Os Isotope Research Articles

Configuration Mixing for Po Isotopes within the Interacting Boson Model-2

We analyze a sequence of 194−204Po isotopes, using the Configuration Mixing (CM) Interacting Boson Model 2 (IBM-2). We set the parameters of Hamiltonian using a least-square fit for the known energy levels, electrical transition rates B(E2), and quadruple moments Q(2+1) for the first excited states. We have a good agreement with the experimental values for all the observables tested, and we infer that the feature of the shape coexistence is concealed in the isotopes of Po, just as in the isotopes of Os and Pt.

Cu and Ni Isotope Variations of Country Rock-Hosted Massive Sulfides Located Near Midcontinent Rift Intrusions

Abstract Previous Cu isotope work has documented a clear disparity between δ65Cu values of sheet-style (–0.5 to 0.5‰) and conduit-style (0.5–2.0‰) intrusions associated with the Midcontinent rift system. The application of metal isotopes to the study of magmatic Ni-Cu-platinum group element (PGE) deposits is in an early stage, and very little is known regarding isotope distributions and mechanisms of fractionation at high temperatures. In order to resolve the previously mentioned Cu isotope disparity, to determine metal sources for the intrusions, and to assess sources of high-temperature metal isotope fractionation, we have measured Cu and Ni isotope ratios from a suite of exceptionally well characterized Ni-Cu-PGE massive sulfides that occur in sedimentary country rocks near intrusions within the Midcontinent rift system in Michigan and Minnesota. Previous mineralogic and S, Pb, and Os isotope measurements indicate that the massive sulfides are of magmatic origin and provide a framework for the interpretation of the Cu and Ni isotope data in terms of magmatic processes, including assimilation of Proterozoic country rocks. Copper and Ni isotope ratios were determined for massive sulfides as well as local sedimentary sulfides, and these results were compared with available Cu and Ni isotope results of magmatic and sedimentary sulfides in the Midcontinent Rift and elsewhere. Nickel isotope ratios of the sulfides have been modeled in terms of the effects of variable silicate/sulfide ratios, or R-factors (the mass ratio of silicate magma to sulfide magma), crustal contamination, and olivine fractional crystallization. The near-zero and slightly negative δ60Ni values of country rock-hosted magmatic sulfides (–0.45 to 0.17‰) near Tamarack and Eagle can be explained by minor degrees of crustal contamination of a mantle-derived melt at variable R-factors. Igneous-sourced, Cu-poor sulfides from below the Partridge River intrusion generally have lower δ60Ni values (−0.77 to –0.52‰) that require substantially more contamination from a low δ60Ni source, similar to some of the local sedimentary rocks. Copper isotope ratios of country rock-hosted massive sulfides near Eagle and Tamarack are lower than those reported by previous workers and are mostly about 0‰, similar to those expected for unaltered mantle. Tamarack samples require very little crustal contamination to explain their isotope ratios, whereas Eagle samples require no contamination from local sedimentary rocks to explain their Cu isotope compositions. Copper isotope ratios of samples beneath the Partridge River intrusion are similar to those from previous analyses of igneous-hosted sulfides, supporting their origin from a magmatic sulfide liquid. The low δ65Cu values (–1.14 to 0.25‰) from samples below the Partridge River intrusion cannot be explained by contamination from the Virginia and Thomson Formations, which are characterized by mostly positive δ65Cu values (–0.33 to 3.12‰), unless a lighter reservoir remains to be discovered in the local Proterozoic rocks. We suggest these values may have been produced by a combination of incomplete sulfide melting during partial melt generation and fractionation related to sulfide segregation at variable R-factors.

Lifetime measurements of excited states in 169,171,173Os: Persistence of anomalous B(E2) ratios in transitional rare earth nuclei in the presence of a decoupled i13/2 valence neutron

Lifetimes of low-lying excited states in the νi13/2+ bands of the neutron-deficient osmium isotopes 169,171,173Os have been measured for the first time using the recoil-distance Doppler shift and recoil-isomer tagging techniques. An unusually low value is observed for the ratio B(E2;21/2+→17/2+)/B(E2;17/2+→13/2+) in 169Os, similar to the “anomalously” low values of the ratio B(E2;41+→21+)/B(E2;21+→0gs+) previously observed in several transitional rare-earth nuclides with even numbers of neutrons and protons, including the neighbouring 168,170Os. Furthermore, the evolution of B(E2;21/2+→17/2+)/B(E2;17/2+→13/2+) with increasing neutron number in the odd-mass isotopic chain 169,171,173Os is observed to follow the same trend as observed previously in the even-even Os isotopes. These findings indicate that the possible quantum phase transition from a seniority conserving structure to a collective regime as a function of neutron number suggested for the even-even systems is maintained in these odd-mass osmium nuclei, with the odd valence neutron merely acting as a “spectator”. As for the even-even nuclei, the phenomenon is highly unexpected for nuclei that are not situated near closed shells.

Meter-Scale Chemical and Isotopic Heterogeneities in the Oceanic Mantle, Leka Ophiolite Complex, Norway

AbstractMantle peridotites from three 3 × 3-meter grids sampled at kilometer distances from one another in the ca. 497 Ma Leka Ophiolite Complex (LOC), Norway, are examined to investigate the chemical and isotopic nature of oceanic mantle domains at the centimeter to kilometer scale. The lithology of each grid locality is predominantly harzburgite, but includes layers and lenses of dunite and pyroxenite. Major and lithophile trace element compositions indicate a history of prior melting at pressures at or slightly below the garnet stability field. The common presence of orthopyroxenite veins likely reflects infiltration of silicic melts associated with supra-subduction zone processes. Osmium isotopes and highly siderophile element (HSE) abundance data for centimeter-scale sampling of traverses from the pyroxenites into the harzburgites reveal that the formation of the veins had little effect on Os isotopic compositions, and Os, Ir, Ru and Re abundances in the harzburgites. Adjacent to one of the orthopyroxenite veins studied, however, Pt and Pd abundances appear to have been strongly modified by interactions with vein-forming melts or fluids at distances of as much as 4–6 cm from the pyroxenite-harzburgite contact. Leka harzburgites have initial γOs values (% deviation from a chondritic reference) that range from −4.7 to +2.2 (6.9% variation), with individual uncertainties of ±0.2 units. Averaged initial Os isotopic compositions for harzburgites from the three grid sites separated by as much as 6 km, by contrast, differ by only a maximum of 2.6%. Isotopic heterogeneity on the centimeter to meter scale is, therefore, larger than kilometer-scale heterogeneity, indicating that at least some of the Os isotopic heterogeneity commonly observed globally among mantle peridotites is the result of processes that acted on a local scale. The general uniformity of these isotopic compositions among the three grid sites suggests that the portion of the oceanic mantle sampled by the LOC was homogenous at the kilometer scale with respect to the long-term Re/Os ratio. The long-term projected Re/Os for LOC harzburgites is similar to the average required for modern abyssal peridotites. This observation strengthens previous interpretations, based largely on data for abyssal peridotites, that state the Os isotopic evolution of oceanic mantle is consistent with a long-term 187Re/188Os of ∼0.38. The present ∼3 to 4% difference between the Os isotopic composition of the modern oceanic mantle and estimates for primitive mantle suggests that at least ∼6% of the mass of the oceanic mantle has been removed from it in the form of Re-enriched, mafic oceanic crust. Despite the recycling of this crust back into the mantle, most of it has evidently not been mixed back into accessible portions of the upper oceanic peridotite mantle. Compared to composition estimates for the primitive mantle, the median HSE compositions for the three grid sites are moderately to strongly depleted in Pd and Re, consistent with the corresponding lithophile element evidence for 20–30% melt depletion. As with initial γOs values, most harzburgites from a given grid are characterized by greater variations in absolute and relative HSE abundances than the differences between the median abundances of the three grid sampling locales. This observation indicates that as with Os isotopes, the HSE abundance heterogeneity among the harzburgites most strongly reflects centimeter- to meter-scale melting and remobilization effects. Except for Ru, median HSE abundances for grid harzburgites are similar to median abundances for abyssal peridotites. The ∼30% lower median Ru/Ir in the LOC compared to the median ratio for abyssal peridotites suggests that the abundance of Ru in the oceanic mantle may be more variable than generally thought.

Inclusion of a suite of weathering tracers in the cGENIE Earth system model – muffin release v.0.9.23

Abstract. The metals strontium (Sr), lithium (Li), osmium (Os) and calcium (Ca), together with their isotopes, are important tracers of weathering and volcanism – primary processes which shape the long-term cycling of carbon and other biogeochemically important elements at the Earth's surface. Traditionally, because of their long residence times in the ocean, isotopic shifts in these four elements observed in the geologic record are almost exclusively interpreted with the aid of isotope-mixing, tracer-specific box models. However, such models may lack a mechanistic description of the links between the cycling of the four metals to other geochemically relevant elements, particularly carbon, or climate. Here we develop and evaluate an implementation of Sr, Li, Os and Ca isotope cycling in the Earth system model cGENIE. The model offers the possibility to study the dynamics of these metal systems alongside other more standard biogeochemical cycles, as well as their relationship with changing climate. We provide examples of how to apply this new model capability to investigate Sr, Li, Os and Ca isotope dynamics and responses to environmental change, for which we take the example of massive carbon release to the atmosphere.

The Age of Gold Mineralization in the Yana–Kolyma Metallogenic Belt, Northeastern Russia: First Data of Re–Os Isotope Geochronology of Native Gold

The Age of Gold Mineralization in the Yana–Kolyma Metallogenic Belt, Northeastern Russia: First Data of Re–Os Isotope Geochronology of Native Gold

Ancient depletion signals in lherzolites from forearc region: Constraints from Lu-Hf isotope compositions

The sub-arc mantle that experienced hydrous melting is commonly characterized by refractory geochemical compositions. Nevertheless, minor lherzolites with fertile compositions have also been reported for mantle peridotites from subduction zone. The petrogenesis and mantle source of the lherzolites are still controversial. The New Caledonia ophiolite (Peridotite Nappe) has been regarded as an allochthonous body of forearc lithosphere. This is supported by refractory compositions of its dominant mantle rocks. A few isolated lherzolitic massifs have also been observed in the northern part of New Caledonia. Those lherzolites are compositionally similar to abyssal peridotites, with negligible subduction-related modification. Here, we present new comprehensive geochemical compositions, in particular high-precision Sr-Nd-Hf isotope data, for the lherzolites. The initial 176Hf/177Hf ratios display moderate correlations with sensitive indicators for the extent of melting (i.e., olivine Fo, whole-rock Mg# and Yb contents in clinopyroxene) and whole-rock initial 187Os/188Os ratios. Some samples have ancient radiogenic Hf isotopes and unradiogenic Os isotope compositions, implying the preservation of ancient depletion signals in the lherzolites. The Nd isotope compositions, together with trace elements and mineral micro-textures, suggest that the lherzolites have been overprinted by a recent melt-rock interaction event. The high equilibrium temperatures of the studied samples have been estimated by the two-pyroxene REE thermometer, yielding temperatures of 1066–1315 °C. The lherzolites have more depleted Nd-Hf isotope compositions and higher equilibrium temperatures than the New Caledonia harzburgites. This indicates that the lherzolites may represent the residues of asthenosphere mantle trapped within the forearc region. Our studies on the New Caledonia lherzolites with ancient depletion signals suggest that ancient mantle domains in the convective mantle can be emplaced in forearc region by the upwelling of asthenosphere during the early stage of subduction initiation.

Systematic investigation of γ-band structure of triaxial even-even neutron-deficient Os nuclei

Highlights of Manuscript on 180-192 Os nuclei • TPSM study of nuclear structure of even-even 180-192 Os nuclei. • The projected states are a mixture of 0-,2- and 4-qp configurations. • Transition probabilities for the yrast band by using TPSM wave-functions. • High spin states predicted in 180-192 Os isotopes. • Prediction of triaxial nature of 180-192 Os nuclei. γ -bands built on triaxial deformation of neutron-deficient even-even Os isotopes in the A ~180 region, are well investigated in the present work within the self-consistent quantum mechanical framework known as triaxial projected shell model (TPSM). The TPSM results on yrast, γ -, 2 γ -bands provide a reasonable description about the triaxial nature of the isotopes. Moreover, the deformation systematics, back-bending in moment of inertia, energy ratios, transition probabilities and g -factors have also been calculated and compared with the known experimental data and, a considerable good agreement has been achieved between the two.

Extent and age of Mesoarchean components in the Nagssugtoqidian orogen, West Greenland: Implications for tectonic environments and crust building in cratonic orogenic belts

The Nagssugtoqidian orogen (NO), which forms the northern margin of the North Atlantic craton in West Greenland, is largely comprised of ~2870 to 2720 Ma juvenile continental crust reworked during Paleoproterozoic orogenic events. Sparse evidence of components older than 3100 Ma in the area (U–Pb zircon ages and bulk-rock Sm–Nd isotopes) have hinted at a unit called the Qorlortoq gneiss but were not substantiated by regional studies. Here we report the “rediscovery” of the Qorlortoq gneiss, documented through a new geochemical and geochronological dataset of this orthogneiss and related components, which include ultramafic cumulate enclaves and late basaltic dykes. Laser Ablation Split Stream (LASS) U-Pb/Lu-Hf isotopic analyses of zircon from the gneiss give a U–Pb concordia upper-intercept age of 3177 ± 12 Ma and weighted mean εHf(t) of 1.7 ± 0.5, indicating a juvenile protolith extracted from a depleted mantle source.Ultramafic enclaves of cumulate origin make up a key component of the Qorlortoq gneiss. Their trace element systematics indicate a parental melt with tholeiitic affinities, sourced from depleted mantle beneath relatively thin lithosphere (<80 km), that was subsequently contaminated by crustal assimilation. Re–Os isotope systematics of the cumulates and their relationship with the younger Qorlortoq dykes place the age of these cumulates close to that of the Qorlortoq gneiss.The age of the Qorlortoq gneiss makes it the oldest known component in the NO by ~300 Ma. The extended timescale between episodes of crustal production in this area, could indicate a geodynamic environment characterized by stagnant-lid or episodic mobile-lid tectonics, at least on a regional scale. These constraints provide important information about the diversity and nature of Archean geodynamic environments.

Pelagic clays as archives of marine iron isotope chemistry

Slowly accumulating pelagic clays are enriched in metals that were formerly in seawater, including iron, an important micronutrient. Because the metals are minimally remobilized in oxygenated porewater, pelagic clays may be a potential archive for records of past marine micronutrient cycling. Here, we present a record of changes in hydrogenous iron (Fe) isotopes since the late Cretaceous derived from pelagic clays that we dated with osmium isotope chronostratigraphy. To optimize the separation of the hydrogenous metal (oxy)hydroxides from bulk sediment, we repeatedly leached an oxic pelagic clay sample under variable conditions (HCl molarity, temperature, time) and measured the element concentrations, Fe isotopes, and Os isotopes. The common behavior of elements amidst the permutations of the leach experiment offers insight into which components were dissolved and we defined a range of successful leaches. We applied our optimal leach for Fe and Os isotopes (1 M HCl, for 24 h at 20 °C) to 45 samples at Site U1366 in the South Pacific Gyre. The resulting record suggests a dynamic Fe cycle in the water column overlying Site U1366 over the past 95 million years. Early in the site's history, trends in the Fe isotopes are interpreted as reflecting changes in hydrothermal Fe with distance from the ridge. Contributions from a background Fe source are identified as well as a transition to dust-like source after 50 Ma until present. Constructing similar records at multiple sites will provide a basin-wide perspective on how the marine Fe cycle has changed over million-year timescales.

Temporally variable crustal contributions to primitive mantle-derived Columbia River Basalt Group magmas

The Steens Formation is one of the earliest and most primitive (>7 wt. MgO) eruptive products of the Columbia River Basalt Group (CRBG) and the CRBG-Yellowstone-Snake River large igneous province. New major-, trace-, and highly siderophile-element abundance and 87Sr/86Sr, 143Nd/144Nd and 187Os/188Os data are reported for the lower and upper Steens Formation to examine likely mantle sources and the nature of magmatic differentiation and crustal contamination acting on lavas. Examined Steens Formation basalts are relatively mafic (7–9 wt% MgO), incompatible trace element enriched, and have weaker Nb and Ta anomalies compared to other CRBG lavas. The most primitive basalts have isotopic compositions at the time of crystallization consistent with originating from a mantle source that was relatively depleted (87Sr/86Sr = ~0.7033; εNdi = ~ + 6.5; γOsi = ~ + 1). Primary magma compositions for the Steens Formation do not provide compelling evidence for a subducted slab component, instead suggesting derivation from primitive mantle sources more similar to those of other Mesozoic continental flood basalts (CFB; e.g., Deccan, North Atlantic Igneous Province). Onset of sulfide saturation in the CRBG occured at lower MgO (<7 wt%) than in other CFB (~ 8 wt%) leading to the high Os contents in the Steens Formation. Collectively, the Steens Formation exhibits decreasing Os contents, εNdi values and increasing 187Os/188Os with decreasing MgO. These geochemical signatures are consistent with increasing crustal contamination to parent melts with time, a feature that is also shared for the CRBG as a whole. Calculations based on Os and Nd isotopes of likely mantle and crust components to different formations of the CRBG indicates a progressive increase in the quantities of crustal contamination from ~1 to 2% from Steens Formation magmatism to more than 6% during Grande Ronde and Wanapum eruptions. These results would indicate increasing crustal contamination and enhanced potential cryptic degassing of CO2 in the later, more voluminous stages of CRBG magmatism, after ~16.5 Ma. Unless mantle-derived melts can produce sufficient greenhouse gas emission, there is likely an offset between the inception of the mid-Miocene Climatic Optimum at 17 Ma and maximum CO2 release, indicating that CRBG eruption was a contributing factor to climate change at that time, but was not the trigger for it.

Changing inputs of continental and submarine weathering sources of Sr to the oceans during OAE 2

Ocean anoxic events (OAE) are characterized by increased organic content of marine sediment on a global scale with accompanying positive excursions in sedimentary organic and inorganic δ 13C values. To sustain the increased C exports and burial required to explain the C isotope excursion, increased supplies of nutrients to the oceans are often invoked during ocean anoxic events. The potential source of nutrients in these events is investigated in this study for Oceanic Anoxic Event 2, which spans the Cenomanian-Turonian boundary. Massive eruptions of one or more Large Igneous Provinces (LIPs) are the proposed trigger for OAE 2. The global warming associated with volcanogenic loading of carbon dioxide to the atmosphere has been associated with increased continental weathering rates during OAE 2, and by extension, enhanced nutrient supplies to the oceans. Seawater interactions with hot basalts at LIP eruption sites can further deliver ferrous iron and other reduced metals to seawater that can stimulate increased productivity in surface waters and increased oxygen demand in deep waters. The relative importance of continental and submarine weathering drivers of expanding ocean anoxia during OAE 2 are difficult to disentangle. In this paper, a box model of the marine Sr cycle is used to constrain the timing and relative magnitudes of changes in the continental weathering and hydrothermal Sr fluxes to the oceans during OAE 2 using a new high-resolution record of seawater 87Sr/86Sr ratios preserved in a marl-limestone succession from the Iona-1 core collected from the Eagle Ford Formation in Texas. The results show that seawater 87Sr/86Sr ratios change synchronously with Os isotope evidence for the onset of massive LIP volcanism 60 kyr before the positive C isotope excursion that traditionally marks the onset of OAE 2. The higher temporal resolution of the seawater Sr isotope record presented in this study warrants a detailed quantitative analysis of the changes in continental weathering and hydrothermal Sr inputs to the oceans during OAE 2. Using an ocean Sr box model, it is found that increasing the continental weathering Sr flux by ∼1.8-times captures the change in seawater 87Sr/86Sr recorded in the Iona-1 core. The increase in the continental weathering flux is smaller than the threefold increase estimated by studies of seawater Ca isotope changes during OAE 2, suggesting that hydrothermal forcing may have played a larger role in the development of ocean anoxic events than previously considered

Highly siderophile element and osmium isotope systematics of basaltic volcanics: A different approach to petrological processes

The highly siderophile element (HSE) or platinum group element (PGE) and Os isotope systematics of basaltic volcanics have recently received a significant attention because of their potential to constrain the petrological processes on magma generation and evolution. The HSE and Os isotope data, which are generally observed at very low concentrations in basalts and obtained by modern enrichment and analytical techniques, are frequently used in petrological studies. The HSE contents and ratios from whole-rock analysis of basalts, and combined evaluation with the theoretical knowledge and modelling of HSE behaviour during the partial melting of mantle and the differentiation of basaltic magma would provide opportunity for geochemical modelling on mantle melting. Besides, HSE contents and Pd-PGE/Ir-PGE ratios are important indicators for the nature of mantle sulfides, the sulfur saturation conditions of the mantle source, sulfide segregation, fractional crystallization, crustal assimilation and partial melting degrees in the origin and evolution of mantle-derived magmas. Therefore, in addition to the traditional whole-rock geochemical data obtained from Cenozoic aged basalts observed widely in Turkey, HSE and Os isotope systematics of these basalts can contribute to define the geochemical features of the mantle source, and to model petrological processes which are effective in the magma evolution.

Deep-water osmium-isotope record of the Permian–Triassic interval from Niushan, China reveals potential delayed volcanic signal post the mass extinction

The end Permian mass extinction event is one of the most severe biotic crisis of the Phanerozoic. The trigger of this event has been widely linked to massive volcanic activity associated with the Siberian Traps Large Igneous Province through the application of multiple geochronological (e.g., UPb and ArAr dating) and geochemical proxies (e.g., C, Hg, Zn, Os, etc.). Of these proxies, a few osmium (187Os/188Os) records are available for near-shore/shallow water depositional settings (e.g., Meishan, China; Opal Creek, Canada), which suggest multiple episodes of volcanism before, during and after the mass extinction event. Here, we present a new initial 187Os/188Os (Osi) stratigraphy across the deep-water Niushan Permian–Triassic boundary interval section of South China that reveals a single unradiogenic Os-isotope shift (from ~0.6 to 0.3) after the end Permian mass extinction event interval, which is interpreted to be related to volcanic activity. Above the unradiogenic excursion, a radiogenic shift to ~1.1 is detected across the Permian–Triassic boundary at Niushan that is correlative to the radiogenic Osi shift observed in the Meishan section. This increase in Os-isotope values is taken to reflect enhanced continental weathering. Both the unradiogenic and radiogenic excursions in the deep-water Niushan section are smaller in magnitude compared with the Os isotope profiles from more shallow-water sections of Meishan and Opal Creek. Our data suggest investigations of multiple sections across a variety of depositional environments may yield a more comprehensive understanding of the scale of the global perturbations related to volcanism and continental weathering intensity of the Permian–Triassic boundary interval.

Rapid coupling between solid earth and ice volume during the Quaternary

The solid earth plays a major role in controlling Earth’s surface climate. Volcanic degassing of carbon dioxide (CO2) and silicate chemical weathering are known to regulate the evolution of climate on a geologic timescale (> 106 yr), but the relationship between the solid earth and the shorter (< 105 yr) fluctuations of Quaternary glacial–interglacial cycles is still under debate. Here we show that the seawater osmium isotope composition (187Os/188Os), a proxy for the solid earth’s response to climate change, has varied during the past 300,000 years in association with glacial–interglacial cycles. Our marine Os isotope mass-balance simulation reveals that the observed 187Os/188Os fluctuation cannot be explained solely by global chemical weathering rate changes corresponding to glacial–interglacial climate changes, but the fluctuation can be reproduced by taking account of short-term inputs of (1) radiogenic Os derived from intense weathering of glacial till during deglacial periods and (2) unradiogenic Os derived from enhanced seafloor hydrothermalism triggered by sea-level falls associated with increases of ice sheet volume. Our results constitute the first evidence that ice sheet recession and expansion during the Quaternary systematically and repetitively caused short-term (< 105 yr) solid earth responses via chemical weathering of glacial till and seafloor magmatism. This finding implies that climatic changes on < 105 yr timescales can provoke rapid feedbacks from the solid earth, a causal relationship that is the reverse of the longer-term (> 106 yr) causality that has been conventionally considered.

Geochemistry and mantle source characteristics of the Itasy volcanic field: Implications for the petrogenesis of basaltic magmas in intra-continental-rifts

We present new major and trace element and Sr, Nd, Pb, Hf, and Os isotope data for Quaternary basaltic lavas and tephra from the Itasy volcanic field, in order to assess the origin and sources of recent volcanism in the central highlands of Madagascar. Our age determinations provide further evidence for Pleistocene volcanism on the island, with ages between ∼31 and 104 ka. Mafic magmas from Itasy exhibit significant geochemical heterogeneity, and they are chemically distinct from those of the neighboring Ankaratra volcanic complex. Trace element signatures of the Itasy volcanic field are very similar to those of ocean island basalts (OIB), with significant enrichment in high field strength elements (e.g. Nb and Ta) and depletion in large ion lithophile elements (e.g. Rb, Cs, and K), and relatively high Nb/U (>45) and Ce/Pb (>25) ratios. Significant intra-volcanic field isotopic heterogeneity is observed, with well-defined negative correlations of 87Sr/86Sr with 206Pb/204Pb and 143Nd/144Nd. These correlations, along with highly radiogenic Os isotopic signatures in many Itasy samples, could be attributed to assimilation of the Precambrian basement. However, with the exception of Os, the elemental and isotopic characteristics of the Itasy magmas are inconsistent with significant crustal assimilation, and instead are interpreted to represent features of their mantle sources. The Itasy ΔεHf and Δ7/4 values fall within the range of MORB and OIB, and indicate derivation primarily from an asthenospheric mantle source. The absence of significantly negative ΔεHf in the Itasy magmas argues against the involvement of ancient recycled oceanic crust or stranded lower crust in their sources, but the presence of a low µ (LOMU) component in some Itasy magmas can be attributed to pollution of the asthenosphere by delaminated subcontinental lithospheric mantle. A simple two-stage, three-component mixing model indicates that a mixture of mantle containing 90% depleted asthenosphere (DMM) and 10% foundered SCLM, which is further mixed with 30 to 50% of a plume-type mantle component, can reproduce the isotopic compositions of the Itasy magmas. Based on our model, it is possible that easily fusible superplume materials might be widely distributed in the upper mantle underneath the EARS, from the Indian Ocean to the Red Sea-Gulf of Aden, and mixed with shallow asthenosphere that has itself incorporated eroded SCLM. These components are heterogeneously distributed at a small spatial scale, similar to that observed recently in other mafic monogenetic volcanic fields in both intraplate and subduction settings.

Analytical Methods for Os Isotope Ratios and Re-PGE Mass Fractions in Geological Samples.

The recent advances in analytical methods of Re-Os and PGE in geological materials including sample dissolution, chemical separation, mass spectrometric determinations, as well as the developments of matrix-matched reference materials for data quality control are thoroughly reviewed. Further, the in-situ measurement methods for Re-PGE mass fractions and 187Os/188Os ratios, as well as the measurement methods for stable isotope ratios of Re and PGE are also briefly reviewed. This review stands as a comprehensive reference for researchers to consider in the development of measurement methods for Re-PGE mass fractions and 187Os/188Os ratios in geological materials.

Osmium isotopic constraints on sulphide formation in the epithermal environment of magmatic-hydrothermal mineral deposits

In the magmatic-hydrothermal environment, fluids with similar metal concentrations and sources may yield contrasting mineral assemblages in successive stages of sulphide mineralization. These differences are linked to the physico-chemical conditions of the mineralizing fluids (e.g., T, pH, fS2, fO2) acquired during their interaction with country rocks and/or by mixing with groundwater. Here, we integrate petrography and osmium (Os) isotope (187Os/188Os) sulphide geochemistry, and discuss novel constraints on magmatic fluid-rock interaction and magmatic fluid-groundwater mixing that are deemed to govern sulphide deposition in magmatic-hydrothermal systems. We studied pyrite (FeS2) and enargite (Cu3AsS4) from the porphyry-related polymetallic Cerro de Pasco (14.54–14.41 Ma) and Colquijirca (10.83–10.56 Ma) epithermal deposits in the Central Andes, Peru. Sulphide mineralization is genetically associated with Miocene magmatism and includes breccia and replacement bodies of carbonate country rocks, and veins cutting the magmatic and sedimentary country rocks.At both deposits, pyrite is followed by enargite in the paragenesis. Pyrite has a radiogenic initial 187Os/188Os isotopic composition (187Os/188Osi-pyrite or Osi-pyrite = 0.80 to 1.45). Enargite (I) enclosing pyrite or filling in cracks in pyrite also has a radiogenic initial 187Os/188Os isotopic composition (Osi-enargite I = 0.56 to 1.24). Conversely, enargite (II) that formed on irregular surfaces on earlier pyrite has an unradiogenic 187Os/188Os isotopic composition (Osi-enargite II = 0.13 to 0.17). Our data show that the paragenetic evolution from pyrite to enargite records a sharp change in the osmium isotope composition within these sulphides.Pyrite and enargite (I) record radiogenic initial 187Os/188Os isotopic compositions, indicating interaction of magmatic hydrothermal fluids with the sedimentary country rocks. However, the unradiogenic initial 187Os/188Os isotopic composition of enargite (II) suggests that magmatic fluids with a mantle-like 187Os/188Os signature ascended from parental magmatic chambers to the epithermal environment without incorporation of crustal Os via fluid-rock interaction or mixing with groundwater. This difference may be due to the country rocks being altered during previous stages, with the radiogenic crustal Os signature being flushed by earlier magmatic pulses. Our findings imply that ore metals (i.e., Cu, Au) are magma-derived, whereas the Os isotopic composition of pyrite and some enargite in epithermal deposits may capture the signature of the interaction of magmatic fluids with country rock lithologies (e.g., the Eifelian black shale in the study area) and/or groundwater. Thus, the isotopic composition of the siderophile and chalcophile trace element Os in sulphides may act as a tracer of metal source, and degree of wall-rock interaction.

Biomarkers and Re–Os geochronology of solid bitumen in the Beiba Dome, northern Sichuan Basin, China: Implications for solid bitumen origin and petroleum system evolution

Solid bitumen is ubiquitous in the Sinian Dengying Formation dolomite, a crucial gas reservoir in the Sichuan Basin. We use biomarkers and Re–Os geochronology, coupled with burial-thermal evolution history to trace the source and formation timing of the solid bitumen, and to reconstruct the petroleum system evolution in the Dengying Formation of the Beiba Dome, northern Sichuan Basin. The bitumen reflectance (Rb) values of solid bitumen range from 1.92 to 3.95%, with the solid bitumen showing no fluorescence, indicating that the solid bitumen in the Dengying Formation dolomite has a high thermal maturity, which consequently belongs to pyrobitumen formed by thermal cracking of crude oil. The isoprenoids and terpanes indicate that the solid bitumen was sourced from a marine shale deposited under a reducing environment. The C27–C29 regular sterane distribution of the solid bitumen is consistent with the Lower Cambrian Guojiaba Formation (Є1g) organic-rich shale, indicating that the solid bitumen was derived from the Є1g shale, rather than dolomite or shale within the Dengying Formation. The burial-thermal evolution history indicates that initial oil generation began in the Late Cambrian to the Early Silurian. Since the Early Permian, the Є1g organic-rich shale re-entered the oil generation window, and formed a giant paleo-oil accumulation during the Late Triassic. Thermal cracking of crude oil occurred from the Late Triassic to the Early Cretaceous forming the extensive solid bitumen. The Re–Os isotopes of solid bitumen yield two similar isochron ages of 128.1 ± 7.3 Ma and 126.2 ± 8.0 Ma, which represents the timing of thermal cracking termination, i.e. the final timing of dry gas generation. This work highlights that the Re–Os geochronology has great potential to constrain the absolute timing of evolution of the petroleum system.

ВОЗРАСТ ЗОЛОТОГО ОРУДЕНЕНИЯ ЯНО-КОЛЫМСКОГО МЕТАЛЛОГЕНИЧЕСКОГО ПОЯСА, СЕВЕРО-ВОСТОК РОССИИ: ПЕРВЫЕ ДАННЫЕ Re-Os ИЗОТОПНОЙ ГЕОХРОНОЛОГИИ САМОРОДНОГО ЗОЛОТА

Presented are the first results of studying the Re-Os isotope system of native gold from the orogenic Malo-Taryny, Khangalas, and Bazovsky deposits located in the central part of the Yana-Kolyma metallogenic belt. Re concentration in the sampled gold varies from 0.168 to 6.997 mg/t while that of Os changes from 0.068 to 1.443 mg/t. The data obtained enabled calculation of the isochrone age which is consistent, within the limits of error, with 40Ar-39Ar and К-Аr dates of sericite from the above deposits. The results obtained indicate that gold deposits under study were formed in the interv of 147.8–137.1 Ma synchronously with Late Jurassic – Early Cretaceous orogenic processes in the Yana-Kolyma metallogenic belt and the eastern margin of the Siberian continent. The initial Os isotope ratios ((187Os/188Os)i= 0.1844–0.2475) in the studied samples and fractions of gold from the Malo-Tarynsky, Khangalas and Bazovsky deposits suggest a significant role of a non-radiogenic component, normally associated with mantle sources.