Storage Options Research Articles

Data Sharing Practices in Agricultural Research: Findings from a Systematized Review

Objective: Agricultural researchers who follow data sharing best practices advance the state of research in a variety of critical areas including plant breeding, cropping systems, and climate change adaptation. Data sharing makes research more reliable and reproducible, therefore, data sharing practices of researchers are integral to advancing science. To assess how agricultural researchers adhere to these practices, we conducted a systematized review of their published output and examined different ways data were shared. Methods: Our study focused on corn and soybean production research published from 2017 to 2022 by authors at our institutions. We searched five databases, retrieved 8,271 articles, and created a randomized sample of 1,250 papers that contained an equal number of examples from each year. Following a rigorous set of criteria, we screened each article for inclusion and recorded the characteristics of the data, funder information, and whether the researchers shared data. Results: Of the articles that met the inclusion criteria, less than 15% shared the full dataset associated with the research. The rate of articles sharing data did not change appreciably over time and was low regardless of funding source. Methods for sharing data varied widely, both in data availability statements and in storage options. Conclusions: These results indicate a need for improved agricultural data sharing and suggest an important role for librarians and data professionals in promoting best data practices to meet increasingly strict funder requirements.

Unlocking the Ultrafast Deposition Kinetics within Bi‐Tailored Core‐Shell Structured Carbon Nanofibers for Highly Efficient and Ultrastable Sodium Metal Batteries

Sodium metal anodes (SMA), featuring high energy content, low electrochemical potential and easy availability, are a compelling option for sustainable energy storage. However, notorious sodium dendrite and unstable solid‐electrolyte interface (SEI) have largely retarded their widespread implantation. Herein, porous amorphous carbon fiber embedded with Bi nanoparticles in nanopores (Bi@NC) was rationally designed as a 3D host for SMA. In‐situ and ex‐situ characterizations, along with theoretical simulations unlock that the in‐situ formed Na‐Bi alloy significantly accelerates sodium metal nucleation and sodium ion diffusion kinetics, enabling uniform sodium plating within the void spaces and a stable SEI outside the carbon fiber. Particularly, the Bi@NC electrode achieved a high Coulombic efficiency of 99.99% at 3 mA cm‐2 and 3 mAh cm‐2 in half‐cell tests, a cycle life of 1000 hours at 5 mA cm‐2 and 10 mAh cm‐2, and sustained performance over 600 cycles under harsh conditions under 30 mA cm‐2 and 3 mAh cm‐2 within symmetrical cells. The full battery assembled with a Na3V2(PO4)3@C cathode and Bi@NC anode delivered long‐term cyclability over 800 cycles, demonstrating its potential for flexible application of sodium‐based energy storage systems. This work highlights the Bi@NC electrode as a promising candidate for high‐performance and flexible sodium metal batteries.

Unlocking the Ultrafast Deposition Kinetics within Bi-Tailored Core-Shell Structured Carbon Nanofibers for Highly Efficient and Ultrastable Sodium Metal Batteries.

Sodium metal anodes (SMA), featuring high energy content, low electrochemical potential and easy availability, are a compelling option for sustainable energy storage. However, notorious sodium dendrite and unstable solid-electrolyte interface (SEI) have largely retarded their widespread implantation. Herein, porous amorphous carbon fiber embedded with Bi nanoparticles in nanopores (Bi@NC) was rationally designed as a 3D host for SMA. In-situ and ex-situ characterizations, along with theoretical simulations unlock that the in-situ formed Na-Bi alloy significantly accelerates sodium metal nucleation and sodium ion diffusion kinetics, enabling uniform sodium plating within the void spaces and a stable SEI outside the carbon fiber. Particularly, the Bi@NC electrode achieved a high Coulombic efficiency of 99.99% at 3 mA cm-2 and 3 mAh cm-2 in half-cell tests, a cycle life of 1000 hours at 5 mA cm-2 and 10 mAh cm-2, and sustained performance over 600 cycles under harsh conditions under 30 mA cm-2 and 3 mAh cm-2 within symmetrical cells. The full battery assembled with a Na3V2(PO4)3@C cathode and Bi@NC anode delivered long-term cyclability over 800 cycles, demonstrating its potential for flexible application of sodium-based energy storage systems. This work highlights the Bi@NC electrode as a promising candidate for high-performance and flexible sodium metal batteries.

The Integration of Thermal Energy Storage Within Metal Hydride Systems: A Comprehensive Review

Hydrogen storage technologies are key enablers for the development of low-emission, sustainable energy supply chains, primarily due to the versatility of hydrogen as a clean energy carrier. Hydrogen can be utilized in both stationary and mobile power applications, and as a low-environmental-impact energy source for various industrial sectors, provided it is produced from renewable resources. However, efficient hydrogen storage remains a significant technical challenge. Conventional storage methods, such as compressed and liquefied hydrogen, suffer from energy losses and limited gravimetric and volumetric energy densities, highlighting the need for innovative storage solutions. One promising approach is hydrogen storage in metal hydrides, which offers advantages such as high storage capacities and flexibility in the temperature and pressure conditions required for hydrogen uptake and release, depending on the chosen material. However, these systems necessitate the careful management of the heat generated and absorbed during hydrogen absorption and desorption processes. Thermal energy storage (TES) systems provide a means to enhance the energy efficiency and cost-effectiveness of metal hydride-based storage by effectively coupling thermal management with hydrogen storage processes. This review introduces metal hydride materials for hydrogen storage, focusing on their thermophysical, thermodynamic, and kinetic properties. Additionally, it explores TES materials, including sensible, latent, and thermochemical energy storage options, with emphasis on those that operate at temperatures compatible with widely studied hydride systems. A detailed analysis of notable metal hydride–TES coupled systems from the literature is provided. Finally, the review assesses potential future developments in the field, offering guidance for researchers and engineers in advancing innovative and efficient hydrogen energy systems.

Why women discontinue exclusive breastfeeding: a scoping review

Background/Aims The World Health Organization recommends exclusive breastfeeding, but global rates remain low. The aim of this review was to provide insight into the reasons behind mothers’ decisions to cease exclusive breastfeeding in the first 6 months. Methods Studies published from 2013 on exclusive breastfeeding cessation were eligible for inclusion in the review. A total of 1910 studies were retrieved in the initial search, with 17 included in the final review. Results There were five main themes encompassing 19 factors that contributed to the decision to cease exclusive breastfeeding. These were challenges related to lactation, the infant, the mother's health, social issues and lifestyle. Lactation issues were the most common reason for stopping exclusive breastfeeding, while returning to work was the main lifestyle-related factor. Conclusions A clear understanding of why mothers stop exclusive breastfeeding should form the foundation of breastfeeding intervention strategies, as clinical support alone is insufficient for helping mothers achieve their breastfeeding goals. Implications for practice Healthcare providers should develop targeted interventions tailored to address reasons for early cessation of exclusive breastfeeding. There is a need for improved lactation support services, including education on proper latch techniques, management of nipple pain and injuries, and strategies to address perceived insufficient milk supply. There is also a need for improved education on breastfeeding techniques, expressing milk and storage options. Healthcare providers should involve family members in breastfeeding education to create a supportive environment for breastfeeding mothers.

Synthesis of Aragonite from Precipitated Calcium Carbonate: A Pilot Scale Study

The CO2 mineralization pathway is considered a promising option for carbon capture usage and storage because the captured CO2 can be permanently stored, and secondly industrial waste (i.e., petrochemical refinery, lime, and cement kiln dust) can be recycled into value-added carbonate materials by controlling the crystal polymorphs and properties of mineral carbonate. This study investigated the CO2 mineralization utilized for the synthesis of precipitated calcium carbonate (PCC) via low temperatures at 30 °C and 55 °C with the addition of 50 and 75 g/L of ammonium chloride (NH4Cl). The pilot scale of PCC production was established to simultaneously produce PCC with low energy demand by reporting the feasibility of economic analysis and to develop the mineral carbonation that can transform limestones and CO2, which was captured from the petrochemical refinery process into economically valuable PCC. It is found that the aragonite phase of PCC can be generated at a room temperature of 30 °C by adjusting the CO2 flow rate. In addition, the use of NH4Cl, which transformed into ammonium carbonate ((NH4)2CO3) during the calcination process, can maintain the stable aragonite phase by varying the NH4Cl concentration.

Sustainable supercapacitors using advanced hydrated amino acid ionic liquids: A novel approach to biodegradable energy storage

In this work, we explore the concepts of molecular dynamics (MD) to investigate the energy storage capacity of supercapacitors (SCs) composed of amino acid-based ionic liquids (AAILs) as pure and hydrated electrolytes, and graphene electrodes. The choice to use AAILs is motivated by environmental concerns, as these compounds are biodegradable. We focused our efforts on models composed of 1-ethyl-3-methylimidazolium (emim) combined with alanine (ala), valine (val), leucine (leu), and isoleucine (ile). Furthermore, we aimed to optimize the biodegradable properties by considering different hydration levels of the electrolyte. We analyzed the models subjected to hydration in proportions of 10 %, 20 %, 30 %, 40 %, and 90 %. This research addresses the lack of detailed studies on the effect of hydration on AAIL electrolytes in supercapacitors, evaluating their impact on energy storage and electric double layer (EDL) formation, and highlights the potential of AAILs as electrolytes for supercapacitors, offering a biodegradable option for energy storage without a loss of efficiency. The results obtained showed capacitances between 2.29 and 2.71 µF/cm2, and gravimetric energy densities ranging from 4.4 to 4.8 J/g for electrolytes with high ion concentrations, and from 6.5 to 6.8 J/g for devices with low ion concentration electrolytes. These values indicate excellent potential for application in the context of energy storage, reinforcing the viability of AAILs as an environmentally friendly and efficient solution for supercapacitors.

Photo-rechargeable zinc ion capacitors using MoS2/NaTaO3/CF dual-acting electrodes prepared by photodeposition method.

This study presents an innovative approach to integrated energy systems by combining solar energy harvesting and electrochemical charge storage in a single modular platform. By strategically incorporating a MoS2/NaTaO3 heterostructure material, we have developed a photo-rechargeable zinc-ion capacitor (PR-ZIC) that utilises the synergistic benefits of this unique configuration. The photoactive MoS2/NaTaO3 cathode effectively absorbs light and charges the capacitor, enabling continuous light-driven operation. Experimental studies show that the MoS2/NaTaO3-based photo-rechargeable zinc-ion capacitor (PR-ZIC) exhibits a significant increase in capacitance when irradiated with light, with a 2.76-fold increase (93.94 mF cm-2) compared to dark conditions (33.95 mF cm-2) at a 10 mV s-1 scan rate. In addition, these capacitors show a photocharge voltage response of about 860 mV and excellent cyclability, retaining about 96% of their capacity over 4000 charge-discharge cycles. The results of this study highlight the potential of the MoS2/NaTaO3 heterostructure as a high-performance photoactive material for advanced photo-rechargeable zinc-ion energy storage devices. This integrated approach offers innovative off-grid energy solutions by optimizing device footprint, minimizing energy transfer losses and providing sustainable energy storage options.

External Field‐Assisted Metal–Air Batteries: Mechanisms, Progress, and Prospects

ABSTRACTMetal–air batteries are an appealing option for energy storage, boasting a high energy density and environmental sustainability. Researchers focus on the catalyst design to solve the problem of sluggish cathode reaction kinetic. However, in some cases, where thermodynamic regulation is required, the role of catalysts is limited. Based on catalysts changing reaction kinetics, external fields can change the thermodynamic parameters of the reaction, further reduce overpotential, and accelerate the reaction rate. By selecting appropriate external fields and adjusting controllable variables, greater flexibility and potential are provided for reaction control. This paper reviews the basic principles by which several external fields influence metal–air batteries. Additionally, some design strategies of photoelectrode materials, the similarities and differences of different magnetic field effects, and some research progress of the ultrasonic field, stress field, and microwave field are systematically summarized. Multifield coupling can also interact and produce additive effects. Furthermore, introducing external fields will also bring about the problem of aggravated side reactions. This paper proposes some research methods to explore the specific reaction mechanism of external field assistance in more depth. The primary objective is to furnish theoretical direction for enhancing the performance of external field‐supported metal–air batteries, thereby advancing their development.

The role of long-term hydrogen storage in decarbonizing remote communities in Canada: An optimization framework with economic, environmental and social objectives

Many small Canadian communities lack access to electricity grids, relying instead on costly and polluting diesel generators, despite the local availability of renewable energies like solar and wind. The intermittent nature of these sources limits reliable power supply; thus, hydrogen is proposed as a cost-effective and eco-friendly long-term energy storage solution. However, it remains uncertain whether hydrogen storage can significantly contribute to a 100% renewable energy system (100RES), given the diverse characteristics of these communities. Additionally, the potential for fully renewable infrastructure to reduce costs, mitigate adverse environmental impacts, and enhance social impact is still unclear. A multi-period optimization model that balances economic, environmental, and social objectives to determine the optimal configuration of 100RESs for isolated communities is introduced and utilized to evaluate hydrogen as an energy storage solution to seasonal fluctuations. By identifying the best combinations of technologies tailored to local conditions and priorities, this study offers valuable insights for policymakers, supporting the transition to sustainable energy and achieving national climate goals. The results demonstrate that hydrogen could serve as an excellent long-term energy storage option to address energy shortages during the winter. Different combinations and sizes of energy generation and storage technologies are selected based on the characteristics of each community. For instance, a community in the northern territories with high wind speeds, low solar radiation, extremely low temperatures, and limited biomass resources should optimally rely on wind turbines to meet 80.7% of its total energy demand, resulting in a 62.0% cost reduction and a 49.5% decrease in environmental impact compared to the existing diesel-based system. By 2050, all communities are projected to reduce energy costs per capita, with northern territories achieving 33% and coastal areas achieving 55% cost reductions, eventually leading to the utilization of hydrogen as the main energy storage medium.

Synergistic Regulation of Bidirectional Conversion of LiPSs and Li2S Using Anthraquinone as a Redox Mediator.

Lithium-sulfur (Li-S) batteries are strong contenders as energy storage options in the next-generation, primarily because of their potential for delivering high energy densities. Nonetheless, their widespread commercialization faces several obstacles, including sluggish sulfur redox kinetics, the insulating properties of the Li2S discharge product, and significant reaction energy barriers. In this work, anthraquinone (AQ) was introduced as a redox mediator and incorporated onto Co-doped carbon materials through π-π interactions. The results showed that synergistic effect between AQ and Co atoms facilitated the bidirectional conversion of lithium polysulfides (LiPSs) and Li2S. During charging, AQ lowered the reaction energy barrier for Li2S oxidation and thereby enhanced the reversibility of sulfur redox reactions. Density functional theory (DFT) calculations showed that AQ-Li2Sx exhibits a lower energy for the lowest unoccupied molecular orbital (LUMO) and a higher energy for the highest occupied molecular orbital (HOMO). Experimental results demonstrated that an impressive initial discharge specific capacity of 1290 mAh g-1 was achieved by the fabricated S@AQ/Co-N-C electrode at 0.1 C. After 600 cycles at 1 C, it retained 64% of this capacity and exhibited a minimal 0.06% capacity decay rate per cycle.

From Lithium-Ion to Sodium-Ion Batteries for Sustainable Energy Storage: A Comprehensive Review on Recent Research Advancements and Perspectives.

A significant turning point in the search for environmentally friendly energy storage options is the switch from lithium-ion to sodium-ion batteries. This review highlights the potential of sodium-ion battery (NIB) technology to address the environmental and financial issues related to lithium-ion systems by thoroughly examining recent developments in NIB technology. It is noted that sodium is more abundant and less expensive than lithium, NIBs have several benefits that could drastically lower the total cost of energy storage systems. In addition, this study examines new findings in important fields including electrolyte compositions, electrode materials, and battery performances of lithium-ion batteries (LIBs) and NIBs. The article highlights advancements in anode and cathode materials, with a focus on improving energy density, cycle stability, and rate capability of both LIBs and NIBs. The review also covers the advances made in comprehending the electrochemical mechanisms and special difficulties associated with NIBs, such as material degradation and sodium ion diffusion. Future research directions are discussed, with an emphasis on enhancing the scalability and commercial viability of sodium-ion technology over lithium on Electric Grid. Considering sustainability objectives and the integration of renewable energy sources, the review's assessment of sodium-ion batteries' possible effects on the future state of energy storage is included in its conclusion.

Comparative Analysis of Hydrogen Production and Economic Feasibility: Direct versus Indirect Coupling of Photovoltaic Systems with Electrolyzers

Hydrogen production using photovoltaics (PV) is essential for decarbonizing many sectors of the economy. The integration of PV and hydrogen electrolyzers is actively debated, with focus on direct versus indirect configurations and the option of storage. Direct configuration connects PV directly to the electrolyzer, offering simplicity and reduced installation costs but depends on the weather for efficient power transfer. Indirect configuration adds a power stage, increasing complexity and losses, but enabling maximum power tracking. Adding batteries allows storage of excess PV energy, extending hydrogen production. This study optimizes a PV generator to maximize annual hydrogen production in the direct configuration, then uses the same PV array for indirect configurations with and without batteries for a fair comparison. Results show that the indirect configuration with a battery yields 78% more hydrogen annually than without a battery and 109% more than the direct configuration. The indirect configuration with a battery uses 86.9% of PV energy for hydrogen production, yielding the highest profit at 2.53 € ⋅ W−1 (euros per watt‐peak of PV), compared to the direct and indirect configurations without a battery, which use 41.9% and 44.6% of PV energy and generate 1.49 and 1.83 € ⋅ W−1, respectively.

Estimating the Target-Consistent Carbon Price for Electricity

The target-consistent price of carbon for an electricity sector decarbonizing through massive variable renewable electricity (VRE) depends sensitively on the VRE penetration level, as the marginal curtailment of VRE rises rapidly beyond a certain level. This article develops a simple linear model to illustrate the relation between the shadow carbon price (SPC) and VRE penetration, illustrated for the island of Ireland’s 2026 target VRE penetration of 55%. The SPC rises rapidly with increased VRE investment beyond a certain point, and can be used to direct mitigating investment in storage, interconnectors, and other flexibility options. The SPC for the final efficient portfolio will be the target-consistent carbon price for electricity that is useful for comparing future decarbonization scenarios and their need for complementary investments. JEL Classification: H23, L94, Q28, Q42, Q48

Mapping the potential of managed aquifer recharge in Africa: GIS-based multi-criteria decision analysis approach

Africa faces numerous challenges related to rainfall variability, droughts, water scarcity, and climate change. Managed Aquifer Recharge (MAR)- groundwater recharge and underground water storage for later use or environmental support presents a viable alternative for water storage and may provide an effective tool for coping with such challenges. However, the potential area where MAR can be feasibly implemented has not been identified. This study mapped MAR feasibility using a Geographic Information System-based Multi-Criteria Decision Analysis (GIS-MCDA) and assessed MAR potential in Africa. The methodology focused on three key pillars of MAR feasibility: intrinsic suitability based on biophysical parameters, water source availability, and water demand. Maps responding to these pillars were developed and combined to create a composite MAR feasibility map. Results show that 18% of the continental area falls into the low feasibility class, 73% into the moderate feasibility class, and 7% into the high feasibility class. The feasibility map was validated against 17 existing MAR schemes in Africa, demonstrating a good correlation between their locations and areas with MAR potential. Results of sensitivity analysis of criteria weights of the biophysical parameters show that geology is the most influential criterion, followed by slope. In general, this first feasibility assessment shows good potential for MAR implementation in Africa. Therefore, MAR should be considered prominently among other water storage options for resilience building in Africa and policymakers should ensure adequate resource allocation for its implementation. The feasibility map can be used to guide MAR planning and investment decisions.

Advances in the Application of Graphene in Lithium-ion Batteries

The search for effective energy storage options has escalated due to the rising global energy demands and environmental concerns. Lithium-ion batteries (LIBs) emerge as a key technology. However, the performance of traditional LIBs still needs to be improved. Therefore, choosing new nanomaterials for the modification of LIBs has become an effective solution. Graphene, as a nanomaterial, is an excellent candidate material for modification. This paper delves into the application of graphene in enhancing the performance of LIBs. Graphene, with its superior electrical conductivity and substantial specific surface area, offers the potential to enhance the performance of both anode and cathode materials in LIBs. This can lead to significant improvements in the overall cycle life, energy density, and power density of these batteries. This work emphasizes the application of graphene in cathode and anode materials. In cathode materials, the layered structure of graphene enables lithium-ion with high theoretical capacity. Meanwhile, graphene helps improve the electron and lithium ion mobility of anode materials. Despite the promising developments, challenges such as lithium loading capacity and coulombic efficiency still remain. The continued exploration of graphene applications is expected to drive LIBs to unprecedented performance metrics. This is in line with the global quest for sustainable and efficient energy storage technologies.

Exploring the demand for inter-annual storage for balancing wind energy variability in 100% renewable energy systems

As research in 100% renewable energy systems progresses, closing remaining research gaps, such as quantifying inter-annual balancing requirements, is necessary. For this study, inter-annual variations of wind power yield and the resulting balancing requirements are analysed for the energy transition towards 100% renewable energy of the United Kingdom and the Republic of Ireland. The energy system components are determined and cost implications are quantified comparing two options for inter-annual storage: e-hydrogen and e-methane for a low, medium, and high security case, which are expanded over ten years. The results indicate that more than 300 TWhth,LHV and 500 TWhth,LHV of inter-annual gas storage capacity in 2050 for the low and the high security case, respectively are required. For both investigated cases, the annual system costs increase notably compared to the reference scenario without inter-annual storage. For the case of e-hydrogen, the annualised system costs increase by 19% compared to an increase of 7% for e-methane for medium security cases. The difference in cost growth is due to significantly higher hydrogen underground storage costs that overcompensate additional system costs for e-methane production. This study provides an expansion from seasonal to inter-annual storage and a first estimate of inter-annual balancing requirements and costs.

Comparison of energy consumption and probiotic stability with pilot scale drying processes

The production of dried probiotics offers multiple advantages including expanded storage options, ease of transportation, enhanced stability, formulation support, and incorporation into a variety of finished products. As probiotic use and application areas increase, the demand for lower production costs and increased product stability follows. The most common methods for drying include lyophilization and spray drying. Lyophilization offers high preservation of viability at the expense of production speed, while spray drying provides high throughput drying with greater loss of probiotic viability. Newer processes, such as electrostatic spray drying, have the potential to bridge the gap. The aim of this study was to evaluate the energy consumption and viability of Lacticaseibacillus rhamnosus GG (LGG) with pilot-scale conventional spray drying, electrostatic spray drying, and lyophilization. Energy consumption of the primary utilities was monitored along with LGG viability immediately and 8–12 weeks after drying. With regards to removal of water, conventional spray drying was the most energy efficient (1.2 kWh/L), followed by electrostatic spray drying (10.9 kWh/L) and lyophilization (16.9 kWh/L). When normalized against recovered viable LGG, electrostatic spray drying was the most efficient at 4.6 × 1010 CFU/kWh, followed by lyophilization and conventional spray drying at 1.1 × 1010 CFU/kWh and 4.8 × 107 CFU/kWh, respectively.

Progress and prospect of flexible MXene‐based energy storage

AbstractThe growing need for flexible and wearable electronics, such as smartwatches and foldable displays, highlights the shortcomings of traditional energy storage methods. In response, scientists are developing compact, flexible, and foldable energy devices to overcome these challenges. MXenes—a family of two‐dimensional nanomaterials—are a promising solution because of their unique properties, including a large surface area, excellent electrical conductivity, numerous functional groups, and distinctive layered structures. These attributes make MXenes attractive options for flexible energy storage. This paper reviews recent advances in using flexible MXene‐based materials for flexible Li−S batteries, metal‐ion batteries (Zn and Na), and supercapacitors. The development of MXene‐based composites is explored, with a detailed electrochemical performance analysis of various flexible devices. The review addresses significant challenges and outlines strategic objectives for advancing robust and flexible MXene‐based energy storage devices.

Comparing green hydrogen and green ammonia as energy carriers in utility-scale transport and subsurface storage

Many of the challenges associated with utility-scale hydrogen transport and storage relate to its low density, high diffusivity, and the risk of hydrogen embrittlement, motivating consideration to integrating ammonia as an energy carrier. Compared to hydrogen, ammonia is more compatible with pipeline materials and delivers energy at higher density. Ammonia is also a mature industry with a greater extent of established pipeline networks and regulations that may accelerate hydrogen transitions and penetration in energy grids. However, converting hydrogen produced by renewable-driven electrolysis into ammonia (and back to hydrogen, depending on end use) complicates logistics, and associated energy and resource demands may offset the green hydrogen's carbon neutrality. This work outlines core considerations for the use of hydrogen vs. ammonia during transport and storage operations, with an emphasis on green hydrogen or green ammonia pathways coupled to pipeline transport and underground storage. We compare tradeoffs in pipeline infrastructure and operations; subsurface storage options; and project economics. We also evaluate round-trip efficiencies (RTE) for both pathways, which indicate that hydrogen is more attractive from an energy efficiency perspective for hydrogen end-use applications due to the efficiency penalties of initial ammonia synthesis and subsequent cracking, but RTE's for ammonia transport and storage are comparable to hydrogen for direct use or ammonia-to-power systems. The tradeoffs presented in this work would need to be considered on a case-by-case basis, but indicate that selective use of ammonia as an energy-dense hydrogen carrier could support decarbonization goals in industry and hydrogen economies.