Organic Fraction Of Municipal Solid Waste Research Articles

Method for C/N ratio estimation using Mask R-CNN and a depth camera for organic fraction of municipal solid wastes

Fast assessment of the initial carbon to nitrogen ratio (C/N) of organic fraction of municipal solid waste (OFMSW) is an important prerequisite for automatic composting control to improve efficiency and stability of the bioconversion process. In this study, a novel approach was proposed to estimate the C/N of OFMSW, where an instance segmentation model was applied to predict the masks for the waste images. Then, by combining the instance segmentation model with the depth-camera-based volume calculation algorithm, the volumes occupied by each type of waste were obtained, therefore the C/N could be estimated based on the properties of each type of waste. First, an instance segmentation dataset including three common classes of OFMSW was built to train mask region-based convolutional neural networks (Mask R-CNN) model. Second, a volume measurement algorithm was proposed, where the measurement result of the object was derived by accumulating the volumes of small rectangular cuboids whose bottom area was calculated with the projection property. Then the calculated volume was corrected with linear regression models. The results showed that the trained instance segmentation model performed well with average precision scores AP50 = 82.9, AP75 = 72.5, and mask intersection over unit (Mask IoU) = 45.1. A high correlation was found between the estimated C/N and the ground truth with a coefficient of determination R2=0.97 and root mean square error RMSE = 0.10. The relative average error was 0.42% and the maximum error was only 1.71%, which indicated this approach has potential for practical applications. Keywords: carbon to nitrogen ratio, estimation, volume measurement, organic fraction of municipal solid waste, depth camera, instance segmentation DOI: 10.25165/j.ijabe.20211405.6382 Citation: Huang J J, Zhang H D, Xiao X, Huang J Q, Xie J X, Zhang L, et al. Method for C/N ratio estimation using Mask R-CNN and a depth camera for organic fraction of municipal solid wastes. Int J Agric & Biol Eng, 2021; 14(5): 222–229.

Evaluating landfill leachate treatment by organic municipal solid waste-derived biochar

Transforming the organic fraction of municipal solid waste (OFMSW) into biochar to reduce fugitive landfill emissions and control organic micropollutants (OMP) during landfill leachate treatment could provide a new circular economy organics diversion approach.

Diversifying the Products From the Organic Fraction of Municipal Solid Waste (OFMSW) by Producing Polyhydroxyalkanoates From the Liquid Fraction and Biomethane From the Residual Solid Fraction

Diversifying the Products From the Organic Fraction of Municipal Solid Waste (OFMSW) by Producing Polyhydroxyalkanoates From the Liquid Fraction and Biomethane From the Residual Solid Fraction

Assessment of Integration between Lactic Acid, Biogas and Hydrochar Production in OFMSW Plants

Biological treatments such as anaerobic digestion and composting are known to be the most widespread methods to deal with Organic Fraction of Municipal Solid Waste (OFMSW). The production of biogas, a mix of methane and carbon dioxide, is worth but alone cannot solve the problems of waste disposal and recovery; moreover, the digestate could be stabilized by aerobic stabilization, which is one of the most widespread methods. The anaerobic digestion + composting integration converts 10% to 14% of the OFMSW into biogas, about 35–40% into compost and 35–40% into leachate. The economic sustainability could be rather increased by integrating the whole system with lactic acid production, because of the high added value and by substituting the composting process with the hydrothermal carbonization process. The assessment of this integrated scenario in term of mass balance demonstrates that the recovery of useful products with a potentially high economic added value increases, at the same time reducing the waste streams outgoing the plant. The economic evaluation of the operating costs for the traditional and the alternative systems confirms that the integration is a valid alternative and the most interesting solution is the utilization of the leachate produced during the anaerobic digestion process instead of fresh water required for the hydrothermal carbonization process.

Co-digestion of organic fraction of municipal solid waste (OFMSW) and industrial organic solid waste

Co-digestion of organic fraction of municipal solid waste (OFMSW) and industrial organic solid waste

The role of dry anaerobic digestion in the treatment of the organic fraction of municipal solid waste: A systematic review

Anaerobic digestion (AD) has been seen as an attractive alternative for the treatment of the organic fraction of municipal solid waste (OFMSW), with the potential to provide useful products such as bio-methane, bio-hydrogen, and a highly concentrated compost. Among the different AD technological routes, dry AD stands out because it makes better use of resources and can handle higher solids concentration, being more robust and flexible as compared to wet AD systems. In this contribution, a systematic review was carried out on the evolution of AD systems, giving emphasis to the role of the dry AD route for OFMSW treatment throughout the last 15 years. As it has been seen as a current trend in the field, the opportunities for technological development of dry AD systems and the challenges to be faced for their implementation in large-scale settings were assessed. Furthermore, aspects associated with input substrates and biodigesters operating conditions were addressed, along with the most important dry AD reactor configurations and commercial technologies. The research studies show that dry AD is most implemented under mesophilic conditions in continuous processes. Furthermore, apart from being influenced by many operational factors (temperature, pH, total solids content, substrate to inoculum ratio, organic loading rate and hydraulic/solids retention time), the performance of dry AD systems in terms of biogas productivity depends on the characteristics of the substrates, co-substrates and inoculum. Laboratory-scale tests are found to be essential to overcome the operational obstacles in full-scale plants, allowing for better system performance, stability and process control.

Efficiency of Two-Phase Anaerobic Fermentation and the Physicochemical Properties of the Organic Fraction of Municipal Solid Waste Processed in a Vortex-Layer Apparatus

Pretreatment of the organic fraction of municipal solid waste (OFMSW) is a necessary step to accelerate the process of anaerobic digestion in order to avoid rapid acidification and inhibition of methanogenesis. This work shows for the first time the effect of pretreatment in a vortex-layer apparatus (VLA) on the physicochemical properties and characteristics of the anaerobic thermophilic, two-phase fermentation of OFMSW. Pretreatment in a VLA led to a decrease in the amount of fat, an increase in pH, a slight increase in the amount of protein in dry matter, and a change in the density and dry matter content. OFMSW processing in a VLA for 2 min increased the specific yield of biogas and methane by 11.6 and 15.8%, respectively.

Carbon Monoxide Formation during Aerobic Biostabilization of the Organic Fraction of Municipal Solid Waste: The Influence of Technical Parameters in a Full-Scale Treatment System

The present study sought to investigate the formation of carbon monoxide (CO) during aerobic biostabilization (AB) of the organic fraction of municipal solid waste (OFMSW) in forced aerated piles. Understanding the factors influencing CO formation may be important not only for safety, but also for environmental and technical reasons. The objective of the study was to determine the effect of the technical parameters of the piles on the concentration of CO in the process gas during AB of the OFMSW in a full-scale waste treatment system: rate of waste aeration (from 3365 to 12,744 m3∙Mg−1), waste mass loads in the pile (from 391 to 702 Mg), thermal conditions, application of sidewalls as an element of pile bioreactor construction, concentration of O2 and CO2 in the waste piles and the duration of the process from 6 to 9 weeks. The temperature and concentration of O2, CO2, CO, CH4 were measured in each pile at weekly intervals. All six reactors provide stable thermal and aerobic conditions, but the presence of CO was observed, ranging from a few to over 2000 ppm, which demonstrated that ensuring optimum conditions for the process is not sufficient for CO to be eliminated. A moderate, non-linear rise in CO concentration was observed along with a rise in the temperature inside the reactors. Concentrations of CO were not highly correlated with those of O2 or CO2. An increase in waste mass loads increased the CO concentration in waste piles, while application of sidewalls decreased CO concentration. Increasing aeration rate had an influence on CO production, and the highest CO concentrations were noted under air flow rate 5.3 m3·Mg−1·h−1.

Effect of Pasteurisation on Methane Yield from Food Waste and Other Substrates in Anaerobic Digestion

The effect of pasteurisation and co-pasteurisation on biochemical methane potential values in anaerobic digestion (AD) was studied. Pasteurisation prior to digestion in a biogas plant is a common hygienisation method for organic materials which contain or have been in contact with animal by-products. Tests were carried out on food waste, slaughterhouse waste, animal blood, cattle slurry, potato waste, card packaging and the organic fraction of municipal solid waste (OFMSW); pasteurisation at 70 °C for 1 h was applied. Pasteurisation had increased the methane yields of blood (+15%) and potato waste (+12%) only, which both had a low content of structural carbohydrates (hemi-cellulose and cellulose) but a particularly high content of either non-structural carbohydrates such as starch (potato waste) or proteins (blood). With food waste, card packaging and cattle slurry, pasteurisation had no observable impact on the methane yield. Slaughterhouse waste and OFMSW yielded less methane after pasteurisation in the experiments (but statistical significance of the difference between pasteurised and unpasteurised slaughterhouse waste or OFMSW was not confirmed in this work). It is concluded that pasteurisation can positively impact the methane yield of some specific substrates, such as potato waste, where heat-treatment may induce gelatinisation with release of the starch molecules. For most substrates, however, pasteurisation at 70 °C is unlikely to increase the methane yield. It is unlikely to improve biodegradability of lignified materials, and it may reduce the methane yield from substrates which contain high contents of volatile components. Furthermore, in this experimental study, the obtained methane yield was unaffected by whether the substrates were pasteurised individually and then co-digested or co-pasteurised as a mixture before batch digestion.

Implementing polyhydroxyalkanoates production to anaerobic digestion of organic fraction of municipal solid waste to diversify products and increase total energy recovery

A simple biorefinery aimed at producing both biomethane (CH4) and polyhydroxyalkanoates (PHAs), was proposed to valorize the organic fraction of municipal solid waste (OFMSW). Anaerobic digestion (AD) was tested at different organic loading rates (OLR-I-II-III) (i.e. 3, 4 and 6 g L−1 d−1, respectively), producing biomethane and volatile fatty acids (VFAs)-rich digestate, the VFAs were then used to produce PHAs. Specific biogas and CH4 production remained similar when adopting different OLRs (biogas of 522–600 NL kg−1 VS and CH4 of 64–67% v/v). VFAs concentrated with OLR increases and their patterns were modified. PHA production was in the range of 117–199 g kg−1 OFMSWTS with the lowest production being associated to different polymer composition.The net energy recovery of this simple biorefinery accounted for 64% of OFMSW energy content, and the PHAs produced represented over 30% of the total energy.

Evaluation of Chlorella vulgaris and Scenedesmus obliquus growth on pretreated organic solid waste digestate

In this research Scenedesmus obliquus and Chlorella vulgaris growth was tested on digestate sludge obtained from the anaerobic co-digestion treatment of the organic fraction of municipal solid waste (OFMSW) together with waste activated sludge (WAS). Digestate was diluted 1:10 and tested in three batch experimental conditions: with no pre-treatments (noPT), after centrifugation (AC) and after filtration (AUF), in order to evaluate microalgae limiting growth factors. The best growth was obtained by C. vulgaris on digestate AC compared to S. obliquus, reaching 479 ± 31 cell million ml−1 and 131 ± 12 cell million ml−1 respectively. Ammonia removal evaluated in C. vulgaris and S. obliquus cultures was 99.2% ± 0.3 and 98.146% ± 0.008 in AC condition, respectively. Considering that AUF showed similar microalgae growth values, the digestate pretreatment for microalgae growth, could be limited to centrifugation.

Stabilization of anaerobic co-digestion of biowaste using activated carbon of coffee ground biomass

Process instability commonly encountered in anaerobic co-digestion (AcoD) of organic fractions of municipal solid wastes (OFMSWs) is addressed by utilizing hydrochar (CB-HTC) and activated hydrochar (ACB-HTC) derived from coffee ground biomass. Addition of CB-HTC or ACB-HTC shortened the lag phase resulting in high biogas yield of 68.57 Nl/kg oTS or 102.86 Nl/kg oTS, respectively within the first week. Improvement in biogas yield (~5% higher than the control) was due to unique properties which prevented washout of consortia of bacteria useful for AcoD and subsequently led to a more stable process. An increase in either OLR [1.0 kg oTS/(m3*d) to 1.5 kg oTS/(m3*d)] or temperature (36.5 °C to 42.5 °C) did not lead to increase in ammonium-nitrogen or TKN in reactors amended with hydrochars. Likewise, ratio of VFA/TA was within 0.2–0.3 after the fourth week in ACB-HTC treated reactor. Addition of ACB-HTC greatly improved nutrient retention in the digestate.

Fixed-bed gasification and pyrolysis of organic fraction of MSW blended with coal samples

Buildup of vast quantities of municipal solid waste (MSW) including refuse derived fuel, organic fraction around the urban areas has negative environmental consequences. Gasification and pyrolysis of municipal solid waste could be an attractive option to utilize or convert to a valuable product. This study investigates the thermochemical properties of refuse derived fuel (RDF), organic fraction of MSW (Org MSW) and coal samples. Along with proximate and elemental analysis, calorific values were provided for RDF, MSW organic fraction, and coal samples. This followed by the thermogravimetric analysis of the same samples. In addition, Org MSW MSW and coal samples were blended in a proportion of 0.5/0.5 and 0.25/0.75 and then thermally treated in horizontal tube furnace both under air and inert gases to investigate the pyrolysis and gasification processes. TGA tests revealed that volatile content from Org MSW and RDF begin to be emitted at temperatures above 180-200 °C. Org MSW and RDF lose all their volatile contents at 500 °C and 700 °C. Pyrolysis experiments revealed that below 500 °C mostly tars are formed from Org MSW. Organic MSW and coal 0.5/0.5 blends yielded higher methane concentrations than coal or MSW alone, reaching 35-37 % at 800 °C. It could be concluded that both fixed bed and thermogravimetric method analysis have provided a good result to investigate the gasification and pyrolysis processes.

Robust operation through effluent recycling for hydrogen production from the organic fraction of municipal solid waste

The stability of fermentative hydrogen production from the organic fraction of municipal solid waste (OFMSW) was evaluated in this work using a strategy of effluent recycling. Three pretreatment conditions were applied on the recycled effluent: a) no heat shock treatment, b) one initial heat shock treatment (90 °C, 30 min) and c) systematic heat shock treatment at the beginning of each fermentation. When a systematic heat shock was applied, a maximal hydrogen yield of 17.2 ± 3.8 mLH2/gVS was attained. The hydrogen productivity was improved by 331% reaching a stable value of 1.51 ± 0.29 mLH2/gVS/h, after 8 cycles of effluent recycling. This strategy caused a sharp decrease of diversity with stable co-dominance of hydrogen- and lactate-producing bacteria, ie. Clostridiales and Lactobacillales, respectively. For the other conditions, a sharp decrease of the hydrogen yields was observed showing the importance of applying a heat shock treatment for optimal hydrogen production with effluent recycling.

Anaerobic mono and co-digestion of organic fraction of municipal solid waste and landfill leachate at industrial scale: Impact of volatile organic loading rate on reaction kinetics, biogas yield and microbial diversity

The present study was aimed to demonstrate a semi-commercial biomethanation plant based on anaerobic gas lift reactor (AGR) for the mono and co-digestion of organic fraction of municipal solid waste (OFMSW) and landfill leachate (LL) for 47 weeks. The reactors were commissioned at a volatile organic loading rate (VOLR) starting from 0.4 to 6.2 kg VS/(m3·day) to investigate the impact of VOLR on the organic matter removal rates, substrate utilization rate using Stover-Kincannon reaction kinetics, biogas yield and microbial diversity. 16s-metagenomic sequencing of the species present in the inoculum that was acclimatized with OFMSW, LL separately and in combination was also performed to identify the dominant microbial species in the mixed microbial consortia. Results revealed that the VS reduction in AGR 1, AGR 2 and AGR 3 at full load was 46%, 42% and 47% respectively with a corresponding biogas generation of 73.8 m3/day, 42 m3/day and 60.8 m3/day. The biodegradability in AGR 1 was between 73% and 81% whereas in AGR 2 and AGR 3, it was between 57% and 78% and 64% and 86% respectively. The operational strategy of digestate recirculation facilitated in the reduced usage of buffering chemicals which impacted on overall financials of the plant. The techno-economic analysis suggests that these kinds of biomethanation plants are remunerative.

Biochemical methane potential of water hyacinth and the organic fraction of municipal solid waste using leachate from Mexico City’s Bordo Poniente composting plant as inoculum

In Mexico City, both the organic fraction of municipal solid waste (OFMSW) and the spread of water hyacinth among water bodies have been reported to increase greatly each year. These wastes have been associated with health problems and with the contamination of water bodies, soil, and air. Previous studies have demonstrated that water hyacinth and OFMSW can be sustainably managed using anaerobic digestion (AD) and anaerobic co-digestion (ACD) processes. In the present study, the biochemical methane potential of water hyacinth and OFMSW was determined. Leachate from Mexico City’s Bordo Poniente composting plant was used as inoculum, and the effects of two substrate-to-inoculum (S:I) ratios on volatile solids (VS) were investigated at lab-scale and under thermophilic conditions with a hydraulic retention time of 50 d. Based on S:I ratio, the AD of OFMSW with an S:I of 1:1 yielded more methane (387 ± 25 NLCH4/kgVSadded) than the ACD process (337 ± 15 NLCH4/kgVSadded), but not significantly (p > 0.05). Inoculum showed great potential to digest wastes used in this research. The ACD S:I ratio of 1:1 demonstrated that the AD process is both to produce renewable energy and to resolve problems associated with water hyacinth, OFMSW, and leachate.

Press-extrusion pretreatment of the organic fraction of municipal solid waste for enhanced methane production

Anaerobic digestion (AD) is a well-established process for the treatment of a wide variety of solid organic substrates, including the organic fraction of municipal solid waste (OFMSW). At industrial scale, the mechanical pretreatment is a fundamental step to reduce OFMSW particle size and to promote the hydrolysis within the subsequent AD process. Among the mechanical pretreatment technologies, press-extrusion has recently raised great interest for its possible application to either enhance the organic load to the digester or improve the overall process stability and methane yields. Aim of this study was in assessing the potential of the press-extrusion pretreatment to improve the performance of OFMSW anaerobic degradation. Batch tests were set up according to a full factorial design of experiments to assess the significance of the main operating parameters. The statistical analysis of results addressed further tests, carried out under semi-continuous feeding mode, to better discuss the possible application of press-extrusion for the greatest valorization of OFMSW under anaerobic conditions.

Anaerobic Co-Digestion Effluent as Substrate for Chlorella vulgaris and Scenedesmus obliquus Cultivation

Anaerobic digestate supernatant can be used as a nutrient source for microalgae cultivation, thus integrating phytoremediation processes with high value products storage in microalgae biomass. Microalgae are able to use nitrogen and phosphorous from digestate, but high nutrient concentration can cause growth inhibition. In this study, two microalgae strains (C. vulgaris and S. obliquus) were cultivated on the anaerobic co-digestion supernatant (obtained from the organic fraction of municipal solid waste (OFMSW) and waste activated sludge (WAS)) in a preliminary Petri plate screening at different dilutions (1:10 and 1:5) using a synthetic medium (ISO) and tap water (TW). Direct Nile red screening was applied on colonies to preliminarily identify hydrophobic compound storage and then a batch test was performed (without air insufflation). Results show that C. vulgaris was able to grow on digestate supernatant 1:5 diluted, while Nile red screening allowed the preliminary detection of hydrophobic compound storage in colonies. The analysis carried out at the end of the test on ammonia, phosphate, nitrate and sulphate showed a removal percentage of 47.5 ± 0.8%, 65.0 ± 6.0%, 95.0 ± 3.0% and 99.5 ± 0.1%, respectively.

Assessment of high-solid mesophilic and thermophilic anaerobic digestion of mechanically-separated municipal solid waste

Mechanically-sorted organic fraction of municipal solid waste (OFMSW) was tested to determine its biogas and biomethane generation efficiency. Methane production capability of OFMSW was examined in biochemical methane potential (BMP) tests. The factors affecting the high-solid anaerobic digestion (AD) of feedstock were investigated in a series of long-term semi-continuous digestion tests performed at dry mesophilic and thermophilic conditions in a continuously rotating drum reactor with working volume of 0.013 m3.OFMSW presented low biogas and methane generation capacity due to its contained non-biodegradable components and the low proteins and starch proportions. Dry mesophilic AD allowed only a relatively limited fraction of OFMSW volatile solids to be consumed for biogas and methane production. Reducing particle size favoured utilization of higher proportions of the available digestible organic substances, and concurrently promoted biogas and biomethane generation rate. Stability of methane generation was also significantly improved by particle downsizing. Small particles compensated the limited mass transfer and restricted distribution of methane production intermediate metabolites caused by water absence in the dry AD system. Dry thermophilic AD converted sufficient quantity of OFMSWs biodegradable content. The average methane released from dry thermophilic AD (0.176 m3kgVS−1) was higher than that of dry mesophilic AD of fine particles (0.148 m3kgVS−1) and much higher than that of dry mesophilic AD of same grain size (0.114 m3kgVS−1). High temperature proved more suitable for anaerobically digesting mechanically-sorted OFMSW.

Biopolymers modulate microbial communities in municipal organic waste digestion.

The development of biopolymers has raised issues about their recalcitrance in the environment. Their disposal is mainly carried out with the organic fraction of municipal solid waste (OFMSW) through thermophilic anaerobic digestion and aerobic composting, bioprocesses aimed at turning organic matter into biogas and compost. However, the effects of biopolymers on OFMSW treatment, on the final compost and on the microbial communities involved are partly unexplored. In this study, the OFMSW treatment was reproduced on a laboratory-scale respecting real plant conditions and testing the impacts of mixing polylactic acid (PLA) and starch-based bioplastic (SBB) separately. The dynamics of bacterial, archaeal and fungal communities during the process was screened by high-throughput sequencing (HTS) of phylogenetic amplicons. Starch-based bioplastic showed a minor and heterogeneous microbial diversity between the anaerobic and aerobic phases. Contrariwise, PLA treatment resulted in wider and more diverse bacterial and fungal communities for the compost and the aerobic biofilm. Since the biodiversity in compost may play a crucial role in its stability and safety, the modulation of environmental microbial communities induced by higher concentrations of PLA in OFMSW treatment can pose relevant issues.