Organic Frame Research Articles

Synthesis, characterization and γ-rays irradiation of cobalt-based metal-organic framework for adsorption of Ce(III) and Eu(III) from aqueous solution

Metal-organic frameworks (MOFs) have important applications in adsorption, because of high porosity, diverse functionalities, and easy modification. Cobalt metal organic frame work (Co-MOF) based on diallylamine as the ligand was synthesized for the adsorption of Ce(III) and Eu(III) from aqueous solutions. Co-MOF was characterized by different spectroscopic techniques such as Fourier Transform-Infrared (FT-IR), X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDX) and scanning electron microscopy (SEM). The effects of adsorbent weight, pH of solutions, contact time, metal ion concentrations and gamma irradiation dose were studied. The adsorption efficiency of Ce(III) and Eu(III) onto Co-MOF was 93.3 and 27.47%, respectively, at pH 5.1. The distribution coefficient (Kd) of Ce(III) increased from 17.46 to 2791.30 ml/g, while for Eu(III) increased from 13.15 to 75.75 ml/g with changed the pH from 1.01 to 5.1. The Ce(III) and Eu(III) adsorption data were well fitted to the pseudo second order kinetic and Langmuir adsorption model. The maximum adsorption capacity of Ce(III) and Eu(III) onto Co-MOF were 102.24 and 52.93 mg/g respectively. The adsorption of Ce and Eu was slightly reduced by about 10% with increase dose of gamma radiation up to 400 kGy.

Experimental investigation of the solid desiccant dehumidification system with metal organic frameworks

• This paper investigate the dehumidification performance of MOFs desiccant coated heat exchanger. • Maximum water uptake capacity of MOFs desiccant was around 0.4 g•g −1 in given operating condition. • 90% of MOFs with 10% of solvent and binder mixture coated on the metallic fin of heat exchanger. • Increase of coating thickness can achieve the 131% of dehumidification performance. • The decrease of space velocity shows the over 160% enhancement of dehumidification performance. In this study, the comprehensive study of the performance investigation of Solid Desiccant Based Dehumidification (SDBD) system which involves the desiccant selection and desiccant coating with metallic heat exchanger was conducted at the mild humid conditions which represent the humid air conditions in summer, South Korea. The water uptake capacity of three different solid desiccants was investigated to find the proper solid desiccant in the SDBD system under the given operating conditions. Among the three different solid desiccants, the aluminum fumarate based metal organic frameworks (MOFs) was selected as the best solid desiccant for SDBD system and it has the maximum water uptake capacity around 0.398 g·g −1 for given operating conditions. The aluminum fumarate based metal organic frame works (MOFs) was coated on the metallic surface of heat exchanger by current developed coating method and the desiccant and binder solution is consistent of 10% of binder and solvent mixture and 90% of aluminum fumarate based MOFs. As a result, the increase of coating thickness from 0.05 mm to 0.2 mm and operating time from 150 s to 300 s can achieve the 113% and 131% of dehumidification performance enhancement in average, respectively. Remarkably, over 160% improvement of dehumidification performance in average can be achieved by the decrease of space velocity from 13 s −1 to 5.2 s −1 .

Removal of phenazopyridine as a pharmacological contaminant using nanoporous metal/covalent-organic frameworks (MOF/COF) adsorbent

This study is aimed at employing the Molecular Dynamics simulations to assess the phenazopyridine (PHP) adsorption, an analgesic drug, on three new metal-organic frameworks (MOFs); IRMOF-16, HKUST-1, and ZIF-8, with excellent behavior in π−π stacking, H-bonding, and electrostatic interactions. To further decipher the adsorption mechanism of PHP on MOFs, coarse-grained (CG) simulations and density functional theory (DFT) calculations were also exploited. Simulations revealed the PHP adsorption intensity of around 100%, 60%, and 40% by IRMOF-16, HKUST-1, and ZIF-8, respectively. Moreover, CG simulations and DFT calculation validated the superior PHP adsorption capacity of IRMOF-16 with the energy value of -343.4 kJ/mol and -1.53 eV, respectively. Furthermore, the PHP adsorption capability of IRMOF-16 was scrutinized under three distinct modifications: functionalization with hydroxyl functional group, tuning porosity size, and hybrid framework formation with DAAQ-TFP Covalent Organic Frame (COF). Interestingly, the modification of IRMOF-16 with hydroxyl groups and grafting with the COF led to considerably better performance in removing PHP, since their modifications increased the negative net charge of the surface, resulting in greater interactions with the positively charged PHP molecules. Furthermore, enlarging the IRMOF-16 pore size relatively reduced the adsorption functionality, due to the limited interactions of PHPs with available active sites.

Facile synthesis of a neodymium doped metal organic frame modified antibacterial material and corrosion resistant coating

Traditional bone implants are prone to postoperative infection due to their poor corrosion and antimicrobial resistance. Thus in this work, based on the original titanium base, we modified and synthesized a novel amorphous spherical metal-organic framework analogue nanoparticles with neodymium ions doped into them. This new rare earth element doped metal-organic framework and hydroxyapatite were co-deposited on titanium dioxide nanotube arrays by electrochemical method which can save a lot of time and energy compared to the traditional coating process. Most importantly, new coating can not only improve the corrosion resistance of the coating by increasing the resistance of the titanium sheet in SBF but also improve the antibacterial ability of Ti base without damaging the good biocompatibility of the titanium.

Construction of a photothermal hydrogel platform with two-dimensional PEG@zirconium-ferrocene MOF nanozymes for rapid tissue repair of bacteria-infected wounds

Because of increasing antibiotic resistance, careful construction of an efficient phototherm-nanozyme-hydrogel synergistic antibacterial platform is imperative for the treatment of bacteria-infected wounds. In this study, a carrageenan-based hydrogel embedded with polyethylene glycol dicarboxylic acid (COOH-PEG-COOH)-functionalized zirconium-ferrocene metal-organic frames nanosheets (PEG@Zr-Fc MOF hydrogel) was successfully constructed through COOH-PEG-COOH modification and physical assembly. The PEG@Zr-Fc MOF hydrogel could capture Gram-negative (Escherichia coli) and Gram-positive (Staphylococcus aureus) bacteria through reactive oxygen species (ROS) destruction and kill some bacteria by disintegration of H2O2 into toxic hydroxyl radicals (•OH). Significantly, by introducing the photothermal performance of the PEG@Zr-Fc MOF hydrogel, the catalytic activity of the target material could be improved to achieve a synergistic sterilization effect. The wound infection model experiment confirmed that the PEG@Zr-Fc MOF hydrogel had powerful bactericidal activity and could achieve a rapid tissue repair effect. More importantly, the PEG@Zr-Fc MOF hydrogel had negligible biological toxicity and reduced the risk of inflammation. This study reveals that phototherm-nanozyme-hydrogel synergy holds great potential for bacterial wound infection therapy. Additionally, this is the first study to use two-dimensional MOF nanozymes in combination with hydrogel for antimicrobial therapy. Statement of significanceBacteria-infected wound is one of the serious threats to public health, and this topic has attracted tremendous attention worldwide in recent decades. Although numerous traditional therapeutic strategies that depend on antibiotics have been developed and applied for treating bacteria-infected wound disease, the effect of wound treatment is becoming increasingly unsatisfactory due to bacterial resistance. The present study provides a feasible method to treat bacterial wound infection by constructing a carrageenan-based hydrogel embedded with polyethylene glycol dicarboxylic acid (COOH-PEG-COOH) functionalized zirconium-ferrocene metal organic frame nanosheets (PEG@Zr-Fc MOF hydrogel). The experiments with the wound infection model confirmed that the PEG@Zr-Fc MOF hydrogel had powerful bactericidal activity and could achieve a rapid tissue repair. This strategy provides a promising avenue to further accelerate the development of antibacterial therapy in biomedical fields.

Bimetallic organic frame nanosheet fluorescent probe used for detecting tetracycline and folic acid

A novel and powerful dual-signal fluorescence measurement method was developed to detect the content of tetracycline (TC) and folic acid (FA) based on the change of the fluorescence signal of the bimetallic Ag@Cu MOFs nanosheet fluorescent probe. Bimetallic Ag@Cu MOFs nanosheets have high fluorescence intensity and good fluorescence stability. By adding TC, the fluorescence signal intensity of the probe is quenched obviously, but the signal intensity is greatly enhanced by adding FA. Based on this, the developed dual-signal fluorescence detection method can detect TC and FA with high sensitivity and selectivity, which can afford a new idea for dual-signal micro-detection by a fast, simple, and reliable method.

The ideology of idoneousness: Mary Anne Hilton and Mercedes Gutierrez as symbols of women’s exclusion from spaces of power in Chilean Pentecostalism

ABSTRACT This article describes the ideology of idoneousness as one of the Pentecostal principles that explain the forms taken by the integration of women in structures of religious power. Their access to and exclusions from power in Chilean Pentecostalism is concealed through the sexualisation of roles based on the stronger masculine/weaker feminine (virile/mulieris) duality, underpinned by the head/hand organic frame. This conceptual proposal was complemented with Pierre Bourdieu’s constructivist structuralism, and focuses on two women who formed part of the foundational myth of Pentecostalism: Mary Anne Hilton and Mercedes Gutierrez. In our methodology we included the analysis of the two institutional journals from the early history of the Pentecostal church history in Chile, namely: Chile Pentecostal (1910–1927 and from (1933–1979), and Fuego de Pentecostés (1928–2019).

Highly porous terpolymer-MOF composite electrode material for high performance supercapattery devices

• MOF based electrode material for supercapattery devices. • High specific capacity of 200C/g and high specific capacitance of 285F/g. • Supercapattery formed by coupling activated carbon with battery grade electrode (MOF//AC). • High power density of 1600 W/kg and high energy density of 38.5 W h/kg. Supercapattery a renowned energy storage device that comprises of the features of the battery and supercapacitor at a time. This unique combination leads to the formation of such device that can deliver high energy density with no compromise on the power density. Here, we have reported a unique class of material known as metal organic frame works (MOF) for the application of energy storage devices. MOF comprises of exceptional properties such as high surface area, excellent chemical stability and high porosity. The material was synthesized via hydrothermal route in three steps. The structure, morphology, surface area, porosity and crystallinity of the synthesized material were carried out through Tunneling Electron Microscopy, Scanning Electron Microscopy, X-ray diffraction and Brunauer-Emmett-Teller. In order to investigate the energy storage application, the electrochemical characterization was carried out in three-electrode assembly and the material express excellent performance by showing a battery graded nature with specific capacity of 199.8 C/g. To further investigate the application in energy storage field a supercapattery was formed as a real device by coupling activated carbon as a cathode with MOF as an anode separated by porous membrane. This asymmetric assembly expresses a specific capacity of 171.15 C/g and embraces an outstanding rate capability of 69% at 2.0 A/g. Furthermore, this supercapattery delivers tremendous energy density of 38.05 Wh.kg −1 with an admirable power density of 1600 W.kg −1 . At last the supercapattery reliability was investigated through cyclic charge discharge and the device has shown exceptional stability by sustaining its capacity of 100% even after 1000 consecutive charge discharge cycles.

In situ growth of NiFe MOF/NF by controlling solvent mixtures as efficient electrocatalyst in oxygen evolution

Two-dimensional metal–organic frame (2D MOF) materials have attracted great attention due to the successful combination of the unique properties of MOF and chemical properties of 2D material. In this paper, NiFe MOF/NF with a two-dimensional layered vertical structure were prepared by bottom-up solvothermal method. We used different solvent mixtures (methanol/water, ethanol/water, acetone/water, N, N-dimethylformamide/water) to control the synthesis of MOF and found that the oligpolar solvent mixture of acetone and water was the best in controlling the formation of these two-dimensional MOFs. The obtained NiFe MOF/NF in acetone/water appeared the best performance as electrocatalyst for the oxygen evolution reaction, in which the NiFe MOF/NF delivered a current density of 50 mA·cm−2 at a low overpotential of 270 mV with a small Tafel slope of 55 mV·dec-1. In addition, NiFe MOF/NF has an excellent stability at a high current density of 100 mA·cm−2.

Observable removal of pharmaceutical residues by highly porous photoactive cellulose acetate@MIL-MOF film

Pharmaceutical products are used tremendously worldwide and subsequently released into wastewater even at very low concentration caused serious environmental problem due to their high activity. Therefore, the present work focuses on remarkable removal of paracetamol as one from the most used pharmaceutical intermediates, by using porous film based on cellulose acetate@metal organic framework (CA@Ti-MIL-NH2). The film was designed to achieve extreme removal of paracetamol by action of both of adsorption and degradation. Metal organic frame work was directly synthesized and inserted within the pre-prepared porous CA film to obtain porous CA@Ti-MIL-NH2 film. The synthesized films were applied in adsorption and photo-degradation of paracetamol separately and together. Due to the photocatalytic activity of Ti-MIL-NH2, the photo-degradation of paracetamol in visible-light was much effective and considerably high degradation of paracetamol was observed (k1 = 760.0 m−1) comparing to the adsorption (k1 = 160.0 m−1). The overall removal of paracetamol was significantly enlarged from 82.7 mg/g for CA film to 519.1 mg/g for porous CA@Ti-MIL-NH2 film. The used film exhibited quite good reusability and the removal of paracetamol was lowered from 96% to 85% after 5 regeneration cycles. Results of total organic carbon confirmed that paracetamol was fully degraded to CO2 and water.

Identification of Mint Scents Using a QCM Based E-Nose

Mints emit diverse scents that exert specific biological functions and are relevance for applications. The current work strives to develop electronic noses that can electronically discriminate the scents emitted by different species of Mint as alternative to conventional profiling by gas chromatography. Here, 12 different sensing materials including 4 different metal oxide nanoparticle dispersions (AZO, ZnO, SnO2, ITO), one Metal Organic Frame as Cu(BPDC), and 7 different polymer films, including PVA, PEDOT:PSS, PFO, SB, SW, SG, and PB were used for functionalizing of Quartz Crystal Microbalance (QCM) sensors. The purpose was to discriminate six economically relevant Mint species (Mentha x piperita, Mentha spicata, Mentha spicata ssp. crispa, Mentha longifolia, Agastache rugosa, and Nepeta cataria). The adsorption and desorption datasets obtained from each modified QCM sensor were processed by three different classification models, including Principal Component Analysis (PCA), Linear Discriminant Analysis (LDA), and k-Nearest Neighbor Analysis (k-NN). This allowed discriminating the different Mints with classification accuracies of 97.2% (PCA), 100% (LDA), and 99.9% (k-NN), respectively. Prediction accuracies with a repeating test measurement reached up to 90.6% for LDA, and 85.6% for k-NN. These data demonstrate that this electronic nose can discriminate different Mint scents in a reliable and efficient manner.

Novel Porphyrin Zr Metal-Organic Framework (PCN-224)-Based Ultrastable Electrochemiluminescence System for PEDV Sensing.

The sensitive detection of coronavirus is of vital importance for the prevention of its rapid spread. Porcine epidemic diarrhea virus (PEDV) is a highly contagious coronavirus that causes severe diarrhea and death in neonatal piglets. In this work, a novel PCN-224-based electrochemiluminescence (ECL) system was constructed for PEDV detection with high sensitivity. We found that PCN-224 can be employed as an ECL reporter with a strong signal because of its zirconium-based organic porous frame nanomaterial with a large specific surface area and stable structure. TiO2 nanoparticles were used as an accelerator for the first time to promote the reduction of coreactant potassium peroxydisulfate on the cathode; thus, the initial ECL signal of PCN-224 was significantly amplified. In the presence of PEDV, the ECL signal decreased due to the block effect to electron transfer. As a result, the novel "signal off" biosensor achieved a sensitive detection of PEDV ranging from 1 pg/mL to 10 ng/mL, with a detection limit of 0.4 pg/mL (S/N = 3). Importantly, the PCN-224 nanomaterial enriched the ECL system in biological analysis, and the proposed strategy provided a new route for coronavirus detection.

Preparation of a pinoresinol diglucoside imprinted polymer using metal organic frame as the matrix for extracting target compound from Eucommia ulmoides

ABSTRACT Fabrication of a post-synthesis imprint modification method for metal-organic frameworks in order to improve its selectivity in the field of separation and analysis is of great interest. For this purpose, a pinoresinol diglucoside (PDG) imprinted polymer was attempted to graft on the surface of metal-organic frameworks MIL-101 to produce a new composite material named MIPs@ED-MIL-101. This modification procedure was monitored by using X-Ray Diffraction, fourier transforms infrared spectroscopy and scanning electron microscopy in the crystal structure, chemical groups and particles topography, respectively. Adsorption kinetics and thermodynamics behavior, rebinding selectivity and applicability in solid-phase extraction for this new material obtained were evaluated. The kinetics test indicated this composite material improved adsorption dynamics relative to the MIL-101, with a 28.6% decrease in adsorption equilibrium time. The adsorption capacity for the MIPs@ED-MIL-101 toward PDG was shown higher than that for the MIL-101 and nonimprint-modified material NIPs@ED-MIL-101 at the same substrate concentration when adsorption was carried out at 298 K in acetonitrile-H2O mixed solution (1:1, V/V). Freundlich model can best fit the isotherm data for the MIPs@ED-MIL-101, indicating site heterogeneity in this composite material and mean adsorption energy of 19.60 kJ mol-1 obtained by Dubinin–Radushkevich model fitting might imply chemical adsorption the main rebinding process. In addition, this imprint composite material could selectively bind template and be utilized as the adsorbent in solid-phase extraction to capture target compound from plant crude extract. This new material can also be reused many times with a slight decrease in adsorption capacity.

New oligomeric metallosiloxane - polyimide nanocomposites for anti-atomic-oxygen erosion

The effect of branched functional metallosiloxane oligomers (BFMSO) used as precursors on the morphology and atomic oxygen resistance of filled polyimide films was studied. Nanocomposites are characterized by elevated glass transition temperatures and greater erosion resistance to atomic oxygen than the original polymer. In situ filling of polyimide with BFMSO-based nanoparticles allows one to reduce the rate of film mass loss under the influence of atomic oxygen by an order of magnitude and reduce the erosion yield by more than 70%. To correctly compare the effectiveness of fillers based on precursors of different chemical structures as protective elements of the polymer surface from the effects of atomic oxygen, the specific erosion yields calculated as the ratio of the erosion yield to the filler concentration expressed in moles of filler per unit mass of polymer were used. This approach made it possible to identify the main factors of the directional regulation of erosion resistance of in situ filled PI to the effects of atomic oxygen. Primarily they include the chemical structure of the organic frame of the central metal atom of the precursor, which determines the effectiveness of the filler in increasing the erosion resistance of nanocomposites. The “replacement” of a phenyl substituent with a methyl substituent at a silicon atom in the composition of BFMSO and, accordingly, particles based on it, reduces the specific erosion yields of nanocomposites by 2.2-2.6 times. The nature of the central metal atom of the precursor is a minor factor. Its change allows reducing the specific erosion yields of coatings based on polyimide and branched functional metallosiloxane oligomers by no more than 1.5 times.

CoP@NC electrocatalyst promotes hydrogen and oxygen productions for overall water splitting in alkaline media

Design and synthesis of high-performance bi-functional electrocatalysts can play a crucial role for electrolytic water splitting. Herein, we develop a simple phosphating process to construct cobalt phosphide@nitrogen-doped carbon (CoP@NC) using metal organic frame (MOF) as a precursor and a template. In alkaline solution, CoP@NC-350 exhibits exceptional hydrogen and oxygen evolution reaction performances with over potentials of 75 mV and 268 mV at 10 mA cm−2, respectively. For a symmetric CoP@NC-350 two-electrode water splitting setup, the potential can be low as 1.69 V to obtain 10 mA cm−2. Therefore, low-temperature phosphating treatment can be a simple and promising method to produce electrocatalysts for water splitting.

Selective CO2 capture through microporous Tb(BTC)(H2O).(DMF)1.1 MOF as an additive in novel MMMs fabricated from Matrimid® 5218

Mixed matrix membranes (MMMs) fabricated with porous metal organic frame works have enhanced the separation performance of polymer membranes. In this context microporous 3D Tb(BTC)(H2O).(DMF)1.1 MOF was incorporated into pristine Matrimid® with loadings of 10, 20 and 30 weight percentages. SEM micrographs indicated proper distribution of filler in the Matrimid and no interfacial voids were observed. Gas permeation studies evidenced the CO2 permeability to be 13.2 (82.32%) and 18.34 (153.31%) and 25.86 Barrer for 10, 20 and 30 wt% MMMs respectively. The 257.18% increase in CO2 permeability of 30 wt% MMM than methane was attributed to polar nature of CO2, its smaller kinetic diameter, condensability, and larger solubility within the Matrimid matrix than non – polar and larger CH4 molecules.Addition of filler influenced the pure gas selectivity of all MMMs positively. So, 30 wt% MMM exhibited the highest 58.04% increase in selectivity that was attributed to the molecular sieving property of the filler and the size exclusion phenomena as followed by CH4 and CO2. The high values of mixed and pure gas selectivity were obtained upon increasing filler concentration. The commercial applicability of these MMMs was tested by checking their selectivity under increased feed concentrations of CO2 and checking permeability and selectivities at high temperatures. The study depicted that, competitive sorption of gases, prevalence of size exclusion phenomena and polymer chains relaxation at higher temperature were responsible for low gas selectivity. MMM with 30 wt% of MOF lied close to Robson’s Upper bound 2008 that indicated its good separation potential.

Electrochemical and photocatalytic applications of Ce-MOF

We report on the applicability of an easy and general synthesis procedure for the formation of Ce(IV)-MOFs. Cerium-based metal–organic frame (Ce-MOF) was successfully synthesized by a simple, cost-effective and green route. Highly homogeneous topology, nano-sized crystals, stable oxidation states Ce(III) and Ce(IV) at room temperature, significant surface area and thermal stability up to 320°C are the notable properties achieved by Ce-MOF. Electron transferability of the cerium electrode was used for the detection of methylene blue (MB) analyte in acidic buffer solution. Also the effect of different pH buffer solutions on electrode response has been studied. Photocatalytic performance of nano-Ce-MOF was studied on the degradation of MB analyte under visible light.

Recent advances in metal organic frame photocatalysts for environment and energy applications

Metal organic frameworks are very popular in fields of environment and energy over the past two decades due to their unique structural advantages and chemical properties. What meets people's expectations is that metal organic frameworks show very good effects in photocatalysis, showing great potential in the degradation of organic pollutants, hydrogen production, CO2 reduction and other aspects, providing a very promising prospect for subsequent development. This review briefly summarizes the latest progress of several popular metal organic frames (Fe-based, Ti-based, Zr-based, and Zn-based) and some novel metal organic frameworks as photocatalysts in environment and energy, summarizes the photocatalytic reaction mechanism, and puts forward a reasonable prospect for the future development of metal organic frameworks photocatalysis. This review may provide new insights for fabricating high-performance metal organic frameworks photocatalysts.

A Hepatocellular Carcinoma Targeting Nanostrategy with Hypoxia-Ameliorating and Photothermal Abilities that, Combined with Immunotherapy, Inhibits Metastasis and Recurrence.

Hepatocellular carcinoma (HCC) is a common and highly malignant tumor that is prone to recurrence and metastasis and has no effective treatment. Unsurprisingly, its prognosis is quite poor; early detection methods and effective low-toxicity treatments are urgently needed. To achieve these goals, we designed a multifunctional, U.S. Food and Drug Administration-approved Prussian blue (PB) nanoparticle (NP) with a porous metal organic frame loaded with sorafenib (SF), conjugated with HCC-specific targeting peptide SP94 and the near-infrared dye cyanine (Cy)5.5. These NPs are amenable to multimodal imaging for dynamic monitoring of their biodistribution and tumor-targeting effects. The SP94-PB-SF-Cy5.5 NPs achieved targeted delivery and controlled SF release and exhibited good photothermal effects. In this strategy, photothermal therapy and SF treatment complement each other, reducing the side effects of SF and achieving a therapeutic effect without local tumor recurrence. In addition, the catalase-like ability of the NPs alleviates tumor hypoxia, and their photothermal effects induce immunogenic cell death, leading to the release of tumor-associated antigens. These effects combine to trigger an antitumor immune response; the NPs also displayed promising inhibitory effects on tumor metastasis and recurrence and produced an abscopal effect and long-term immunological memory when combined with antiprogrammed death-ligand 1 (PD-L1) immunotherapy. These safe, multifunctional NPs represent a valuable treatment option for HCC. In addition, this next-generation treatment model may provide some ideas for the management of HCC and other cancers.

MOFs in carbon capture-past, present and future

• Microwave assisted solvo-thermal synthesis was found promising.· • Cu-BTC gave the highest CO 2 uptake was 9.59 mmol/g among various MOFs.· • Adsorption of CO 2 by MOFs mostly followed Pseudo second order kinetics along with Toth or modified Langmuir isotherm.· • Fixed and fluid bed type of contactors were the best suited for MOF based Carbon capture· • Photo-responsive MOFs have a great potential in future that could give a CO 2 uptake of 89 cc/g. Metal Organic Frame works (MOFs) are being widely used in carbon capture through adsorption and membrane techniques, which are yet to be commercialized. This is due to their high affinity towards acidic gases and exceptional characteristics such as crystallinity, structural stability, high surface area and flexible pore dimensions. In this review, wide range of topics viz., synthesis protocols, modifications employed to further improve their attributes, comprehensive comparison of different MOFs used in carbon capture, thermo-kinetics modelling studies, contactors and material screening. Every section has been discussed in detail in terms of developmental trends, future challenges and prospects besides summarizing in the form of comprehensive tables at a glance for the benefit of the readers. Solvo-thermal method was found to be the most effective synthesis method besides ultra-sonication and microwave assisted methods, which also gave very good crystalline structures. The copper ligand based unmodified Cu-BTC MOF gave the maximum CO 2 uptake value of 9.59 mmol/g at 273 K and 1 atm. Zn(Bmic)(AT) MOF was the only species to be tested at 353 K. Alternatively, a photo-responsive MOF, Mg-IRMOF-74-III functionalized with azopyridine gave a CO 2 uptake of 89 cc/g which is comparable to many of the conventional MOFs. Kinetics indicate MOF adsorption mostly follows pseudo second order reactions either along with Toth isotherms or modified Langmuir isotherms. Fixed and fluidized bed reactors perform the best in terms of carbon capture studies. Moisture affinity, active sites and crystallinity were found to be the best factors considered whilst screening of proper MOFs.