Oscillatory Zoning Research Articles

Geochemical Characteristics of Garnet from Zinc–Copper Ore Bodies in the Changpo–Tongkeng Deposit and Its Geological Significance

The Changpo–Tongkeng tin polymetallic deposit in Dachang, Guangxi, is a world-class, superlarge, polymetallic tin deposit consisting of lower skarn zinc–copper ore bodies and upper tin polymetallic ore bodies. Garnet is the main gangue mineral in the skarn zinc–copper ore bodies and has a granular texture. Based on hand specimens and microscopic observations, the existing garnet can be divided into two generations: an early generation (Grt I) and a late generation (Grt II). The results of electron probe microanalysis (EPMA) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) in situ microanalysis show that the contents of SiO2 and CaO in the garnets from the two generations present limited variations, while the FeOT and Al2O3 contents vary significantly, indicating the grossular–andradite solid solution series (Gro29–82And12–69). Compared with Grt I (Gro72And25), Grt II (Gro39And59) is Fe-enriched and oscillatory zoning is developed. The total rare earth element (REE) contents in the two generations of garnet are relatively low, showing light rare earth element (LREE) depletion and heavy rare earth element (HREE) enrichment patterns. Grt II has higher REE content than Grt I and exhibits significant negative Eu anomalies (δEu = 0.18–0.44). The contents and variation characteristics of the major and trace elements in the two generations of garnet suggest that there were variable redox conditions and water/rock ratios in the hydrothermal system during the crystallization process of garnet. In the early stage, skarnization was in a relatively closed and low-oxygen fugacity system, with hydrothermal diffusion metasomatism being dominant, forming homogeneous Grt I lacking well-developed zoning. In the late stage of skarnization, the oxygen fugacity of the ore-forming fluids increased, with infiltration metasomatism being dominant, forming Grt II with well-developed oscillatory zoning. The contents of Sn, As, W, In, and Ge in the garnets are relatively high and increase with the proportion of andradite. Sn in zinc–copper ore bodies mainly exists in the form of isomorphic substitution in garnet, which may be the main reason for the lack of tin ore bodies during the skarn stage. This paper compares the trace element contents in garnets from domestic skarn deposits. The results indicate that the Sn content and δEu in garnet can be used to evaluate the tin-forming potential of skarn deposits.

Transcrustal magma plumbing process in the Cenozoic Dali potassic lamprophyre dyke formation in the southeastern Tibet Plateau

(Ultra-)potassic lamprophyres are volumetrically rare, but are widely distributed in diverse geological settings and extensively applied to trace the mantle source and melting processes. However, it is still debatable whether the lamprophyre formation involved transcrustal magmatic processes. In this study, we describe the diverse zoning patterns and textures of clinopyroxene (Cpx) from a Cenozoic potassic lamprophyre dyke in southeastern Tibet Plateau. Three types of Cpx macrocrysts with normal- and reverse oscillatory zoning and sieved textures, and Cpx microcrysts from Cpx–Phl nodules are recognized. The Cpx macrocrysts have highly variable Mg# (62–89) and chemical compositions. Their oscillatory-zoned mantle has alternating coarse layers or closely-packed layers, with distinct resorption surface shown in backscattered electron (BSE) images. High-amplitude oscillation of Mg# (±5 to ±12), Al, Cr and Sr at the boundary layers of mantle may reflect multiple magma mixing/recharge events. In contrast, low-amplitude and high-frequency oscillation of Mg# (varying from < ±3) across the closely-packed layers could be attributed to local magma mixing or kinetic effect at the crystal-melt interface. The sieved domains occur in the Cpx macrocrystic core with spongy space and linking the external groundmass by cracks, and have major and minor compositions and 87Sr/86Sr ratios similar to those of the rims. This indicates that the sieved domains are probably originated from dissolution of the Cpx macrocrysts by groundmass melt and later reprecipitation. The estimated pressure and temperature for the Cpx macrocryst high-Mg# cores and low Mg# rims are 580–1160 MPa (avg. 919 MPa) and 30–1270 MPa (avg. 681 MPa), and 1116–1266 °C (avg. 1216 °C) and 955–1215 °C (avg. 1110 °C), respectively, suggesting polybaric differentiation or Cpx-saturated magmas. The estimated pressure and temperature for the reverse-zoned Cpx marcocryst cores are 450–1310 MPa (avg. 953 MPa) and 1097–1209 °C (avg. 1166 °C), respectively, indicating that they are likely formed in equilibrium with a more evolved magma batch, and then were entrapped by more primitive mantle-derived potassic magmas during magma upwelling. The La/Yb and Dy/Yb modelling of equilibrium melts suggest that magmas of the Cpx–Phl nodules and their lamprophyre host were derived from similar mantle sources. Therefore, the complex zoning patterns and compositions of Cpx macrocrysts could indicate transcrustal magmatic processes in the potassic lamprophyre dyke formation.

High-Resolution Cathodoluminescence Images of Igneous and Metamorphic Monazite.

Monazite is one of the most important dating accessory minerals for deciphering geological processes. The growth history of monazite can be identified by its internal structure; thus, high-resolution imaging is necessary for in situ U-Th-Pb dating. In this study, cathodoluminescence (CL) techniques were optimized via the key parameters of working distance, accelerating voltage, and beam current and were then applied to monazites from igneous and metamorphic rocks. The CL images of igneous monazites show concentric oscillatory zoning, whereas those of metamorphic monazites clearly show homogeneous, patchy, or core-rim structures. CL imaging is a more effective approach than back-scattered electron (BSE) imaging for the observation of the internal structure of monazite and may yield additional information. CL can add to the interpretation of X-ray maps and the two techniques that may complement each other. The CL spectra of monazite consist of broad peaks and sets of narrow emission rare earth element 3+ (REE3+) peaks (Gd3+, Tb3+, Dy3+, and Sm3+). The microstructures observed via CL imaging techniques can show a certain relationship between light REE (LREE) and U, Th, and Si in some igneous monazites and heavy REE (HREE) variation in some metamorphic monazites.

Robust dating of Pb–Zn skarn systems by LA–ICP–MS garnet U–Pb geochronology

Lawu and Yaguila are two Pb–Zn skarn deposits in the eastern Nyainqêntanglha metallogenic belt, central Lhasa subterrane, Tibet. The genesis of Pb–Zn deposits in this belt and the crustal processes leading to their formation remain ill-constrained, mostly because of the lack of precise mineralization ages. We integrate textural information, geochemistry, and in-situ garnet U–Pb geochronology to constrain the timing and genesis of Pb–Zn mineralization. Garnets from the two deposits display oscillatory compositional zoning (And14Gr86 to And100) and contain variable U contents (0.07–5.3 ppm). Aluminum-rich garnet displays a chondrite-normalized rare earth element (REE) fractionation pattern in which LREEs are depleted relative to flattish HREE segments. In contrast, Fe-rich garnet shows LREE-enriched, relatively HREE-poor patterns with positive Eu-anomalies. Uranium concentration is correlated with total REE and Fe components in garnets, implying that U incorporation is largely controlled by coupled substitution mechanisms. The same garnets also contain measurable contents of other metals (up to hundreds of ppm), such as Sn, W, and In. The distribution and fractionation of major and trace elements in zoned garnets record periodic fluid pluses with different compositions during hydraulic fracturing. The new garnet U–Pb data show that the Yaguila deposit formed between 68.5 ± 3.4 and 65.0 ± 4.7 Ma, and the Lawu deposit formed at 54.6 ± 2.9 Ma. Within the geochronological framework of igneous rocks and Pb–Zn mineralization in the Nyainqêntanglha metallogenic belt, the new garnet ages suggest a magmatic-hydrothermal origin for related mineralization, with the causative magma likely derived from partial melting of ancient continental material due to rollback and subsequent breakoff of the Neo-Tethys oceanic slab during India–Asia continental collision. This study highlights the opportunities offered by garnet U–Pb dating for elucidating the formation age and ore genesis of base metal skarn systems.

Oscillatory Zoned Liddicoatite from Anjanabonoina, Central Madagascar. III. Trace Elements

Abstract Large crystals of liddicoatite (tourmaline) from the Anjanabonoina Pegmatite of Central Madagascar are well-known for their distinct patterns of oscillatory zoning. This study follows two previous investigations, in which the crystal chemistry (Lussier et al. 2011a) and variations of major chemical constituents (Lussier &amp; Hawthorne 2011) were characterized in detail. Here, the variations of elements present only at the trace level are investigated. The measurement by laser ablation inductively coupled plasma mass spectrometry of 26 trace elements, with abundances spanning four orders of magnitude (∼10−1 to 103 ppm) is reported. Trace elements were analyzed along continuous analytical traverses from the core to the rim of the crystal. Abundance profiles for most of the trace elements quantified (21 of 26) show clear oscillations that coincide with optical oscillatory zoning features. Throughout the crystal, the occurrence of compositional oscillation is independent of trace-element abundance; even where mean abundance is low, ∼1 ppm (e.g., V3+, Y3+, Th4+), oscillatory behavior is clear. Conversely, the magnitude of the oscillatory amplitude shows a strong near-linear dependence on element abundance. Within individual oscillatory zones, four unique line-shapes are observed, each differentiated by (1) the direction of a compositional discontinuity at the zone limits and (2) the orientation of the nonlinear curvature across the zone. For any individual zone, the variation in element concentration, C, can be fitted to the equation C = ±Aeλ(x−Φ)+ Δ where A is the zone amplitude; Φ is a reference position, and λi and Δi are fitted parameters. Comparison of the fitted equations shows that linear correlation between element pairs is common, occurring between pairs consisting of trace–trace, trace–major, and major–major elements. The oscillatory behavior of constituent elements is related to the location of the trace element in the tourmaline structure, with elements at the X- and Y-sites typically showing increases and decreases in abundance over single oscillatory zones. Throughout each zone, Mg has high abundance (∼104 ppm) at the start of each zone, followed by an extremely abrupt decrease in abundance, typically over a distance of &amp;lt;1 mm, making its behavior different to that of other elements (both trace and major). Finally, there are systematic differences in trace-element abundances between pyramid {201} and prism {100} sectors of the crystal, echoing the differences observed for major elements between these two sectors and consistent with face-dependent differences in element uptake.

INTERPRETATION OF THE MAGMA CHAMBER PROCESSES USING MICRO-TEXTURE AND ZONING STYLES IN PLAGIOCLASE CRYSTALS: EVIDENCE FROM THE ANDESITIC ROCKS IN SABZEVAR ZONE (NE IRAN)

Investigation of variations in the micro-texture and chemical composition of plagioclases (core to rim) allows the sequencing of the magma chamber processes and helps interprete and associate textures to specific processes. In this contribution, the micro-textures and chemical zoning of the plagioclases, significant recorder of magma chamber processes, from the west of Torbat-e-Heydariyeh andesitic rocks (WTHAR) are considered to decipher the physical and chemical parameters of magma evolution. The rocks are cropped out in the northern branch of Neotethyan magmatic belt and considered as the products of Eocene magmatic activities of the Sabzevar zone (N-NE Iran). The rocks show vitrorphyric and vitroglomeroporphyric textures with main phenocrysts, plagioclase (andesine, labradorite, and bytownite), clinopyroxene (augite), orthopyroxene and magnetite scattered in a glassy matrix. The recognized micro-textures of the WTHA plagioclases can be divided into two categories: (i) growth- related textures in the form of coarse-sieved (CS), fine-sieved (FS), core sieved and intact margin (CSIM), core intact and sieved margin (CISM) and entirely sieved (ES) morphologies, oscillatory zoning (OZ), rounded zone corner (RZC) and resorption surfaces (RS) formed due to the changes in temperature, melt H2O content, pressure, composition of the melt, equilibrium at the crystal-melt interface and (ii) morphological textures such as glomerocrysts (GLO), synneusis (SY), swallow-tail (ST) crystals, broken crystals (BC), formed by the effect of dynamic behavior of the crystallizing magma (convection, degassing, etc.) and magmatic differentiation. Also, the occurrence of these changes can be related to the self-mixing process in the magma chamber. The self-mixing with recharge event can be the reason for the dynamic activities in the magma chamber.

Geochronology and in-situ apatite geochemistry of late Paleoproterozoic A-type granites in the Jiao-Liao-Ji Belt, North China Craton: Implications for petrogenesis and tectonic evolution

A-type granite shows unique geochemical characteristics and refers to specific formation conditions and tectonic environments, and therefore plays an important role in reconstructing orogenic events. In this paper, we systematically investigated the zircon UPb, whole-rock geochemistry, in-situ zircon Hf, apatite trace elements, and in-situ Nd data of the Huanren monzogranite to discuss its petrogenesis and the tectonic evolution of Jiao-Li-Ji belt. The studied zircon and apatite grains show typical oscillatory zoning and subhedral texture as well as obvious internal structure without any fluid/mineral inclusions, referring to a magmatic origin. Therefore, zircon UPb dating results suggest that the Huanren monzogranite was formed in the late Paleoproterozoic (1863–1842 Ma). The studied rocks show typical A-type granite affinities as high SiO2 (64.54–69.06 wt%), Na2O + K2O (8.00–9.34 wt%), and Zr + Nb + Ce + Y (381–598 ppm) concentrations, and FeOT/(FeOT + MgO) (0.82–0.85) and 10000Ga/Al (2.37–2.65) ratios. Their high whole-rock Zr temperature (812–866 °C, generally >840 °C), and low whole-rock Sr (109–157 ppm), apatite Sr (43.4–79.3 ppm) contents, whole-rock Sr/Y (4.79–8.22) and apatite Sr/Y (0.014–0.033) ratios, combined with slightly depleted in-situ zircon Hf (−1.62 to +2.50) and in-situ apatite Nd (−3.22 to −1.65) isotopic compositions, and ancient zircon Hf two-stage model ages (TDM2; 2606–2351 Ma), apatite Nd-TDM2 (2576–2451 Ma), suggest that the studied rocks were formed by partial melting of Neoarchean to Paleoproterozoic granitic gneiss in a high temperature and low-pressure condition. The studied A-type granite, together with regional A-type granite and alkaline syenite in the North China Craton, record the post-collisional event between the Nangrim and Longgang blocks, which combined with coeval worldwide A-type granite magmatisms, representing a response of the initial breakup of Columbia supercontinent.

LA-ICP-MS U-Pb dating, chemical composition and evolution of oscillatory zoned andradite from the Chengmenshan Cu-Au deposit, Jiangxi province

The Chengmenshan Cu-Au deposit is a typical porphyry-skarn deposit in the Middle-Lower Yangtze River Valley Metallogenic Belt (MLYRMB), developing abundant oscillatory zoned andradite. However, the physiochemical conditions, hydrothermal evolution and age of skarn formation is unknown. This paper presents BSE image, EMPA point analyses, LA-ICP-MS point analyses and mapping, U-Pb isotope data for andradite from the Chengmenshan Cu-Au deposit. From core to rim, three generations of andradite could be identified (Grt-1, Grt-2, Grt-3). Grt-1 (Adr73-88) exhibit compositional variations as oscillatory zoning. Grt-2 (Adr93-100) is almost pure andradite, with smooth surface. Grt-3 (And71-93) occur as halo surrounding earlier andradite, with broken surface. Incorporation of REE and U into all generations of andradite mainly follows coupled YAG-type substitution mechanism and the coupled substitution of [U4+]VIII + 2[Fe3+, Al3+]Ⅳ – [Ca2+] – 2[Si4+]Ⅳ in the dodecahedral position, respectively. Their associated intrusions, mineral assemblages and consistent positive Eu anomalies indicate an acidic, oxidizing and low salinity forming conditions. From core to rim, the contents of REE and HFSE are decreasing, and the REE patterns evolve from flatted, through LREE-enriched, HREE-depleted, to REE-depleted. The chemical composition and evolution of oscillatory zoned andradite suggest that the fluids in Chengmenshan deposit experienced the sequences of pore fluid-mixed, through magmatic-hydrothermal dominated, to meteoric water influx. In this process, the temperature, pH and fluid compositions varied. U contents are closely correlated with REE contents, especially LREE contents. The andradite samples yield Tera-Wasserburg lower intercept 206Pb/238U ages of 140.1 ± 2.6 Ma (MSWD = 1.8), representing the age of Cu-Au mineralization. These results indicate the evolutionary characteristics of hydrotheraml fluids and precisely date the Cu-Au skarn formation, which may serve as a useful indicator in the exploration of similar skarn deposits and point selection for U-Pb dating.

Gold source and ore-forming process of the Linglong gold deposit, Jiaodong gold province, China: Evidence from textures, mineral chemical compositions and sulfur isotopes of pyrite

The Linglong gold orefield is located northwest of the Jiaodong gold province, in the eastern North China Craton (NCC) area. It consists of over 10 gold mines with a total gold resource of approximately 1000 t, and gold mineralization occurs in gold-quartz veins. The Linglong gold deposit underwent four stages of ore-forming processes namely: Pyrite-quartz (stage I) – milky-white quartz vein with euhedral pyrites, Quartz-pyrite (stage II) – smoky quartz veins with euhedral-subhedral pyrites, Polymetallic sulfides (stage III) – quartz veins with large amounts of polymetallic sulfides (pyrite, pyrrhotite, sphalerite, galena), hematite, and native gold, and the Quartz–carbonate (stage IV) – calcite-quartz veins. This study focuses on the investigation of pyrites from three main mineralization stages (I-III), exploring their textures, in-situ major and trace element concentrations, and in-situ sulfur isotopic compositions.The study examined pyrite through various methods including BSE and EMPA major element, LA-ICP-MS trace element, and LA-MC-ICP-MS sulfur isotope analyses. Pyrite from three distinct stages of ore-forming processes were analyzed. Pyrites from stage I (Py-I) exhibited euhedral crystals with homogeneous brightness in the BSE, lacked mineral inclusions, porous microtextures, and oscillatory zones. Py-I possessed low contents of Au, Ag, As, Bi, Cu, Sb, Zn, Co, and Ni. Pyrites from stage II (Py-II) showed fine-coarse grains and euhedral-subhedral features with slight fractures, similar to Py-I, however, had the higher concentrations of As and Sb. Pyrites from stage III (Py-III) were found in the quartz-polymetallic sulfide veins and exhibited subhedral to anhedral features and more significant concentrations of metallic elements, particularly Au and As. The δ34S values of Py-I, Py-II and Py-III were in the ranges of 6.76‰–7.47‰, 6.11‰–7.27‰ and 6.07‰–8.33 ‰, respectively. Analysis of the texture and geochemical composition of pyrite suggested that invisible gold was primarily present in pyrite in the form of solid solution (Au+), accompanied by a small amount of nano-form gold. The ore-forming fluids that led to this mineralization were mostly derived from mantle-derived mafic magma mixed with some minor metamorphic sedimentary material. A decrease in fluids temperature, water–rock interactions and fluid boiling led to the depositions of sulfides and gold. In the Late Mesozoic, lithospheric delamination of the eastern block of the NCC triggered decompression and melting of the upwelling asthenospheric mantle resulting in partial melting of the lithospheric mantle. This lithospheric mantle-derived mafic magma provided the ore-forming fluids for large-scale gold mineralization in the Jiaodong gold province.

IN SITU U-Pb DATING OF GARNET AND CASSITERITE FROM THE KANBAUK W-Sn(-F) SKARN DEPOSIT, DAWEI REGION, SOUTHERN MYANMAR: NEW INSIGHTS ON THE REGIONAL Sn-W METALLOGENY IN THE SOUTHEAST ASIAN TIN BELT

Abstract Skarn ores have recently been identified beneath the historically mined placer Sn deposit at Kanbauk of the Dawei region, southern Myanmar. A large-tonnage skarn ore reserve at Kanbauk is estimated to be over 100 million tonnes, with reported ore grades of 0.17% WO3, 0.26% Sn, and 15.4% CaF2, potentially making it one of the largest W-Sn skarn deposits in the Southeast Asian tin belt. The mineralized skarns lie between marbles to the east and metasediments of the Mergui Group to the west. The timing of the mineralization is unclear, and thus the genetic relationship with regional magmatic events is not known. We report laser ablation-inductively coupled plasma-mass spectrometry U-Pb ages of garnet and cassiterite from the mineralized skarns. Garnet grains from the massive prograde skarns are typically subhedral to euhedral and show both sector and oscillatory zoning. They have 15 to 23% andradite (Ad), 55 to 67% grossularite (Gr), and 16 to 30% pyralspite (Py) (Ad15-23Gr55-67Py16-30) and contain 0.08 to 306 ppm U with a lower intercept 206Pb/238U age of 56.0 ± 1.5 Ma. Cassiterite grains from retrograde veinlets are subhedral to anhedral and have U contents from 110 to 12,000 ppm with a lower intercept 206Pb/238U age of 54.2 ± 1.7 Ma. Garnet and cassiterite have ages consistent within error and can be taken to indicate the formation of the Kanbauk W-Sn(-F) skarn deposit at around 55 Ma. Together with published ages of primary Sn-W deposits in the Dawei region, our study confirms a westwardly younging trend of mineralization toward the coast and provides support for rollback of the Neo-Tethyan subducting slab since the Late Cretaceous, which is considered as the main mechanism for the regional, extensive Sn-W mineralization.

A new model for the origin of pyrochlore: Evidence from the St Honoré Carbonatite, Canada

The Neoproterozoic St Honoré carbonatite complex is one of three currently mined niobium deposits. In these and most other carbonatite-hosted niobium deposits, pyrochlore is the principal ore mineral. Four major pyrochlore-bearing rock types are observed in the St Honoré complex, namely, biotitite, magnetite-biotite rock, apatitite and carbonatite. The textural relationships among the different rock types and within each rock type are extremely complex, as are the textures and crystal chemistry of the pyrochlore. Compositionally, there are two major types of pyrochlore. Type-1 is enriched in Ta, U, Zr, Sr, Th, Fe, REE and Cl and Type-2 is a Ca-Na-F-rich pyrochlore, with proportions of other elements close to or below their detection limits. Type-1 pyrochlore is yellow- to red-brown and, in many cases, displays oscillatory zoning. This variety occurs most commonly in the cores of crystals in apatitite, where it has its highest concentrations of the elements listed above. It also is observed in biotitite, but the proportions of the above elements are much lower. Type-2 pyrochlore is light to dark brown and, generally, does not exhibit oscillatory zoning. It forms overgrowths on Type-1 pyrochlore in apatitite and biotitite, and occurs as large crystals in the magnetite-biotite rock (Type-1 pyrochlore is not present in this rock). We propose that Type-1 pyrochlore crystallised from a highly evolved, fluid-undersaturated carbonatitic magma, whereas Type-2 pyrochlore crystallised from a carbonatitic magma that had undergone fluid exsolution, which depleted the magma in elements that tend to partition preferentially into aqueous fluids, i.e., U, Sr, Fe, REE, Ba and Cl.The processes that governed the evolution of the carbonatitic magma (which was mantle-derived and introduced in numerous small batches) and crystallisation of pyrochlore at St Honoré were biotitisation (by the magma), crystallisation of calcite and aqueous fluid exsolution. Biotitisation of the host syenite consumed MgO, H2O and CO2 from each magma batch (the CO2 was released as a gas), leading to the crystallisation of Type-1 pyrochlore in biotitite. This process also locally increased the CaO content of the magma to a level sufficient to saturate it with calcite, leaving a residual phoscoritic magma that crystallised the most Ta-U-enriched variety of Type-1 pyrochlore. Exsolution of the aqueous fluid occurred as a result of prolonged crystallisation and/or pressure release and led to the crystallisation of Type-2 pyrochlore. The evolution of each of the magma batches was different and depended on the extent of biotitisation, on whether calcite crystallised, and on the timing of fluid exsolution. As the two types of pyrochlore and their temporal relationship have been described for many carbonatite complexes, the hypotheses presented in this paper are likely also applicable to the genesis of pyrochlore in these other complexes.

Hydrothermal TiO2 polymorphs in a pyrite stratiform deposit: Lessons from a mineralogical and geochemical multiproxy record

This paper presents results of mineralogical and geochemical study of TiO2 polymorphs that occur within two hydrothermal stratiform zones of the Wiśniówka area (south-central Poland). These two mineralized zones consist primarily of alternating pyritiferous and REE-bearing sedimentary quartzites, quartzitic sandstones and silty-clayey shales. Of the TiO2 phases, anatase is a predominant type (mean of 56%) with a lesser amount of rutile (30%) and mixed rutile-anatase phases (11%) as well as rare rutile-brookite (2%) and brookite (1%) as evidenced by laser Raman microspectrometry. TiO2 polymorphs typically form interstitial euhedral to anhedral or skeleton-like grains and aggregations averaging 30–50 μm in diameter occasionally attaining 110 μm. Extremely scarce pyritiferous microfossils are infilled with needle- and lath-like anatase. Under backscattered electron microscope images, TiO2 grains are generally homogenous, in places with tiny inclusions of zircon, monazite, niobium oxide and palladium telluride. In addition, some rutile grains show oscillatory zonation or zonal-brecciated and patchy patterns. Results derived from electron microprobe examinations show enrichments of most TiO2 phases in niobium (up to 4.98 wt%), zirconium (up to 0.58 wt%) and tantalum (up to 0.57 wt%) substituting titanium in the TiO2 crystal structure. The TiNb pair shows the highest correlation (r2 = 0.98). Concentrations of these and other elements vary substantially within individual anatase/rutile grains. The lack of other potential Ti-bearing rock-forming or oxide minerals (e.g., biotite, pyroxene, hornblende, titanite, ilmenite, titanomagnetite, titanohematite) in sedimentary siliciclastic rocks of the study area also indicates that anatase and rutile may have crystallized along with prevailing pyrite, xenotime, aluminum-phosphate-sulfate (APS) minerals and most monazite directly from hydrothermal fluids at relatively low temperatures, presumably around 200 °C (range of 150 to 300 °C). Among these ore minerals, only goyazite and mixed goyazite-gorceixite aggregations contain up to 20.07 wt% Ti and 24.09 wt% Ti, respectively. Mineral and microtextural relationships show that TiO2 polymorphs may have formed in two phases under reducing and subsequently oxidizing conditions of the Wiśniówka Late Cambrian depositional basin.

A Comparative Study of Two Common Pump-Controlled Hydraulic Circuits for Single-Rod Actuators

Pump-controlled hydraulic circuits are proven to be more efficient than conventional valve-controlled circuits. Pump-controlled hydraulic circuits for double rod cylinders are well developed and are in use in many practical applications. Existing pump-controlled circuits for single-rod actuators experience oscillation issues under specific operating conditions; that is identified as a critical operating zone on the load-velocity plane. The challenge in these circuits is to find out the proper way to compensate for the differential flow at both sides of the cylinder in all operating conditions. The two main types of valves commonly used by researchers, to compensate for differential flow in single-rod cylinder circuits, are: pilot-operated check valves, and shuttle valves. In this research, a performance comparison between circuits equipped with either valves, in terms of the size of the critical zone and the oscillations’ characteristics, was accomplished. Simulation studies showed that the circuits that utilize pilot-operated check valves possesses smaller oscillatory zones and less severe oscillations, when compared to circuits with shuttle valves. Experimental work verified the simulation results and proved the accuracy of the mathematical models. Hence, pump-controlled circuits with pilot-operated check valves are recommended to be the basic platform for further efforts to solve the oscillation problem in pump-controlled circuits.

Multiple magmatic processes revealed by distinct clinopyroxene populations in the magma plumbing system: A case study from a Miocene volcano in West Qinling, Central China

Abstract The application of whole-rock compositions to trace magma evolution or crystal-melt equilibrium may be called into question when foreign crystals are incorporated into host magmas. To address this challenge, establishing the origins (orthocrysts, antecrysts, xenocrysts, etc.) of minerals with variable textures in magmatic plumbing systems is necessary. In this paper, we describe complex oscillatory zoning patterns of clinopyroxenes (Cpx) from the Miocene Majuangou (MJG) alkali basalts from West Qinling, China. Our detailed petrographic, mineralogical, and geochemical analyses unravel the origins of various Cpx crystals with distinct textural patterns, thereby providing information about magma storage, recharging and/or mixing, and transportation, as well as the reactions between crystals and melts/fluids. Based on textural patterns, Cpx may be divided into four types: normal (Type-1 Cpx), simple oscillatory (Type-2 Cpx), complex oscillatory (Type-3 Cpx), and grains that lack zoning (Type-4 Cpx, suggested to be orthocrysts). Through the textural characterization of Cpx, the comparison between different types of Cpx, and the relationships between Cpx major compositions from different lithologies, we concluded that Type-1–3 Cpx cores are antecrysts or xenocrysts with diverse origins: primitive magma (Type-1 Cpx cores), magma mush (Type-2 Cpx cores), and crustal granulite (Type-3 Cpx cores). The zoning patterns and the compositions of these Cpx crystals indicate at least three batches of magmatic activity, i.e., the Batch-1 low-Mg# magma (Mg#: 47.4–53.3), the Batch-2 primitive magma (Mg#: 57.2–64.5), and the Batch-3 low-Mg# host alkali magma (Mg#: 47.2–54.6). Cpx-melt thermobarometry demonstrates that at least two crustal magma reservoirs existed in the magma plumbing system at depths of 30.1 and 40.9 km. The antecrystic/xenocrystic Cpx cores were captured by, continued to grow in, and subsequently reacted with ascending K-rich melt/fluid. The spongy textures in Cpx cores/mantles are attributed to this reaction, which may be expressed as: Melt 1 (primitive or evolved) + K-rich melts/fluids + Cpx (CaMgSi2O6) = K-feldspar (KAlSi3O8) + ilmenite (FeTiO3) + Melt 2 (derivative). The products of this reaction (K-feldspar and ilmenite) filled the sieves in the spongy zones of Type-1–3 Cpx. This detailed investigation of compositional and textural features of Cpx antecrysts/xenocrysts suggests that the interactions between various interconnected magma reservoirs are widespread beneath the magmatic plumbing system. Our study emphasizes the importance of the incorporation of foreign crystals and the Cpx-melt/fluid reaction in magmatic plumbing system, which can significantly modify the whole-rock compositions and lead to the formation of spongy textures without the need for fractures and cracks in minerals.

Tracking the Transition From a Gondwana LIP to the South Atlantic Ocean With Geochronological and Geochemical Indicators

AbstractEvidence of early oceanization during transition from large igneous provinces (LIPs) to new ocean crust is mostly missing in the geological record. Mafic dykes geochemically akin to mid‐ocean ridge basalts (MORBs) occur in late stages of LIPs, but their tectonic role during margin evolution remains poorly constrained. Here we use whole‐rock and high‐resolution clinopyroxene chemistry of two distinct types of mafic dykes from the southeastern Brazilian margin to show that a MORB‐like plumbing system became magmatically active in the central South Atlantic ∼2 Ma after the volcanic peak of the Paraná‐Etendeka Magmatic Province. The LIP basaltic dyke compositions resulted from the mixing between a highly metasomatized lithospheric mantle comprising enriched DMM and Archean contributions. The lack of elemental oscillatory zoning in clinopyroxene crystals suggests that they were produced by a single magma pulse, consistent with the strong magma fluxes in LIPs. In contrast, the MORB‐like dykes, which exhibit strong similarities with South Atlantic MORBs, are interpreted to represent early stages of oceanization deriving from the mixing of enriched asthenospheric melts either with ancient SCLM contributions or small crustal assimilation. The MORB‐like intrusions ascended and cooled rapidly along faults and were fed by numerous magma injections that suggest episodic decompression of the asthenospheric source ∼20 Ma before the birth of central South Atlantic. The combination of subduction‐influenced and MORB‐like dykes is recurrent in ancient and modern rifts globally, suggesting that thinned lithospheric blocks affected by ancient subduction events may become more susceptible to early oceanization in rifted margins.

Metal source and ore precipitation mechanism of the Ashawayi orogenic gold deposit, southwestern Tianshan Orogen, western China: Constraints from textures and trace elements in pyrite

The metal source and ore precipitation mechanism of orogenic gold mineralization are not yet well understood, partly because ore metals may be derived from different sources. Pyrite is a dominant Au-hosting mineral in the Ashawayi orogenic gold deposit in the southwestern Tianshan orogen, western China. Petrographic features of pyrite in host rocks and orebodies define four generations: diagenetic preore (Py1), hydrothermal early-ore (Py2), main-ore (Py3), and late-ore (Py4) pyrites.Trace element abundances were analyzed in situ by femtosecond laser ablation inductively coupled plasma mass spectrometry (fs-LA-ICP-MS) to unravel the pyrite formation history. Preore Py1 contains the lowest Cu, Mo, Se, Au and As contents, consistent with a diagenetic origin. Py2 has higher Au and As contents than Py1 and may have formed by the reaction between hydrothermal fluid and preexisting Py1, as indicated by diagenetic pyrite-like As/Ni and Bi/Au ratios but lower hydrothermal pyrite-like Sb/Au ratios in Py2. Hydrothermal pyrite (Py3) contains more abundant As (1723–65182 ppm) and Au (0.32–107 ppm) but lower Co and Ni contents than Py2, suggesting a greater hydrothermal fluid contribution. Oscillatory zoning and abundant mineral inclusions (e.g., arsenopyrite and chalcopyrite) in porous Py3 indicate that fluid boiling was responsible for gold deposition during the main-ore stage. Py4 is a relict of hydrothermal pyrite (Py3) but not diagenetic pyrite, as supported by Py4 and Py3 clustering into a class based on hierarchical cluster analysis. The application of a machine learning method (i.e., artificial neural network) to the syn-ore pyrite indicates that the Ashawayi gold deposit has affinity to those from orogenic-type gold deposits worldwide. Our study, therefore, highlights that ore metals in orogenic gold deposits may originate from different sources, such as Au and As, which are largely sourced from metamorphic fluids, while Co and Ni are mainly released from preore sedimentary pyrite, fluid boiling and fluid-rock interaction triggered precipitation of Au and other metals.

How colored noise shifts the boundaries of oscillatory zones in suspension flows

A mathematical model of the suspension flow forced by colored random disturbances is considered. We focus on the parameter zone adjacent to the Andronov–Hopf bifurcation separating stable equilibrium and self‐oscillatory modes. A phenomenon of stochastic excitement with colored‐noise‐induced generation of spiking oscillations in the equilibrium zone is investigated. We show how colored noise shifts boundaries of oscillation modes, and study dependence of this shift on the correlation time parameter. Zones of the stochastic resonance are revealed and parametrically described in terms of probability of excitement.

Neoproterozoic amphibolite-facies metamorphism of the Douling complex in the northern Yangtze Craton and its tectonic implications: Constraints from petrology and zircon U-Pb-Hf-O isotopes

Neoproterozoic evolution of the Yangtze Craton has long been debated. The Douling complex, representing one of the oldest crystalline basements, records Neoproterozoic high-grade metamorphism and may provide pivotal clues into a reliable Neoproterozoic configuration of the Yangtze Craton. However, its metamorphic evolution and tectonic significance have not been well constrained. In this contribution, we conduct an integrated study of petrography, zircon U-Pb age and Hf-O isotopic compositions for two garnet amphibolites and one gneiss from the Douling complex. Phase equilibrium modeling and conventional geothermobarometry calculation define peak P-T conditions of 9–10 kbar and 670-690 °C, and shape a clockwise P-T path. Zircon grains from the gneiss mostly reveal core-rim structure. The cores display oscillatory zoning, high Th/U ratios and trace element contents, as well as HREE-enriched patterns, high 176Lu/177Hf ratios and δ18O values, consistent with a magmatic origin. They yield a weighted mean 206Pb/238U age of 868 ± 9 Ma, which is taken as the protolith age. The cores have strongly positive ƐHf(t) values of 7.0–15.6 and young two-stage Hf model ages of ca. 1310–760 Ma, indicating that the protolith was dominantly sourced from prompt reworking of Meso-Neoproterozoic juvenile crust. On the other hand, the zircon overgrowth rims in the gneiss exhibit no zoning patterns, low Th/U ratios and trace element contents, flat HREE patterns and pronouncedly negative Eu anomalies, variable 176Lu/177Hf ratios and comparable ƐHf(t) values to the magmatic cores, indicating their coeval formation with garnet and plagioclase under amphibolite-facies metamorphism and might be generated by dissolution-reprecipitation. Zircon crystals from the two amphibolites perform weak zoning patterns, low Th/U ratios and trace element contents, high formation temperatures, flat to weakly enriched HREE patterns, insignificantly and/or clear negative Eu anomalies, and low 176Lu/177Hf ratios and ƐHf(t) values, suggesting that they may form near the peak stage of amphibolite-facies metamorphism. Metamorphic zircon in the three samples yield homogeneously high δ18O values (10.81 ± 0.17‰, 11.45 ± 0.40‰, 10.92 ± 0.08‰), indicating the participation of external fluid originated from surrounding metasedimentary rocks. These metamorphic zircon grains together yield a weighted mean age of 817 ± 4 Ma (MSWD = 0.63), which is taken as the best estimated age for the upper amphibolite-facies metamorphism in the Douling complex. Considering the widespread contemporaneous magmatism in the northern Yangtze Craton, we propose that the Douling complex recorded a tectonic regime switch from compression to extension at ca. 830–820 Ma, in response to outboard oceanic subduction on the periphery of the Yangtze Craton and then tectonic extension and collapse of the thickened lithosphere.

Ore-forming process of the W–Sn and Cu skarn mineralization in the Huangshaping deposit (Nanling Range): Constraints from scheelite geochemistry and cassiterite U–Pb geochronology

The Nanling Range in South China is endowed with abundant Jurassic W–Sn and Cu skarn deposits; however, the ore-forming age and process of these deposits lack adequate comparative studies. The Huangshaping deposit in the Nanling Range coincidently develops both W–Sn and Cu skarn mineralization systems, providing a good window to address these issues. Multiple generations of hydrothermal scheelite were identified at Huangshaping, including SchA-1, SchA-2, and SchA-3 in the W–Sn system, and SchB-1, SchB-2, and SchB-3 in the Cu system. Scheelite in the two systems has similar textural evolution, presenting as regular oscillatory zoning (SchA-1, SchB-1), chaotic oscillatory zoning (SchA-2, SchB-2) truncating the regular oscillatory zoning of SchA-1 and SchB-1, respectively, and homogeneous texture (SchA-3, SchB-3) replacing the early scheelite in the respective system. Rare earth elements (REEs) substitute into SchA-1 and SchB-1 mainly via mechanism of 3Ca2+ = 2(REEs, Y)3+ + □Ca, whereas those incorporate into SchA-2, SchA-3, SchB-2, and SchB-3 via mechanisms of Ca2+ + W6+ = (REEs, Y)3+ + Nb5+ and 3Ca2+ = 2(REEs, Y)3+ + □Ca. Continuously decreasing Mo concentrations and increasing Eu anomalies from SchA-1 to SchA-3 and from SchB-1 to SchB-3 reflect progressively decreasing oxygen fugacity (fO2) of hydrothermal fluids in the two systems. The higher Sr concentrations in scheelite from the W–Sn system than that from the Cu system indicate stronger fluid-rock interaction in the W–Sn system, consistent with its more development of skarn. Cassiterite U–Pb geochronology from the W–Sn and Cu systems at Huangshaping yielded lower intercept ages of 159.1 ± 0.6 Ma (MSWD = 1.8, N = 38) and 161.5 ± 0.8 Ma (MSWD = 1.6, N = 25), respectively. Combined with previously published age data from the regional W–Sn and Cu skarn deposits in the Nanling Range, it is inferred that Cu skarn mineralization may have formed earlier than W–Sn with age boundary of ∼ 159 Ma. And the age of ∼ 159 Ma might represent an important shifting time for the Cu mineralization to W–Sn mineralization in the Nanling Range. This study highlights that the textural and geochemical evolution of scheelite can provide important constraints on the ore-forming process in different skarn mineralization systems.

Magmatic-Hydrothermal Fluid Processes of the Sn-W Granites in the Maniema Province of the Kibara Belt (KIB), Democratic Republic of Congo

The Kibara belt (KIB) in the Maniema province hosts orebodies bearing cassiterite-wolframite, which are associated with equigranular to pegmatitic late Mesoproterozoic (1094–755 Ma) granites and Sn-W bearing quartz veins that cut through metasedimentary country rocks. Alteration assemblages of muscovite-quartz (±topaz-fluorite-tourmaline) occur in the granites, and muscovite-sericite-quartz occurs in Sn-W quartz veins. Petrographic analyses, including cathodoluminescence (SEM-CL) on cassiterite grains, reveal two types of cassiterite: yellow transparent cassiterite (lighter under SEM-CL: type I) and dark translucent cassiterite (darker under SEM-CL: type II). These types are organized in micro-textures as oscillatory (growth) zones and replacement zones (type II replaces type I). Unlike cassiterite, wolframite is texturally homogenous. LA-ICP-MS results reveal that type II cassiterite is relatively enriched in Fe, Al, Ga, In, As, Pb, Zn, and U, whereas type I is enriched in V, Ti, Zr, Ta, Hf, and Nb. Contrasting Ce anomaly values in the cassiterite types suggest a transition of redox potentials during the Sn precipitation. Fluid inclusion assemblages (FIAs) in quartz, fluorite, and cassiterite are dominantly aqueous, liquid- or vapor-rich, and rarely carbonic-bearing aqueous inclusions. These often texturally coexist in a single “boiling” assemblage in granites. Raman spectroscopy on the bubble part of fluid inclusions in quartz and cassiterite shows various gas species, including CO2, CH4, N2, and H2. Boiling assemblages in the granites suggest that fluid phase separation occurred at about 380–610 bars, which is about 1–2 km (lithostatic) or 3–5 km (hydrostatic) in apparent paleodepth. FIAs in the granites show ranges of salinities of 4–23 wt.% (NaCl equivalent) and homogenization temperatures (Th) of 190–550 °C. FIAs hosted in cassiterite displayed distinctively lower and narrower ranges of salinities of 2–10 wt.% and Th of 220–340 °C compared to the FIAs hosted in quartz in the granites (salinity of 4–23 wt.%, Th of 190–550 °C) and the quartz veins (salinity of 1–23 wt.%, Th of 130–350 °C). This suggests a less salinized and cooler fluid during the cassiterite precipitation. We suggest that magmatic-derived Sn-W bearing fluids be mixed with less saline and cooler aqueous fluids, possibly meteoric water, during the major cassiterite and possibly wolframite depositions in the KIB. This is based on (1) temperature and salinities, (2) hydrothermal alterations, (3) cassiterite micro-textures, and (4) trace element distributions.