Ordinary Portland Cement Paste Research Articles

Effect of test related factors on the degradation of cement-based materials on acetic acid exposure

Abstract Exposure of concrete to various acids can hardly be overstated due to the widespread use of concrete in the construction industry. The effect of selected factors on the degradation of ordinary Portland cement (OPC 53 grade) paste and mortar exposed to acetic acid is investigated in this paper. Various test parameters such as mass loss, loss in cross-sectional area, relative dynamic elastic modulus (RDEM), loss in flexural and compressive strength are used to assess the selected factors and the results obtained are analysed to determine the most favourable test conditions for degradation, that can be adopted for developing an accelerated test method. The factors used for the investigation are replenishment of acid solution, concentration of acid solution, ratio of surface area of specimen to volume of liquid acid solution (S/L), shape of the specimen and nature of the specimen. This paper also investigates the interrelationships among test parameters and adopts interpretation of acid consumption to assess the aggressiveness of the acid solution. It was found that renewing conditions and high concentrations of acid solution (0.5 M) indicate rapid degradation. The aggressiveness of 0.125 M acetic acid solutions in renewing conditions is about 5 times that of non-renewing conditions respectively. The rate of degradation is inversely related to S/L ratio. Cylindrical specimens have a marginal increase in degradation than prismatic specimens. It is preferable to evaluate acid attack on mortar specimens rather than paste specimens due to higher loss in cross-sectional area and relative dynamic elastic modulus (RDEM).

Physical and mechanical properties of special cementitious materials modified by nano-particles

Compared to ordinary Portland cement (OPC), sulphoaluminate/ferroaluminate cement (SAC/FAC) and aluminate cement (CAC) are the most promising repair materials due to their excellent early strengths, but the later strengths of SAC/FAC develop slowly, and the later strengths of CAC are obviously declined. This paper studied the effects of nano-SiO2 and nano-ZnO on the physical properties, mechanical properties and early hydration processes of three special cement-based materials and compared them with OPC-based materials. The strength development and early hydration mechanism were revealed by hydration heat, scanning electron microscopy and X-ray diffraction. The test results showed that with the increasing content of nano-SiO2, the setting time of the four cement pastes was gradually shortened, the fluidity of four fresh mortars was gradually reduced, and their compressive and flexural strengths at all ages were improved to different degrees. Nano-ZnO significantly prolonged the setting time of OPC paste and increased the fluidity of OPC mortar, which had a negative effect on its early compressive and flexural strengths, but enhanced its late strengths. After the addition of 1 % nano-ZnO, the initial and final setting time of OPC were about 12 times and 13.4 times that of ordinary OPC paste, respectively. The effect of incorporating nano-ZnO on the physico-mechanical properties of three special cements was similar to that of nano-SiO2. The strength loss of CAC mortar with two kinds of nanoparticles was greatly reduced. The incorporation of nano-SiO2 and nano-ZnO could promote the hydration process of three special cements, resulting in the denser microstructure and higher crystallinity of hydration products.

Recycling and optimum utilization of GFRP waste into low-carbon geopolymer paste for sustainable development

To provide an eco-friendlier alternative to traditional ordinary Portland cement (OPC) binder, this study utilized glass fiber reinforced polymer (GFRP) waste powder as a precursor material to prepare geopolymer paste (GP). Through a series of mechanical, thermal, and mineral admixture activation procedures, efforts are made to augment the reactivity of GFRP powder-based geopolymers. The research reveals that subjecting GFRP powder to a 30-min grinding process amplifies the compressive strength of GP by up to 37 %. Moreover, elevating curing temperatures to 60 °C leads to a substantial enhancement in the strength of GFRP powder-based GP, attributable to the formation of more amorphous N-A-S-H and C-(A)-S-H gels. However, prolonged grinding durations yield only marginal alterations in particle size, while curing at 80 °C demonstrates a detrimental effect on strength. The choice of resin exhibits a discernible impact on both workability and strength. Notably, pure glass fiber powder-based GP displays superior compressive strength but exhibits increased brittleness, whereas GFRP powder-based GP excels in flexural strength. Moreover, the inclusion of ground granulated blast furnace slag (GGBS) in the mixture accelerates setting time and reduces flowability of GFRP powder-based GP. Strength shows a positive correlation with GGBS content, although the impact on flexural strength is less pronounced compared to compressive strength. Life cycle assessment (LCA) showed GFRP powder-based GP with 50 % GGBS replacement had a 35 %–48 % lower Global Warming Potential (GWP)/strength ratio compared to OPC pastes. Furthermore, this formulation demonstrates a 15 % decrease relative to GGBS-based GP, and a reduction of 13 %–25 % compared to GGBS/Fly Ash (FA)-based GPs. These results underscore its potential as an environmentally preferable building material.

Detailed Analytical EPMA Study of the OPC Pastes Prepared with the Addition of Raw and Milled Fly Ashes

Concrete and cement pastes belong to the most used building materials in human history and represent a solidified mixture of ordinary Portland cement (OPC), water, course and fine-grained aggregates. Fly ash is used as a pozzolanic additive to improve concrete properties. The fly ash property can also be modified by various treatments such as milling or size reduction with sieving. It was suggested that a beneficial pozzolanic reaction with fly ash gives high mechanical properties. Such pozzolanic reaction results in calcium silicate hydrate (C-S-H) phase formation. In this research comparative analytical EPMA study of the paste samples prepared with the addition of the milled and non-milled fly ashes has been performed to elucidate the pozzolanic reaction of the OPC with the milled and non-milled fly ashes. A higher pozzolanic reaction with CSH phase formation was observed in milled fly ash added paste.

Study on the global and nano-scale characterization of heat-induced changes in ordinary Portland cement paste

Cement-based composite materials can be damaged by distributed micro-cracking and degradation of hydration products when exposed to sustained high temperatures. In this study, a nano-scale characterization tool (dynamic nanoindentation) and global mechanical methods (vibration resonance frequency and damping) are employed to better understand the degradation of ordinary Portland cement paste subjected to high temperature exposures. A connection between the methods is demonstrated.

Effect of ground granulated blast-furnace slag (GGBS) and sulphoaluminate cement (SAC) on the strength and microstructure of ordinary Portland cement paste at elevated temperatures

This study explored the potential of GGBS and SAC to enhance the thermal resistance of cement. The research explores changes in compressive strength and pore structure at various temperatures, employing microscopic analysis to elucidate underlying mechanisms. The results indicated that an optimal GGBS content enhanced strength, whereas SAC significantly reduced strength. The strength variation was not correlated with porosity or pore size distribution but rather with the hydration products of the blended cement. GGBS promoted the generation of C-A-S-H gels by introducing Al to replace Si in C-S-H gels, thereby increasing both the quality and quantity of gels. This enhancement suggested that GGBS improved thermal resistance by augmenting hydrate formation. SAC promoted ettringite formation even at high temperatures but reduced the quantity of hydrate gels, illustrating that SAC did not provide Al for the generation of C-A-S-H gels, consequently diminishing strength.

Comparison of thermogravimetry response of alkali-activated slag and Portland cement pastes after stopping their hydration using solvent exchange method

AbstractThe critical step for any subsequent instrumental analysis of cementitious binders is to stop their hydration reactions, i.e., to remove free water. One of the most available techniques is a solvent exchange method. However, the solvents are known to be strongly bound in ordinary Portland cement (OPC) paste and alter the results of thermogravimetric analysis (TGA) and sensitive hydrates, while their effect on TGA response of alkali-activated slag (AAS) has not been comprehensively investigated. Therefore, the objective of this paper is to track the effects of fundamental aspects of the solvent exchange on the TGA response of AAS with different sodium activators (hydroxide, carbonate, waterglass) and to support these results by X-ray diffraction and effluent gas analysis. All solvents used (acetone, diethyl ether, isopropyl alcohol, ethanol, and methanol) affected the TGA response of all tested pastes, and their effect was enhanced by prolonged immersion time. All solvents induced an additional mass loss at around 800 °C and, especially for OPC paste, increased in situ carbonation, even in an inert atmosphere. Methanol and ethanol had a detrimental effect on ettringite and decreased the basal distance of the C–(A)–S–H gel, while they only marginally affected gaylussite. For AAS, hydration stoppage by washing out the alkali-rich pore solution with water was also investigated and can usually be recommended (except for its detrimental effect on gaylussite), as it is more efficient than organic solvents, which lack solubility for activators. Methanol and ethanol are the most suitable alternatives, particularly for NaOH.

Impact of Ground Granulated Blast Furnace Slag on Calcium Leaching of Low-Heat Portland Cement Paste.

Low-heat Portland cement and ground granulated blast furnace slag are widely used for the preparation of hydraulic concrete. Nevertheless, the effect and mechanism of corrosion on low-heat Portland cement paste mixed with ground granulated blast furnace slag need to be further explored. This paper investigated the impact of ground granulated blast furnace slag on the calcium leaching of low-heat Portland cement paste by evaluating its mass loss, porosity, leaching depth, compressive strength, and Vickers hardness, and comparing it with the leaching performance of ordinary Portland cement paste. Furthermore, the phase composition and morphology of low-heat Portland cement paste containing ground granulated blast furnace slag were analyzed by X-ray diffraction, mercury intrusion porosimetry, and scanning electron microscopy. The results indicate that, after 180 days of soaking in ammonium chloride solution, the mass loss rate, growth rate of porosity, leaching depth, and compressive strength loss rate of low-heat Portland cement paste were 8.0%, 43.6%, 9.1 mm, and 27.7%, respectively, while those of ordinary Portland cement paste were 7.4%, 37.8%, 8.4 mm, and 30.1%, indicating that low-heat Portland cement paste is slightly more damaging than ordinary Portland cement. The addition of ground granulated blast furnace slag could significantly improve the leaching resistance of low-heat Portland cement. For instance, after adding 20% ground granulated blast furnace slag, the above test values were 2.4%, 28.5%, 5.6 mm, and 20.8%, respectively. The reason for this is that ground granulated blast furnace slag has the potential to reduce the porosity of low-heat Portland cement paste, and it can also undergo the secondary hydration reaction with its hydration product Ca(OH)2 to enhance the paste structure. Considering the cost performance, the suitable dosage of low-heat Portland cement paste for satisfactory leaching resistance is about 20%.

Development of innovative alkali activated paste reinforced with polyethylene fibers for concrete crack repair.

Concrete structures are susceptible to cracking, which can compromise their integrity and durability. Repairing them with ordinary Portland cement (OPC) paste causes shrinkage cracks to appear in the repaired surface. Alkali-activated binders offer a promising solution for repairing such cracks. This study aims to develop an alkali-activated paste (AAP) and investigate its effectiveness in repairing concrete cracks. AAPs, featuring varying percentages (0.5%, 0.75%, 1%, 1.25%, 1.5%, and 1.75%) of polyethylene (PE) fibers, are found to exhibit characteristics such as strain hardening, multiple plane cracking in tension and flexure tests, and stress-strain softening in compression tests. AAP without PE fibers experienced catastrophic failure in tension and flexure, preventing the determination of its stress-strain relationship. Notably, AAPs with 1.25% PE fibers demonstrated the highest tensile and flexural strength, exceeding that of 0.5% PE fiber reinforced AAP by 100% in tension and 70% in flexure. While 1% PE fibers resulted in the highest compressive strength, surpassing AAP without fibers by 17%. To evaluate the repair performance of AAP, OPC cubes were cast with pre-formed cracks. These cracks were induced by placing steel plates during casting and were designed to be full and half-length with widths of 1.5 mm and 3 mm. AAP both with and without PE fibers led to a substantial improvement in compressive strength, reducing the initial strength loss of 30%-50% before repair to a diminished range of 2%-20% post-repair. The impact of PE fiber content on the compressive strength of repaired OPC cube is marginal, providing more flexibility in using AAP with any fiber percentage while still achieving effective concrete crack repair. Considering economic and environmental factors, along with observed mechanical enhancements, AAPs show promising potential for widespread use in concrete repair and related applications, contributing valuable insights to the field of sustainable construction materials.

Effect of Solution-to-Binder Ratio and Molarity on Volume Changes in Slag Binder Activated by Sodium Hydroxide at Early Age.

This research investigates the impact of solution concentration and solution-to-binder ratio (S/B) on the volume changes in alkali-activated slags with sodium hydroxide at 20 °C. Autogenous and thermal strains are monitored with a customized testing device in which thermal variations are controlled. Consequently, both the autogenous strain and coefficient of thermal expansion (CTE) are determined. Heat flow and internal relative humidity (IRH) are also monitored in parallel, making this research a multifaceted study. The magnitudes of autogenous strain and CTE are higher than those of ordinary Portland cement paste. Decreasing the solution concentration or S/B generally decreases the autogenous strain (swelling and shrinkage) and the CTE. The shrinkage amounted to 87 to 1981 µm/m, while the swelling reached between 27 and 295 µm/m and was only present in half of the compositions. The amplitude of the CTE, which increases up to 55 µm/m/°C for some compositions while the CTE of OPC remains between 20 and 25 µm/m/°C, can be explained by the high CTE of the solution in comparison with water. The IRH of paste cannot explain the autogenous strain's development alone. Increasing S/B eliminates the self-desiccation-related decrease.

Selection of suitable cellulose nanofibers derived from eco-friendly sources for the production of lightweight cementitious composites with tuned rheological, mechanical, and microstructure properties

Different cellulose nanofibers (CNF) and ordinary Portland cement (OPC) were combined to prepare CNF-OPC composite pastes at different water to cement ratios (W/C) to optimize density, thermal conductivity, and mechanical strength. The rheological data of CNF-OPC composites showed that the viscosity and yield stress of the mixtures were abruptly increased in comparison to those of OPC pastes at equal W/C. Rheological and morphological data showed that the uniformity of the CNF and degree of fiber entanglement plays a significant role in tuning the composite properties. CNF suspensions with short fibers were observed to improve the mechanical properties of the composite while suspensions with entangled fiber networks were found to decrease density and thermal conductivity. Loss of flexural strength of CNF-OPC compared to OPC was found to be to a lesser extent than loss of compressive strength. The dry density and thermal conductivity of the CNF-OPC composites were substantially reduced to the range of 750 (kg/m3) and 0.1 (W/m−1K−1) at W/C = 2. CNF caused a reduction in peak temperature and postponed the hydration peak by more than 2 h compared to OPC.

Enhancing geopolymer binder reactivity and performance via mechanochemical activation: A comprehensive study of rheological, mechanical, and microstructural properties

In this study, mechanochemical activation was utilized to formulate an eco- and user-friendly geopolymeric binder. This method offers an alternative approach to address challenges inherent in conventional two-part geopolymers. The process involves milling solid-state raw materials with diverse compositions, followed by the addition of water solely to initiate the geopolymerization reaction. Comparative analyses were conducted using conventionally activated geopolymer (CAG) paste and ordinary Portland cement (OPC) paste. The study also investigates the effects of ground granulated blast furnace slag/fly ash (GGBFS/FA) ratios (50:50, 75:25, and 100:0) and sodium silicate/sodium hydroxide (SS/SH) ratios (0.5, 1.5, and 2.5) on the rheological, fresh, mechanical, and microstructure characteristics of mechanochemically activated geopolymer (MAG) paste. The experimental findings indicate that mechanochemical activation reduced rheological characteristics and setting time, accompanied by an 11% increase in strength compared to the conventional activation method. Additionally, increased GGBFS content positively influenced rheological characteristics and mechanical properties, whereas higher SS/SH ratios adversely impacted these aspects. Setting time was significantly reduced with higher GGBFS content but increased with higher SS/SH ratios. Microstructural analysis revealed the presence of additional unreactive particles in both conventionally activated geopolymer and MAG paste containing 50% GGBFS.

Research on mix design and mechanical performances of MK-GGBFS based geopolymer pastes using central composite design method

In order to alleviate environmental problems and reduce CO2 emissions, geopolymers had drew attention as a kind of alkali-activated materials. Geopolymers are easier access to raw materials, green and environment friendly than traditional cement industry. Its special reaction mechanism and gel structure show excellent characteristics such as quick hardening, high strength, acid and alkali resistance. In this paper, geopolymer pastes were made with metakaolin (MK) and ground granulated blast furnace slag (GGBFS) as precursors. The effects of liquid–solid ratio (L/S) and modulus of sodium silicate (Ms) on the performances of MK-GGBFS based geopolymer paste (MSGP) were characterized by workability, strength and microstructural tests. The regression equations were obtained by central composite design method to optimize the mix design of MSGP. The goodness of fit of all the equations were more than 98%. Based on the results of experiments, the optimum mix design was found to have L/S of 0.75 and Ms of 1.55. The workability of MSGP was significantly improved while maintaining the strength under the optimum mix design. The initial setting time of MSGP decreased by 71.8%, while both of the fluidity and 28-d compressive strength increased by 15.3%, compared with ordinary Portland cement pastes. Therefore, geopolymers are promising alternative cementitious material, which can consume a large amount of MK and GGBFS and promote green and clean production.

Influences of alumina type and sulfate content on hydration and physicochemical changes in Portland–limestone cement

This study explored the influence of alumina type and gypsum content on the hydration, mechanical properties, and chemical changes of Portland–limestone cement (PLC) using isothermal calorimetry, inductively coupled plasma-optical emission spectroscopy (ICP-OES), ionic chromatography (IC), compressive strength testing, X-ray diffraction (XRD), 27Al magic angle spinning nuclear magnetic resonance (27Al MAS NMR) spectroscopy, and mercury intrusion porosimetry (MIP) testing. The addition of alumina shortened the induction period, accelerated the acceleration period, and increased the mechanical strength of the PLC pastes with 3 and 7 wt% gypsum. The acceleration effect and strength enhancement were not distinct in the PLC pastes with less gypsum (0.1 wt%). The addition of γ-alumina led to the greatest accelerating effect and strength improvement in the PLC pastes with 3 and 7 wt% gypsum, and the compressive strength achieved was comparable to those of pure Ordinary Portland cement (OPC) pastes without limestone. The addition of γ-alumina induced the rapid dissolution of gypsum and consumption of sulfate ions. The chemical change affected by the addition of alumina varied greatly depending on the gypsum content, and trends in AFt and AFm formation in the PLC pastes with different gypsum contents were confirmed. Finally, pore size refinement was observed through the addition of alumina to PLC pastes with 3 and 7 wt% gypsum.

Experimental Study on Water-Plugging Performance of Grouted Concrete Crack.

In this paper, ordinary Portland cement, ultrafine cement, polyurethane, and epoxy resin were selected as typical grouting materials. Grouting simulation tests were first conducted to prepare the grouted concrete crack sample. The effect of concrete crack parameters (i.e., crack aperture and roughness), grout water-cement ratio, and grouting pressure on the water-plugging performance of different grouting materials was explored through the impermeability test. The microstructure of grouted concrete cracks was analyzed by means of scanning electron microscopy (SEM) and computed tomography (CT), and the difference in water-plugging performance of different grouting materials was explained at the micro level. The results show that the impermeability of the four grouting materials was ranked as follows: Epoxy resin > polyurethane > ultra-fine cement > ordinary Portland cement. The concrete cracks grouted by epoxy resin have the highest plugging failure water pressure and the lowest permeability, which is the optimal grouting material. The effectiveness of crack grouting in water-plugging was directly proportional to the grouting pressure, provided the pressure did not exceed a certain value. When the pressure surpassed the threshold, the increase in pressure did not have a significant impact on the water plugging performance. For the two cement-based materials, the threshold pressure was 1 MPa, while for the other two chemical grouts, it was 2 MPa. The two cement-based grouts with a water-cement ratio of 0.8 showed optimal water-plugging performance. The water-plugging performance of ordinary Portland cement paste, ultra-fine cement pastes, and polyurethane grout was negatively correlated with crack aperture and positively correlated with crack roughness. However, the water-plugging performance of epoxy resin grout was not affected by crack aperture or roughness.

The multi-objective optimization and mix parameter evaluation of one-part alkali-activated grouting material

To obtain a green and cost-effective one-part alkali-activated grouting material (OAGM) with good comprehensive performance for subgrade reinforcement and determine its proper mix parameters. In this study, using response surface methodology (RSM), multiple objective particle swarm optimization (MOPSO) algorithm and the technique for order preference by similarity to an ideal solution (TOPSIS) algorithm coupled with entropy weight method, two multi-objective optimization schemes for OAGM were performed, one only considering performance and another considering performance, embodied CO2 emission (ECO2e) and cost. Then, the correlation-based feature selection (CFS) algorithm was used to evaluate the importance of various molar ratios as mix parameters on the performance of OAGM. Finally, the effects of key mix parameters on the microstructure and reaction products of OAGM were studied. RSM results show that W/S (water to solid) ratio, borax (BR) content and UCG content chiefly govern the flowability, initial setting time and mechanical strength of OAGM respectively, and the interactions between some factors also significantly affect these properties. MOPSO and entropy-TOPSIS algorithm can be used to optimize OAGM objectively. Two optimal OAGM pastes both have better comprehensive performance and much lower ECO2e than ordinary Portland cement (OPC) paste. And the optimal OAGM considering performance, ECO2e and cost even has 7.68% lower cost than OPC paste. But another optimal OAGM has the best comprehensive performance. CFS results show that the molar ratios of Si/Al, Al/Ca, Na2O/H2O, B2O3/CaO and B2O3/Al2O3 are the key mix parameters of OAGM. Al/Ca rather than Si/Al is the most important mix parameter to the 28-day compressive strength. And higher Si/Al and Al/Ca deteriorates the microstructure and hinders the formation of C-A-S-H gel, while higher Na2O/H2O has the opposite effect. This study provides guidance for objective optimization and the determination of proper mix parameters of OAGM, and promotes the market-oriented application of OAGM.

Prediction of Hydration Heat for Diverse Cementitious Composites through a Machine Learning-Based Approach.

Hydration plays a crucial role in cement composites, but the traditional methods for measuring hydration heat face several limitations. In this study, we propose a machine learning-based approach to predict hydration heat at specific time points for three types of cement composites: ordinary Portland cement pastes, fly ash cement pastes, and fly ash-metakaolin cement composites. By adjusting the model architecture and analyzing the datasets, we demonstrate that the optimized artificial neural network model not only performs well during the learning process but also accurately predicts hydration heat for various cement composites from an extra dataset. This approach offers a more efficient way to measure hydration heat for cement composites, reducing the need for labor- and time-intensive sample preparation and testing. Furthermore, it opens up possibilities for applying similar machine learning approaches to predict other properties of cement composites, contributing to efficient cement research and production.

Determination of the maximum dissolution rates of the Belgian reference glasses at very alkaline pH and 30 °C

To assess the chemical durability of the Belgian reference glasses SON68, SM513, and SM539 under hyper-alkaline conditions, maximum glass dissolution rates were measured at 30 °C and pH 13.5 by performing Single-Pass Flow-Through tests with a KOH solution and a synthetic young cementitious water containing Ca (YCWCa). In both leachants, the highest dissolution rate was determined for the Al-rich glass SM539, while similar rates were found for SM513 and SON68 glasses, whose compositions are comparable. For all glasses, the dissolution rates in YCWCa were lower than in KOH due to the presence of Ca, which leads to the formation of a slightly protective calcium silicate layer. The dissolution rates in YCWCa were similar to those determined from glass monolith mass losses in static tests carried out at 30 °C in YCWCa in the presence of hardened Ordinary Portland Cement paste powder with a cement-to-glass ratio of 1.Graphical abstract

Effects of temperature on autogenous deformation and early-age stress evolution in cement pastes with low water to cement ratio

This paper investigates the influence of temperature on autogenous deformation and early-age stress (EAS) evolution in ordinary Portland cement paste using a recently developed Mini Temperature Stress Testing Machine (Mini-TSTM) and Mini Autogenous Deformation Testing Machine (Mini-ADTM). In the Mini-TSTM/ ADTM, CEM I 42.5 N paste with a water-cement ratio of 0.30 was tested under a curing temperature of 10, 15, 20, 25, 30, and 40 °C. X-Ray diffraction (XRD) tests were conducted to measure the amount of ettringite and calcium hydroxide, which reveals the micro-scale mechanisms of autogenous expansion. The applicability of the Maturity Concept (MC) for the prediction of autogenous deformation and relaxation modulus under different temperatures was also examined by the experimental data and the viscoelastic model. This paper leads to the following findings: 1) The autogenous deformation of ordinary Portland cement paste is a four-stage process comprising the initial shrinkage, autogenous expansion, plateau, and autogenous shrinkage; 2) Higher temperature leads to higher early-age cracking (EAC) risk because it accelerates the transitions through the first three stages and causes the autogenous shrinkage stage to start earlier. Moreover, higher temperatures also result in increased rates of autogenous shrinkage and EAS in the autogenous shrinkage stage; 3) Autogenous expansion and plateau are attributed to the crystallization pressure induced by CH. Temperature-dependent CH formation rates determine the duration of the plateau stage; 4) Low-temperature curing can delay but not completely prevent the EAC induced by autogenous deformation; 5) The MC cannot predict the autogenous deformation at different temperatures but can be used to calculate the relaxation modulus, which in turn aids in EAS prediction based on autogenous deformation data.

Formulation development of metakaolin geopolymer with good workability for strength improvement and shrinkage reduction

This study aims to optimize formulation and preparation of metakaolin based geopolymer for good workability, high compressive strength, and reduced drying shrinkage by considering alkaline activator composition, liquid to solid mass ratio, curing condition, and admixtures. The optimized geopolymer paste was further modified by granulated blast furnace steel slag (GBFS) and ordinary Portland cement (OPC) as calcium sources and carbon fibers as reinforcing additive for further strength improvement and shrinkage alleviation, in which the improvement mechanisms were manifested through mechanical strengths and microstructure observations. An optimized combination of modifiers and curing condition was obtained by Orthogonal Array Testing method. Experimental results indicate that sodium silicate is essential in the synthesis of alkali activator with nominal composition of Na2O·1.3SiO2·10.8H2O for strength development and cracking prevention. Good workability and high compressive strength of paste specimens could be attained by liquid to solid mass ratio of 1.21 between alkaline activator and metakaolin with ambient curing. The modified geopolymer pastes presented further improved compressive strength and reduced drying shrinkage. The microstructure images showed that the formation of cement hydration products, ettringite crystals, and more condensed matrix structure by using OPC as additive in geopolymer. The optimized geopolymer paste was made with 2% carbon fiber, 33% Portland cement and 10% GBFS and cured at ambient temperature achieved ultimate compressive strength of 73 MPa with reduced drying shrinkage. This ultimate compressive strength was 55% and 65% higher than non-modified geopolymer and ordinary Portland cement pastes, respectively, and was higher than 80% values in related studies.