Introduction. Gold ore pre-concentration is an urgent issue that can efficiently be solved by the technology of X-ray radiometric separation (XRS). Quarts and quarts-sulfide gold ore XRS is based on the methods of indirect sorting by gold accompanying chemical elements or genetic associate minerals laying the foundation for the creation of separation characteristics for these ores. Additional separation characteristics are required for efficient gold-quartz and gold-quartz-sulfide ore sorting; Irgiredmet Research Institute works on these characteristics search and development. Research methodology. Optimal ore separation characteristics for each specific deposit are chosen after studying and analyzing the spectral information acquired at XRF separators when detecting secondary characteristic radiation from each specific deposit ore samples. The recent modernization of XRF separators significantly enhanced the technological capabilities of XRS concerning intensive search and study of new separation characteristics for gold ore. It has been established that most ores can be efficiently sorted by three characteristics. Research results. A new method of gold ore XRS has been developed which consists of simultaneously applying three, two, or one decision criterion of a lump separation depending on the type, geologicalmineralogical properties, and material composition of the processed ore