Optoelectronic Probe Research Articles

Nanoscale Structure–Property Relationships in Low-Temperature Solution-Processed Electron Transport Layers for Organic Photovoltaics

Here we elucidate the nanostructure–property relationships in low-temperature, solution-processed ZnO based thin films employed as novel electron transport layers (ETLs) in organic photovoltaic (OPV) devices. Using a low-cost zinc precursor (zinc acetate) in a simple amine–alcohol solvent mix, high-quality ETL thin films are prepared. We show that at a processing temperature of 110 °C the films are composed of nanoparticles embedded in a continuous organic matrix consisting of ZnO precursor species and stabilizers. Using a combination of transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS), we study the thermally induced morphological and compositional changes in the ETLs. Transient optoelectronic probes reveal that the mixed nanocrystalline/amorphous nature of the films does not contribute to recombination losses in devices. We propose that charge transport in our low-temperature processed ETLs is facilitated by the network of ZnO nanoparticles, with the organic matrix servin...

Temporal profiles for measuring threshold of random lasers pumped by ns pulses

The working threshold is an important parameter to assess the performance of cavity-free random lasers. Here, the temporal profile measurement is proposed as an alternative method to determine the thresholds of the surface plasmon based random lasers pumped by ns pulses based on analyzing the delay time (tDelay) and rising time (tR) of the emission signal. The obvious and slight inflection points of the curves of tDelay and tR varying with the pump power density are observed as indicators for the thresholds of random lasing and for the transition of lasing mode, respectively. The proposed method supplies consistent values to those supplied by traditional methods in frequency-domain for the random systems with different gain length. The demonstrated temporal profile approaches are free from the spectrometers and may be as a candidate for measuring the threshold of random lasers in ultrafast optics, nonlinear optics and bio-compatible optoelectronic probes.

A low power flash-FPGA based brain implant micro-system of PID control.

In this paper, we demonstrate that a low power flash FPGA based micro-system can provide a low power programmable interface for closed-loop brain implant inter- faces. The proposed micro-system receives recording local field potential (LFP) signals from an implanted probe, performs closed-loop control using a first order control system, then converts the signal into an optogenetic control stimulus pattern. Stimulus can be implemented through optoelectronic probes. The long term target is for both fundamental neuroscience applications and for clinical use in treating epilepsy. Utilizing our device, closed-loop processing consumes only 14nJ of power per PID cycle compared to 1.52μJ per cycle for a micro-controller implementation. Compared to an application specific digital integrated circuit, flash FPGA's are inherently programmable.

Micro-drive and headgear for chronic implant and recovery of optoelectronic probes

Silicon probes are multisite electrodes used for the electrophysiological recording of large neuronal ensembles. Optoelectronic probes (OEPs) are recent upgrades that allow, in parallel, the delivery of local optical stimuli. The procedures to use these delicate electrodes for chronic experiments in mice are still underdeveloped and typically assume one-time uses. Here, we developed a micro-drive, a support for OEPs optical fibers, and a hat enclosure, which fabrications consist in fitting and fastening together plastic parts made with 3D printers. Excluding two parts, all components and electrodes are relatively simple to recover after the experiments, via the loosening of screws. To prevent the plugging of OEPs laser sources from altering the stability of recordings, the OEPs fibers can be transiently anchored to the hat via the tightening of screws. We test the stability of recordings in the mouse hippocampus under three different conditions: acute head-fixed, chronic head-fixed, and chronic freely moving. Drift in spike waveforms is significantly smaller in chronic compared to acute conditions, with the plugging/unplugging of head-stage and fiber connectors not affecting much the recording stability. Overall, these tools generate stable recordings of place cell in chronic conditions, and make the recovery and reuse of electrode packages relatively simple.

Swirl ratio and post injection strategies to improve late cycle diffusion combustion in a light-duty diesel engine

Nitrogen oxides (NOx) and soot emissions are the most important pollutants from direct-injection diesel engines. In particular, soot formation and oxidation determine the net engine-out soot emissions. These phenomena are complex and competing processes during diesel combustion. Despite many researches implicate the mechanisms of soot formation with soot emissions, the enhancement of the late cycle soot oxidation is the dominant mechanism for a reduction of engine-out soot emissions. The mixing process and the in-cylinder bulk temperature are two important parameters in the development of soot oxidation process. The current research compares different engine strategies to enhance the late cycle mixing controlled combustion process and therefore enhance soot oxidation while maintaining similar gross indicated efficiency in a light-duty engine. For this purpose, a simplified methodology has been used, which analyzes the effect of mixing process and in-cylinder bulk gas temperature on soot oxidation during the late cycle combustion. For carrying out this research, theoretical and experimental tools were used. In particular, the experimental measurements were made in a single-cylinder direct-injection light-duty diesel engine varying the swirl ratio and the injection pattern as injection pressure, Start of Energizing (SoE), Energizing Time (ET) and number of injections events. To analyze soot emissions, the combustion luminosity was measured by an optoelectronic probe and the optical thickness parameter (KL) was evaluated by the two-color pyrometry method. The apparent combustion time (ACT-1) was used as mixing time tracer. Results show that an increase in swirl ratio implies an improvement on the mixing process and higher values of average bulk temperature during the late-cycle diffusion combustion. Both phenomena produce an enhancement in the soot oxidation process. In the lowest swirl ratio case, a suitable injection strategy based on multiple injections, provides similar results of soot oxidation process (and therefore, the emissions) as high swirl ratio case.

Feature issue introduction: Multimaterial and Multifunctional Optical Fibers

The development of multimaterial and multifunctional optical fibers is opening exciting opportunities in photonic and optoelectronic devices, optical probes, diagnosis and surgical tools, as well as advanced fibers and textiles. It also constitutes a rich platform for the fundamental study of novel materials science and processing concepts, as well as in optics and photonics. This Feature Issue is a collection of thirteen peer-reviewed articles that present original work in areas at the frontier of this emerging scientific and technological field. These contributions highlight the maturity of the techniques employed to date, their potential to further develop and the prospects for a new generation of optical fiber based devices. (C) 2017 Optical Society of America

(Invited) Carbon-Based Nanomaterials for Bioelectronics

Carbon-based nanomaterials, such as carbon nanotubes (CNTs) and graphene, have gained significant interest as one of the most promising materials in biological applications due to their unique physical and chemical properties. Recently we have developed an optoelectronic probing system, combining CNT/graphene transistors with scanning photocurrent measurements, fluorescence microscopy, and optical trapping techniques to investigate the molecular interface between CNTs/graphene and biological systems. Here, optical tweezers have been used to manipulate individual DNA molecules with sub-piconewton force precision and to directly measure the binding force between a DNA molecule and a CNT. Three-dimensional scanning photocurrent microscopy has been utilized to monitor the morphology changes of CNTs, allowing for a comprehensive reconstruction of the CNT-DNA interaction dynamics. We have also integrated graphene-based scanning photocurrent microscopy with microfluidic platforms to study the electrical activity in neuronal networks. These fundamental studies not only provide a new platform for exploring mechanical and electrical coupling at nanobio-interfaces, but also shed light on new design rules for future nanobioelectronics.

Flexible and stretchable nanowire-coated fibers for optoelectronic probing of spinal cord circuits.

Studies of neural pathways that contribute to loss and recovery of function following paralyzing spinal cord injury require devices for modulating and recording electrophysiological activity in specific neurons. These devices must be sufficiently flexible to match the low elastic modulus of neural tissue and to withstand repeated strains experienced by the spinal cord during normal movement. We report flexible, stretchable probes consisting of thermally drawn polymer fibers coated with micrometer-thick conductive meshes of silver nanowires. These hybrid probes maintain low optical transmission losses in the visible range and impedance suitable for extracellular recording under strains exceeding those occurring in mammalian spinal cords. Evaluation in freely moving mice confirms the ability of these probes to record endogenous electrophysiological activity in the spinal cord. Simultaneous stimulation and recording is demonstrated in transgenic mice expressing channelrhodopsin 2, where optical excitation evokes electromyographic activity and hindlimb movement correlated to local field potentials measured in the spinal cord.

Smart bandage with wireless connectivity for optical monitoring of pH

Wound care technologies need to adapt in order to cope with the growing socio-economic burden of chronic wounds. Non-invasive analytical systems which monitor important wound status biomarkers such as pH of wound fluid, are needed. In this work, a wireless smart bandage for optical determination of pH, as an indicator of wound status, is demonstrated and characterised. The bandage is constructed by immobilising cellulose particles, covalently modified with a pH indicator dye, within a biocompatible hydrogel. Thin layers of the pH sensitive hydrogel are cast onto a conventional dressing and interfaced to a wireless platform via a miniaturised optoelectronic probe. The smart bandage can detect pH changes in the physiologically relevant range with high accuracy and precision, and communicate this information with an external readout unit using radio-frequency identification (RFID). The new system could provide insight into temporal changes in wound status in a convenient and non-invasive manner, and prompt an appropriate response from a healthcare provider.

Temperature dependence of pyro-phototronic effect on self-powered ZnO/perovskite heterostructured photodetectors

Self-powered ZnO/perovskite heterostructured ultraviolet (UV) photodetectors (PDs) based on the pyro-phototronic effect have been recently reported as a promising solution for energy-efficient, ultrafast-response, and high-performance UV PDs. In this study, the temperature dependence of the pyro-phototronic effect on the photo-sensing performance of self-powered ZnO/perovskite heterostructured PDs was investigated. The current responses of these PDs to UV light were enhanced by 174.1% at 77 K and 28.7% at 300 K owing to the improved pyro-phototronic effect at low temperatures. The fundamentals of the pyro-phototronic effect were thoroughly studied by analyzing the chargetransfer process and the time constant of the current response of the PDs upon UV illumination. This work presents in-depth understandings about the pyrophototronic effect on the ZnO/perovskite heterostructure and provides guidance for the design and development of corresponding optoelectronics for ultrafast photo sensing, optothermal detection, and biocompatible optoelectronic probes.

Functional Scanning Probe Imaging of Nanostructured Solar Energy Materials.

From hybrid perovskites to semiconducting polymer/fullerene blends for organic photovoltaics, many new materials being explored for energy harvesting and storage exhibit performance characteristics that depend sensitively on their nanoscale morphology. At the same time, rapid advances in the capability and accessibility of scanning probe microscopy methods over the past decade have made it possible to study processing/structure/function relationships ranging from photocurrent collection to photocarrier lifetimes with resolutions on the scale of tens of nanometers or better. Importantly, such scanning probe methods offer the potential to combine measurements of local structure with local function, and they can be implemented to study materials in situ or devices in operando to better understand how materials evolve in time in response to an external stimulus or environmental perturbation. This Account highlights recent advances in the development and application of scanning probe microscopy methods that can help address such questions while filling key gaps between the capabilities of conventional electron microscopy and newer super-resolution optical methods. Focusing on semiconductor materials for solar energy applications, we highlight a range of electrical and optoelectronic scanning probe microscopy methods that exploit the local dynamics of an atomic force microscope tip to probe key properties of the solar cell material or device structure. We discuss how it is possible to extract relevant device properties using noncontact scanning probe methods as well as how these properties guide materials development. Specifically, we discuss intensity-modulated scanning Kelvin probe microscopy (IM-SKPM), time-resolved electrostatic force microscopy (trEFM), frequency-modulated electrostatic force microscopy (FM-EFM), and cantilever ringdown imaging. We explain these developments in the context of classic atomic force microscopy (AFM) methods that exploit the physics of cantilever motion and photocarrier generation to provide robust, nanoscale measurements of materials physics that are correlated with device operation. We predict that the multidimensional data sets made possible by these types of methods will become increasingly important as advances in data science expand capabilities and opportunities for image correlation and discovery.

Light-induced pyroelectric effect as an effective approach for ultrafast ultraviolet nanosensing.

Zinc oxide is potentially a useful material for ultraviolet detectors; however, a relatively long response time hinders practical implementation. Here by designing and fabricating a self-powered ZnO/perovskite-heterostructured ultraviolet photodetector, the pyroelectric effect, induced in wurtzite ZnO nanowires on ultraviolet illumination, has been utilized as an effective approach for high-performance photon sensing. The response time is improved from 5.4 s to 53 μs at the rising edge, and 8.9 s to 63 μs at the falling edge, with an enhancement of five orders in magnitudes. The specific detectivity and the responsivity are both enhanced by 322%. This work provides a novel design to achieve ultrafast ultraviolet sensing at room temperature via light-self-induced pyroelectric effect. The newly designed ultrafast self-powered ultraviolet nanosensors may find promising applications in ultrafast optics, nonlinear optics, optothermal detections, computational memories and biocompatible optoelectronic probes.

Submicron Surface Vibration Profiling Using Doppler Self-Mixing Techniques

Doppler self-mixing laser probing techniques are often used for vibration measurement with very high accuracy. A novel optoelectronic probe solution is proposed, based on off-the-shelf components, with a direct reflection optical scheme for contactless characterization of the target’s movement. This probe was tested with two test bench apparatus that enhance its precision performance, with a linear actuator at low frequency (35 µm, 5–60 Hz), and its dynamics, with disc shaped transducers for small amplitude and high frequency (0.6 µm, 100–2500 Hz). The results, obtained from well-established signal processing methods for self-mixing Doppler signals, allowed the evaluation of vibration velocity and amplitudes with an average error of less than 10%. The impedance spectrum of piezoelectric (PZ) disc target revealed a maximum of impedance (around 1 kHz) for minimal Doppler shift. A bidimensional scan over the PZ disc surface allowed the categorization of the vibration mode (0, 1) and explained its deflection directions. The feasibility of a laser vibrometer based on self-mixing principles and supported by tailored electronics able to accurately measure submicron displacements was, thus, successfully demonstrated.

The human ear canal: investigation of its suitability for monitoring photoplethysmographs and arterial oxygen saturation

For the last two decades, pulse oximetry has been used as a standard procedure for monitoring arterial oxygen saturation (SpO2). However, SpO2 measurements made from extremities such as the finger, ear lobe and toes become susceptible to inaccuracies when peripheral perfusion is compromised. To overcome these limitations, the external auditory canal has been proposed as an alternative monitoring site for estimating SpO2, on the hypothesis that this central site will be better perfused. Therefore, a dual wavelength optoelectronic probe along with a processing system was developed to investigate the suitability of measuring photoplethysmographic (PPG) signals and SpO2 in the human auditory canal. A pilot study was carried out in 15 healthy volunteers to validate the feasibility of measuring PPGs and SpO2 from the ear canal (EC), and comparative studies were performed by acquiring the same signals from the left index finger (LIF) and the right index finger (RIF) in conditions of induced peripheral vasoconstriction (right hand immersion in ice water). Good quality baseline PPG signals with high signal-to-noise ratio were obtained from the EC, the LIF and the RIF sensors. During the ice water immersion, significant differences in the amplitude of the red and infrared PPG signals were observed from the RIF and the LIF sensors. The average drop in amplitude of red and infrared PPG signals from the RIF was 52.7% and 58.3%. Similarly, the LIF PPG signal amplitudes have reduced by 47.52% and 46.8% respectively. In contrast, no significant changes were seen in the red and infrared EC PPG amplitude measurements, which changed by +2.5% and −1.2% respectively. The RIF and LIF pulse oximeters have failed to estimate accurate SpO2 in seven and four volunteers respectively, while the EC pulse oximeter has only failed in one volunteer. These results suggest that the EC may be a suitable site for reliable monitoring of PPGs and SpO2s even in the presence of peripheral vasoconstriction.

A coaxial optrode as multifunction write-read probe for optogenetic studies in non-human primates

BackgroundAdvances in optogenetics have led to first reports of expression of light-gated ion-channels in non-human primates (NHPs). However, a major obstacle preventing effective application of optogenetics in NHPs and translation to optogenetic therapeutics is the absence of compatible multifunction optoelectronic probes for (1) precision light delivery, (2) low-interference electrophysiology, (3) protein fluorescence detection, and (4) repeated insertion with minimal brain trauma. New methodHere we describe a novel brain probe device, a “coaxial optrode”, designed to minimize brain tissue damage while microfabricated to perform simultaneous electrophysiology, light delivery and fluorescence measurements in the NHP brain. The device consists of a tapered, gold-coated optical fiber inserted in a polyamide tube. A portion of the gold coating is exposed at the fiber tip to allow electrophysiological recordings in addition to light delivery/collection at the tip. ResultsCoaxial optrode performance was demonstrated by experiments in rodents and NHPs, and characterized by computational models. The device mapped opsin expression in the brain and achieved precisely targeted optical stimulation and electrophysiology with minimal cortical damage. Comparison with existing methodsOverall, combined electrical, optical and mechanical features of the coaxial optrode allowed a performance for NHP studies which was not possible with previously existing devices. ConclusionsCoaxial optrode is currently being used in two NHP laboratories as a major tool to study brain function by inducing light modulated neural activity and behavior. By virtue of its design, the coaxial optrode can be extended for use as a chronic implant and multisite neural stimulation/recording.

Contact-free fault location and imaging with on-chip terahertz time-domain reflectometry

We demonstrate in a first experimental study the application of novel micro-machined optoelectronic probes for a time-domain reflectometry-based localization of discontinuities and faults in electronic structures at unprecedented resolution and accuracy (± 0.55 µm). Thanks to the THz-range bandwidth of our optoelectronic system--including the active probes used for pulse injection and detection--the spatial resolution and precision of high-end all-electronic detection systems is surpassed by more than one order of magnitude. The new analytic technology holds great promise for rapid and precise fault detection and location in advanced (3D) integrated semiconductor chips and packages.

An optoelectronic probe with loss compensation for electromagnetic monitoring at low frequencies

We explore the development of an optoelectronic probe for MF/HF/VHF (up to ∼ 37 MHz) radio frequency bands able to display the complete waveforms. It was built from simple, low cost and robust components. A passive loop antenna generates RF current which modulates an ultra-bright LED of display/illumination. The light signals are transmitted along a PMMA plastic optical fibre (POF) to an optical receiver placed in a remote site. All characterization measurements were carried out in the near-field region. Far-field radio transmissions could also be detected. The probe presented at 0.5 MHz tuning-band has shown a 62 dBµV dynamic range and was able to detect down to Hmin ∼ 0.8 nA cm−1 magnetic field amplitude. A new technique for loss compensation of the fibre link is proposed and successfully tested.

Evaluation of the prediction of alternative measures of pork carcass composition by three optical probes

The accuracy of 3 optical probes (HGP4 Hennessey Grading Probe, Destron-Feering PG-100 probe, and Giraldo OPTO-Electronic PG-200 probe) to predict the carcass percentage of 5 alternative measures of carcass composition (fat-tissue-free lean, lipid-free soft tissue, lipid-free lean, total fat tissue, and soft tissue lipid) was evaluated on 203 barrows and gilts of 7 genetic populations. The optical probe backfat depths were more closely correlated (P < 0.001, 0.963 to 0.983) than the LM depths (r = 0.695 to 0.734). The optical probe backfat depths were related to lean percentage (r = -0.82 to -0.88), total fat tissue percentage (r = 0.84 to 0.88), and soft tissue lipid percentage (r = 0.86 to 0.87). Optical probe LM depths were weakly related (P < 0.05; r = 0.23 to 0.34) to measures of carcass lean percentage and total fat tissue percentage (r = -0.16 to -0.26). Fat-free lean percentage was predicted with residual SD (RSD) of 3.7% for equations including last-rib midline backfat thickness, 2.4 to 2.7% for equations including optical probe backfat and LM depth, and 2.3% for ribbed carcass measurements. The RSD for the optical probe equations ranged from 2.1 to 2.4% for lipid-free soft tissue percentage and from 2.0 to 2.3% for lipid-free lean percentage. The RSD for the optical probe equations ranged from 2.9 to 3.3% for total fat tissue percentage and 2.5 to 2.8% for soft tissue lipid percentage. Quadratic and cross-product variables of optical probe fat depth, LM depth, and carcass weight were significant (P < 0.05) and reduced the RSD of the equations. Optical probe backfat and LM measurements can be used to predict alternative measures of carcass composition. The predicted relationships in fat-free lean percentage to backfat depth were nearly identical for each optical probe.

Accuracy of digitization of bony landmarks for measuring change in scapular attitude

Digitizing bony landmarks is a common technique used to measure scapular position, but it has not been validated against a gold standard. The aim of this study was to determine the accuracy of this technique for four physiological arm movements using optoelectronic markers mounted on scapular bone pins as a gold standard. Eight subjects had bone pins inserted into their lateral scapular spine. Three points were digitized on the scapula with an optoelectronic probe: the medial root of the scapular spine, the posterolateral corner of the acromion, and the inferior angle of the scapula. The four active movements tested in this study were glenohumeral abduction, glenohumeral horizontal adduction, hand behind back, and forward reaching. The three bony landmarks were digitized six times in three different positions for each movement. Data from one subject were rejected secondary to pin loosening. The overall position-specific r.m.s. errors ranged from 2.0 degrees to 12.5 degrees. The full abduction position had considerably higher r.m.s. errors than the other positions (posterior tipping, 12.5 degrees; upward rotation, 7.3 degrees; internal rotation, 12.0 degrees). It appears that the digitization of bony landmarks may be a valid method for measuring changes in scapular attitude with the following caveats: the full abduction position has a high r.m.s. error, and small scapular motions have high percentage errors.

Integrated Optoelectronic Probe Including a Vertical Cavity Surface Emitting Laser for Laser Doppler Perfusion Monitoring

An integrated optoelectronic probe with small dimensions, for direct-contact laser Doppler blood flow monitoring has been realized. A vertical cavity surface emitting laser (VCSEL), and a chip with photodetectors and all necessary electronics are integrated in a miniature probe head connected to a laptop computer. The computer sound processor is utilized for acquisition and digital signal processing of the incoming Doppler signal. In this paper, the design of the laser Doppler perfusion monitor is described and its performance is evaluated. We demonstrate our perfusion monitor to be less sensitive to subject motion than a commercial fiber-optic device. For medium and high perfusion levels, the performance of our integrated probe is comparable to the fiberoptic flowmeter containing a normal edge-emitting laser diode. For very low perfusion levels, the signal-to-noise ratio of the fiber-optic device is higher. This difference can mainly be attributed to the shorter coherence length of the VCSEL compared with the edge-emitting laser diode.