Orientation Of Inclusions Research Articles

Electrically aligned Ti3C2Tx MXene composite with multilayered gradient structure for broadband microwave absorption

High-performance electromagnetic microwave (EM) absorbers demand not only wide effective absorption bandwidth (EAB) and strong absorption capability, but also lightweight and small thickness. In this work, a new strategy was developed to simultaneously strengthen the lossy capacity and reduce the inclusion loading by designing the orientation of inclusions and constructing multilayered gradient structures. Accordingly, Ti3C2Tx MXene fillers were aligned in the same chains by the electric field-assisted alignment technique, forming a parallel-plate structure, throughout epoxy matrix resulting in strong lossy capacity. The widest EAB of aligned 16 wt% MXene/epoxy composite reached 5.08 GHz with a thickness of 1.34 mm. By comparison, the random 16 wt% MXene/epoxy composite exhibited an EAB of only 0.96 GHz with a thickness of 1.96 mm. Further, the impedance matching was optimized by designing multilayered gradient structures based on aligned MXene/epoxy composites. The trilayered gradient structure with an equivalent filler content of 10.97 wt% illustrated the best EAB of 6.01 GHz at only 1.53 mm thickness. In addition, the synergistic effect of the multiple loss mechanisms was also discussed. Overall, the proposed method demonstrates the effectiveness of coupling the alignment of inclusions with gradient structural design to prepare lightweight, thin, and high-performance EM absorbing materials.

Theoretical investigation of the nanoinclusions shape impact on the capacitance of a nanocomposite capacitor

A first-principles theoretical approach to the effective dielectric permittivity of a nanocomposite, which contains nanoinclusions dispersed in a host dielectric enclosed between two parallel metallic electrodes, is developed. The inclusions are modeled by spheroids, and their response to the external electric field is found using the point dipole approximation and Green’s function approach. As a result, besides the mutual interactions between the induced dipoles, the local field in the nanocomposite contains also a contribution from the dipole field reflected from the capacitor electrodes. It is shown that the nanocomposite dielectric permittivity is determined by an average inclusion polarizability density, and its dependence on the aspect ratio and orientations of inclusions is found analytically and investigated. The theoretical predictions derived in the paper are in excellent agreement with the available experimental data and can be used for a proper design of nanocomposite capacitors.

The relationship between inclusion/void orientation and speed in wheel-thrown pots

The activity of wheel-throwing a ceramic vessel is governed by a number of physical forces. These are the rotational kinetic energy (expressed in terms of angular velocity and the moment of inertia) and manual pressures. Given the importance of the potter's wheel worldwide, and the frequently postulated socio-cultural meaning of wheel-throwing in particular, foundational research on the physics behind wheel-throwing has been under-represented, and there is a lack of understanding of the relationship between speed of wheel rotation, lifting speed and the orientation of clay pores or inclusions. The speed of rotation is highly relevant as different wheels can achieve different speeds. Thus, knowing the speed during manufacture may allow scholars to reconstruct the original device, manufacturing technique, and perhaps even the potter's level of skill. Two contrasting views can be found in the literature: a) there is a direct positive relationship between these variables, and that the angle of the inclusions/voids can therefore tell us about the wheel's speed at the time of making the pot and hence the device used; b) because pots are never thrown in one single motion, the angle of inclusions/voids is an averaging of all actions executed by the potter, and thus cannot provide meaningful inferences about speeds or device. Experiments with professional potters were devised to explore the relationship between these variables. They show that the interaction between the various physical forces, clay and potter is complex, leading to a large variance even within the work of a single potter, with finger pressure recognized as a major influencing variable. It is clear that angles of inclusions or voids cannot be used to project backwards to the wheel speed, lifting speed, skill level or device used.

Deformation mechanism and quantitative characterization of Al2O3 inclusions in powder metallurgy superalloys

By means of implanting inclusions artificially, the evolution law of three-dimensional morphology and size of Al2O3 inclusions in FGH96 powder metallurgy (PM) superalloy during hot iso-static pressing (HIP), hot extrusion (HEX) and hot isothermal forging (HIF) process was investigated by SEM and quasi in situ Micronano-CT. The size change of inclusions during different stages was studied quantitatively, the three-dimensional (3D) morphology of the inclusions was characterized, and the deformation mechanism was proposed. The results showed that the inclusions in powder stage were long stripe or plate-like shape. During HIP, Al2O3 inclusions were mechanically bonded to the alloy matrix, and its chemical composition, morphology and size remained unchanged. During HEX, Al2O3 inclusions were broken and elongated into chain shape due to shear stress. The quantitative relationship between inclusion size after extrusion and extrusion ratio as well as original inclusion size was established. During HIF, the relationship between 3D morphology, size, orientation and deformation of a single inclusion during forging compression was quantitatively characterized by quasi in-situ micronano-CT for the first time. The above evolution law provides theoretical basis and technical support for improving the purity level of powder turbine disk.

Inclusion orientation dependent flaking process in rolling contact fatigue observed by laminography using ultrabright synchrotron radiation X‐ray

AbstractThe formation and propagation of cracks in rolling contact fatigue were observed by synchrotron radiation computed laminography, and the effect of stringer‐type inclusion orientation was examined. For longitudinal inclusions, cracks started forming at their tips. After cracks propagated toward the rolling direction, a longitudinal crack was kinked simultaneously at both its tips, and propagated toward the direction perpendicular to the rolling direction to form lateral cracks. After kinking, horizontal cracks were formed from the deepest point of a lateral crack, leading to flaking. On the other hand, for specimens with lateral inclusions, cracks propagated to the lateral direction without the formation of longitudinal cracks. Since the propagation life of lateral cracks and that of horizontal cracks were unrelated to the inclusion orientation, the rolling contact fatigue life of specimens with longitudinal inclusions was considerably longer than that of specimens with lateral inclusions.

Numerical study on effect of inclusions on hydrogen segregation in steel under stress conditions

It is generally believed that hydrogen embrittlement (HE) of metallic material is closely related to the presence of hydrogen traps such as inclusions inside. Therefore, the study of hydrogen segregation in the inclusions is essential for the further understanding of the mechanism of HE phenomena. In this study, a numerical model for exploring the hydrogen transport and hydrogen segregation in inclusions under stress conditions was developed, and the effect of inclusion's shape and orientation, micro-cracks and stress magnitude on hydrogen segregation was investigated. Results showed that, inclusion's shape made a great effect on the hydrogen concentration at the inclusions/matrix interface, which became higher as inclusion closed to a globular shape. The hydrogen concentration inside the inclusions was affected by both the shape of inclusions and the angle between the orientation of inclusions and the hydrogen diffusion direction. The hydrogen segregation in inclusions with micro-cracks was much greater than that without micro-cracks, which caused 3–4 times local hydrogen concentration increase in inclusions, leading to the enhancement of HE susceptibility of the steel. The magnitude of stress did not change the regions of hydrogen segregation, but the hydrogen concentration at each region increased with the increasing stress.

Embracing Diversity, Equity, and Inclusion in the Scientific Community-Viewpoints of the Diversity, Equity, and Inclusion Committee of the North American Vascular Biology Organization.

Recent increased visibility on racial issues in the United States elicited public outcry and a collective call for action. The social justice movement has facilitated energetic discussions about race, sexual orientation, and various issues of diversity, equity, and inclusion. This article discusses issues faced by people of color that we as scientists can address, as well as challenges faced by women and internationally trained scientists in the scientific community that need immediate attention. Moreover, we highlight various ways to resolve such issues at both institutional and individual levels. Silence and incremental solutions are no longer acceptable to achieving lasting social justice and ensure prosperous societies that work for all.

Neutron Tomography Studies of Two Lamprophyre Dike Samples: 3D Data Analysis for the Characterization of Rock Fabric

The rock fabric of two lamprophyre dike samples from the Koy-Tash granitoid intrusion (Koy-Tash, Jizzakh region, Uzbekistan) has been studied, using the neutron tomography method. We have performed virtual segmentation of the reconstructed 3D model of the tabular igneous intrusion and the corresponding determination of dike margins orientation. Spatial distributions of inclusions in the dike volume, as well as further analysis of size distributions and shape orientations of inclusions, have been obtained. The observed shape preferred orientations of inclusions as evidence of the magma flow-related fabric. The obtained structural data have been discussed in the frame of the models of rigid particle motion and the straining of vesicles in a moving viscous fluid.

Exhumation of deep continental crust in a transpressive regime: The example of Variscan eclogites from the Aiguilles‐Rouges massif (Western Alps)

AbstractMafic eclogites are found in many orogens as lenses embedded in quartzofeldspathic migmatites. These high‐pressure relics are interpreted either as remnants of ancient sutures and thus formed during oceanic subduction or as fragments of lower crust exhumed from the root of orogenic thickened crust. It is critical to distinguish between these two endmember scenarios as the resulting palaeogeographic and geodynamic reconstructions may significantly differ. In this contribution, we investigated eclogite relics from Lac Cornu in the Aiguilles‐Rouges massif, one of the External Crystalline Massifs of the Western Alps. Phase equilibrium modelling suggests that these mafic rocks were buried along a prograde path (M1) from ~600°C/1.2 to 1.6 GPa to peak conditions of ~630–775°C and >1.6 GPa. Zircon rims, with a rare earth element signature typical of eclogite facies zircon (no Eu anomalies, flat HREE spectrum), and rutile were dated by U–Th–Pb laser ablation inductively coupled plasma mass spectrometry (LA‐ICPMS) at c. 335–330 Ma. Prograde deformation has not been identified in the field and is only recognized thanks to the crystallographic preferred orientation (CPO) of inclusions of omphacite and rutile in garnet. Peak pressure conditions were followed by a decompression stage (M2) from ~760°C/1.4 GPa to ~600–650°C/0.9 GPa supported by the breakdown of omphacite into plagioclase–clinopyroxene symplectite and the crystallization of plagioclase–amphibole corona around garnet. The M2 retrogression stage is associated with the development of a main sub‐horizontal planar fabric and the CPO of minerals composing symplectite. This deformation stage is interpreted as the result of horizontal lower crustal flow. The final stage of exhumation (M3) is characterized by the replacement of symplectite and garnet by plagioclase and large euhedral amphibole and by the breakdown of rutile and ilmenite into titanite dated at c. 300 Ma. The CPO of titanite and amphibole are consistent with the development of vertical dextral shear zone in a transpressive regime. The combination of field observations and petrological, microtextural and geochemical analyses suggests that the mafic eclogites preserved in migmatitic rocks of the Aiguilles‐Rouges massif are remnants of a continental lower crust exhumed and juxtaposed with lower‐grade migmatites in crustal‐scale vertical transpressive shear zones.

Failure Analysis of Friction Weld in Rear Axle Casing

In this study, Housing and Spindle failed at Friction weld (FRW) interface and sample submitted was from a Passenger vehicle after covering 18410 Kms was considered to address the repeated weld failures reported in Rear Axle Casing. The Metallurgical examinations revealed, chemical composition and hardness found satisfactory whereas Microstructure reveals presence of MnS (Manganese Sulphide) Inclusions at the friction weld interface resulting in insufficient friction weld fusion.SEM and Metallographic examinations confirmed the Orientation of MnS (Manganese sulphide) along the surface of the Spindle that was subjected to Friction welding (FRW) resulting in insufficient weld fusion. Microstructure observation of Spindle shows inclusions of Type A - Thick 2 against the allowable limits in Raw Material Type A - Thick 1. Also, the elongated MnS inclusions at the Friction weld (FRW) Interface act as initiation sites, "Stress raiser "that is more vulnerable to failure due to comparatively less tensile and impact strength than base metal similar to the effect of flake graphite’s in cast iron. Due to the anisotropy and orientation of the sulfide inclusions there is reduction in transverse ductility in reduced area and not much significant effect in longitudinal direction. Inclusion control by calcium treatment or Electro slag re-melting in spindle raw material will significantly improve the ductility and toughness of friction weldments. This paper aims to study the effect of Sulfide inclusions on weldability, mechanical properties of weld Interface and role as fracture initiation site.

Modeling the Effective Conductive Properties of Polymer Nanocomposites with a Random Arrangement of Graphene Oxide Particles

Сomposite materials are widely used in various industrial sectors, for example, in the aviation, marine and automotive industries, civil engineering and others. Methods based on measuring the electrical conductivity of a composite material have been actively developed to detect internal damage in polymer composite materials, such as matrix cracking, delamination, and other types of defects, which make it possible to monitor a composite’s state during its entire service life. Polymers are often used as matrices in composite materials. However, almost always pure polymers are dielectrics. The addition of nanofillers, such as graphene and its derivatives, has been successfully used to create conductive composites based on insulating polymers. The final properties of nanomodified composites can be influenced by many factors, including the type and intrinsic properties of nanoscale objects, their dispersion in the polymer matrix, and interphase interactions. The work deals with modeling of effective electric conductive properties of the representative volume elements of nanoscale composites based on a polymer matrix with graphene oxide particles distributed in it. In particular, methods for evaluating effective, electrically conductive properties have been studied, finite element modelling of representative volumes of polymer matrices with graphene oxide particles have been performed, and the influence of the tunneling effect and the orientation of inclusions on the conductive properties of materials have been investigated. The possibility of using models of resistive strain gauges operating on the principle of the tunneling effect is studied. Based on the finite-element modeling and graph theory tools, we created approaches for estimating changes in the conductive properties of the representative volume elements of a nanomodified matrix subjected to mechanical loading.

A mechanistic damage model for solid oxide fuel cell ceramic materials - Part I: Constitutive modeling

A multiscale mechanistic damage model for solid oxide fuel cell (SOFC) ceramics that combines micromechanics of stiffness reduction due to material porosity change and microcracking with a continuum damage mechanics (CDM) description for the evolution of microcracks up to fracture is developed in this work. The model also accounts for volumetric swelling of the anode due to redox cycling. Porosity change and swelling during redox combined with normal operating thermomechanical loads could increase the stress, strain and damage distributions in SOFC stacks leading them to failure. The proposed model involves three governing parameters: (i) the porosity in terms of the pore or void volume fraction, (ii) material swelling magnitude prescribed at a given loading step, and (iii) the damage variable that describes microcracking caused by thermomechanical loads and swelling. Pores and microcracks in the ceramics are modeled as randomly distributed ellipsoidal inclusions with negligible stiffness by an Eshelby-Mori-Tanaka formulation combined with an inclusion orientation distribution method. Microcracking damage evolution is described by a CDM formulation. Volumetric swelling is treated in a similar way to thermal expansion in the constitutive relations. After validation and numerical checks, the damage model is used to analyze a simplified SOFC positive-electrode/electrolyte/negative-electrode (PEN) structure subjected to a redox cycle in addition to thermomechanical loads experienced during normal operation of a SOFC stack.

Mathematical modeling of pyroxene-magnetite crystalline shales elastic and acoustic properties

The analysis of the results of mathematical modeling of the influence of the format, mineral concentration and fracture of metamorphic crystalline shales of the Pishcha iron ore structure is presented. The aim of this work is to analyze the influence of mineral composition, types, orientation and concentration of mineral inclusions and microcracks on the acoustic and elastic properties of a group of samples of “quartz-magnetite-pyroxene” crystalline shales of Pishchans’ka iron ore structure. Based on the method of conditional moments, mathematical modeling of the influence of the format, orientation and content of mineral grains, as well as the concentration and format of cracking on the acoustic and elastic properties of rocks of the Pishchans`ka iron ore structure was performed. According to the obtained data, a weak effect of changes in the content of rock-forming minerals and a significant effect of different types of fractures on the value of elastic and acoustic anisotropy (10-40%) was proved. Elastic constants of models with layered and chaotic orientation of structural-textural elements are calculated. It is established that most models, as well as basic samples have a rhombic type of acoustic symmetry. When comparing the stereoprojections of the anisotropy parameters of real samples with the stereoprojections obtained during modeling, the authors found that in most samples there is a double system of cracking: chaotic and directed in the area of shale. The results of mathematical modeling showed that for models with ordered crack orientation, the change in the format and concentration of voids is a defining characteristic. This effect is significantly smaller for models with a chaotic arrangement of structural elements. It is proved that models with a combined (layered and chaotically oriented) type of fracture are the closest to real samples. The authors show that this technique allows you to create and operate models close to the real geological environment.

Measurement of crystallographic orientation of quartz crystal using Raman spectroscopy: application to entrapped inclusions

Raman spectroscopy has been widely used in mineralogy and petrology for identifying mineral phases. Some recent applications of Raman spectroscopy involve measuring the residual pressure of mineral inclusions, such as quartz inclusions in garnet host, to recover the entrapment pressure condition during metamorphism. The crystallographic orientations of entrapped inclusions and host are important to know for the modelling of their elastic interaction. However, the analysis of tiny entrapped mineral inclusions using EBSD technique requires time consuming polishing. The crystallographic orientations can be measured using polarized Raman spectroscopy, as the intensities of Raman bands depend on the mutual orientation between the polarization direction of the laser and the crystallographic orientation of the crystal. In this study, the Raman polarizability tensor of quartz is first obtained and is used to fit arbitrary orientations of quartz grains. We have implemented two rotation methods: (1) sample rotation method, where the sample is rotated on a rotation stage, and (2) polarizer rotation method, where the polarization directions of the incident laser and the scattered Raman signal are parallel and can be rotated using a circular polarizer. The precision of the measured crystallographic orientation is systematically studied and is shown to be ca. 0.25 degrees using quartz wafers and quartz plates that are cut along known orientations. It is shown that the orientation of tiny mineral inclusions (ca. 2–5 μm) can be precisely determined and yield consistent results with EBSD.

Investigation into the geometry and distribution of oil inclusions in sea ice using non-destructive X-ray microtomography and its implications for remote sensing and mitigation potential

As climate change brings reduced sea ice cover and longer ice-free summers to the Arctic, northern Canada is experiencing an increase in shipping and industrial activity in this sensitive region. Disappearing sea ice, therefore, makes the Arctic region susceptible to accidental releases of different types of oil and fuel pollution resulting in a pressing need for the development of appropriate scientific knowledge necessary to inform regulatory policy formulation.In this study, we examine the microstructure of the surficial layers of sea ice exposed to oil using X-ray microtomography. Through analysis, 3D imaging of the spatial distribution of the ice's components (brine, air, and oil) were made. Additional quantitative information regarding the size, proximity, orientation, and geometry of oil inclusions were computed to ascertain discernable relationships between oil and the other components of the ice. Our results indicate implications for airborne remote sensing and bioremediation of the upper sea ice layers.

Stress concentrator at the plate-like inclusion tip as an enhancement factor of diffusion flux

The work aims to evaluate stress-assisted effects in the diffusion growth of plate-like inclusions. We estimate the correction for diffusion flux onto plate-like inclusion tip accounting for the mechanical stress produced by phase transition. Also, the external stress effect on the stress-concentrator and upper-bound flux is evaluated. The stress factor results in the shift of solubility measured as the mean concentration in solution at precipitation. The impact of the stress concentrator was estimated for different thermodynamic systems: θ′-phase (Al2Cu) growth in Al-Cu alloy, zirconium hydrides growth, and perlitic transformation. The stress factor could play a sufficient role in nonstationary conditions and is negligible in steady-state approximation. Stress factor can also have substantial effects on the inclusion orientation if an external stress is present: rigid inclusion lengthening parallel to the external stress, while stacks of inclusions can behave differently depending on nucleation barriers competition for shear and hydrostatic stress components.

Relating matrix stress to local stress on a hard microstructural inclusion for understanding cleavage fracture in high strength steel

Macroscale cleavage fracture toughness of high strength steels is strongly related to the fracture of hard microstructural inclusions. Therefore, an accurate determination of the local stress on these inclusions based on the matrix stress is necessary for the statistical modelling of macroscale cleavage fracture. This paper presents analytical equations to quantitatively estimate the stress of the microstructural inclusions from the far-field stress of the matrix. The analytical equations account for the inclusion shape, the inclusion orientation, the far-field stress state and matrix material properties. Finite element modelling of a representative volume element containing a hard inclusion shows that the equations provide an accurate representation of the local stress state. The equations are implemented into a multi-barrier model and compared with CTOD experiments with two different levels of constraint.

A magnetoelastic theory for Kirchhoff rods having uniformly distributed paramagnetic inclusions and its buckling

We present a theory for finite and spatial elastic deformation of rods under the influence of arbitrary magnetic field and boundary condition. The rod is modeled as a Kirchhoff rod and is assumed to have uniformly distributed array of uniaxial spheroidal paramagnetic inclusions embedded in it all pointing in the same direction in the undeformed state. The governing equations of the magnetoelastic rod are derived which are further non-dimensionalized and linearized to investigate buckling in such rods. Analytical expressions for the onset of buckling from the rod’s trivial state are obtained in terms of loading parameters (applied magnetic field, axial load, torque) as well as geometric (inclusion orientation in the undeformed state) and material (ratio of bending and torsional stiffnesses) parameters for different combinations of boundary conditions. The buckled shape of the rod at the onset of buckling is also examined. The presented work can be useful in simulation and design of magnetic soft continuum robots.

Low cycle fatigue and high cycle fatigue of K4750 Ni-based superalloy at 600 °C: Analysis of fracture behavior and deformation mechanism

The fracture behavior and deformation mechanism of a new casting Ni-based superalloy K4750 during strain-controlled low cycle fatigue (LCF) and stress-controlled high cycle fatigue (HCF) at 600 °C were investigated. The crack in LCF originated from surface and propagated perpendicular to the loading direction in a striations-assisted Stage II manner. Whereas, the crack in HCF mostly initiated at large-size inclusions and its propagation followed a crystallographic Stage I mode. The microstructures controlling the alloy failure in the two tests were also different. The crack propagation in LCF was accelerated by MC carbides which induced second cracks in front of the primary crack tip. By contrast, the formation of crack in HCF was more affected by the inclusion, grain size and grain orientation. Their presence in unfavorable forms led to premature failure of the alloy and a substantial scatter in the stress-life data. In addition, STEM observation showed that the deformation in LCF occurred on multiple parallel {111} planes with high density of entangled dislocations. The produced slip bands were in close proximity with average spacing below 0.1 μm. However, the distribution of slip bands in HCF was more isolated with separation up to a few microns. The dislocations in slip bands often traversed the γ/γ′ structure in pairs as constrained by the anti-phase boundary in γ′ phase. The heterogeneous deformation in highly isolated slip bands was deemed to account for the Stage I cracking in HCF, which was discussed in this study.

Ferro-tschermakite with polysomatic chain-width disorder identified in silician magnetite from Wirrda Well, South Australia: A HAADF STEM study

Abstract Silician magnetite within ~1.85 Ga lithologies hosting the ~1.6 Ga Wirrda Well iron oxide copper gold (IOCG) prospect, South Australia, was examined at the nanoscale. The magnetite is oscillatory-zoned with respect to the density and orientation of nanometer-scale inclusions, among which Si-Fe-nanorods and Al-rich amphibole (as much as hundreds of nanometers long and tens of nanometers wide) form swarms along <111> directions in magnetite. The amphibole is identified as ferro-tschermakite (Ftsk) with the crystal-chemical formula: A(K0.06Na0.01)0.07B(Ca1.65Na0.35)2C(Fe2.072+Al1.64Mg1.15Ti0.06Fe0.043+Mn0.04)5T(Si6.48Al1.52)8O22W(OH)2. This contains single and double rows of a triple-chain silicate attributed to clinojimthompsonite (Cjt) as coherently intergrown (010) zippers along the entire length of the grains. High-angle annular dark-field scanning transmission electron microscopy (HAADF STEM) imaging and simulation of Ftsk and Cjt on the [001] zone axis provide direct visualization of crystal structures. These are defined by the 7- and 10-atom octahedron strips (B+C sites) and flanked by double- and triple-pairs of Si atoms (T sites). Remarkably, the sites for light cations and/or vacancies are clearly imaged as single and double, darkest, diamond-shaped motifs separating the octahedron strips showing that A cavities known in amphibole are readily depicted in the wider-chain silicate. I-beam models show that nanoscale intergrowths among the two silicates are coherent along zigzag chains of cations at the edges of the octahedron strips, with single and double rows of the triple-chain silicate corresponding to 1 and 1.5 unit cells of Cjt (27 and 41 Å intervals along the b axis). This type of polysomatic chain-width disorder is widely reported in Mg-rich pyriboles but is shown here in an Al-Fe-rich amphibole. The lack of planar defects and/or reaction fronts at mutual contacts between three-chain zippers and host amphibole indicates primary co-crystallization growth, promoted by the formation of the Si-Fe-nanorods. Co-crystallizing plagioclase is also preserved in close vicinity to the amphibole hosted by magnetite (from a few nanometers to micrometers apart). In contrast, the replacement of amphibole by phyllosilicates is recognizable as irregular swells along the (010) zippers and results in extensive chloritization of the amphibole during an overprinting event. Pressures of ~11.5 kbar are estimated using Al-in-hornblende nano-geobarometry and calculated Al content in Ftsk (3.16 apfu). Assuming the amphibole-plagioclase association buffered by host magnetite fulfills the textural equilibration criteria required for application of this barometer, we interpret the Ftsk nanoinclusions in magnetite as preserved evidence for amphibolite facies metamorphism affecting host lithologies at Wirrda Well with subsequent retrograde alteration during the ~1.6 Ga IOCG mineralizing event. Magnetite records petrogenetic processes by accommodating variable ranges of nanomineral inclusions and preserving them over geological time scales. HAADF STEM imaging is ideally suited to the depiction of crystal-structural modularity and also provides insights into the evolution of geological terranes with protracted histories.