleplexes by tuning a single parameter.