The transition characteristics of dynamic airfoil have significant effects on the aerodynamic performance of wind turbines, helicopter rotor blades, jet engine compressor blades, etc. The time domain and time-frequency domain characteristics of transition on a NACA0012 airfoil during its pitching oscillation were experimentally studied using wall pressure measurement technology with high time accuracy in this paper. The variable slip window technology was used to detect the transition position, and the proper orthogonal decomposition (POD) method and wavelet analysis were combined to perform the time-frequency analysis. In the gradual forward movement of the transition, the low-frequency instability is gradually enhanced by the main flow and the inverse pressure gradient, and significantly submerges the high-frequency fluctuated feature. The higher order moments of the wall pressure during dynamic airfoil transition deviate significantly from the Gaussian characteristics, which is caused by the low-frequency instability and high-frequency burst. The POD method is able to distinguish low-frequency instability from the high-frequency feature. The reduced frequency had significant effects on the transition. With the increase of the reduced frequency, the hysteresis effect of the transition became more and more significant, and the frequency component of transition was more concentrated and the energy was stronger.