Yellow Orange Research Articles

Cost-effective production of kombucha bacterial cellulose by evaluating nutrient sources, quality assessment, and dyeing methods.

Kombucha is a popular fermented beverage that involves fermentation using a symbiotic culture of bacteria and yeast (SCOBY) and produces bacterial cellulose (BC). Carbon and nitrogen sources are essential in kombucha processing and BC production. However, studies on cost-effective BC production as an alternative source of leather have remained scarce. This study aimed to assess the effects of various nitrogen and carbon sources on the production of kombucha BC, investigate the qualities, and dye the product using natural colorant. Different nitrogen sources (such as black tea, white tea, and green tea) and carbon sources (honey, sugar cane, palm sugar, and brown sugar) were used to produce kombucha BC, as well as to appraise the product qualities, which were dyed using three distinct natural dyes (coffee, ginger, and sappan wood). The results revealed that different nitrogen and carbon sources produced different BC with different properties. Green tea (N-source) and palm sugar (C-source) containing medium produced a BC thickness of 0.194 ± 0.04mm with the highest tensile strength (24.42 ± 3.90g). Different dyes also result in the fabric having different colors: brownish yellow (coffee), yellowish orange (ginger), and red (sappan wood). All BC products showed color stability after 8months of storing at room temperature. In conclusion, effective BC production could use green tea and palm sugar as the best nitrogen and carbon sources, respectively. Dyed BC showed good visual quality and is promising for its eco-friendly and sustainable application in fashion products.

Adjustable emission color by gadolinium tungstate phosphor for multiple applications

Crystalline monoclinic structure Gd2(WO4)3 phosphors were prepared by calcining a co-precipitated precursor at 800°C. The XRD patterns exhibited strong signals at the (-221) and (023) planes. The UV-vis absorption spectrum showed strong absorbance in the UV range, with an estimated bandgap energy of about 4 eV. When excited the synthesized phosphors emitted green (Tb3+), red (Eu3+), yellow (Dy3+), and reddish orange (Sm3+), respectively. Utilizing these luminescent properties, flexible composite sheets were fabricated by mixing the phosphors with PDMS. When applied to UV-LED chips. The composites could be molded into various shapes figures. Under normal light, the composites appeared white, but under UV light, they displayed distinct colors, demonstrating their potential for anti-counterfeiting applications. Additionally, when the synthesized phosphor powder was sprinkled onto a glass substrate with fingerprints and illuminated with a UV lamp, the unique features of the fingerprints were clearly visible, indicating potential use in forensic fingerprint analysis.

Fabrication and adsorption characteristics of cuprammonium cellulose-based membranes for removing anionic and cationic dyes

A cotton linter-based source was used to form conjugate electrospun membranes composed of cuprammonium cellulose, polyethylene oxide, and polyacrylonitrile for the removal of the anionic and cationic dyes from aqueous media. The highest removal efficiencies of 94 %, 89.9 %, 87.4 % were achieved for the anionic dyes Congo red (CR), Metanil yellow (MY), and Methyl orange (MO), respectively, and less so on the cationic dyes Crystal violet (CV), and Rhodamine B (RB) were 55.8 % and 15.1 %, respectively. The pseudo-second-order model effectively described the adsorption kinetics for both types of dyes. The composite membrane exhibited adsorption behaviors following the Dubinin-Radushkevich (D-R) isothermal model. Thermodynamics study suggests that the adsorption process was spontaneous except for the RB dye. The activation energy values of CR, MY, MO, CV, and RB dyes were 27.65, 21.17, 11.50, 10.47, and 71.12 kJ/mol, respectively, confirming the physisorption phenomenon for CR, MY, MO, and CV dyes, while chemisorption occurs for RB dyes. This study investigates the potential of a conjugate electrospun membranes as a reusable adsorbent for dye removal. The effects of solution pH, temperature, and dye concentration on adsorption performance were systematically evaluated. The conjugate electrospun membrane efficiency declined by only 10 % after undergoing five adsorption/desorption cycles.

Pengaruh Aplikasi Pupuk NPK Terhadap Pertumbuhan dan Produksi Tanaman Wortel (Daucus carota L.)

Indonesia is one of the tropical countries that has a variety of plants including vegetables and fruits. One that has the largest production is carrots (Daucus carota L.). Carrots are a type of shrub-shaped vegetable plant, which grows upright with a height of 30-100 cm or more. Carrots (Daucus carota L.) are a tuberous vegetable type plant that is usually reddish yellow or yellowish orange with a wood-like texture. The edible part of a carrot is the bulb or root. The plant stores food reserves in the bulb. The stem is short, has a taproot that changes its shape and function into a round and elongated tuber. The skin of carrot bulbs is thin and if eaten raw, it feels crunchy and slightly sweet. Here's a picture of a carrot plant. One way to increase the yield of carrot plants is by increasing soil productivity, using the addition of NPK fertilizer. This study used a factorial randomized group design (RAK). For accuracy in this study, it was repeated 3 times. namely: NPK fertilizer (N) with 3 levels, namely: N0 = Control, N1 = 15 g/plot, and N2 = 25 g/plot. From the ANOVA test results, the variance of treatments that have a significant effect is continued with the Duncan DMRT test at the 5% level. The results of the ANOVA test showed that the effect of NPK fertilizer treatment on plant height 21 hst and 28 hst, the number of leaves had no significant effect, but the observation of the diameter of the base of the tuber, the fresh weight of the plant per sample and the fresh weight of the plant per plot had a significant effect. Keywords: NPK fertilizer, NPK dosage, and carrot plants

Physical properties, nutritional profile, and consumer acceptability of gluten-free breakfast flakes from cassava flour

Driven by the increasing demand for gluten-free and affordable breakfast options, this study investigated the potential of cassava flour, as a primary ingredient and gluten-free alternative, for producing extruded breakfast flakes. Cassava flakes were prepared using a twin-screw extruder at a constant screw speed of 35 rpm, constant cutter speed of 21.2 rpm and barrel temperatures of 81 °C, 93 °C, and 89 °C in the first, second, and third zones, respectively. The physical properties, nutritional profile, and consumer acceptability of the cassava flakes were compared to a commercially available breakfast cereal. Cassava flakes exhibited significantly different (p < 0.05) physical properties. They had a higher WSI (57.6 %) but lower values of bulk density (0.3 g/cm3), WAI (2.3 g g-1), and color value (yellow orange ±1.73). Cassava flakes had lower fat (0.3 %), protein (6.6 %), and dietary fiber (1.8 %) compared to the commercial product, except for ash (2.3 %), moisture (6.0 %), carbohydrates (89.0 %), and energy (384.7 Kcal/100 g). Despite these differences, cassava flakes met the UNBS requirements for breakfast cereals. Additionally, the cassava flakes’ nutritional adequacy for school going children and adolescents was assessed by determining their %contribution to RDA per serving (30 g cassava flakes + 100 g milk). Their contribution to the RDAs of school going children was minimal with only the contribution of carbohydrates for all age groups and the contribution of protein for 4–8 years aged children meeting recommendations due to the low protein, fat and fiber content. It is, therefore, important to consider reformulation of the cassava flakes and incorporation of other ingredients to improve their protein, fiber, and energy content. Overall, cassava flakes were acceptable with good functionality, but the acceptability can further be enhanced through optimization of the sensory and nutritional qualities.

Structure Evolution and Optical Tuning of One-Dimensional Post-perovskite (TDMP)PbBr4 under High Pressure.

Optimizing the structure and tuning the optical properties in low-dimensional organic-inorganic halide perovskites are crucial to practical applications for stable solid-state lighting. Herein, we performed high-pressure investigations on one-dimensional (1D) postperovskite (TDMP)PbBr4 (TDMP = trans-2,5-dimethylpiperaziniium), and structure and optical properties under pressure are studied. (TDMP)PbBr4 exhibits color tunable emission from cool white light to yellow orange as the pressure increases from atmospheric pressure to 20.0 GPa. It was found that high pressure would facilitate trapping the free exciton (free exciton) to form a self-trapped exciton (STE) state due to increased electron-phonon interaction, thus enhancing STE emission in the pressure range of 4.0-7.0 GPa. At above 7.0 GPa, the STE emission is quenched, which is due to the phonon-assisted nonradiative relaxation. Meanwhile, (TDMP)PbBr4 displays reversible piezochromism from colorless to yellow under pressure as a result of the compound undergoing a reversible structural transformation. This work provides an insightful perspective on revealing the relationship between structure and optical properties of 1D postperovskites under high pressure.

Multicolor Emission in o-Carborane Derivatives Induced by Conformation Diversity through C-C Double Bond Substitution.

Rationally designed molecules with versatile conformations are ideal candidates for creating challenging single component-based multicolor emissive materials. Herein, a new strategy is presented by introducing a C-C double bond in an o-carborane derivative. Compared to a linear connection using a C-C triple bond (CbPyY), a C-C double bond connection (CbPyE) exhibited a zigzag structure and unique fluorescence behavior. Yellow, yellowish orange, and red crystals or films of CbPyE can be obtained, while only orange ones of CbPyY were achieved under the same condition. Single crystal XRD and theoretical calculation studies revealed the zigzag structure brings asymmetry to one arm of CbPyE, which causes conformation diversity and leads to the multicolor emission. Interestingly, different emissions showed different responses to acetone vapor; the yellow one showed much higher sensitivity and faster response than the other two. It is believed that the prepared materials and the proposed strategy would contribute to future advances in single-fluorophore-based multicolor emissive materials.

Alkali metal-doped C20 fullerene sensors for COVID-19 biomarker detection: DFT insights into naked-eye and infrared techniques

Prompt diagnosis and prevention from coronavirus disease (COVID-19), a highly contagious infection, are critically required. While PCR testing is effective, it is costly, painful, and time-consuming. Alternatively, breath analysis for detecting COVID-19 provides a cost-effective and instant diagnostic approach. COVID-19 infected patients exhale ethyl butyrate (EB) as a biomarker of the infection. This study explores the doping of C20 fullerene with alkali metals to enhance its ability to detect ethyl butyrate. EB was weakly adsorbed onto C20 and strong adsorbed on doped fullerenes (M@C20) with maximum adsorption energies of −27.66 kcal/mol for Li@C20. QTAIM and IRI analyses confirmed Van der Waals interactions between EB and M@C20. NBO and MEP analyses provided evidence of charge transfer from the biomarker towards the M@C20. This charge transfer decreased the carbonyl bond stretching frequency from 1838 cm−1 to 1772, 1782, and 1788 cm−1 in three complexes (EB−Li@C20, EB−Na@C20, and EB−K@C20), respectively. This IR analysis supports the potential application of doped fullerenes in infrared-based detectors. Absorption maxima (λmax) were calculated as 534 nm (green), 594 nm (yellowish orange), and 587 nm (yellow) for three complexes. These shifts indicate potential application of M@C20 in naked-eye detectors. The shortest recovery time was 2.9 × 10−11 s for K@C20, suggesting it a suitable reusable sensor. These findings enable the development of fullerene-based sensors for both naked-eye and infrared-based detection of COVID-19.

Bio-inspired magnetic chitosan/Iron oxide macromolecules for multiple anionic dyes adsorption from aqueous media

Organic anionic dyes are major water pollutants due to their low degradability caused by complex aromatic structures. Not only do they exert toxic, mutagenic, teratogenic, tumorigenic, and genotoxic effects, but they also decrease fertility and cause irritation to the skin and respiratory system in humans. This long-term toxicity has detrimental effects on aquatic organisms and their surroundings, resulting in an imbalanced ecosystem. In this study, a Cs@Fe3O4 magnetic biosorbent was synthesised to uptake three anionic dyes and characterised for FTIR, BET/BJH, XRD, TGA, VSM, and FESEM analyses. The biosorbent average surface area was confirmed to be 52.6524 m2/g, with average pore sizes of 7.3606 nm and 6.9823 nm for adsorption-desorption processes, respectively. Batch adsorption studies pH values, contact times, temperature, initial dye concentrations, and adsorbent dosages were examined. Several isotherm and kinetic models were studied to determine the adsorption mechanism. The adsorption data of these dyes at equilibrium was observed to match Langmuir's isotherm and pseudo-second-order kinetic models. The thermodynamic study revealed that the adsorption process for these dyes was an exothermic reaction. Maximum adsorption capacities for congo red, methyl orange, and metanil yellow were 117.77 mg/g, 137.77 mg/g, and 155.57 mg/g, respectively. The reusability of recovered Cs@Fe3O4 after dye adsorption was evaluated up to five continuous adsorption-desorption cycles for its possible industrial applications.

Thermally stable Tb3+/Sm3+-doped Lu2O2S phosphors with tunable multicolor luminescence under light and X-ray excitation

Lu2O2S has high density, high melting temperature, and favorable thermal stability, making it an excellent matrix material for rare earth luminescence and X-ray sensitization screens. However, achieving high quality fluorescent powders with high crystal quality on a large scale is still challenging. By employing an optimized solid phase approach, Lu2O2S:Tb3+/Sm3+phosphors with a hexagonal shape and uniform particle size and showing high crystallization have been successfully synthesized. Spectral analysis reveals energy interaction between Sm3+ and Tb3+ in the Lu2O2S system (multistage interaction), indicated by spectral overlap, relative changes in luminescence intensity, and lifetime decay. By changing the excitation wavelength and dopant concentration, multicolor phosphors such as yellow-–green, orange–red, and orange–yellow could be created. Temperature-dependent emission spectroscopy shows that the system shows good luminescence performance even at high temperatures. X-ray excitation spectroscopy further confirm that the phosphors emit different colors (yellow, green and red) depending on the doping concentrations of Tb3+ and Sm3+ ion, indicating that the system has wide application potential in color displays and other relevant fields.

Piezochromic Behavior of 2,4,6‐Triphenylpyrylium Tetrachloroferrate

In advanced photonics, there is a growing interest in piezochromic luminescent materials that exhibit multicolor switching, driven by their potential applications in optical recording, memory, and sensors. Here, the piezochromic behavior of 2,4,6‐triphenylpyrylium tetrachloroferrate (Py‐FeCl4) under high pressures from 0 to 9 GPa is reported. The observed multicolor changing properties of Py‐FeCl4 (yellow–orange–red–maroon–black) are found to be fully reversible upon decompression to ambient conditions. The mechanism of Py‐FeCl4 piezochromism is investigated via Raman, infrared, and UV–vis spectroscopy combined with powder X‐ray Diffraction. The absence of structural phase transitions as well as the abrupt shifts of bandgap values together with characteristic Raman and IR peaks within 0‐9 GPa suggests that the Py‐FeCl4 multicoloring switching behavior is driven by an electron transfer between the inorganic FeCl4− anion and the organic pyrylium cation. The obtained results demonstrate that Py‐FeCl4 dye is a good candidate for developing high‐pressure sensing technologies designed to function in extreme environments. Moreover, due to the inherent role of molecular‐structure relationships in the pyrylium salt's photophysical properties, findings suggest the potential discovery of piezochromic behavior in other pyrylium compounds.

Environmental friendly multifunctional orange pigment for cool coating applications

The present study illustrates the development of an environmentally benign intense orange inorganic pigment, by substituting Si4+ metal ion at the Bi3+ site of Bi4V2O11 via solid-state method. The partial replacement of Si4+, induced a strain in the crystal lattice of the compound, which resulted in a substantial improvement in the visible light reflectance. A reduction in oxygen deficiency in the lattice structure facilitated the colour tuning of the pigment series from brownish red to orange and then on to yellowish orange. The composition Bi3.8Si0.2V2O11+δ exhibited a bright orange hue with colour co-ordinates a* = 39, b* = 34 and L* = 52. Furthermore, NIR solar reflectance of the pigment was 86%, which is superior than the reported and commercial orange pigments. Compared to commercial pigment coatings, Bi3.8Si0.2V2O11+δ achieved a temperature reduction of 2 °C inside a foam model house. An exceptional corrosion resistance of 1.6 × 1010 Ωcm2, was registered by the pigment loaded epoxy coating with good stability. The corrosion inhibition mechanism of the pigment operates through the hand in hand working of passive Bi-O and Si-O, active FeOOH and vanadate moiety. On the whole, the new multifunctional orange pigment has the potential to be a viable replacement for the toxic commercial pigments in the market.

Use Of Natural Dyes From Plants In Coloring Woven Yarns

The use of natural dyes as an environmentally friendly alternative to reduce the use of synthetic dyes which have a negative impact on the environment. Natural dyes can be obtained from various natural sources such as plants, animal waste, and minerals, with plants being the most common source. Plant pigments such as anthocyanins, tannins, flavonoids, and chlorophyll provide a variety of colors that can be used for coloring. The natural dyeing process involves four stages: making the dye solution, fabric preparation, dyeing, and fixation. Testing the quality of natural dyes includes color visualization tests, color aging, color differences and fastness to washing. The methodology for writing this article is a literature study, reviewing various related research from 2013 to 2023. The results show that several plants such as Tarum, Coconut, Secang, Noni, Turmeric, and Shallots can produce colors such as dark blue, brownish cream, red , yellow, and brownish orange on fabric. In conclusion, natural dyes not only support environmental sustainability but also offer a safe and low-cost coloring alternative, although there are challenges in the manufacturing and application process of these natural dyes.

Green Synthesis of Silver Nanoparticles using Lawsonia inermis for Enhanced Degradation of Organic Pollutants in Wastewater Treatment

&lt;p&gt;In response to the growing demand for eco-friendly and efficient catalysts in wastewater treatment, this study introduces a novel, biosynthesized silver nanoparticle (AgNP) using leaf extract from Lawsonia inermis, a widely available plant. We employed a unique concentration mixture of 0.015 mg/mL leaf extract and 2.0 mM silver nitrate to achieve optimal results under atmospheric conditions. Comprehensive characterization was conducted through X-ray diffraction, transmission electron microscopy, scanning electron microscopy, and ultraviolet-visible absorption spectroscopy. Remarkably, these Lawsonia inermis-synthesized AgNPs (LI-AgNPs) demonstrated superior catalytic degradation of organic pollutants, such as 4-nitrophenol, methylene blue, eosin yellow, and methyl orange. Among them, 4-nitrophenol was reduced most efficiently, following pseudo-first order kinetics. The LI-AgNPs exhibited unprecedented catalytic potential, evidenced by a sharp decline in methyl orange absorption and the emergence of a new hydrazine compound signal at 280 nm. With a catalytic loading as low as 0.2 mg/mL, we achieved an astounding 82.5% dye removal. This innovative approach advances the field of environmental remediation&lt;/p&gt;&#x0D;

Pilanesbergite: a new rock-forming mineral occurring in nepheline syenite from the Pilanesberg Alkaline Complex, South Africa

Abstract. The new mineral pilanesbergite, with the ideal formula Na2Ca2Fe2Ti2(Si2O7)2O2F2, was found in a nepheline syenite, locally known as green foyaite, from the Pilanesberg Complex located in the North West Province of South Africa. Pilanesbergite occurs in green foyaite in association, and partly intergrown, with aegirine. The two minerals share an assemblage of inclusions, comprising euhedral nepheline, titanite and minor sodalite. Pilanesbergite belongs to the wöhlerite group and is isomorphic with låvenite, normandite and madeiraite. It is related to these species through the homovalent chemical substitutions Mn2+↔Fe2+ and Zr4+↔Ti4+. The empirical formula calculated on the basis of 18 anions is Na2.00(Ca1.74Na0.26)Σ2.00(Fe1.00Mn0.52Ca0.49Zr0.05)Σ2.06(Ti1.69Zr0.14Mg0.09Nb0.08)Σ2.00(Si2O7)2.00O1.84F2.16 (Z=2). The new mineral is translucent with a brown orange colour and a brownish streak. The Mohs hardness is estimated between 5 and 6 by comparison with låvenite, and no cleavage is observed. Measured and calculated densities are Dmeas=3.47 g cm−3 and Dcalc=3.40 g cm−3. In the thin section the pleochroism is strong, between straw yellow and orange red, while in immersion the strong pleochroism is observed between light yellow (α) and yellowish orange (γ). The crystals are optically biaxial (+) with α=1.743(3), β=1.768(3), γ=1.795(5) and a 2 V angle close to 90∘. The crystal structure is monoclinic (P21/a), with the unit-cell parameters a=10.7811(2), b=9.7836(1), c=7.0348(1) Å, β=108.072(2)∘ and V=705.41(2) Å3, and has been refined to R1=2.06 %. The strongest lines of the powder X-ray diffraction pattern [d, Å (I, %) (h k l)] are 3.219 (60) (310), 2.851 (100) (12-2), 2.802 (51) (320), 2.743 (27) (22-2), 2.423 (19) (40-2) and 1.723 (19) (44-2). Pilanesbergite formed under relatively reducing conditions from an agpaitic nepheline syenite magma that had evolved by fractional crystallization mainly of aegirine. Further crystallization of arfvedsonite caused an increase in oxygen fugacity and a change towards higher Mn/Mn+Fe of the magma, causing a change of mineral composition from pilanesbergite towards normandite.

Rapid adsorptive removal of eosin yellow and methyl orange using zeolite Y

In this study, zeolite Y was synthesised using a novel method. The heat generated from the reaction of H2SO4 with metakaolin was used as a heat source instead of applying external heat for the dealuminated process. The synthesised zeolite Y produced was analysed by scanning electron microscope (SEM), X-ray diffraction (XRD), Fourier-infrared spectroscopy (FTIR), energy dispersive X-ray spectroscopy (EDS) and Brunauer–Emmett–Teller (BET). Zeolite Y synthesis was mesoporous because of its pore diameter (30.53 nm), as shown in the BET results. Surface area and pore size decrease after adsorption due to dye deposition on the adsorbent’s surface. FTIR has bonds like O–H, C–H, –CH3, and –COOH responsible for adsorption. The maximum adsorption capacity of eosin yellow (EY) and methyl orange (MO) on to zeolite Y by the Langmuir isotherm was 52.91 mg/g and 20.62 mg/g respectively, at pH 2.5 and 8 for EY and MO dye. The batch adsorption studies were conducted, and the influence of different parameters (i.e., adsorbent dose, adsorption time, initial dye concentration, pH and temperature) was investigated. Experimental data were analysed by two linear model equations (Langmuir and Freundlich isotherms), and it was found that the Langmuir isotherm model best describes the adsorption data for methyl orange and Freundlich isotherm for eosin yellow, respectively. Adsorption rate constants were determined using linear pseudo-first-order and pseudo-second-order. The results showed that MO and EY dye adsorption onto zeolite Y followed a pseudo-second-order kinetic model. Thermodynamic studies show that adsorption was an exothermic reaction (enthalpy < 0) and feasible ((Gibbsfreeenergy)<0\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$(Gibbs free energy)<0$$\\end{document}) at various temperatures under investigation.

Colorimetric Detection of Cu2+ and Ag+ Ions Using Multi-Responsive Schiff Base Chemosensor: A Versatile Approach for Environmental Monitoring.

In this study, we have synthesized a novel Schiff base-centered chemosensor, designated as SB, with the chemical name ((E)-1-(((6-methylbenzo[d]thiazol-2-yl) imino)methyl)naphthalen-2-ol). This chemosensor was structurally characterized by FT-IR, 1H NMR, UV-Vis and fluorescence spectroscopy. After structural characterization the chemosensor SB was subsequently employed for the detection of Cu2+ and Ag+, using fluorescence spectroscopy. The chemosensor SB showed excellent ability to recognize the target metal ions, leading to fluorescence enhancement and color change from yellow to yellowish orange for Cu2+ and yellow to radish for Ag+ ions. The detection capabilities of this chemosensor were impressive, showing excellent selectivity and an exceptionally low detection limit of 0.0016 µM for Cu2+ and 0.00389 µM for Ag+. Most notably, our approach enables the quantitative detection both metal ions in different water and soil samples at trace level. This achievement holds great promise for analytical applications and offers significant contributions to the field of chemical sensing and environmental protection.

Quantification of overcompensated cations in layer-by-layer membrane by Orange yellow II

The charge density of the nanofiltration (NF) membrane separation layer is critical for ion separation because the charge-based Donnan exclusion plays a critical role. To quantified the charge density has been an important but difficult task. We recently discovered the excellent performance of poly(styrene sulfonate) (PSS)/ poly (allylamine hydrochloride) (PAH) layer-by-layer (LBL) NF membranes for Mg2+/Li+ separation. The overcompensated amine groups (R-NH3+) in PAH were assumed to be the main contribution, but lacked a quantification of the charge density for further proof. Here, a simple quantitative experimental method by Orange yellow II staining was reported for the first time to measure the overcompensated amine groups in the separation layer. The sulfonic acid group (R-SO3-) in Orange yellow II stoichiometrically adsorbed to the excessive R-NH3+ at pH = 3 by electrostatic interaction, and desorbed at pH = 12. Thermodynamics and kinetics analysis of the sorption process demonstrated a Langmuir monolayer sorption and the sorption was controlled by sorption reaction not diffusion. The pore size distribution and rejection measurement confirmed that Orange yellow II sorption did not disrupt the original PSS/PAH layer. A linear relationship was observed between the charge density and the coating bi-layers or PAH layers. The accurate, easy assessment of charge density of LBL NF membrane provides future possibility for understanding overcompensation during LBL assembly and a bottom-up understanding of the charges to the NF performance in separation.

β-Cyclodextrin capped ZnS nanoparticles for CER-assisted colorimetric and spectrophotometric detection of Pb2⁺, Cu2⁺, and Hg2⁺ in an aqueous solution

Herein, simple, low-cost, and room-temperature synthesis of beta-cyclodextrin (β-CD) stabilized zinc sulfide nanoparticle (ZnS NP) through the chemical precipitation method has been reported for cation exchange reaction (CER) based colorimetric sensing of Pb2+, Cu2+, and Hg2+. Formation of β-CD stabilized ZnS NPs (ZnS@β-CD) was verified by physicochemical characterization techniques such as XRD, XPS, FE-SEM, and TEM. ZnS@β-CD NPs showed color change selectively for the metal ions Pb2⁺, Cu2⁺, and Hg2⁺ among the various metal ions including Sn2⁺, Cr³⁺, Mn2⁺, Fe³⁺, Co2⁺, Ni2⁺, and Cd2⁺. The solubility product of reactants and the transformed products are the reason for selective CER of ZnS@β-CD NPs towards Pb2⁺, Cu2⁺, and Hg2⁺ ions. ZnS@β-CD NPs dispersion revealed rapid color change from white to orange, black, and bright yellow on the addition of higher concentrations of Pb2⁺, Cu2⁺, and Hg2⁺ respectively. This color change is due to the formation of complete CER-transformed nanostructures such as PbS, CuS, and HgS in higher concentrations (10⁻1- 10⁻³ M) of corresponding metal ions. The partial CER altered products Zn1−x,PbxS, Zn1−xCuxS and Zn1−xHgxS were detected due to the appearance of pale color in the lower metal ions concentrations of 10⁻⁴ - 10⁻⁶ M. This CER assisted transformation was also monitored through spectrophotometric methods. Moreover, infrared spectroscopic analysis was used to testify the structure of CER transformed product. The synthesized ZnS@β-CD NPs act as an efficient CER-based sensor for distinguishing and determining Pb2⁺, Cu2⁺, and Hg2⁺ at different level concentrations in the aqueous solution.

Decoding the fashion trend of sports shoes with empowered computer vision

To adapt to the rapidly changing market and capricious trends, fashion brands need to understand trends and market conditions precisely and fast to produce marketable products. The traditional fashion trend analysis has relied heavily on the subjective judgement of experts, inevitably leading to biased decisions and is time-consuming. The development of computer vision and machine learning provides an objective and systematic approach to processing images and analysis of fashion products. However, most studies focus on clothing trends analysis, few are on shoe trends analysis. Hence, this study aimed to decode and analyse the fashion trend of sports shoes with empowered computer vision technology. In this paper, a dataset containing e-commerce images of sports shoes with precise annotations was established; then Mask-RCNN was utilized to classify and extract the shoe from the background image; a modified version of the K-means clustering algorithm was employed to detect the shoe colour. The results indicated that fashionable sports shoes and casual sports shoes were the most prevalent two styles. Besides neutral tones, yellow, red ochre and reddish orange were popular in casual sports shoes, fashion sports shoes and basketball shoes respectively and Atlantic Blue in board shoes and trainers. This study demonstrated the promising potential of computer vision and machine learning as a new method to analyse footwear fashion trends efficiently and economically.