Ordinary Portland Cement Mortar Research Articles

Study on the pore structure of eco-regenerated mortar using corn cob based on nuclear magnetic resonance

This study aims to investigate the influence of corn cob particles on pore structure of mortar. By using NMR technology, the pore parameters of fast-hardening sulfoaluminate cement mortar (SAC) and ordinary Portland cement mortar (PO) were measured and compared. The influence of corncob particles on the mechanical properties of eco-mortar was evaluated by uniaxial compression test. The results indicate that medium and large pores of both SAC and PO increases with corn cob particle, as well as the porosity. The fractal dimensions of harmful and multiple harmful pores are negatively correlated with the volume fraction of corn cob particles. The addition of corn cob particles reduced the overall fractal dimension of the mortar and decreased the complexity of internal pores. The probability density function of grayscale values transitions from being “thin and tall” to “short and wide”, with an increasing proportion of high grayscale values. This leads to an increase in the proportion of large pores within the mortar, resulting in a continuous deterioration of pore structure. The addition of corn cob particles greatly reduces the strength of SAC and PO, but the peak stress of SAC is higher than that of PO. When corn cob particle content is 30wt% and 50wt%, the peak stress of SAC is increased by 23.37% and 14.25%, respectively, compared with the peak stress of PO.

Flyash and coffee silverskin binary blended geopolymer

Exploring alternative precursors other than flyash, slag, metakaolin and palm oil fuel ash for geopolymer synthesis has become very essential owing to the need for reduction in cost and accumulation of solid waste that could contribute to environmental pollution. The use of coffee silverskin (CSS) in binary blending with flyash (FA) in geopolymer synthesis is not yet fully understood, although its performance in ternary blending with silica fume for ordinary Portland cement (OPC) mortar has been established. Thus, binary blended CSS (0–30 %) with FA - such that CSS/(FA+CSS) varied from 0 to 0.3 - was activated by sodium hydroxide (8MNaOH) and sodium silicate (Na2SiO3), and then subsequently cured at 60 °C. Mechanical property, binder morphology, compound product phases and bond characteristics were studied through compressive strength test, scanning electron microscope (SEM/EDS), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIRS), respectively. CSS (CSS/(FA+CSS) = 0.3) significantly contributed to strength loss due to microcracks, carbon content and fiber induced microstructural discontinuity, such that 7-,14-and 28-d strengths recorded were 5.2, 7.8 and 9.7 MPa, respectively. Maximum 28-day strength of 16.5 MPa was recorded in CSS/(FA+CSS) = 0.1. CSS caused the formation of monetite, and disappearance of muscovite and augite in flyash/coffee silverskin based (FACSS) geopolymer.

Influence of graphene nanoplatelets on the passivation and corrosion resistance of carbon steel bars in ordinary portland cement mortar

This study investigates the influence of adding graphene nanoplatelets (GNPs) to mortar mixtures on the corrosion behavior of embedded carbon steel rebars. Mortar mixtures were prepared with a water-to-cement ratio of 0.42 and GNP replacement levels of 0, 0.05, and 1 percent by weight of cement. After 28 days of curing in an environmental chamber, the passivity and kinetics of chloride induced corrosion initiation for the rebars were studied using a suite of electrochemical tests. The results suggest that incorporating GNPs at low concentrations may enhance the passivity and resistance to chloride-induced corrosion of carbon steel rebars; however, due to the large variability in the data, the findings are inconclusive. Potentiodynamic measurements revealed that the estimated average polarization resistance of steel rebars in 0 G (no GNP), 0.05 G, and 1 G specimens in the passive state was on average −182.3, −276.5, and −304.2 kΩ, respectively. Upon exposure to chloride solution, 0 G specimens, with an average corrosion potential of −600 mV vs. SCE, exhibited the lowest resistance, whereas 0.05 G specimens, with an average of −491 mV vs. SCE, showed the highest corrosion resistance. Results from electrical impedance spectroscopy were consistent with the potentiodynamic findings. Surface characterization also revealed that the inclusion of GNPs does not alter the surface roughness of the interface between steel rebar and paste. However, the interface between rebar ribs and mortar paste had higher surface roughness and porosity in all specimens regardless of GNPs replacement level. Visual inspections confirmed that the area around the rebar ribs at the interface is more conducive to the formation of crevice and pitting corrosion.

Performance enhancement, life cycle assessment, and feature analysis of wheat starch-based NaCl-binder as a sustainable alternative to OPC mortar

The primary aim of this investigation is to advance the properties of an innovative and sustainable wheat starch-based NaCl-binder (WSB) material. The scope encompasses the material's ecological and structural applications and potential for paving usage. The creation of hydrophobic and environmentally friendly WSB samples under microwave curing conditions was achieved by using a salt mortar with varying sizes of salt grains, water, and wheat starch as a binding agent. This study investigated the effects of curing time, water and starch amounts, and salt particle size on strength, modulus of rupture, and modulus of elasticity. Additionally, XRD, XRF, and SEM analyses were carried out to assess the chemical characteristics of WSB and the bonding between its particles. The mix design with the highest compressive strength, which consisted of 1 wt% starch, 8 min of microwave treatment, and 10 wt% water, attained a strength of 25.27 MPa. Furthermore, coconut oil was employed to effectively make the samples water-resistant. Following different guidelines, WSB could be categorized as structural concrete and utilized for structural and paving bricks. A vital aspect of this study is the exceptional environmental performance of WSB as a structural material, highlighting its originality and importance.

Study on the Chloride–Sulfate Resistance of a Metakaolin-Based Geopolymer Mortar

The chloride–sulfate corrosion environment of concrete is a significant engineering problem. This paper investigates the effect of the complete/semi–immersion mode on the durability of concrete in a chloride–sulfate environment by using different granulated blast furnace slag (GBFS) dosage rates (10–50%) of a metakaolin (MK)-based geopolymer mortar. The chloride–sulfate corrosion environment is discussed by analyzing the apparent morphology, mass change, and mechanical property change in specimens at the age of 120 d of erosion combined with XRD and SEM. The high Ca content in GBFS has an important effect on the strength and erosion resistance of the metakaolin geopolymer (MGP) group mortar; an increase in the GBFS dosage makes the MGP group mortar denser, and the initial strength of the MGP group mortar is positively correlated with the dosage of GBFS. After 120 d of erosion, the GBFS dosage is negatively correlated with erosion resistance, with the high GBFS dosage groups showing more severe damage. Semi-immersion resulted in more severe deterioration at the immersion–evaporation interface zone due to the difference in the ionic concentration and the ‘wick effect’ at the immersion–evaporation interface zone. Compared with the commonly used OPC mortar, the M40 and M50 groups have improved strength and corrosion resistance and are suitable for engineering environments in highly erosive areas.

Study on optimization of mixing ratio and shrinkage property of alkali-activated ultrafine fly ash-slag mortar

Alkali-activated cementitious materials have received widespread attention due to their favorable mechanical properties and environmental benefits. However, there are fewer studies on the optimal mixing ratio of alkali-activated ultrafine fly ash-slag (AAUS) mortar, and shrinkage cracking is a critical issue that hinders its further application. Based on this, the study used the response surface method (RSM) to optimize the mixing ratio of AAUS mortar, explored the effect of basalt fibers (BF) on the compressive strength and drying shrinkage of AAUS mortar, and finally analyzed the energy consumption and carbon emission of fiber-reinforced AAUS mortar. The experiment used X-ray diffraction (XRD) and scanning electron microscopy (SEM) techniques for microstructural characterization to research the microstructure and mineral phase changes of AAUS mortar. The results demonstrated that the 28d compressive strength of AAUS mortar reached its maximum when the substitution ratio of ultrafine fly ash (UFA) was 14.5%, the alkali equivalent was 10.34%, and the modulus of the activator was 1.6, based on the RSM; BF of appropriate length and volume fraction can productively improve the compressive strength of AAUS mortar and limit drying shrinkage; AAUS mortar with optimal mixing ratio can be sufficiently activated by alkali activator to construct a considerable number of C-(A)-S-H gels to establish a high-density microstructure; the carbon emission of the B124 test group was reduced by 61.1% compared with ordinary Portland cement (OPC) mortar.

Physical and mechanical properties of special cementitious materials modified by nano-particles

Compared to ordinary Portland cement (OPC), sulphoaluminate/ferroaluminate cement (SAC/FAC) and aluminate cement (CAC) are the most promising repair materials due to their excellent early strengths, but the later strengths of SAC/FAC develop slowly, and the later strengths of CAC are obviously declined. This paper studied the effects of nano-SiO2 and nano-ZnO on the physical properties, mechanical properties and early hydration processes of three special cement-based materials and compared them with OPC-based materials. The strength development and early hydration mechanism were revealed by hydration heat, scanning electron microscopy and X-ray diffraction. The test results showed that with the increasing content of nano-SiO2, the setting time of the four cement pastes was gradually shortened, the fluidity of four fresh mortars was gradually reduced, and their compressive and flexural strengths at all ages were improved to different degrees. Nano-ZnO significantly prolonged the setting time of OPC paste and increased the fluidity of OPC mortar, which had a negative effect on its early compressive and flexural strengths, but enhanced its late strengths. After the addition of 1 % nano-ZnO, the initial and final setting time of OPC were about 12 times and 13.4 times that of ordinary OPC paste, respectively. The effect of incorporating nano-ZnO on the physico-mechanical properties of three special cements was similar to that of nano-SiO2. The strength loss of CAC mortar with two kinds of nanoparticles was greatly reduced. The incorporation of nano-SiO2 and nano-ZnO could promote the hydration process of three special cements, resulting in the denser microstructure and higher crystallinity of hydration products.

Carbon nanofibers encapsulated by polyethylene glycol increase the mechanical properties and durability of OPC mortars

Carbon nanofibers (CNF) are promising additives for the reinforcement of cementitious materials. However, due to their high specific surface and hydrophobic nature, CNF are difficult to disperse in ordinary Portland cement (OPC) mortars when using conventional plasticizers. In this work, we evaluate the production of mortars with CNF encapsulated by a thin layer of polyethylene glycol (PEG) covalently grafted at their surface (CNF@PEG). CNF@PEGs were chemically prepared using two methods with PEG of various molecular weights. In all cases, the dispersion of the CNF@PEG in water as well as in a simulated cement pore solution was improved. Remarkably, mortars fabricated with CNF@PEG4k (PEG of molecular weight 4000 g/mol) exhibited a 20 % increase in compressive strength, 10 % increase in flexural strength and 25 % increase of the Young's modulus measured after 7 days, in comparison to a reference mortar. Finally, electrochemical impedance spectroscopy (EIS) was used to assess the ionic resistivity of the mortar. Mortars containing CNF@PEG4K had an ionic resistivity 43 % higher than the reference sample at 28 days leading to better durability. These results demonstrate that encapsulation of CNF by PEG is a successful strategy to improve the mechanical performance and durability of CNF-containing OPC mortars.

Impact of exposure conditions on alkali-silica reaction in alkali-activated material systems

The influence of different testing methods on alkali-silica reaction (ASR) behavior is a result of the difference in the effect of exposure conditions on it. This study investigated the impact of temperature and the addition of alkali on ASR behavior in an alkali-activated material (AAM) system and compared it with an ordinary Portland cement (OPC) system. The results showed that the ASR in the AAM system was more independent of the exposure conditions than that in the OPC system because of its inherently high alkalinity and dense microstructure. More ASR products with higher Na:Si ratios were evident in the alkali-activated slag (AAS) mortars than in the OPC mortars. The accelerated test conditions developed for OPC systems could be applied to AAM systems. However, owing to the difference in the acceleration effect, comparing the ASR-induced expansion in OPC and AAM systems using the accelerated test method was misleading to some extent. This study contributes to the understanding of the ASR in AAM systems and is of considerable importance for the industrial application of AAMs.

Microstructural analysis and densification of ordinary Portland cement mortars incorporated with minimal nano-TiO2: intermixing and surface coating on both fresh and hardened surfaces

The present study investigated the microstructural properties of ordinary Portland cement (OPC)-modified with minimum dosage of nano TiO2 on fresh and hardened cement mortar surfaces and intermixed samples. X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDX) were used to analyze the morphology and hydration products of the OPC specimens doped with nanotitanium (NT).Additionally, XRD coupled with Rietveld refinement was employed to quantify the crystal phases and refine the crystal structure model through the comparison of the calculated diffraction pattern to the measured pattern. Subsequently, crystallographic analysis was conducted to evaluate the crystallographic structure and to confirm the existence of specific atoms and bonds within the crystal structure altered with NT. The findings revealed that the addition of minimal NT resulted in a more compact and denser microstructure, characterized by increased formation of calcium silicate hydrate (CSH) gel and a reduction in calcium hydroxide (CH) crystals.This led to a reduction in the porosity of the hardened coating surface, with similar improvements observed for the fresh coating and intermixed samples compared to those of the control mortar. A decrease in the lattice parameters, accompanied by an increase in the number of atoms, bonds and polyhedra in the crystal structure, led to alterations in the interatomic spacing and contributed to the densification of the cementitious matrix.The findings also showed that NT integration led to a more compact structure with shorter bond distances and smaller polyhedral volumes for the Ti samples than for the control sample. Moreover, compared with the freshly cast and hardened coating samples, the NT-intermixed samples exhibited the shortest Ti–O bond distances and the smallest polyhedral volume. Overall, the analysis presented in this study significantly contributes to the development of novel and environmentally friendly photocatalytic cementitious materials at minimal dosages.

Synthesis of eco-sustainable seawater sea-sand geopolymer mortars from ternary solid waste: Influence of microstructure evolution on mechanical performance

To fully utilize abundant marine resources and reduce the carbon footprint in the construction sector, this study developed a seawater sea-sand geopolymer mortar (SSGM) using seawater, sea-sand, and ternary solid waste. Three different alkaline content levels (4%, 5%, and 7%) were tailored for the SSGM, in addition to freshwater river sand mixed geopolymer mortars (FRGM), seawater sea-sand ordinary Portland cement mortar (SSCM), and SSGM without additional fibres (SSGM-0). The workability, setting time, mechanical performance, and drying shrinkage of all samples were studied. The microstructural characteristics of each mortar were meticulously scrutinized through techniques including X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, and mercury intrusion porosimetry (MIP). The results showed that as alkaline content increased, SSGM formed more hybrid sodium, calcium aluminosilicate hydrate (N, C-A-S-H) gels, resulting in a denser matrix. Under the influence of magnesium ions and sulfate ions in seawater, the formation of magnesium aluminosilicate hydrates, magnesium silicate hydrates, and silica gels filled the pores, making SSGM has more mesopores and gel pores compared to FRGM, thus exhibiting superior mechanical properties. However, the Ca/Si ratio of the primary hydration products of SSGM was lower than that of SSCM and FRGM, indicating a more disordered microstructure of SSGM, leading to greater shrinkage. Despite moisture migration reaching a stable state, SSGM exhibited persistent shrinkage, revealing their inherent time-dependent (creep) response to drying conditions, indicative of typical viscoelastic/visco-plastic matrix behavior.

Reinforcing steels in low-carbon mortars subjected to chloride attack and natural carbonation: Contradictory trends in passivation ability and corrosion resistance

After a 7-year exposure to simulated marine environments with chloride attack and natural carbonation, the passivation ability and corrosion resistance of carbon steel and 2304 duplex stainless steel in two types of low-carbon mortars, designed with alkali-activated slag and Bayer red mud, were investigated, which were compared with those observed in ordinary Portland cement (OPC) mortar. Although a reduced passivation ability was confirmed for steels in the low-carbon mortars, an improved corrosion resistance was highlighted after long-term exposure. Accordingly, the underlying mechanisms for the detrimental impacts and beneficial effects on the corrosion resistance of steels provided by these low-carbon mortars were discussed in terms of pore solution chemistry, pore structure as well as electrical resistivity, which will shed new lights on the design of novel cementitious materials with low carbon footprint and high corrosion protection.

Utilization of industrial waste sodium sulfate for calcined clay-based sustainable binder

This study explored the utilization of industrial waste Na2SO4 to develop a calcined clay-based sustainable cementitious composite inspired by ancient Roman concrete. Na2SO4 with or without the addition of NaCl was utilized, keeping the total Na2O quantity constant, and their performances at the macro and micro scale were compared. A separate set of samples was prepared using seawater. A medium-grade calcined clay, along with lime, was utilized as the binder. The salts were first dissolved in water and then used as the mixing water for sample preparation. A diverse array of characterization methods was utilized, encompassing thermogravimetric analysis, chemical extraction, X-ray diffraction (XRD), and Backscattered Scanning electron microscopy (SEM). It was observed that the salt-containing batches achieved compressive strength faster than the seawater samples. However, the strength remained in a comparable range (∼30 MPa) for all the samples after 28 days of curing. The initial strength of salt-containing samples was attributed to the formation of gypsum, ettringite, and hydrocalumite. Additionally, the geopolymer gel and calcium aluminum silicate hydrate (C-A-S-H) gel phases were present in all samples. Finally, this study also showed that lime-clay mortars can achieve a reduction in carbon footprint of up to 50 % compared to ordinary portland cement (OPC) mortars.

Bonding Performance and Microstructural Mechanism between Rapid Repair Materials and Old Concrete Pavement

In China, airports predominantly utilize airport cement concrete pavement, which inevitably undergoes deterioration in service. To uphold pavement durability and functionality, and ensure aircraft operational safety, prompt repairs of affected areas are imperative. Therefore, ordinary Portland cement mortars were used as the control group to compare and analyze the bonding performances of two common airport pavement repair materials: modified Portland cement mortars and phosphate cement mortars. Meanwhile, through microscopic experiments, the microscopic characteristics of the interfacial transition zone (ITZ) were studied, and the interface bonding mechanism was analyzed. The research results indicate that the interface bonding strength between phosphate cement mortar and old concrete pavement is the highest. This was because the elements in phosphate cement penetrated the old concrete pavement through hydration reactions, forming van der Waals forces and chemical bonding forces. In addition, the research results indicated that the presence of old concrete pavement made the three repair materials produce similar sidewall effects with the old concrete pavement, leading to a low hydration degree of the repair materials. However, the chemical bonding and penetrating structure of phosphate cement compensated for the weakening effect of the ITZ in the repair materials.

Engineering properties as a supplement cementitious material of ground copper reduction slag extracted valuable metal from Cu slag

We have examined whether the copper reduction slag (CRS) generated after recovering valuable metals from copper slag (CS) by reduction process can be used as supplementary cementitious materials (SCMs). According to the test results, the Cu secondary slag with low Fe, Cu, and heavy metal contents had a suitable oxide composition for using as a SCM. CRS showed better grinding efficiency than that of ground blast furnace slag (GGBS). Ground CRS contributed to the formation of tobermorite under autoclaved curing conditions. The compressive strength of CRS mortar replacing 50 % of OPC generated 93 % of that of the OPC mortar. Based on the results of this study, we found that the CRS has highly appropriate engineering characteristics for using as SCMs for concrete. In addition, it is judged that the method of using secondary slag as a material for precast concrete produced under hydrothermal conditions can greatly contribute to the construction process of buildings by securing mechanical performance.

Reuse of waste rockwool for improving the performance of LC3-based mortars made with natural and recycled aggregates for sustainable building solutions

The objective of this study is to investigate the effect of waste rockwool (RW) addition on the thermo-physical, mechanical, and fire resistance properties of limestone calcined clay cement (LC3)-based mortars. LC3 binder has been produced by replacing 60 wt% of OPC with limestone (LS) powder and metakaolin (MK) at a percentage of LS to MK of 1:2 (wt%). Waste RW was added at various ratios of 1, 3 and 5 % (by weight of binder) into two types of LC3-based mortars made with natural sand (NS) and ferrochrome waste slag (FCS) aggregates with a binder-to-aggregate vol% of 1:3. Upon the addition of 5 wt% of waste RW, significant enhancements of about 19 % and 21 % were obtained for the compressive strength of NS and FCS mortars, respectively, and attributed to the improved physical packing. After exposure to standard fire for 1 h with a maximum applied temperature of 945 °C, residual strengths of about 57.5 % and 63.8 % have been maintained by the sand and FCS-blended LC3 mortars, respectively. Generally, the incorporation of RW led to a slight increase in the thermal conductivity of both types of mortars; however, the FCS-blended LC3 mortar possessed relatively higher increment rates as compared with the sand mortar, which is helpful in improving the thermal performance in hot climate regions. Remarkable improvements in the microstructure characteristics in terms of compactness, uniformity, and interfacial transition zone (ITZ) tightness were attained by RW addition. Lifecycle assessment (LCA) results demonstrated that about 38–45 % lower carbon emission is associated with the designed LC3-based mortars than the conventional OPC mortar.

How does carbonation of alkali-activated slag and Portland cement systems impact steel corrosion differently?

Carbonation of cementitious materials, associated with neutralization of pore solution, is one of the prevalent reasons for inducing corrosion of steel in concrete. Compared with ordinary Portland cement (OPC) concrete, the poorer carbonation resistance of alkali-activated slag (AAS) concrete leads to serious durability concerns of a higher risk of steel corrosion. This work investigates the corrosion behaviors of steel embedded in intact and carbonated AAS and OPC mortars exposed to various relative humidity conditions, with the aim of fostering a better understanding of how carbonation impacts steel corrosion differently in these two cementitious systems. The results show that uncarbonated AAS mortars have better protective ability against corrosion than OPC counterparts; however, poorer performance after complete carbonation. It is mainly attributed to the combined effect of severe deterioration and coarsening of pore structure and increased ratio of chloride ion concentration to hydroxide ion concentration ([Cl−]/[OH−]) in pore solution, resulted from the consumption of hydroxide ions and release of bound chloride after carbonation. Besides, the different shifts of R-C (material resistivity versus corrosion rate) relationship lines in AAS and OPC mortars after carbonation are observed, which is ascribed to the different compositional and microstructural evolutions induced by carbonation in these two cementitious systems.

Study on the rheology, mechanical properties and microstructure of polypropylene fibers in different binder systems

To explore the effects of polypropylene fiber (PPF) on the properties of different binder materials, the effects of PPF on the rheology, shrinkage, mechanical properties and microstructure of alkali-activated mortar (AAM) and ordinary Portland cement mortar (PCM) were studied. The results showed that the addition of PPF reduced the fluidity of the mortar, and the lower the initial yield stress and plastic viscosity of the paste were, the more obvious the increase. PPF reduced the drying shrinkage of both the AAMs and PCMs by 7.63–12.85 %. The inclusion of PPF to the mortar had a limited effect on enhancing the mortar compressive and flexural strength, but it notably improved the mortar toughness. At a fiber content of 0.5 %, the samples from the cement and slag-steel slag systems exhibited a more compact of the interfacial transition zone (ITZ) between the fiber and paste. Conversely, the slag-steel slag-fly ash and slag-fly ash systems showed poorer compact of the ITZ, which was attributed to increased unreacted precursors and shrinkage cracks. This phenomenon primarily accounted for the superior residual stresses observed in the cement and slag-steel slag systems. This study provides an avenue for analysis the effect of the same fiber on different binder systems.

Study on the Properties of Belite Calcium Sulfoaluminate Cement–Ordinary Portland Cement Composite Cementitious System

Due to low early strength and high shrinkage, ordinary Portland cement (OPC) has difficulty meeting the actual needs of modern construction projects, while belite calcium sulfoaluminate cement (BCSA–OPC) composite cement provides a new solution. The mechanical and the drying shrinkage properties of the BCSA–OPC mortar were determined, the hydration heat of the BCSA–OPC was studied, and the pore size distribution of the mortar was investigated. In addition, the hydration products of the BCSA–OPC were analyzed by X-ray diffraction (XRD) and simultaneous thermal analysis (TG-DSC), and the microscopic morphology of the BCSA–OPC mortar was observed by scanning electron microscopy (SEM). The results show that with the increase in BCSA dosage in the BCSA–OPC, compared with OPC, the flexural strengths of the mortar of 50% dosage of BCSA at the hydration age of 1 d, 3 d, 7 d, and 28 d are improved by 33.3%, 36.6%, 23.6%, and 26.8%, and the compressive strengths are improved by 50.8%, 35.7%, 13.4%, and 27.7%. The drying shrinkage and total porosity of the mortar at the hydration age of 28 d are reduced by 117.4% and 21.55%, respectively. It is attributed to the filling effect of a large amount of ettringite (AFt) and intertwined with the fibrous C-S-H gel to form a network. This study will provide a theoretical basis for the application of the BCSA–OPC engineering.

Fabrication and Mechanical Evaluation of Eco-Friendly Geopolymeric Mortars Derived from Ignimbrite and Demolition Waste from the Construction Industry in Peru

Ignimbrite rock is a volcanic material located in the Arequipa region (Peru), and for centuries, it has been used as a construction material, giving a characteristic light pastel, white to pink color to the city of Arequipa, with white being the most common. In the present study, the potential use of three types of Arequipa raw materials (ignimbrite rock powder, calcined clay powder, and demolition mortar powder) as the main source of new binders or the manufacture of environmentally friendly mortars, without the addition of ordinary Portland cement (OPC) is discussed. In this work, an in-depth characterization of the materials used was carried out. The proposed fabrication route for geopolymeric materials was considered for the manufacture of binders and mortars using an alkaline solution of NaOH with values between 12 and 18 molar, as a trigger for the geopolymerization process. Geopolymeric mortars were obtained by adding a controlled amount of fine sand to the previously prepared mixture of binder raw material and an alkaline solution. Conventional OPC and geopolymeric mortars manufactured under the same conditions were mechanically evaluated by uniaxial compression tests at a constant compression rate of 0.05 mm/min and under normal conditions of temperature and atmosphere, where the most optimal values were obtained for 15 molar alkaline solutions of ignimbrite without the addition of aggregates, with values of compressive strength of 42 MPa and a modulus elastic of 30 GPa. The results revealed a significant increase in the maximum strength and modulus of elasticity values when the volumetric fractions of OPC are completely replaced with geopolymeric binders in the study conditions of this work, demonstrating the enormous potential of the ignimbrite rock and construction waste studied, as raw material of alternative mortar binders without the addition of OPC. With this work, the ignimbrite rock, of great value in the region and also found in other areas of the Earth’s geography, was characterized and valued, in addition to the calcined clay and demolition mortar of the region.