Orthorhombic Research Articles

Necessary and Sufficient Elastic Stability Conditions for Single Crystals

Necessary and sufficient elastic stability conditions for single crystals for the seven crystal systems are specified for both stiffness and compliance tensors. For Laue classes of four of these crystal systems, conditions for the positive-definite forms of suitably chosen 4 × 4 real symmetric matrices are shown to be both useful and relevant. Other supposedly equivalent and often simpler conditions proposed in the literature for tetragonal, orthorhombic and monoclinic crystal systems are analysed; all are shown to be incorrect.

Evaluation of Nanocrystalline Magnetic ErFeO3 Composite for the Sorptive Removal of Cesium and Cobalt Ion from Aqueous Solution

Abstract The effect of nano-scale size in the magnetic semiconductor rare earth ferrite system, ErFeO3, has been studied. The orthorhombic crystal structure in the nano-scale was found for ErFeO3 prepared by the sol-gel method to be 8 nm. Fe-O stretching vibration was identified in the IR band at around 561 cm-1, whereas the O-Fe-O deformation vibration was identified in the band at about 437 cm-1. The semiconducting behavior of ErFeO3 was found, and its energy gap equals 1.75eV. As the frequency increases, the charge transport mechanism showed transition from the small polaron model, dominated by thermally activated hopping, to a quantum mechanical tunneling model, where charge carriers move through the material by tunneling between localized states without trapping. This transition is driven by the charge carriers having less time to become localized at higher frequencies, allowing for more direct tunneling transport. The new application of nano-crystalline ErFeO3 to remove hazardous elements was evaluated. The adsorption isotherm of Cs(I) and Co(II) by ErFeO3 nanocomposite was studied. The findings of the present studies highlight the potential use of ErFeO3 as a new, efficacious sorbent for removing Cs(I) and Co(II) from the waste stream, providing a reliable and efficient solution to environmental pollution

Synthesis, spectroscopic, crystal structure and DFT investigation of the Cu(II) complex with mixed 2,2’-dimethylmalonate/2,2'-bipyridine ligands

In this study; a mixed ligand Cu(II) complex, [Cu(Me2mal)(bpy)(H2O)]∙H2O (Me2mal-2= Dimethylmalonate dianion, bpy=2,2'-bipyridine) was synthesized and characterized experimentally and theoretically by IR, UV and single crystal X-ray diffraction. The complex crystallizes in the orthorhombic system with space group Pnnm. In the complex, the Cu center is coordinated by a Me2mal-2 dianion and a bpy molecule, and the N2O2 exhibits square-planar geometry. The axial position was occupied by the water molecule. The crystal packing of the complex is stabilized by O-H…O hydrogen bonds and  interactions. The contribution of hydrogen bonding and  stacking interactions to crystal packing was also investigated. Theoretical calculations using the DFT method were also carried out in this study. DFT (B3LYP/6-31G) and TD-DFT (B3LYP/LanL2DZ) calculation methods were used to obtain the geometric, vibrational and electronic properties of the synthesized complex and the obtained theoretical calculation results and experimental results are presented comparatively in this study.

Band Gap Tuning in Mercaptoacetic Acid Capped Mixed Halides Perovskites and Effect of Solvents on Their Fluorescence Dynamics: A Potential Sensor for Polarity.

From synthesis to application, there are always certain interactions between the polar solvents and perovskite nanocrystals (NCs). To explain the effect of solvent polarity especially on the photoluminescence (PL) properties of NCs is highly desirable, especially for sensing applications. Herein We have synthesized the methylammonium lead mixed halides (MAPbCl3 - nBrn, where n = 0, 0.5, 1, 1.5) perovskite nanocrystals (NCs) at room temperature by using ligand-assisted re-precipitation (LARP) method, by employing mercaptoacetic acid (MAA) as a capping ligand. Different techniques have been employed to get information regarding the structural and optical properties of the synthesized material. Powder X-ray diffraction (PXRD) confirms the orthorhombic crystal structure of the MAPbCl3 - nBrn perovskite NCs. FT-IR (Fourier-transform infrared) analysis confirms the successful interaction of capping ligands with NCs. By increasing MABr precursor concentration during the synthesis of perovskite NCs, a red shift in the UV-Vis absorption and PL spectra has been observed. The steady-state photoluminescence (SSPL) and time-resolved photoluminescence (TRPL) techniques suggested that these perovskite NCs exhibit tunable PL relative to the substitution of Cl with Br in NCs. The comparative PL studies in non-polar (benzene) and polar (tetrahydrofuran (THF)) revealed that the PL properties are highly sensitive and selective toward the solvent chosen. All synthesized NCs possess longer PL lifetime in benzene than in THF. Relatively, perovskite NCs synthesized with 0.166 mM MABr precursor concentration show a longer PL lifetime (6.51 ns in benzene) as compared to other MABr concentrations. These studies not only propose that by controlling precursors concentration, one can synthesize NCs having tunable PL with a longer radiative PL lifetime, but also provide a comparative understanding of PL dynamics of NCs in different solvents.

Synthesis, crystal structure, and Hirshfeld analysis of a novel Schiff base compound 5-hydroxy-2-{[(propan-2-yl)iminio]methyl}phenolate

5-hydroxy-2-{[(propane-2-yl)iminio]methyl}phenolate, with an empirical formula of C 10 H 13 NO 2 was synthesized by a reaction between 2, 4-Dihydroxybenzaldehyde and isopropyl amine in an aqueous ethanolic medium. The Schiff base compound was characterized by elemental analysis, infrared (IR) spectroscopy, Nuclear magnetic spectroscopy (NMR), Mass spectrometry (MS), thermogravimetry (TG), and single-crystal X-ray diffraction (XRD). The compound was crystallized in an orthorhombic crystal system with a space group of Pna21. The azomethine functional group (-HC=N-) was confirmed by the band at 1638 cm -1 in its IR spectrum. The compound is thermally stable from 40-154 o C losing only 0.2% of its weight. The thermogram (TG) indicated the absence of any water of hydration or lattice water. The compound exhibits keto-enol tautomerism with a zwitterionic structure. The non-covalent interactions (NCI) were studied by various computational methods such as Hirshfeld surface analysis, NCI plot, and scatter plot (RDG vs sign (λ 2 )ρ). The major contributors to the Hirshfeld surface (HS) contacts are O--/H--O (21.5%) and C--/H--C (25.3%). The non-covalent interactions (NCI) and the crystal parameters are, a (Å): 10.3839(9), b (Å):9.9442(8), c (Å): 9.2223(8), α=β=γ= 90 o , Z = 4.

Enhanced two-photon absorption in hydrothermally synthesized La2O6Te nanorods for visible light photodetection.

In the present study, lanthanum oxytellurate (LOT) samples with varying La : Te ratios are successfully synthesized using a simple hydrothermal method that has enormous advantages. The prepared samples crystallize in a La2O6Te composite phase with an orthorhombic crystal system. A nanorod-like morphology is observed for each sample, and the presence of constituent elements is verified from EDX results. Chemical compositions and their oxidation states are obtained from XPS studies. Optical studies of the materials demonstrated band gap values between 2.65 and 2.78 eV, confirming the LOT samples' semiconducting nature. Broad photoluminescence (PL) spectra with peaks ranging between 650 and 750 nm were observed, and a red shift occurred by increasing the Te concentration in the samples. Overall, the samples exhibit good photoresponse characteristics under dark and light conditions with high Ion/Ioff ratios and sensitivity values. These parameters confirm the potential of LOT materials to stand out as an alternative for susceptible and effective photodetector devices. Among the samples, LOT-2 showed 10.64 μA W-1 responsivity, 5.8 × 107 Jones of detectivity, and a rise and fall time of 16.25 and 23.13 s, respectively, which was the best photodetection performance compared to the other two samples. Results from the nonlinear optical (NLO) Z-scan study demonstrated the RSA behavior and valley-peak configuration with positive n2 values corresponding to the self-focusing effect. The NLO characteristics of the materials are governed by the two-photon absorption (2PA) mechanism. Here, the LOT-2 sample displayed comparatively better results than the other two. The third-order nonlinear optical NLO susceptibility χ(3) values suggest that LOT materials have the potential to become a new candidate for various NLO applications in the coming days.

Crystal Structure and Solid State Assembly Inspection by Hirshfeld Surface Analysis of The Imidazole-Based Ligand

The previously synthesized 4-(2,4,5-triphenyl-1H-imidazol-1-yl)benzoic acid (THBA) structure was characterized by single crystal and finally confirmed by single crystal X-ray diffraction method. This molecule crystallizes in the orthorhombic crystal system, P212121 space group, with crystal parameters, found a = 9.3659 (8) Å, b = 10.9060 (8) Å, c = 21.2433 (18) Å, Z = 4 and V = 2169.9 (3) Å3. A single-crystal X-ray investigation of the compound revealed that hydrogen bonds and van der Waals interactions play a crucial role in the stability of the crystal packing. At this point, comparative studies on crystallographic properties and Hirshfeld surface analysis have been carried out to characterize the binding states and crystal structure of THBA at molecular stability. The supramolecular features contain N—H∙∙∙O (inter) and C—H∙∙∙O (inter and intra) hydrogen bonding interactions, which are supported using Hirshfeld surface and 2D fingerprint analysis.

Eu2Pt3Pb5 and SrPt2Pb4-lead-based intermetallics with Y2Rh3Sn5/NdRh2Sn4-type polyanionic platinum-lead 3D frameworks.

Two platinide plumbides, Eu2Pt3Pb5 and SrPt2Pb4, were discovered using high-temperature exploratory synthesis and flux-assisted crystal growth. Their crystal structures were determined from single-crystal X-ray diffraction. Both compounds crystallize in the orthorhombic system; Eu2Pt3Pb5 belongs to the Y2Rh3Sn5 structure type (Cmc21, a = 4.6146(2) Å, b = 27.3082(12) Å, c = 7.5147(3) Å, Z = 4, R1 = 0.0310, and wR2 = 0.0736) and SrPt2Pb4 to the NdRh2Sn4 type (Pnma, a = 19.411(5) Å, b = 4.5834(13) Å, c = 7.6548(19) Å, Z = 4, R1 = 0.0399, and wR2 = 0.0906). Both compounds feature complex frameworks of Pt-Pb and Pb-Pb bonds with very similar motifs, with Eu or Sr cations filling the cavities, which differ by the presence of the TiNiSi-type EuPtPb layer in Eu2Pt3Pb5. According to the DFT calculations, both compounds are metallic and feature Sr and Eu divalent cations along with a negatively charged mostly covalent framework of Pt and Pb atoms. Magnetic measurements show that the SrPt2Pb4 compound is non-magnetic, while Eu2Pt3Pb5 is a paramagnet above ca. 85 K and below that temperature transitions to the ferromagnetically ordered state with very low coercivity.

Crystal structure and dielectric properties of novel temperature-stable SrLn2O4 (Ln=Ho, Tm) microwave dielectric ceramic

In this paper, a comprehensive investigation was conducted to the factors affecting the crystal structure and microwave dielectric properties of the SrLn2O4 (Ln= Ho, Tm) ceramics. Rietveld refinement results of the XRD patterns conclude that SrLn2O4 (Ln= Ho, Tm) ceramics belong to orthorhombic system with Pnam symmetry. The effects of porosity, packing fraction and lattice energy on the properties of SrLn2O4 (Ln= Ho, Tm) ceramics were precisely analyzed. Excellent properties for SrTm2O4 ceramics (εr = 14.49, Q×f = 41138GHz, τf = -36.69 ppm/℃) and SrHo2O4 ceramics (εr = 14.87, Q×f = 24021GHz, τf = -17.03 ppm/℃) can be achieved due to good densities and high packing fraction and lattice energy. In addition, CaTiO3 is proved to be well compatible with SrLn2O4 (Ln= Ho, Tm) ceramics. Near-zero τf were obtained in SrTm2O4 + 1.8wt% CaTiO3 ceramic and SrHo2O4 + 1.2wt% CaTiO3 ceramic, making them ideal candidates for applications in microwave band.

Study of Optical Properties Blue Emitting Co2+ Doped Zn2SiO4 Phosphor

This study presents the synthesis and optical characterization of a blue-emitting Co2+-doped Zn2SiO4 phosphor, prepared via an economical solid-state reaction method. Co2+ doping concentrations were systematically varied (1, 2, 4, 6, 8, and 10 mol%) to explore their effect on the phosphor's properties. Powder X-ray diffraction (PXRD) analysis confirmed the orthorhombic crystal structure (ICCD No. 00-001-1975) of Zn2SiO4, with an average crystallite size of approximately 34.79 nm calculated using the Debye-Scherrer formula. Photoluminescence (PL) measurements revealed a prominent blue emission peak at 460 nm, attributed to the 4A2 → 4T1 (4P) + transition of Co2+ ions under 334 nm excitation. Additionally, the color coordinates and correlated color temperature (CCT) of the emission were determined, underscoring the phosphor's potential as a robust, efficient blue emitter suitable for optoelectronic and lighting applications.

Synthesis, Crystal Structure and Bonding Analysis of Intermetallic Compound BaAu3Zn2

The intermetallic compound BaAu3Zn2 has been synthesized through fusion of stoichiometric metals in sealed Ta tube at 800 °C using high-frequency furnace followed by annealing at 400°C for two weeks. The synthesized compound characterized by powder, single crystal X-ray diffraction techniques. BaAu3Zn2 crystallized in the orthorhombic system with space group Pnma and Pearson symbol - oP24 and utilizes the same set of Wyckoff sequence (dc4 ) as SrZn5 structure where Au atoms replace Zn atoms on 4c Wyckoff sites with different bonding patterns. The structure contains three structural motifs (a) Hexagonal-diamond-like gold host lattice (b) Interstitial Ba atoms (blue) and (c) Infinite linear chains along b axis formed by only Zn atoms (green). Bonding analyses indicate a typical polar intermetallic behavior for BaAu3Zn2. Keywords: Polar intermetallics; gold rich phases; LMTO-ASA approximation; isotropic deformation; DOS and COHP calculations; X-ray diffraction.

A computational exploration of structural, electronic, and optical properties of Hf- substituted CaZr1-x HfxS3 (x = 0.25, 0.50, and 0.75) for photovoltaic applications

Abstract This study investigates the structural, electronic, and optical properties of Hf-substituted CaZrS₃ (CaZr_(1-x) Hf_x S_3, where x =0.25,0.50, and 0.75) for photovoltaic applications. Using first-principles calculations within the Quantum Espresso framework, we explore the effects of Hf incorporation on the orthorhombic crystal structure (Pnma space group). The study reveals that Hf substitution significantly influences the material’s properties, including lattice parameters, band gap, and optical absorption. The calculated band gaps for Hf-substituted CaZrS₃ are smaller than the experimental value for unsubstituted CaZrS₃, indicating enhanced suitability for photovoltaic applications. Moreover, Hf substitution improves the thermal, mechanical, and chemical stability of the material. The results suggest that Hf-substituted CaZrS₃ is a promising candidate for high-efficiency, stable, and environmentally friendly photovoltaic devices.

The Synthesis and Characterization of CdS Nanostructures Using a SiO2/Si Ion-Track Template

In the present work, we present the process of preparing CdS nanostructures based on templating synthesis using chemical deposition (CD) on a SiO2/Si substrate. A 0.7 μm thick silicon dioxide film was thermally prepared on the surface of an n-type conduction Si wafer, followed by the creation of latent ion tracks on the film by irradiating them with swift heavy Xe ions with an energy of 231 MeV and a fluence of 108 cm−2. As a result of etching in hydrofluoric acid solution (4%), pores in the form of truncated cones with different diameters were formed. The filling of the nanopores with cadmium sulfide was carried out via templated synthesis using CD methods on a SiO2 nanopores/Si substrate for 20–40 min. After CdS synthesis, the surfaces of nanoporous SiO2 nanopores/Si were examined using a scanning electron microscope to determine the pore sizes and the degree of pore filling. The crystal structure of the filled silica nanopores was investigated using X-ray diffraction, which showed CdS nanocrystals with an orthorhombic structure with symmetry group 59 Pmmn observed at 2θ angles of 61. 48° and 69.25°. Photoluminescence spectra were recorded at room temperature in the spectral range of 300–800 nm at an excitation wavelength of 240 nm, where emission bands centered around 2.53 eV, 2.45 eV, and 2.37 eV were detected. The study of the CVCs showed that, with increasing forward bias voltage, there was a significant increase in the forward current in the samples with a high degree of occupancy of CdS nanoparticles, which showed the one-way electronic conductivity of CdS/SiO2/Si nanostructures. For the first time, CdS nanostructures with orthorhombic crystal structure were obtained using track templating synthesis, and the density of electronic states was modeled using quantum–chemical calculations. Comparative analysis of experimental and calculated data of nanostructure parameters showed good agreement and are confirmed by the results of other authors.

Facile synthesis of novel nanocomposite composed of Co3O4, MgO, and Mg3B2O6 for malachite green dye decontamination from aqueous media

Malachite green is a hazardous chemical that poses serious threats to aquatic ecosystems due to its toxicity and persistence in the environment. Additionally, it is harmful to human health, recognized as a carcinogenic and mutagenic agent that can cause long-term adverse effects. Hence, in this study, malachite green dye was efficiently removed from aqueous media using Co3O4/MgO/Mg3B2O6 novel nanocomposites, known as CBM600 and CBM800. The CBM600 and CBM800 nanocomposites were facilely fabricated through the Pechini sol-gel procedure at 600 and 800 °C, respectively. Besides, X-ray diffraction analysis showed their crystalline structures, including Co3O4 and MgO in cubic systems, and Mg3B2O6 in an orthorhombic system. For the CBM600 and CBM800 nanocomposites, the average crystal sizes are 40.76 nm and 57.43 nm, with BET surface areas of 74.25 m2/g and 57.59 m2/g, respectively. The highest uptake capacities for malachite green dye by the CBM600 and CBM800 nanocomposites are 492.61 mg/g and 440.53 mg/g, respectively. The pseudo-second-order model and Langmuir isotherm were the best fits for the adsorption data. Also, the uptake of malachite green dye by the CBM600 and CBM800 nanocomposites is spontaneous, physical, and exothermic. The nanocomposites were regenerated using 6 M HCl and repeatedly used to remove malachite green dye with very small loss in efficiency, demonstrating their robust reusability.

New alkaline earth and rare earth representatives adopting the Ce2Al16Pt9-type structure

Abstract The M 2Al16Pt9 series with M = Ca, La–Nd and Sm–Gd was synthesized from the elements in analogy to the literature known compounds Ce2Al16Pt9 and Sr2Al16Pt9. All compounds crystallize in the orthorhombic crystal system with space group Immm and have been characterized by powder X-ray diffraction. For La2Al16Pt9 and Eu2Al16Pt9 also single-crystal investigations have been conducted. In all cases, Al3Pt2 as well as the members of the REAl5Pt3 series (YNi5Si3 type, space group Pnma) have been observed as side phases. Annealing led in all cases to an increase of the side phases, suggesting that the title compounds decompose peritectically. In the crystal structures, polyanionic [Al16Pt9] δ– networks can be found with large fourfold capped hexagonal prismatic cavities (M@Al6Pt6Al4), which host the respective M atoms. As seen from the unit cell volumes, the La–Nd, Sm and Gd compounds exhibit a formally trivalent oxidation state while the Ca and Eu atoms in Ca2Al16Pt9 and Eu2Al16Pt9 are divalent.

STUDI IDENTIFIKASI PASANGAN COMMERCIALLY PURE TITANIUM DAN UHMWPE UNTUK APLIKASI MATERIAL IMPLAN LUTUT

Orthopedics is a science that studies the human body skeleton. This field of science helps patients who experience joint and skeletal problems. One of the problems faced is the need for body frame components to be replaced, for example the knees. This replacement requires a man-made component, namely an implant. Implants can be made from metal, polymer, and ceramic. The biomaterial implant identification process includes X-Ray Diffraction analysis, hardness and tensile testing. XRD testing of CP–Titanium and UHMWPE using the Rigaku XRD tool. CP–Titanium hardness testing uses Vickers micro hardness, while for UHMWPE uses Shore D. CP–Titanium tensile testing uses a universal test machine with JIS Z2201 standards. Another material, namely UHMWPE, is tested using the same equipment as the ASTM D638 standard. The XRD test results for CP - Titanium show peaks of 35.3˚, 38.6˚, 40.2˚, namely the hexagonal structure of the compound element α - Ti. Meanwhile, UHMWPE material shows peaks (110) at 21.66˚ and (200) at 24.16˚. The peak data is an orthorhombic crystal structure, which is characteristic of polyethylene. The CP – Titanium hardness test results show an average hardness of 360.47 VHN. The hardness value of UHMWPE shows an average hardness of 48.5 Shore D. CP - Titanium tensile testing shows a maximum stress value of 534.4 MPa and a maximum strain value of 0.022. The UHMWPE tensile test showed an average maximum stress value of 23.87 MPa and an average maximum strain value of 1.36. The data above shows that the materials tested are CP - Titanium and UHMWPE. Hardness data indicates that these CP – Titanium and polyethylene materials are too soft for applications requiring wear resistance.

Confined Synthesis of 2D Molybdenum Diphosphide Nanosheets via Gas-Solid Transformation.

Molybdenum diphosphide (MoP2), a topological semimetal, possesses distinctive properties and applications in catalysis, energy storage, and condensed matter physics. However, synthesizing high-purity MoP2 is complex and often results in undesired stoichiometric by-products. Additionally, the intrinsic orthorhombic crystal structure makes it difficult to synthesize MoP2 in a 2D morphology, which is desirable for device and energy applications. Here, the robust synthesis of MoP2 with a well-defined 2D morphology is achieved using the confined gas-solid phosphorization of a MoS2 precursor on substrates. The use of 2D precursors and the surface confinement provided by the substrate maintain the 2D morphology and result in a thickness-dependent stoichiometry of the phosphorization products. The chemical composition and crystal structure of MoP2 nanosheets are comprehensively characterized. At room temperature, MoP2 nanosheets exhibit metallic transport with high conductivity over 5500 S cm-1. Furthermore, MoP2 nanosheets demonstrate excellent electrocatalytic activity and durability for hydrogen evolution in both neutral and acid mediums. Notably, MoP2 nanosheets possess better durability than amorphous Pt film and commercial Pt/C, positioning MoP2 as a promising catalyst for hydrogen evolution in neutral mediums. This work advances the synthetic chemistry of 2D MoP2 and provides 2D semimetals with a novel member for future explorations in diverse fields.

Crystallographic symmetry increasing in the pressure-induced phase transition of the hydrogen-bonded organic crystal 1-methylhydantoin.

In situ high-pressure Raman spectroscopy and synchrotron angular dispersive x-ray diffraction techniques, combined with first-principles calculations, have been performed to investigate the 1-methylhydantoin (C4H6N2O2, 1-MH) molecular crystal. High-pressure experiments have shown that phase I (monoclinic system) begins to transform into phase II (orthorhombic system) at pressures above 4.0GPa, and the transformation range is from 4.0 to 14.2GPa. It is proposed that the mechanism of phase transition is the interlayer contraction and rearrangement of the hydrogen-bonding network due to the enhanced strong hydrogen-bonded interactions at high pressures. This study provides some theoretical basis for this rare pressure-induced phase transition from low symmetry to high symmetry in organic supramolecular polymorphism.

Synthesis and Optical Properties of Organic-Inorganic Hybrid [(18-Crown-6)K][MoOCl4(H2O)

Crown ether anchored organic-inorganic hybrid halides have been recently reported as interesting luminescent materials in the visible region of electromagnetic spectrum. Is it possible to develop such crown ether anchored hybrid materials for near infrared emission? Motivated by this question, we designed a new hybrid material, namely, [(18-Crown-6)K][MoOCl4(H2O)]. 18-Crown-6 ether bound with K+ form the cationic part [(18-Crown-6)K]+. The K+ of [(18-Crown-6)K]+ electrostatically interacts with Cl- of the anionic part [MoOCl4(H2O)]-, forming the hybrid crystal [(18-Crown-6)K][MoOCl4(H2O)]. It crystallizes in orthorhombic crystal system with Pnma space group. The Mo(V) possesses one d-electron (d1) in point group symmetry in the [MoOCl4(H2O)]- polyhedra. This electronic configuration leads to multiple spin-allowed transitions along with a ligand to metal charge transfer (LMCT) resulting into multiple optical absorption bands in the near UV-visible-near infrared (NIR) region. The lowest energy transition via 2E ( , )/2E ( ) 2B2 ( ) leads to NIR PL with peak at 952 nm, but with a poor intensity at room temperature.

Studies of Structural and Optical Properties of Nickel Chloride and Glycine Doped Potassium Hydrogen Phthalate (KHP) Crystal

A semi-organic single crystal of potassium hydrogen phthalate (KHP, K(C6H4COOH.COO)) doped with Nickel Chloride (NiCl2) and Glycine (C₂H₅NO₂) was successfully harvested at room temperature to enhance the characteristics of KHP using a slow evaporation approach. The concentration of 1 mol % of Nickel Chloride and 6 mol % Glycine was used during the fabrication of the Nickel Chloride and Glycine doped KHP single crystal. Powder X-Ray diffraction (XRD), ultraviolet visible spectroscopy (UV-Vis), and Fourier transform Infrared (FTIR) analysis were used to analyze the grown single crystal. Powder XRD investigation verified an orthorhombic crystal structure and lattice parameter .To evaluate optical energy band gap and optical transparency using UV-Vis spectral. According to, FTIR analysis, and dielectric studies, it is evident that the crystal modification noticeably by adding dopant.