Orientation Of Layers Research Articles

Vacuum Deposited Perovskites with a Controllable Crystal Orientation.

The preferential orientation of the perovskite (PVK) is typically accomplished by manipulation of the mixed cation/halide composition of the solution used for wet processing. However, for PVKs grown by thermal evaporation, this has been rarely addressed. It is unclear how variation in crystal orientation affects the optoelectronic properties of thermally evaporated films, including the charge carrier mobility, lifetime, and trap densities. In this study, we use different intermediate annealing temperatures Tinter between two sequential evaporation cycles to control the Cs0.15FA0.85PbI2.85Br0.15 orientation of the final PVK layer. XRD and 2D-XRD measurements reveal that when using no intermediate annealing primarily the (110) orientation is obtained, while when using Tinter = 100 °C a nearly isotropic orientation is found. Most interestingly for Tinter > 130 °C a highly oriented PVK (100) is formed. We found that although bulk electronic properties like photoconductivity are independent of the preferential orientation, surface related properties differ substantially. The highly oriented PVK (100) exhibits improved photoluminescence in terms of yield and lifetime. In addition, high spatial resolution mappings of the contact potential difference (CPD) as measured by KPFM for the highly oriented PVK show a more homogeneous surface potential distribution than those of the nonoriented PVK. These observations suggest that a highly oriented growth of thermally evaporated PVK is preferred to improve the charge extraction at the device level.

Resistivity size effect in epitaxial VNi2 layers

Epitaxial VNi2 layers are deposited onto MgO(001) and their resistivity ρ measured as a function of layer thickness d = 10.5–138 nm to quantify the resistivity size effect. The layers exhibit resistivity minima at both stoichiometric V:Ni = 1:2 composition and 700 °C growth temperature, which is attributed to electron scattering at V–Ni antisite defects and is described using the ordering parameter within the framework by Rossiter. A cube-on-cube epitaxy of the fcc parent structure on MgO(001) leads to two possible layer orientations for orthorhombic VNi2(010) and VNi2(103), resulting in considerable atomic disorder at domain boundaries, consistent with relatively small x-ray coherence lengths of 8 and 14 nm in-plane and along the growth direction of a 33.5 nm thick layer. In situ ρ vs d measurements yield a bulk resistivity of ρo = 46 ± 2 μ Ω cm and a benchmark quantity of ρoλ = (138 ± 5) × 10−16 Ω m2, where λ is the bulk electron mean free path. Air exposure causes a minor resistivity increase due to 2 ± 1 nm thick surface oxide that perturbs the surface potential. Resistivities at 77 K are Δρ = 16 ± 3 μ Ω cm below those at room temperature. This Δρ is thickness independent and is close to the previously predicted 13.9 μ Ω cm bulk resistivity for VNi2 along [100]. However, the measured bulk resistivity is well above this prediction, which is attributed to electron scattering at domain boundaries/atomic disorder. Consequently, the theoretically predicted superior directional conduction cannot be experimentally confirmed in this study. The overall results indicate that VNi2 is only a promising compound for narrow interconnects if a synthesis scheme can be developed that results in a strong atomic order, a negligible domain boundary density, and a [100] crystalline orientation along the transport direction.

Fiber orientation and crimp level might control the auxetic effect of biological tissues

We propose an analytical micromechanical model for studying the lamellar-composite-like structure of fibrous soft tissue. The tissue under consideration is made up of several lamellae, and is designed to resemble the annulus fibrosus (AF) tissue or media layer of arterial tissue, for example. The collagen fibers are arranged in parallel in each lamella and the fiber orientation differs from one lamella to its neighbors. The parallel fibers in each lamella of AF tissue, for example, have been observed to have a crimped microstructure. The proposed model incorporates this quality, considering fiber waviness as a sinusoidal shape and taking into account the fiber dispersion in different layers, where both fiber and matrix are considered as solid phases. We find that collagen-fiber waviness and layer orientation have a significant influence on Poisson’s ratio. The effective Poisson’s ratio predicted by the proposed model demonstrates that the crimped collagen fiber microstructure might weaken the auxetic effect of fibrous soft tissue, which might explain why, as the literature suggests, the auxetic behavior is more difficult to observe than large Poisson’s ratios. As opposed to the many studies that use the well-known hyperelastic fiber-based constitutive model, in which out-of-plane expansion is often observed, the present work explains the auxetic response found in modeling and in experimental data from the perspective of collagen fiber microstructure.

Frequency characteristics of axisymmetric conical boattail models with different slant angles

This study focuses on the unsteady behavior of the flow around axisymmetric conical boattail models under low-speed conditions. Particle image velocimetry was conducted on the symmetric plane for four boattail models with angles of 0°, 10°, 16°, and 22°. Different data processing techniques, including variational mode decomposition (VMD), fast Fourier transform, proper orthogonal decomposition (POD), and multiscale proper orthogonal decomposition (mPOD), were applied to understand the effects of boattail angles on the characteristic frequency of the wake flow. Our results indicated that vortex shedding, bubble pumping, and the rotation of vortex shedding are the three dominant modes for four boattail configurations. However, the energy of vortex shedding mode becomes comparable to that of bubble pumping for the model with the boattail angle of 22°. The orientation of the shear layer remarkably changes near the boattail surfaces for different angles, which is connected to the flow behavior on the surface. This study also suggests that VMD and mPOD are advantageous data-driven methods for analyzing turbulent flows.

Investigation on damage evolution law of anisotropic shale at different hydraulic pressures

Shale gas is a significant energy worldwide, and hydraulic fracturing is an essential method for shale gas extraction. To understand the effect of drilling direction and hydraulic pressure on shale failure property in hydraulic fracturing, Brazilian splitting and acoustic emission tests are applied to shales with 5 layer orientations (θ = 0°, 30°, 45° 60° and 90°) and 4 hydraulic pressures (p = 0, 5, 10 and 15 MPa). The results show that with the p increase, the tensile strength, absorbed energy and crack deviation distance of shale decrease by 19.32–42.03%, 12.13–49.21% and 12.23–42.44%, respectively. The high hydraulic pressure can weaken the shale mechanical strength, then hydraulic cracks form more easily. When θ = 60°, the layer shear slip is the most aggravated, average tensile strength of shale is also the smallest, only 6.14 MPa. The stability of shale AE energy can be characterized by avalanche events. The larger the power exponent s′ of avalanche event, the low AE energy released more from shale, which means the more secondary crack propagation. The shale with θ = 60° and p = 15 MPa has the maximum s′ value of 1.835. To ensure the propagability and stability of hydraulic fracture at the same time, p = 10 MPa and θ = 45°, were selected as the reference technical conditions for hydraulic fracturing.

Computational modelling of collagen-based flexible electronics: assessing the effect of hydration

Collagen substrates in flexible electronics emerged as an alternative to the commonly used stretchable synthetic polymers such as polyethylene terephthalate, polyether sulfone, polydimethylsiloxane etc., thanks to their biocompatibility, flexibility and piezoelectric behaviour. Although researchers were successful in manufacturing these flexible-electronics component, still, the mismatch in the levels of stiffness between a softer polymeric substrate and a stiffer metallic layer (electrodes) might cause interfacial delamination. In use, collagen-based flexible electronics might be exposed to both dry and wet conditions. Experimental analysis showed a drastic change in the mechanical behaviour for these two conditions (the modulus changed by three orders of magnitude); hence, it is essential to investigate the behaviour of polymer-metal interface in both situations. In addition, the effect of geometry and orientation of metallic layers should also be considered; this could help to optimize the design of these electronic devices. In this study, 3D computational models were developed in Abaqus Simulia CAE with dimensions similar to those of elements in collagen-based flexible electronics—collagen (substrate) being the base layer while gold (conductive) and chromium (adhesive) were the top and middle layers, respectively. It was found that delamination in wet collagen was much less pronounced and slower as compared to dry collagen. The effects of geometry and orientation also showed significant differences in the pattern and an area of delamination.

Optical properties of tilted surfaces in material jetting

Material jetting (MJT) is a promising additive manufacturing (AM) technique that offers high-quality appearance reproduction. Considering the limited selection of aesthetic materials available for MJT technology, a thorough optical analysis is required to determine their optimal application. This study focuses on the prominent appearance attributes in MJT and the role of texture variation due to different build orientations (BOs). For this purpose, tilted surfaces were manufactured in a direction ranging from 0° to 90° degrees at 15° intervals. The spectral reflectance, absorbance, transmittance, color difference, gloss, haze, scattering, and texture of MJT objects with varying BOs were investigated. To illustrate the variation in visual appearance and texture of the studied surfaces, the optical properties were rendered to three-dimensional (3D) spherical models. Further, the interaction of the appearance of 3D printing interacts with the quality improvement of AM surfaces is discussed. The results indicated that BO significantly affected the surface texture and layer orientation, leading to variation in surface quality by impacting all studied appearance attributes. Furthermore, tilted MJT surfaces exhibited more variation in reflectance than transmittance. As a result of the Kendall rank correlation coefficient and principal component analysis (PCA), light transmittance through parts manufactured at BO 75° showed the largest variation compared to 0°. Regarding light reflectance, 60° showed more variation among studied angles. The results of gloss, haze, and scattering studies revealed the significance of the measurement direction due to the role of microsurface normals in the surface texture.

Low cycle fatigue behaviour of wire arc additively manufactured ER70S-6 steel

Wire arc additive manufacturing (WAAM) is a method of 3D printing that is well suited to the cost-sensitive construction industry. Fundamental test data on the mechanical properties of WAAM materials, especially under cyclic loading, are however lacking. To bridge this gap, an experimental study into the low cycle fatigue (LCF) behaviour of WAAM ER70S-6 steel has been conducted and is presented herein. Following quasi-static mechanical and geometric characterisation, a series of as-built and machined coupons was tested in different directions relative to the print layer orientation (θ = 0°, 45° and 90°) under constant amplitude LCF loading, covering a range of strain amplitudes from ±0.2% to ±2.0%. Fractographic analysis of the tested coupons was also performed to assess their failure mechanisms. On the basis of the experimental results, strain-life relationships and cyclic stress-strain curves were derived. The geometric undulations of the as-built coupons resulted in a weakening in the LCF properties, and the weakening effect increased with the loading angle θ and strain amplitude. The cyclic hardening/softening response of the WAAM material varied with the imposed strain amplitudes, while significant non-Masing behaviour was observed.

Graphitizability of Polymer Thin Films: An In Situ TEM Study of Thickness Effects on Nanocrystalline Graphene/Glassy Carbon Formation

AbstractPolymer pyrolysis has emerged as a versatile method to synthesize graphenoid (graphene like) materials with varying thickness and properties. The morphology of the thin film, especially the thickness, greatly affects the graphitizability and the properties of the graphenoid material. Using in situ current annealing inside a transmission electron microscope (TEM), the thickness‐dependent structural evolution of the polymer film with a special focus on thickness effects is followed. At high temperatures, thin samples form large graphene layers oriented parallel to the substrate, whereas in thick samples multi‐walled cage‐like structures are formed. Moleclar Dynamics (MD) simulations reveal a film thickness of 40 Å below which, the carbonized layers align parallel to the surface. For thicker samples, the orientation of the layers becomes increasingly misoriented starting from the surface to the center. This structural change can be attributed to the formation of bonded multi‐layers from the initially unsaturated activated edges. The resulting cage‐like structures are stable even during simulated annealing at temperatures as high as 3500 K. An atomistic understanding of the formation of these structures is presented. The results clearly indicate the critical effect of thickness on the graphitizability of polymers and provide a new understanding of the structural evolution during pyrolysis.

Effect of mold on curing deformation of resin transfer molding‐made textile composites

AbstractIn the process of preparing textile composites by resin transfer molding (RTM) method, both the upper and lower surface of the mold will interact with the composite parts due to the mismatch of thermal expansion coefficient between the mold and the part, resulting in warpage deformation. To address this key technical problem, this article first studied the effect of mold on the warpage deformation of composite material under different fiber volume fractions. Then a mold–part interaction modeling method for RTM process with nonthermoelastic deformation is proposed. By introducing shear layers between the upper and lower surfaces of the mold and the composite part, a finite element simulation model for predicting the curing deformation of the component is established and experimentally verified. The results show that the effect of mold–part interaction on the warpage deformation of the composite decreases with increasing fiber volume fraction. Meanwhile, the proposed modeling method can avoid complete material characterization, and the comparison between experimental and simulation results proves that the model can accurately simulate the curing deformation of composite components under the same process conditions. Finally, the analysis reveals that the interaction caused by thermal mismatch between the composites and the mold is less related to the intermediate layup, but mainly related to the fiber orientation of the layup layer in contact with the mold.Highlights The warpage deformation law of the mold on the composites with different fiber volume fractions is investigated. A mold–part interaction modeling method for a resin transfer molding process with nonthermoelastic deformation is proposed, where the mold stretching effect is represented by the cumulative effect of the interaction between the two layers on the upper and lower surfaces of the part.

Controlled orientation and microstructure of p-type SnO thin film transistors with high-k dielectric for improved performance

Despite its relatively high hole mobility, the electrical performance of p-type SnO thin-film transistors (TFTs) lags behind that of n-type oxide TFTs. In this study, we present an approach to enhance the performance of p-type SnO TFTs by utilizing an atomic-layer-deposited SnO/high-k structure, with crystalline HfO2 (c-HfO2) serving as a high-k dielectric. However, the grain boundaries on the c-HfO2 surface influenced the microstructure and orientation of the SnO layer, resulting in a random orientation and surface roughening. To address this issue, we modified the c-HfO2 surface with an amorphous ultrathin Al2O3 layer to eliminate the grain boundaries on the deposition surface. This enabled the alignment of the (00l) SnO planes parallel to the substrate surface and provided a smooth surface. Moreover, the introduction of ultrathin Al2O3 into SnO/high-k stacks substantially improved the electrical performance of p-type SnO TFTs. Our findings highlight the potential of integrating van der Waals semiconductors with high-k dielectrics, facilitating opportunities for advanced device applications.

Effects of copper additives on load carrying capacity and micro mechanisms of fracture in 3D-printed PLA specimens

This study deals with the effects of employing copper additives on the fracture resistance and fracture micro-mechanisms of 3D-printed Polylactic Acid (PLA) specimens under mixed mode I/II loading. Several comparative fracture tests are conducted on pre-cracked Semi-Circular Bend (SCB) specimens made of pure PLA and particulate copper-reinforced PLA (PLA/Cu) printed using the Fused Deposition Modeling (FDM) technique. The SCB specimens are fabricated in three different layer orientations. The comparison of the experimental results reveals that employing copper additives increases the load carrying capacities (LCCs) of the pre-cracked SCB specimens with the flat, on-edge, and upright layer orientations by 2.9%, 15.5%, and 27.7%, respectively. In addition, to determine the tensile properties of two desired materials, dogbone specimens made of PLA and PLA/Cu in three different layer orientations are fabricated and tested. The experimental results obtained from the characterization tests similarly indicate that the presence of copper additives in 3D printed PLA specimens increases ultimate tensile strength by 15.9%, 14%, and, 10.4% in the three flat, on-edge, and upright layer orientations, respectively. Aside from performing experimental tests, the LCCs of pre-cracked specimens are predicted theoretically by utilizing Equivalent Material Concept (EMC) combined with the well-known Average Strain Energy Density (ASED) criterion. It is shown that the EMC-ASED criterion can estimate accurately the experimental LCCs of both FDM-PLA and FDM-PLA/Cu specimens. Finally, the Scanning Electron Microscope (SEM) technique is employed to provide a better understanding of the effects of copper additives on the micro-mechanisms of fracture.

Multiaxial fatigue behavior and modelling of additive manufactured Ti-6Al-4V parts: The effects of layer orientation and surface texture

Additive manufacturing (AM) technologies have enabled industries to create and manufacture highly intricate parts with designs that have previously been deemed impossible via subtractive means. Analogous to conventionally fabricated parts, additively manufactured (AM) parts are often subjected to cyclic loadings throughout their service life. Consequently, fatigue performance becomes an important consideration in design and qualification. The geometric complexity of AM parts is accompanied by varying thermal histories which affect microstructure, porosity, surface texture, and residual stresses. The aforementioned factors influence fatigue performance and possibly introduce multiaxial stress states even when the loading is uniaxial. Therefore, understanding the fatigue behavior under multiaxial loadings is necessary to assess reliable in-service part performance. In this study, the effects of build layer orientation and surface texture on the multiaxial fatigue behavior of unmachined Ti-6Al-4V parts fabricated via a laser beam powder bed fusion process are investigated. Fatigue tests include axial, torsion, in-phase, and 90° out-of-phase axial/torsion loadings. Results indicate that the fatigue cracks in unmachined Ti-6Al-4V start from surface defects and are oriented along the maximum tensile stress plane. Accordingly, fatigue results are correlated using the tensile-based Maximum Principal Stress (MPS) approach. Finally, the influence of surface defects on the fatigue performance is incorporated by evaluating the surface micro-notches along the MPS using Murakami’s area parameter to obtain an initial crack size, which is then used with the NASGRO crack propagation model to predict fatigue lives.

Molecular Orientation and Energy Transfer Dynamics of a Metal Oxide Bound Self-Assembled Trilayer.

Self-assembly of molecular multilayers via metal ion linkages has become an important strategy for interfacial engineering of metalloid and metal oxide (MOx) substrates, with applications in numerous areas, including energy harvesting, catalysis, and chemical sensing. An important aspect for the rational design of these multilayers is knowledge of the molecular structure-function relationships. For example, in a multilayer composed of different chromophores in each layer, the molecular orientation of each layer, both relative to the adjacent layers and the substrate, influences the efficiency of vectorial energy and electron transfer. Here, we describe an approach using UV-vis attenuated total reflection (ATR) spectroscopy to determine the mean dipole tilt angle of chromophores in each layer in a metal ion-linked trilayer self-assembled on indium-tin oxide. To our knowledge, this is the first report demonstrating the measurement of the orientation of three different chromophores in a single assembly. The ATR approach allows the adsorption of each layer to be monitored in real-time, and any changes in the orientation of an underlying layer arising from the adsorption of an overlying layer can be detected. We also performed transient absorption spectroscopy to monitor interlayer energy transfer dynamics in order to relate structure to function. We found that near unity efficiency, sub-nanosecond energy transfer between the third and second layer was primarily dictated by the distance between the chromophores. Thus, in this case, the orientation had minimal impact at such proximity.

Experimental study on wire and arc additively manufactured steel double-shear bolted connections

Wire and arc additive manufacturing (WAAM) has emerged as a highly promising technique for manufacturing large-scale steel structural elements. However, the distinct mechanical properties of WAAM steel could potentially lead to different performance of WAAM steel bolted connections compared to the traditional steel bolted connections. This study aims to investigate the material properties of WAAM steel and the structural behaviours of WAAM steel bolted connections, focusing on the effects of print layer orientation and connection plate geometrical dimensions. A total number of 24 WAAM steel coupon specimens with three different print layer orientations and 36 WAAM double-shear bolted connections with two print layer orientations and different geometric dimensions were designed, fabricated and tested under monotonic tension. These specimens were measured using a 3D laser scanner and Digital Image Correlation (DIC) was adopted to measure the structural response during testing. The impact of print layer orientations on WAAM material properties and the effects of WAAM material properties on bolted connections were analysed and discussed. The current design codes for traditional steel bolted connections were evaluated against the test results of WAAM steel bolted connections. The study found that the print layer orientations of WAAM steel plates initiated an anisotropic material property of the coupon specimens, demonstrated by the differences in ultimate tensile strength and strain of specimens with different print layer orientations. Five failure modes, including net section tension, shear-out, bearing, end-splitting, and block shear failure were observed for the bolted connections. The material anisotropy further affects the performance of the bolted connections, though in the same dimensions, 28% of the specimens presented different failure modes due to the different print layer orientations. The effectiveness of current steel design standards was compromised by inaccurate predictions of failure modes due to the distinct end-splitting failure mode and the effects of material anisotropy, though the predictions of the ultimate capacities of the WAAM lap shear specimens were relatively accurate.

Exploring the impact of water on the morphology and crystallinity of xylan hydrate nanotiles

There has been a resurgence of studies on xylan particles describing various properties and exploring new applications. The aim of this study was to analyze xylan hydrate crystals in the wet state and after air-drying using state-of-art imaging techniques in order to assess the impact of water on both crystallinity and particle morphology. Xylan from esparto grass (Stipa tenacissima) was crystallized and formed convex platelets, termed ‘nanotiles’. Fully hydrated xylan crystals were examined in a layer of vitreous ice by cryogenic electron microscopy. Selected area electron diffraction of the xylan hydrate crystals revealed an oriented crystalline core, unlike the dried crystals that showed no orientation. The surface topographies and thickness of wet and air-dried xylan nanotiles were observed using atomic force microscopy imaging in both liquid and in air. X-ray diffraction was used to assess the crystallinity of xylan nanotiles after drying to varying levels. Air-dried crystals gave diffraction maxima corresponding to xylan hydrate, while wet crystals gave diffraction maxima corresponding to xylan dihydrate. This study offers new insight into xylan hydrate particles, focusing on the role of water on their crystallinity, ultrastructure, and orientation of the crystalline layers.

Scrutinizing pre- and post-device fabrication properties of atomic layer deposition WS2 thin films

In this work, we investigate the physical and electrical properties of WS2 thin films grown by a plasma-enhanced atomic layer deposition process, both before and after device fabrication. The WS2 films were deposited on thermally oxidized silicon substrates using the W(NMe2)2(NtBu)2 precursor and a H2S plasma at 450 °C. The WS2 films were approximately 8 nm thick, measured from high-resolution cross-sectional transmission electron imaging, and generally exhibited the desired horizontal basal-plane orientation of the WS2 layers to the SiO2 surface. Hall analysis revealed a p-type behavior with a carrier concentration of 1.31 × 1017 cm−3. Temperature-dependent electrical analysis of circular transfer length method test structures, with Ni/Au contacts, yielded the activation energy (Ea) of both the specific contact resistivity and the WS2 resistivity as 100 and 91 meV, respectively. The similarity of these two values indicates that the characteristics of both are dominated by the temperature dependence of the WS2 hole concentration. Change in the material, such as in sheet resistance, due to device fabrication is attributed to the chemicals and thermal treatments associated with resist spinning and baking, ambient and UV exposure, metal deposition, and metal lift off for contact pad formation.

Optimization through response surface methodology of 3D printed membrane preparation conditions for use in vanadium redox flow battery: A vanadium/proton selectivity study

AbstractSPEEK membrane applicable in Vanadium Redox Flow Battery (VRFB) have been 3D printed via Fused Deposition Modeling (FDM). Response Surface Methodology (RSM) has been used to optimize conditions for 3D printing membrane. Good membranes characteristics were obtained by manipulating three parameters, namely the printing temperature, the orientation of the printing layer and the sulfonation time. We evaluated the effects of these three variables on the permeability of membranes to protons and vanadium ions. Results have shown that sulfonation is the most significant variable influencing vanadium and proton permeability. The optimal printing conditions were found at 408°C temperature with a horizontal layer orientation, while the best sulfonation is obtained at 6 min. The optimal membrane has an ion exchange capacity of 0.86 mmolg−1, a water uptake ratio of 22%, a VO2+ permeability of 6.1 × 10−8 cm2 min−1, a H+ permeability of 7.0 × 10−6 cm2 min−1, excellent mechanical stability and better H+/VO2+ perm selectivity than conventional sulfonated polyether ether ketone (SPEEK), Fap450 and Nafion211 membranes. The above results show that the 3D‐SPEEK membrane has great advantages and broad prospects for VRFB applications.

Experimental Verification for the Graphitization of Inertinite

In order to explore the graphitization of inertinite, this paper conducted high-temperature thermal simulation experiments (HTT) and high-temperature high-pressure simulation experiments (HTHP) on isolated samples enriched in inertinite. X-ray diffraction (XRD), Raman spectroscopy, and transmission electron microscopy (TEM) were used to analyze the graphitization process of inertinite. ① Results of HTT: the graphitization of inertinite has a “threshold condition” with the temperature threshold ranging between 2100 °C and 2400 °C. Below this threshold, the d002 value of the samples remains above 0.342 nm. ② Results of HTHP: (i) External forces have a significant positive effect on the graphitization of inertinite. Compared to the HTT, the addition of external forces significantly reduces the temperature required for inertinite graphitization. (ii) Proper combinations of temperature and pressure conditions are crucial for efficiently promoting the graphitization of inertinite. Changes in pressure, either increasing or decreasing from the optimal pressure, have a suppressive effect on the graphitization of inertinite. ③ The mechanism of external forces on the graphitization of inertinite was analyzed. Shear stress promotes the rotation and orientation of aromatic layers, while static hydrostatic pressure contributes to the contraction and reduction of interlayer spacing in carbon layers.

Preparation and characterization of porcupine-fish-spine-inspired AZ91/SiC composites with radial lamellar structures

There is a growing demand for lightweight, damage-tolerant, and wear-resistant structural materials, and it is difficult to produce such materials with conventional methods. In this work, we prepared AZ91/SiC composites with a porcupine-fish-spine-inspired structure through radial freeze casting and pressureless infiltration, and investigated the effect of the thermal conductivity of the freezing mold (copper, brass, and stainless steel molds) on the structure and mechanical properties of the composite prepared. Owing to a higher axial-radial temperature gradient ratio, scaffolds prepared with the steel mold had a stronger orientation of ceramic layers, and the corresponding composites had higher flexural strength and fracture toughness compared with those prepared using the copper mold. The main toughening mechanisms were crack deflection and uncracked-ligament bridging. In particular, a radially frozen composite had a lower dry wear rate (by 20%) at cross-sectional surfaces than a conventional axially frozen composite. This paper presents an economical and scalable method for the preparation of high-performance lightweight metal matrix composites.