Reducing procurement risks to ensure the supply of emergency supplies is crucial for mitigating the losses caused by mine thermodynamic disasters. The risk preference of decision-makers and supply chain collaboration are the important aspects for this reductiom. In this study, a novel P-CVaR (Piecewise conditional risk value) distributionally robust optimization model is proposed to accurately assist the decision-makers’ decision of risk preference for reducing procurement risks. Meanwhile, the role of cooperation between procurement and reserves are considered for the weakening procurement risks. A risk-averse bi-level optimization model is proposed to obtain the optimal procurement strategy. Furthermore, by applying the Lagrange duality theorem, the complexity of the bi-level optimization model is simplified then solved using a PSO algorithm. Using empirical analysis, it has been verified that the model presented in this paper serves as a valuable guideline for mine thermodynamic pre-disaster emergency material procurement strategies for the prevention of thermodynamic disasters.